N.Y. Comp. Codes R. & Regs. tit. 12 § 800.5

Current through Register Vol. 46, No. 50, December 11, 2024
Section 800.5 - Permissible exposure limits

An employee 's exposure to any substance listed in Table Z-1-A, Z-2, or Z-3 of this section shall be limited in accordance with the requirements of the following paragraphs of this section.

(a)TABLE Z-1-A.
(1) Substances in transitional limits columns with limits preceded by " C"-ceiling values. An employee's exposure to any substance in Table Z-1-A under the transitional limits column, the exposure limit of which is preceded by a "C", shall at no time exceed the exposure limit given for that material in Table Z-1-A under the transitional limits columns.
(2) Other substances in transitional limits columns-8-hour time weighted average. An employee's exposure to any substance in table Z-1-A under the transitional limits columns, the exposure limit of which is not preceded by a "C", shall not exceed the 8-hour time weighted average given for that substance in table Z-1-A under the transitional limits columns in any 8-hour work shift of a 40-hour work week.
(3) Final rule limits columns. An employee's exposure to any substance listed in table Z-1-A shall not exceed the time weighted average (TWA), short term exposure limit (STEL), and ceiling limit specified for that substance in table Z-1-A under the final limits columns.
(4) Skin designation. To prevent or reduce skin absorption, an employee's skin exposure to substances listed in table Z-1-A with an "X" in one or both of the skin designation columns following the substance name shall be prevented or reduced to the extent necessary in the circumstances through the use of gloves, coveralls, goggles, or other appropriate personal protective equipment, engineering controls or work practices.
(5) Definitions. The following definitions are applicable to the final rule limits columns of table Z-1-A:
(i)Time weighted average (TWA) is the employee's average airborne exposure in any 8-hour work shift of a 40-hour work week which shall not be exceeded.
(ii)Short term exposure limit (STEL) is the employee's 15-minute time weighted average exposure which shall not be exceeded at any time during a work day unless another time limit is specified in a parenthetical notation below the limit. If another time period is specified, the time weighted average exposure over that time period shall not be exceeded at any time during the working day.
(iii)Ceiling is the employee's exposure which shall not be exceeded during any part of the work day. If instantaneous monitoring is not feasible, then the ceiling shall be assessed as a 15-minute time weighted average exposure which shall not be exceeded at any time over a working day.
(6) Additional definition. The terms substance, air contaminant, and material are equivalent in meaning for 29 CFR 1910.1000. ( 29 CFR 1910 was previously filed with the Secretary of State on February 2, 1988, under File Number 240. It is available for inspection at the NYS Department of State and the NYS Department of Labor, and can be obtained from the U.S. Government Printing Office in Federal Register, Volume 52, No. 176, pp. 34460-34578, September 11, 1987).
(b)Table Z-2. Table Z-2 is applicable for the transitional period and to the extent set forth in subdivision (f) of this section.
(1) Eight-hour time weighted averages. An employee's exposure to any material listed in table Z-2, in any 8-hour work shift of a 40-hour work week, shall not exceed the 8-hour time weighted average limit given for that material in table Z-2.
(2) Acceptable ceiling concentrations. An employee's exposure to a material listed in table Z-2 shall not exceed at any time during an 8-hour shift the acceptable ceiling concentration limit given for the material in the table, except for a time period, and up to a concentration not exceeding the maximum duration and concentration allowed in the column under "acceptable maximum peak above the acceptable ceiling concentration for an 8-hour shift".
(3) Example. During an 8-hour work shift, an employee may be exposed to a concentration of Substance A (with a 10 ppm TWA, 25 ppm ceiling and 50 ppm peak) above 25 ppm (but never above 50 ppm) only for a maximum period of 10 minutes. Such exposure must be compensated by exposures to concentrations less than 10 ppm so that the cumulative exposure for the entire 8-hour work shift does not exceed a weighted average of 10 ppm.
(c)Table Z-3.

Table Z-3 is applicable for the transitional period and to the extent set forth in subdivision (f) of this section. An employee's exposure to any substance listed in table Z-3, in any 8-hour work shift of a 40-hour work week shall not exceed the 8-hour time weighted average limit given for that substance in the table.

(d)Computation formulae.

The computation formula which shall apply to employee exposure to more than one substance for which 8-hour time weighted averages are listed in subpart Z of 29 CFR part 1910 in order to determine whether an employee is exposed over the regulatory limit is as follows:

(1)
(i) The cumulative exposure for an 8-hour work shift shall be computed as follows:

(E = C(a) T(a) + C(b) T(b) + . . . . C(n) T(n)) divided by 8

Where:

E is the equivalent exposure for the working shift.

C is the concentration during any period of time T where the concentration remains constant.

T is the duration in hours of the exposure at the concentration C.

The value of E shall not exceed the 8-hour time weighted average specified in Subpart Z or 29 CFR part 1910 for the material involved.

(ii) To illustrate the formula prescribed in subparagraph (i) of this paragraph, assume that Substance A has an 8-hour time weighted average limit of 100 ppm noted in table Z-1-A. Assume than an employee is subject to the following exposure: Substituting this information in the formula, we have

Two hours exposure at 150 p/m

Two hours exposure at 75 p/m

Four hours exposure at 50 p/m

(2 * 150 + 2 * 75 + 4 * 50) divided by 8 = 81.25 p/m

Since 81.25 p.p.m. is less than 100 p.p.m., the 8-hour time weighted average limit, the exposure is acceptable.

(2)
(i) In case of a mixture of air contaminants an employer shall compute the equivalent exposure as follows:

E(m) = (C(1) divided by L(1) + C(2) divided by L(2)) + . . . (C)(n) divided by L(n))

Where:

E(m) is the equivalent exposure for the mixture.

C is the concentration of a particular contaminant.

L is the exposure limit for that substance specified in Subpart Z of 29 CFR part 1910.

The value of E(m) shall not exceed unity (1).

(ii) To illustrate the formula prescribed in subparagraph (d)(2)(i) of this section, consider the following exposures:

SubstanceActual concentration of 8-hour exposure (ppm)8 hr.TWA PEL (ppm)
B ....... 5001,000
C ....... 45200
D ....... 40200

Substituting in the formula, we have: E(m) = 500 divided by 1,000 + 45 divided by 200 + 40 divided by 200 E(m) = 0.500 + 0.225 + 0.200 E(m) = 0.925

Since E(m) is less than unity (1), the exposure combination is within acceptable limits.

(e) To achieve compliance with subdivisions (a) through (d) of this section, administrative or engineering controls must first be determined and implemented whenever feasible. When such controls are not feasible to achieve full compliance, protective equipment or any other protective measures shall be used to keep the exposure of employees to air contaminants within the limits prescribed in this section. Any equipment and/or technical measures used for this purpose must be approved for each particular use by a competent industrial hygienist or other technically qualified person. Whenever respirators are used, their use shall comply with 1910.134.
(f)Effective dates, start-up dates and transitional provisions.
(1) Effective date. The effective date for the permissible exposure limits specified in the final rule limits columns of table Z-1-A is March 1, 1989.
(2)
(i) The permissible exposure limits specified in the final rule columns of table Z-1-A shall be achieved by any reasonable combination of engineering controls, work practices and personal protective equipment effective September 1, 1989, through December 30, 1992. (See note at end of table Z-1-A).
(ii)
(a) The permissible exposure limits specified in the final rule limits columns of table Z-1-A shall be achieved by the method of compliance specified in subdivision (e) of this section effective December 31, 1992, if by December 31, 1991, a final rule has been published in the Federal Register amending or determining not to amend subdivision (e) of this section.
(b) If no final rule has been published in the Federal Register by December 31, 1991, amending or determining not to amend subdivision (e) of this section, then the permissible limits specified in the final rule limits columns of table Z-1-A shall be achieved by the methods of compliance specified by subdivision (e) of this section effective December 31, 1993, and subparagraph (f)(2)(i) of this section shall remain in effect through December 30, 1993.
(iii) The skin designations in the final rule limits columns become effective September 1, 1989. The skin designations in the transitional limits columns are in effect from March 1, 1989, through August 31, 1989.
(3) Transitional provisions.
(i) The permissible exposure limits specified in the transitional limits columns of table Z-1-A, table Z-2 and table Z-3 shall continue to be achieved by the methods of compliance specified in subdivision (e) of this section through December 30, 1992. If clause (2)(ii)(b) of this subdivision takes effect, this provision is extended through December 30, 1993. The permissible exposure limits specified in tables Z-2 and Z-3 for substances mentioned in the final rule limits column of table Z-1-A only by cross reference to table Z-2 or Z-3 shall remain in effect indefinitely and continue to be achieved by the methods of compliance specified in subdivision (e) of this section.
(ii) The permissible exposure limits specified in the transitional limits columns of table Z-1-A, Z-2 and Z-3 shall be applicable to the extent cross referenced in 29 CFR parts 1915, 1917 and 1918.
(iii) If any new or amended provisions or new or revised limits for any substance or substances are either administratively stayed or judicially stayed or vacated, then the existing provisions or limits for those substances specified in the transitional limits columns of table Z-1-A, table Z-2 or table Z-3 shall remain in effect until such stay is lifted, or indefinitely, if the limit is vacated.
(4) Enforcement of the limits are indefinitely stayed for: aluminum alkyls; ethylidene norbornene; hexafluoracetone; mercury (alkyl compounds); oxygen difluoride; phenylphosphine; and sulfur pentafluoride; until OSHA publishes in the Federal Register a notice that a sampling and analytical technique is available.

TABLE Z-1-A. LIMITS FOR AIR CONTAMINANTS

NOTE: Footnotes specfic only to a limited number of substances are also shown within the table.

* The transitional PELs are 8-hour TWAs unless otherwise noted; a (C) designation denotes a celing limit.

** Unless otherwise noted, employers in General Industry (i.e., those covered by 29 CFR 1910) may use any combination of controls to achieve these limits until December 31, 1993 as set forth in 29 CFR 1910.1000(f).

*** As determined from breathing-zone air samples;

a Parts of vapor or gas per million parts of contaminated air by volume at 25 degrees C and 760 torr.

b Milligrams of substance per cubic meter of air. When a numerical entry for a substance is in the mg/m(3) column and not in the ppm column, then the number in the mg/m(3) is exact. When numerical entries for a substance are in both the ppm and mg/m(3) columns, then the number in the ppm column is exact and the number in the mg/m(3) column may be rounded off.

c Duration is for 15 minutes, unless otherwise noted.

d The final benzene standard in 1910.1028 applies to all occupational exposures to benzene except some subsegments of industry where exposures are consistently under the action level (i.e., distribution and sale of fuels, sealed containers and pipelines, coke production, oil and gas drilling and production, natural gas processing, and the percentage exclusion for liquid mixtures); for the excepted subsegment, the benzene limits in table Z-2 apply.

e Exposures under 10,000 ppm ato be cited de minimus.

f The CAS number is for information only. Enforcement is based on the substance name. For an entry covering more than one metal compound measured as the metal, the CAS number for the metal is given-not CAS numbers for the individual compounds.

g Compliance with the subtilisins PEL is assessed by sampling with a high volume sampler (600-800 liters per minute) for at least 60 minutes.

h The Acetone STEL does not apply to the cellulose acetate fiber industry. It is in effect for all other sectors.

i The final rule limit STEL of 5 mg/m(3) is not in effect as a result of reconsideration. Calcium hydroxide is covered by the exposure limits for particulates not otherwise regulated of 5 mg/m(3) respirable dust and 5 mg/m(3) total dust.

j The final rule limit TWA of 5 mg/m(3) is not in effect as a result of reconsideration. The calcium oxide transitional limit of 5 mg/m(3) remains in effect and employee exposures shall be kept below that level pursuant to the methods of compliance specified in CFR 1910.1000(e).

k The final rule limit STEL of 0.1 mg/m(3) is not in effect as a result of reconsideration for the industrial sector of civilian manufacture and distribution of explosives and propellants for civilian use. The final rule limits skin designation and the transitional limits ceiling limit of 1 mg/m(3) remain in effect for this sector until completion to the reconsideration.

l The final rule limit STEL of 0.1 mg/m(3) is not in effect as a result of reconsideration for the industrial sector of civilian manufacture and distribution of explosives and propellants for civilian use. The final rule limits skin designation and the transitional limits ceiling limit of 2 mg/m(3) remain in effect for this sector until completion of the reconsideration.

m Sampling for the carbon monoxide ceiling shall be averaged over 5 minutes but an instantaneous reading over 1500 ppm shall not be exceeded.

Acetaldehyde

CAS NO (f): 75-07-0

Transitional Limits:

PEL*

200 ppm(a)

360 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

100 ppm (a)

180 mg/m(3)(b)

STEL(c)

150 ppm (a)

270 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Acetetic acid

CAS NO(f): 64-19-7

Transitional Limits:

PEL*

10 ppm (a)

25 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

10 ppm (a)

25 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Acetic anhydride

CAS NO(f): 108-24-7

Transitional Limits:

PEL*

5 ppm(a)

20 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

5 ppm(a)

20 mg/m(3)(b)

Skin Designation

-

Acetone (h)

CAS NO(f):67-64-1

Transitional Limits:

PEL*

1000 ppm(a)

2400 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

750 ppm (a)

1800 mg/m(3)(b)

STEL(c)

1000 ppm (a) (h)

2400 mg/m(3)(b) (h)

CEILING

-

-

Skin Designation

-

Footnote (h) The Acetone STEL does not apply to the cellulose acetate fiber industry. It is in effect for all other sectors.

Acetonitrile*

CAS NO(f):75-05-8

Transitional Limits:

PEL*

40 ppm(a)

70 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

40 ppm(a)

70 mg/m(3)(b)

STEL(c)

60 ppm (a)

105 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

2-Acetylaminofluorine;

CAS NO(f): 53-96-3

see 1910.1014

Acetylene dichloride;

see 1, 1-Dichloroethylene

Acetylene tetrabromide

CAS NO(f):79-27-6

Transitional Limits:

PEL*

1 ppm (a)

14 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

1 ppm(a)

14 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Acetylsalicylic acid (Aspirin)

CAS NO(f):50-78-2

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Acrolein

CAS NO(f):107-02-8

Transitional Limits:

PEL*

0.1 ppm(a)

0.25 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

0.1 ppm(a)

0.25 mg/m(3)(b)

STEL(c)

0.3 ppm(a)

0.8 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Acrylamide

CAS NO(f):79-06-1

Transitional Limits:

PEL*

-

0.3 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

0.03 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Acrylic acid

CAS NO(f):79-10-7

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

10 ppm(a)

30 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Acrylonitrile;

CAS NO(f): 107-13-1

see 1910.1045

Aldrin

CAS NO(f):309-00-2

Transitional Limits:

PEL*

-

0.25 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

0.25 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Allyl alcohol

CAS NO(f):107-18-6

Transitional Limits:

PEL*

2 ppm(a)

5 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

2 ppm(a)

5 mg/m(3)(b)

STEL(c)

4 ppm(a)

10 mg/m(3)(b)

CEILING

-

-

Skin Designation

X

Allyl chloride

CAS NO(f):107-05-1

Transitional Limits:

PEL*

1 ppm(a)

3 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

1 ppm(a)

3 mg/m(3)(b)

STEL(c)

2 ppm(a)

6 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Allyl glycidyl ether (AGE)

CAS NO(f):106-92-3

Transitional Limits:

PEL*

(C) 10 ppm(a)

(C) 45 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

5 ppm(a)

22 mg/m(3)(b)

STEL(c)

10 ppm(a)

44 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Footnote (C) denotes a ceiling limit.

Allyl propyl disulfide

CAS NO(f):2179-59-1

Transitional Limits:

PEL*

2 ppm(a)

12 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

2 ppm(a)

12 mg/m(3)(b)

STEL(c)

3 ppm(a)

18 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

alpha-Alumina

CAS NO(f):1344-28-1

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Aluminum (as Al) Metal

CAS NO (f): 7429-90-5

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

15 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Pyro Powders

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Welding Fumes***

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Footnote*** As determined from breathing-zone air samples.

Soluble Salts

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

2 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Alkyls

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

2 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

4-Aminodiphenyl;

CAS NO(f):92-67-1

see 1910.1011

2-Aminoethanol;

see Ethanolamine

2-Aminopyridine

CAS NO(f):504-29-0

Transitional Limits:

PEL*

0.5 ppm(a)

2 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

0.5 ppm(a)

2 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Amitrole

CAS NO(f):61-82-5

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

0.2 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Ammonia

CAS NO(f):7664-41-7

Transitional Limits:

PEL*

50 ppm(a)

35 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

35 ppm(a)

27 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Ammonium chloride fume

CAS NO(f):12125-02-9

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

10 mg/m(3)(b)

STEL(c)

20 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Ammonium sulfamate

CAS NO(f):7773-06-0

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

20 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

n-Amyl acetate

CAS NO(f): 628-63-7

Transitional Limits:

PEL*

100 ppm(a)

525 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

100 ppm(a)

525 mg/m(3)(b)

STEL(c)

20 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

sec-Amyl acetate

CAS NO(f): 626-38-0

Transitional Limits:

PEL*

125 ppm(a)

650 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

125 ppm(a)

650 mg/m(3)(b)

STEL(c)

20 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Aniline and homologs

CAS NO(f): 62-53-3

Transitional Limits:

PEL*

5 ppm(a)

19 mg/m(3)(b)

Skin Designation

2X

Final Rule Limits**:

TWA

ppm(a)

8 mg/m(3)(b)

STEL(c)

20 mg/m(3)(b)

CEILING

-

-

Skin Designation

X

Anisidine (o-,p-isomers)

CAS NO(f):29191-52-4

Transitional Limits:

PEL*

0.5 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

0.5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Antimony and compounds (as Sb)

CAS NO(f):7440-36-0

Transitional Limits:

PEL*

-

0.5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

0.5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

ANTU (alpha Naphthylthiourea)

CAS NO(f):86-88-4

Transitional Limits:

PEL*

-

0.3 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

0.3 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Arsenic, organic compounds (as As)

CAS NO(f):7440-38-2

Transitional Limits:

PEL*

-

0.5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

0.5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Arsenic, inorganic compounds (as As);

see 1910.1018

Arsine

CAS NO(f):7784-42-1

Transitional Limits:

PEL*

0.05 ppm(a)

0.2 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

0.05 ppm(a)

0.2 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Asbestos

CAS NO (f): Varies

see 1910.1001 and 1910.1101

Atrazine

CAS NO(f):1912-24-9

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Azinphos-metyl

CAS NO(f):86-50-0

Transitional Limits:

PEL*

-

0.2 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

0.2 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Barium, soluble compounds (as Ba)

CAS NO(f):7440-39-3

Transitional Limits:

PEL*

-

0.5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

0.5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Barium sulfate

CAS NO(f):7727-43-7

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Benomyl

CAS NO(f):17804-35-2

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Benzene

CAS NO(f):71-43-2

see 1910.1028

See Table Z-2 for the limits applicable in the operations or sectors excluded in 1910.1028(d) Footnote (d) The final benzene standard in 1910.1028 applies to all occupational exposures to benzene except some subsegments of industry where exposures are consistently under the action level (i.e., distribution and sale of fuels, sealed containers and pipelines, coke production, oil and gas drilling and production, natural gas processing, and the percentage exclusion for liquid mixtures); for the excepted subsegments, the benzene limits in Table Z-2 apply.

Benzidine

CAS NO(f):92-87-5

see 1910.1010

p-Benzoquinone;

see Quinone

Benzo (a) pyrene;

see Coal tar pitch volatiles

Benzoyl peroxide

CAS NO(f):94-36-0

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Benzyl chloride

CAS NO(f):100-44-7

Transitional Limits:

PEL*

1 ppm(a)

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

1 ppm(a)

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Beryllium and beryllium compounds

(as Be)

CAS NO(f):7440-41-7

Transitional Limits:

PEL*

Tbl. Z-2

-

Skin Designation

-

Final Rule Limits**:

TWA

Tbl. Z-2

Tbl. Z-2

STEL(c)

Tbl. Z-2

CEILING

-

-

Skin Designation

-

Biphenyl;

see Diphenyl

Bismuth telluride, Undoped

CAS NO(f):1304-82-1

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Bismuth telluride, Se-doped

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Borates, tetra, sodium salts

Anhydrous

CAS NO (f): 1330-43-4

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Decahydrate

CAS NO(f):1303-96-4

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

10 mg/m (3) (b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Pentahydrate

CAS NO(f):12179-04-3

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Boron oxide

CAS NO(f):1303-86-2

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Boron tribromide

CAS NO(f):10294-33-4

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

1 ppm(a)

10 mg/m(3)(b)

Skin Designation

-

Boron trifluoride

CAS NO(f):7637-07-2

Transitional Limits:

PEL*

(C) 1 ppm(a)

(C) 3 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

1 ppm(a)

3 mg/m(3)(b)

Skin Designation

-

Footnote (C) denotes a ceiling limit.

Bromacil

CAS NO(f):314-40-9

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

1 ppm(a)

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Bromine

CAS NO(f):7726-95-6

Transitional Limits:

PEL*

0.1 ppm(a)

0.7 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

0.1 ppm(a)

0.7 mg/m(3)(b)

STEL(c)

0.3 ppm(a)

2 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Bromine pentafluoride

CAS NO(f):7789-30-2

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

0.1 ppm(a)

0.7 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Bromoform

CAS NO(f):75-25-2

Transitional Limits:

PEL*

0.5 ppm(a)

5 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

0.5 ppm(a)

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Butadiene (1,3-Butadiene)

CAS NO(f):106-99-0

Transitional Limits:

PEL*

1000 ppm(a)

2200 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

1000 ppm(a)

2200 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Butane

CAS NO(f):106-97-8

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

800 ppm(a)

1900 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Butanethiol;

see Butyl mercaptan

2-Butanone (Methyl ethyl ketone)

CAS NO(f):78-93-3

Transitional Limits:

PEL*

200 ppm(a)

590 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

200 ppm(a)

590 mg/m(3)(b)

STEL(c)

300 ppm(a)

885 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

2-Butoxyethanol

CAS NO(f):111-76-2

Transitional Limits:

PEL*

50 ppm(a)

240 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

25 ppm(a)

120 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

n-Butyl-acetate

CAS NO(f):123-86-4

Transitional Limits:

PEL*

150 ppm(a)

710 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

150 ppm(a)

710 mg/m(3)(b)

STEL(c)

200 ppm(a)

950 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

sec-Butyl acetate

CAS NO(f):105-46-4

Transitional Limits:

PEL*

200 ppm(a)

950 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

200 ppm(a)

950 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

tert-Butyl-acetate

CAS NO(f):540-88-5

Transitional Limits:

PEL*

200 ppm(a)

950 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

200 ppm (a)

950 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Butyl acrylate

CAS NO(f):141-32-2

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

10 ppm(a)

55 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

n-Butyl alcohol

CAS NO(f):71-36-3

Transitional Limits:

PEL*

100 ppm(a)

300 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

50 ppm(a)

150 mg/m(3)(b)

Skin Designation

X

sec-Butyl alcohol

CAS NO(f):78-92-2

Transitional Limits:

PEL*

150 ppm(a)

450 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

100 ppm(a)

305 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

tert-Butyl alcohol

CAS NO(f):75-65-0

Transitional Limits:

PEL*

100 ppm(a)

300 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

100 ppm(a)

300 mg/m(3)(b)

STEL(c)

150 ppm(a)

450 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Butylamine

CAS NO (f): 109-73-9

Transitional Limits:

PEL*

(C) 5 ppm(a)

(C) 15 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

5 ppm(a)

15 mg/m(3)(b)

Skin Designation

X

Footnote (C) denotes a ceiling limit.

tert-Butyl chromate (as CrO (3))

CAS NO(f):1189-85-1

Transitional Limits:

PEL*

-

(C) 0.1 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

0.1 mg/m(3)(b)

Skin Designation

X

Footnote (C) denotes a ceiling limit.

n-Butyl glycidyl ether (BGE)

CAS NO(f):2426-08-6

Transitional Limits:

PEL*

50 ppm(a)

270 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

25 ppm(a)

135 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

n-Butyl lactate

CAS NO(f):138-22-7

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

5 ppm(a)

25 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Butyl mercaptan

CAS NO(f):109-79-5

Transitional Limits:

PEL*

10 ppm(a)

35 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

0.5 ppm(a)

1.5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

o-sec-Butylphenol

CAS NO(f):89-72-5

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

5 ppm(a)

30 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

p-tert-Butyltoluene

CAS NO(f):98-51-1

Transitional Limits:

PEL*

10 ppm(a)

60 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

10 ppm(a)

60 mg/m(3)(b)

STEL(c)

20 ppm(a)

120 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

* Cadmium fume (as Cd)

CAS NO(f): 7440-43-9

(This entire line has been replaced per 57 FR 42388, Sept. 14, 1992 by the following):
Cadmium; see 1910.1027. See Table Z-2 for the exposure limits for any operations or sectors where the exposure limits in 1910.1027 are stayed or otherwise not in effect.

Cadmium dust (as Cd)

CAS NO(f): 7440-43-9

(This entire line has been replaced per 57 FR 42388, Sept. 14, 1992 by the following):
Cadmium; see 1910.1027. See Table Z-2 for the exposure limits for any operations or sectors where the exposure limits in 1910.1027 are stayed or otherwise not in effect.

Calcium Carbonate

CAS NO(f):1317-65-3

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

15 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Calcium cyanamide

CAS NO(f):156-62-7

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

0.5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Calcium hydroxide (i)

CAS NO(f):1305-62-0

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)(i)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Footnote (i) The Final Rule Limit of 5 mg/m(3) is not in effect as a result of reconsideration.
Calcium hydroxide is covered by the exposure limits for particulates not otherwise regulated of 5 mg/m(3) respirable dust and 5 mg/m(3) total dust.

Calcium oxide (j)

CAS NO(f):1305-78-8

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)(j)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Footnote (j) The Final Rule Limit TWA of 5 mg/m(3) is not in effect as a result of reconsideration.
The calcium oxide Transitional Limit of 5 mg/m(3) remains in effect and employee exposures shall be kept below that level pursuant to the methods of compliance specified in 29 CFR 1910.1000(e).

Calcium Silicate

CAS NO(f):1344-95-2

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

15 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Calcium sulfate

CAS NO(f):7778-18-9

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

15 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Camphor, synthetic

CAS NO(f):76-22-2

Transitional Limits:

PEL*

-

2 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

2 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Caprolactam

CAS NO(f):105-60-2

Dust

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

1 mg/m(3)(b)

STEL(c)

3 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Vapor

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

5 ppm(a)

20 mg/m(3)(b)

STEL(c)

10 ppm(a)

40 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Captafol (Difolatan (R))

CAS NO(f): 2425-06-1

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

0.1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Captan

CAS NO(f): 133-06-2

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Carbaryl (Sevin (R))

CAS NO(f): 63-25-2

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Carbofuran (Furadan (R))

CAS NO(f): 1563-66-2

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

0.1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Carbon black

CAS NO(f): 1333-86-4

Transitional Limits:

PEL*

-

3.5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

3.5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Carbon dioxide

CAS NO(f): 124-38-9

Transitional Limits:

PEL*

5000(e) ppm(a)

9,000 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

10,000 ppm(a)

18,000 mg/m(3)(b)

STEL(c)

30,000 ppm(a)

54,000 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Footnote (e) Exposures under 10,000 ppm to be cited de minimus.

Carbon disulfide

CAS NO(f): 75-15-0

Transitional Limits:

PEL*

Tbl. Z-2

Final Rule Limits**:

TWA

4 ppm(a)

12 mg/m(3)(b)

STEL(c)

12 ppm(a)

36 mg/m(3)(b)

CEILING

-

-

Skin Designation

X

Carbon monoxide

CAS NO(f): 630-08-0

Transitional Limits:

PEL*

50 ppm(a)

55 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

35 ppm(a)

40 mg/m(3)(b)

STEL(c)

-

-

CEILING

200 ppm(a)(m)

229 mg/m(3)(b)(m)

Skin Designation

-

Note: Stayed CEILING for blast furnace operations, vessel blowing at basic oxygen furnaces and sinter plants in the steel industry (SIC 33), termination pending (FR 55: 3724, 2/5/90)
Footnote (m) Sampling for the carbon monoxide ceiling shall be averaged over 5 minutes but an instantaneous reading over 1500 ppm shall not be exceeded.

Carbon tetrabromide

CAS NO(f): 558-13-4

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

0.1 ppm(a)

1.4 mg/m(3)(b)

STEL(c)

0.3 ppm(a)

4 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Carbon tetrachloride

CAS NO(f): 56-23-5

Transitional Limits:

PEL*

Tbl. Z-2

Skin Designation

-

Final Rule Limits**:

TWA

2 ppm(a)

12.6 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Carbonyl fluoride

CAS NO(f): 353-50-4

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

2 ppm(a)

5 mg/m(3)(b)

STEL(c)

5 ppm(a)

15 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Catechol (Pyrocatechol)

CAS NO(f): 120-80-9

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

5 ppm(a)

20 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Cellulose

CAS NO(f): 9004-34-6

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

15 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Cesium hydroxide

CAS NO(f): 21351-79-1

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

2 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Chlordane

CAS NO(f): 57-74-9

Transitional Limits:

PEL*

-

0.5 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Chlorinated camphene

CAS NO(f): 8001-35-2

Transitional Limits:

PEL*

-

0.5 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

0.5 mg/m(3)(b)

STEL(c)

1 mg/m(3)(b)

CEILING

-

-

Skin Designation

X

Chlorinated diphenyl oxide

CAS NO(f): 55720-99-5

Transitional Limits:

PEL*

-

0.5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

0.5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Chlorine

CAS NO(f): 7782-50-5

Transitional Limits:

PEL*

(C) 1 ppm(a)

(C) 3 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

0.5 ppm(a)

1.5 mg/m(3)(b)

STEL(c)

1 ppm(a)

3 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Footnote (C) denotes a ceiling limit.

Chlorine dioxide

CAS NO(f): 10049-04-4

Transitional Limits:

PEL*

0.1 ppm(a)

0.3 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

0.1 ppm(a)

0.3 mg/m(3)(b)

STEL(c)

0.3 ppm(a)

0.9 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Chlorine trifluoride

CAS NO(f): 7790-91-2

Transitional Limits:

PEL*

(C) 0.1 ppm(a)

(C) 0.4 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

0.1 ppm(a)

0.4 mg/m(3)(b)

Skin Designation

-

Footnote (C) denotes a ceiling limit.

Chloroacetaldehyde

CAS NO(f): 107-20-0

Transitional Limits:

PEL*

(C) 1 ppm(a)

(C) 3 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

1 ppm(a)

3 mg/m(3)(b)

Skin Designation

-

Footnote (C) denotes a ceiling limit.

a-Chloroacetophenone (Phenacyl chloride)

CAS NO(f): 532-27-4

Transitional Limits:

PEL*

0.05 ppm(a)

0.3 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

0.05 ppm(a)

0.3 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Chloroacetyl chloride

CAS NO(f): 79-04-9

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

0.05 ppm(a)

0.2 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Chlorobenzene

CAS NO(f): 108-90-7

Transitional Limits:

PEL*

75 ppm(a)

350 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

75 ppm(a)

350 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

o-Chlorobenzylidene malononitrile

CAS NO(f): 2698-41-1

Transitional Limits:

PEL*

0.05 ppm(a)

0.4 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

0.05 ppm(a)

0.4 mg/m(3)(b)

Skin Designation

X

Chlorobromomethane

CAS NO(f): 74-97-5

Transitional Limits:

PEL*

200 ppm(a)

1050 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

200 ppm(a)

1050 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

2-Chloro-1,3-butadiene;

see b-Chloroprene

Chlorodifluoromethane

CAS NO(f): 75-45-6

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

1000 ppm(a)

3500 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Chlorodiphenyl (42% Chlorine) (PCB)

CAS NO(f): 53469-21-9

Transitional Limits:

PEL*

-

1 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Chlorodiphenyl (54% Chlorine) (PCB)

CAS NO(f): 11097-69-1

Transitional Limits:

PEL*

-

0.5 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

0.5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

1-Chloro, 2,3-epoxypropane;

see Epichlorohydrin

2-Chloroethanol;

see Ethylene chlorohydrin

Chloroethylene;

see Vinyl chloride

Chloroform (Trichloromethane)

CAS NO(f): 67-66-3

Transitional Limits:

PEL*

(C) 50 ppm(a)

(C) 240 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

2 ppm(a)

9.78 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Footnote (C) denotes a ceiling limit.

bis (Chloromethyl) ether

CAS NO(f): 542-88-1

see 1910.1008

Chloromethyl methyl ether

CAS NO(f): 107-30-2

see 1910.1006

1-Chloro-1-nitropropane

CAS NO(f): 600-25-9

Transitional Limits:

PEL*

20 ppm(a)

100 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

2 ppm(a)

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Chloropentafluoroethane

CAS NO(f): 76-15-3

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

1000 ppm(a)

6320 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Chloropicrin

CAS NO(f): 76-06-2

Transitional Limits:

PEL*

0.1 ppm(a)

0.7 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

0.1 ppm(a)

0.7 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

beta-Chloroprene

CAS NO(f): 126-99-8

Transitional Limits:

PEL*

25 ppm(a)

90 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

10 ppm(a)

35 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

o-Chlorostyrene

CAS NO(f): 2039-87-4

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

50 ppm(a)

285 mg/m(3)(b)

STEL(c)

75 ppm(a)

428 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

o-Chlorotoluene

CAS NO(f): 95-49-8

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

50 ppm(a)

250 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

2-Chloro-6-trichloro-methyl pyridine

CAS NO(f): 1929-82-4

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

15 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Chlorpyrifos

CAS NO(f): 2921-88-2

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

0.2 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Chromic acid and chromates (as CrO (3))

CAS NO(f): 7440-47-3

Transitional Limits:

PEL*

-

Tbl. Z-2

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

0.1 ppm(a)

Skin Designation

-

* Chromium (II) compounds (as Cr)

CAS NO(f): 7440-47-3

(This entry removed by 57 FR 29205, July 1, 1992)

Chromium, Sol. chromic, chromous salts (as Cr)

CAS NO(f): 7440-47-3

Transitional Limits:

PEL*

-

0.5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

0.5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Chromium, metal and soluble salts

CAS NO(f): 7440-47-3

Transitional Limits:

PEL*

-

1 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Chrysene:

see Coal tar pitch volatiles

Clopidol

CAS NO(f): 2971-90-6

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

15 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Coal dust (Less than 5% SiO (2))

Respirable fraction

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

9 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Coal dust (Greater than or equal to 5% SiO (2))

Respirable quartz fraction

Transitional Limits:

PEL*

-

Tbl. Z-3

Skin Designation

-

Final Rule Limits**:

TWA

-

0.1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Coal tar pitch volatiles

CAS NO(f): 65996-93-2

(Benzine soluble fraction), Anthracene, BaP, Phenanthrene, Acridine, Chrysene, Pyrene

Transitional Limits:

PEL*

-

0.2 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

0.2 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Cobalt metal, dust, and fume (as Co)

CAS NO(f): 7440-48-4

Transitional Limits:

PEL*

-

0.1 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

0.05 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Cobalt carbonyl (as Co)

CAS NO(f): 10210-68-1

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

0.1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Cobalt hydrocarbonyl (as Co)

CAS NO(f): 16842-03-8

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

0.1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Coke oven emissions;

see 1910.1029

Copper

CAS NO(f): 7440-50-8

Fume (as Cu)

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

0.1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Dusts and mists (as Cu)

Transitional Limits:

PEL*

-

1 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Cotton dust (Raw)

Transitional Limits:

PEL*

1 mg/m(3)(b)

TWA

-

1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

This 8-hour TWA applies to respirable dust as measured by a vertical elutriator cotton dust sampler or equivalent instrument. The time-weighted average applies to the cotton waste processing operations of waste recycling (sorting, blending, cleaning, and willowing) and garnetting. See also 1910.1043 for cotton dust limits applicable to other sectors.

Crag herbicide (Sesone)

CAS NO(f): 136-78-7

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Cresol, all isomers

CAS NO(f): 1319-77-3

Transitional Limits:

PEL*

5 ppm(a)

22 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

5 ppm(a)

22 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Crotonaldehyde

CAS NO(f): 123-73-9; 4170-30-3

Transitional Limits:

PEL*

2 ppm(a)

6 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

2 ppm(a)

6 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Crufomate

CAS NO(f): 299-86-5

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Cumene

CAS NO(f): 98-82-8

Transitional Limits:

PEL*

50 ppm(a)

245 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

50 ppm(a)

245 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Cyanamide

CAS NO(f): 420-04-2

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

2 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Cyanides (as CN)

CAS NO(f): Varies With Compound

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Cyanogen

CAS NO(f): 460-19-5

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

10 ppm(a)

20 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Cyanogen chloride

CAS NO(f): 506-77-4

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

0.3 ppm(a)

0.6 mg/m(3)(b)

Skin Designation

-

Cyclohexane

CAS NO(f): 110-82-7

Transitional Limits:

PEL*

300 ppm(a)

1050 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

300 ppm(a)

1050 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Cyclohexanol

CAS NO(f): 108-93-0

Transitional Limits:

PEL*

50 ppm(a)

200 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

50 ppm(a)

200 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Cyclohexanone

CAS NO(f): 108-94-1

Transitional Limits:

PEL*

50 ppm(a)

200 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

25 ppm(a)

100 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Cyclohexene

CAS NO(f): 110-83-8

Transitional Limits:

PEL*

300 ppm(a)

1015 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

300 ppm(a)

1015 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Cyclohexylamine

CAS NO(f): 108-91-8

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

10 ppm(a)

40 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Cyclonite

CAS NO(f): 121-82-4

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

1.5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Cyclopentadiene

CAS NO(f): 542-92-7

Transitional Limits:

PEL*

75 ppm(a)

200 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

75 ppm(a)

200 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Cyclopentane

CAS NO(f): 287-92-3

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

600 ppm(a)

1720 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Cyhexatin

CAS NO(f): 13121-70-5

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

* 2,4-D (Dichlorophenoxyacetic acid)

CAS NO(f): 94-75-7

Transitional Limits:

PEL*

-

10 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Decaborane

CAS NO(f): 17702-41-9

Transitional Limits:

PEL*

0.05 ppm(a)

0.3 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

0.05 ppm(a)

0.3 mg/m(3)(b)

STEL(c)

0.15 ppm(a)

0.9 mg/m(3)(b)

CEILING

-

-

Skin Designation

X

Demeton (Systox (R))

CAS NO(f): 8065-48-3

Transitional Limits:

PEL*

-

0.1 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

0.1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Dichlorodiphenyltrichloroethane (DDT)

CAS NO(f): 50-29-3

Transitional Limits:

PEL*

-

1 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Dichlorvos (DDVP)

CAS NO(f): 62-73-7

Transitional Limits:

PEL*

-

1 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Diacetone alcohol (4-Hydroxy-4-methyl-2-pentanone)

CAS NO(f): 123-42-2

Transitional Limits:

PEL*

50 ppm(a)

240 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

50 ppm(a)

240 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

1,2-Diaminoethane;

see Ethylenediamine

Diazinon

CAS NO(f): 333-41-5

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

0.1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Diazomethane

CAS NO(f): 334-88-3

Transitional Limits:

PEL*

0.2 ppm(a)

0.4 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

0.2 ppm(a)

0.4 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Diborane

CAS NO(f): 19287-45-7

Transitional Limits:

PEL*

0.1 ppm(a)

0.1 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

0.1 ppm(a)

0.1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

1,2-Dibromo-3-chloropropane

CAS NO(f): 96-12-8

see 1910.1044

2-N-Dibutylaminoethanol

CAS NO(f): 102-81-8

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

2 ppm(a)

14 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Dibutyl phosphate

CAS NO(f): 107-66-4

Transitional Limits:

PEL*

1 ppm(a)

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

1 ppm(a)

5 mg/m(3)(b)

STEL(c)

2 ppm(a)

10 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Dibutyl phthalate

CAS NO(f): 84-74-2

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Dichloroacetylene

CAS NO(f): 7572-29-4

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

0.1 ppm(a)

0.4 mg/m(3)(b)

Skin Designation

-

o-Dichlorobenzene

CAS NO(f): 95-50-1

Transitional Limits:

PEL*

(C) 50 ppm(a)

(C) 300 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

50 ppm(a)

300 mg/m(3)(b)

Skin Designation

-

Footnote (C) denotes a ceiling limit.

p-DICHLOROBENZENE

CAS NO(f): 106-46-7

Transitional Limits:

PEL*

75 ppm(a)

450 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

75 ppm(a)

450 mg/m(3)(b)

STEL(c)

110 ppm(a)

675 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

3,32 -Dichlorobenzidine;

CAS NO(f): 91-94-1

see 1910.1007

Dichlorodifluoro-methane

CAS NO(f): 75-71-8

Transitional Limits:

PEL*

1000 ppm(a)

4950 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

1000 ppm(a)

4950 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

1,3-Dichloro-5,5-dimethyl hydantoin

CAS NO(f): 118-52-5

Transitional Limits:

PEL*

-

0.2 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

0.2 mg/m(3)(b)

STEL(c)

-

0.4 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

1,1-Dichloroethane

CAS NO(f): 75-34-3

Transitional Limits:

PEL*

100 ppm(a)

400 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

100 ppm(a)

400 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

1,2-Dichloroethylene

CAS NO(f): 540-59-0

Transitional Limits:

PEL*

200 ppm(a)

790 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

200 ppm(a)

790 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Dichlorethyl ether

CAS NO(f): 111-44-4

Transitional Limits:

PEL*

(C) 15 ppm(a)

(C) 90 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

5 ppm(a)

30 mg/m(3)(b)

STEL(c)

10 ppm(a)

60 mg/m(3)(b)

CEILING

-

-

Skin Designation

X

Footnote (C) denotes a ceiling limit.

Dichloromethane; see Methylene chloride

Dichloromonofluoro-methane

CAS NO(f): 75-43-4

Transitional Limits:

PEL*

1000 ppm(a)

4200 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

10 ppm(a)

40 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

1,1-Dichloro-1-nitroethane

CAS NO(f): 594-72-9

Transitional Limits:

PEL*

(C) 10 ppm(a)

(C) 60 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

2 ppm(a)

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

Footnote (C) denotes a ceiling limit.

1,2-Dichloropropane;

see Propylenedichloride

1,3-Dichloropropene

CAS NO(f): 542-75-6

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

1 ppm(a)

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

2,2-Dichloropropionic acid

CAS NO(f): 75-99-0

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

1 ppm(a)

6 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Dichlorotetrafluoroethane

CAS NO(f): 76-14-2

Transitional Limits:

PEL*

1000 ppm(a)

7000 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

1000 ppm(a)

7000 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Dicrotophos

CAS NO(f): 141-66-2

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

0.25 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Dicyclopentadiene

CAS NO(f): 77-73-6

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

5 ppm(a)

30 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Dicyclopentadienyl iron

CAS NO(f): 102-54-5

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

Dieldrin

CAS NO(f): 60-57-1

Transitional Limits:

PEL*

0.25 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

.025 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Diethanolamine

CAS NO(f): 111-42-2

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

3 ppm(a)

15 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Diethylamine

CAS NO(f): 109-89-7

Transitional Limits:

PEL*

25 ppm(a)

75 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

10 ppm(a)

30 mg/m(3)(b)

STEL(c)

25 ppm(a)

75 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

2-Diethylaminoethanol

CAB NO(f): 100-37-8

Transitional Limits:

PEL*

10 ppm(a)

50 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

10 ppm(a)

50 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Diethylene triamine

CAS NO(f): 111-40-0

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

1 ppm(a)

4 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Diethyl ether;

see Ethyl ether

Diethyl ketone

CAS NO(f): 96-22-0

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

200 ppm(a)

705 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Diethyl phthalate

CAS NO(f): 84-66-2

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Difluorodibromomethane

CAS NO(f): 75-61-6

Transitional Limits:

PEL*

100 ppm(a)

860 mg/m(3)(b)

Skin Designation

Final Rule Limits**:

TWA

100 ppm(a)

860 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Diglycidyl ether (DGE)

CAS NO(f): 2238-07-5

Transitional Limits:

PEL*

(C) 0.5 ppm(a)

(C) 2.8 mg/m(3)(b)

Skin Designation

Final Rule Limits**:

TWA

0.1 ppm(a)

0.5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Footnote (C) denotes a ceiling limit.

Dihydroxybenzene;

see Hydroquinone

Diisobutyl ketone

CAS NO(f): 108-83-8

Transitional Limits:

PEL*

50 ppm(a)

290 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

25 ppm(a)

150 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Diisopropylamine

CAS NO(f): 108-18-9

Transitional Limits:

PEL*

5 ppm(a)

20 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

5 ppm(a)

20 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

4-Dimethylaminoazobenzene;

CAS NO(f): 60-11-7

see 1910.1015

Dimethoxymethane;

see Methylal

Dimethyl acetamide

CAS NO(f): 127-19-5

Transitional Limits:

PEL*

10 ppm(a)

35 mg/m(3)(b)

Skin Designation

Final Rule Limits**:

TWA

10 ppm(a)

35 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Dimethylamine

CAS NO(f): 124-40-3

Transitional Limits:

PEL*

10 ppm(a)

18 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

10 ppm(a)

18 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Dimethylaminobenzene;

see Xylidine

* Dimethylaniline (N,N-Dimethylaniline)

CAS NO(f): 121-69-7

Transitional Limits:

PEL*

5 ppm(a)

25 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

5 ppm(a)

25 mg/m(3)(b)

STEL(c)

10 ppm(a)

50 mg/m(3)(b)

CEILING

-

-

Skin Designation

X

Dimethylbenzene;

see Xylene

Dimethyl-1,2-dibromo-2,2-dichloroethyl phosphate

CAS NO(f): 300-76-5

Transitional Limits:

PEL*

-

3 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

3 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Dimethyloformamide

CAS NO(f): 68-12-2

Transitional Limits:

PEL*

10 ppm(a)

30 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

10 ppm(a)

30 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

2,6-Dimethyl-4-hepta-none;

see Diisobutyl ketone

1,1-Dimethylhydrazine

CAS NO(f): 57-14-7

Transitional Limits:

PEL*

0.5 ppm(a)

1 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

0.5 ppm(a)

1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Dimethylphthalate

CAS NO(f): 131-11-3

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Dimethyl sulfate

CAS NO(f): 77-78-1

Transitional Limits:

PEL*

1 ppm(a)

5 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

0.1 ppm(a)

0.5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Dinitolmide (3,5-Dinitro-o-toluamide)

CAS NO(f): 148-01-6

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Dinitrobenzene (all isomers)

CAS NO(f): (alpha-) 528-29-0; (meta-) 99-65-0; (para-) 100-25-4

Transitional Limits:

PEL*

-

1 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Dinitro-o-cresol

CAS NO(f): 534-52-1

Transitional Limits:

PEL*

-

0.2 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

0.2 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Dinitrotoluene

CAS NO(f): 25321-14-6

Transitional Limits:

PEL*

-

1.5 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

1.5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Dioxane (Diethylene dioxide)

CAS NO(f): 123-91-1

Transitional Limits:

PEL*

100 ppm(a)

360 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

25 ppm(a)

90 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Dioxathion (Delnav)

CAS NO(f): 78-34-2

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

0.2 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Diphenyl (Biphenyl)

CAS NO(f): 92-52-4

Transitional Limits:

PEL*

0.2 ppm(a)

1 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

0.2 ppm(a)

1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Diphenylamine

CAS NO(f): 122-39-4

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Diphenylmethane diisocyanate;

see Methylene bisphenyl isocyanate

Dipropylene glycol methyl ether

CAS NO(f): 34590-94-8

Transitional Limits:

PEL*

100 ppm(a)

600 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

100 ppm(a)

600 mg/m(3)(b)

STEL(c)

150 ppm(a)

900 mg/m(3)(b)

CEILING

-

-

Skin Designation

X

Dipropyl ketone

CAS NO(f): 123-19-3

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

50 ppm(a)

235 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Diquat

CAS NO(f): 86-00-7

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

0.5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Di-sec octyl phthalate (Di-2-ethylhexyl-phthalate)

CAS NO(f): 117-81-7

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

10 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Disulfiram

CAS NO(f): 97-77-8

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

2 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Disulfoton

CAS NO(f): 298-04-4

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

0.1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

2,6-Di-tert-butyl-p-cresol

CAS NO(f): 128-37-0

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Diuron

CAS NO(f): 330-54-1

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Divinyl benzene

CAS NO(f): 1321-74-0

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

10 ppm(a)

50 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

* Emery

CAS NO(f): 12415-34-8

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Endosulfan

CAS NO(f): 115-29-7

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

0.1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Endrin

CAS NO(f): 72-20-8

Transitional Limits:

PEL*

-

0.1 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

0.1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Epichlorohydrin

CAS NO(f): 106-89-8

Transitional Limits:

PEL*

5 ppm(a)

19 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

2 ppm(a)

8 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

EPN

CAS NO(f): 2104-64-5

Transitional Limits:

PEL*

-

0.5 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

0.5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

1,2-Epoxypropane;

see Propylene oxide

2,3-Epoxy-1-propanol;

see Glycidol

Ethanethiol;

see Ethyl mercaptan

Ethanolamine

CAS NO(f): 141-43-5

Transitional Limits:

PEL*

3 ppm(a)

6 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

3 ppm(a)

8 mg/m(3)(b)

STEL(c)

6 ppm(a)

15 m/m(3)(b)

CEILING

-

-

Skin Designation

-

Ethion

CAS NO(f): 563-12-2

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

0.4 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

2-Ethoxyethanol

CAS NO(f): 110-80-5

Transitional Limits:

PEL*

200 ppm(a)

740 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

200 ppm(a)

740 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

2-Ethoxyethyl acetate (Cellosolve acetate)

CAS NO(f): 111-15-9

Transitional Limits:

PEL*

100 ppm(a)

540 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

100 ppm(a)

540 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Ethyl acetate

CAS NO(f): 141-78-6

Transitional Limits:

PEL*

400 ppm(a)

1400 mg/m(3)(b)

Skin Designation

Final Rule Limits**:

TWA

400 ppm(a)

1400 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Ethyl acrylate

CAS NO(f): 140-88-5

Transitional Limits:

PEL*

25 ppm(a)

100 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

5 ppm(a)

20 mg/m(3)(b)

STEL(c)

25 ppm(a)

100 mg/m(3)(b)

CEILING

-

-

Skin Designation

X

Ethyl alcohol (Ethanol)

CAS NO(f): 64-17-5

Transitional Limits:

PEL*

1000 ppm(a)

1900 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

1000 ppm(a)

1900 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Ethylamine

CAS NO(f): 75-04-7

Transitional Limits:

PEL*

10 ppm(a)

18 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

10 ppm(a)

18 mg/m(3)(b)

STEL

-

-

CEILING

-

-

Skin Designation

-

Ethyl amyl ketone (5-Methyl-3-heptanone)

CAS NO(f): 541-85-5

Transitional Limits:

PEL*

25 ppm(a)

130 mg/m(3)(b)

Skin Designation

Final Rule Limits**:

TWA

25 ppm(a)

130 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Ethyl benzene

CAS NO(f): 100-41-4

Transitional Limits:

PEL*

100 ppm(a)

435 mg/m(3)(b)

Skin Designation

Final Rule Limits**:

TWA

100 ppm(a)

435 mg/m(3)(b)

STEL(c)

125 ppm(a)

545 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Ethyl bromide

CAS NO(f): 74-96-4

Transitional Limits:

PEL*

200 ppm(a)

890 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

200 ppm(a)

890 mg/m(3)(b)

STEL(c)

250 ppm(a)

1110 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Ethyl butyl ketone (3-Heptanone)

CAS NO(f): 106-35-4

Transitional Limits:

PEL*

50 ppm(a)

230 mg/m(3)(b)

Skin Designation

Final Rule Limits**:

TWA

50 ppm(a)

230 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Ethyl chloride

CAS NO(f): 75-003

Transitional Limits:

PEL*

1000 ppm(a)

2600 mg/m(3)(b)

Skin Designation

Final Rule Limits**:

TWA

1000 ppm(a)

2600 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Ethyl ether

CAS NO(f): 60-29-7

Transitional Limits:

PEL*

400 ppm(a)

1200 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

400 ppm(a)

1200 mg/m(3)(b)

STEL(c)

500 ppm(a)

1500 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Ethyl formate

CAS NO(f): 109-94-4

Transitional Limits:

PEL*

100 ppm(a)

300 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

100 ppm(a)

300 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Ethyl mercaptan

CAS NO(f): 75-08-1

Transitional Limits:

PEL*

(C) 10 ppm(a)

(C) 25 mg/m(3)(b)

Skin Designation

Final Rule Limits**:

TWA

0.5 ppm(a)

1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Footnote (C) denotes a ceiling limit.

Ethyl silicate

CAS NO(f): 78-10-4

Transitional Limits:

PEL*

100 ppm(a)

850 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

10 ppm(a)

85 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Ethylene chlorohydrin

CAS NO(f): 107-07-3

Transitional Limits:

PEL*

5 ppm(a)

16 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

1 ppm(a)

3 mg/m(3)(b)

Skin Designation

X

Ethylenediamine

CAS NO(f): 107-15-3

Transitional Limits:

PEL*

10 ppm(a)

25 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

10 ppm(a)

25 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Ethylene dibromide

CAS NO(f): 106-93-4

Transitional Limits:

PEL*

Tbl. Z-2

Tbl. Z-2

Skin Designation

Tbl. Z-2

Final Rule Limits**:

TWA

STEL(c)

Tbl. Z-2

Tbl. Z-2

CEILING

Tbl. Z-2

Tbl. Z-2

Skin Designation

Tbl. Z-2

Ethylene Dichloride

CAS NO(f): 107-06-2

Transitional Limits:

PEL*

Tbl. Z-2

Tbl. Z-2

Skin Designation

Tbl. Z-2

Final Rule Limits**:

TWA

1 ppm(a)

4 mg/m(3)(b)

STEL(c)

2 ppm(a)

8 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Ethylene glycol

CAS NO(f): 107-21-1

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

50 ppm(a)

125 mg/m(3)(b)

Skin Designation

-

Ethylene glycol dinitrate(k)

CAS NO(f): 628-96-6

Transitional Limits:

PEL*

(C) 0.2 ppm(a)

(C) 1 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

-

STEL(c)

-

0.1 mg/m(3)(b)(k)

CEILING

-

-

Skin Designation

X

Footnote (C) denotes a ceiling limit.
Footnote (k) The Final Rule Limit STEL of 0.1 mg/m(3) is not in effect as a result of reconsideration for the industrial sector of civilian manufacture and distribution of explosives and propellants for civilian use. The Final rule limits skin designation and the Transitional limits ceiling limit of 1 mg/ m(3) remain in effect for this sector until completion of the reconsideration.

Ethylene glycol methyl acetate;

see Methyl cellosolve accetate

Ethyleneimine;

CAS NO(f): 151-56-4

see 1910.1012

Ethylene oxide;

CAS NO(f): 75-21-8

see 1910.1047

Ethylidene chloride;

see 1,1-Dichlorethane

Ethylidene norbornene

CAS NO(f): 16219-75-3

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

5 ppm(a)

25 mg/m(3)(b)

Skin Designation

-

N-Ethylmorpholine

CAS NO(f): 100-74-3

Transitional Limits:

PEL*

20 ppm(a)

94 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

5 ppm(a)

23 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Fenamiphos

CAS NO(f): 22224-92-6

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

0.1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Fensulfothion (Dasanit)

CAS NO(f): 115-90-2

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

0.1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Fenthion

CAS NO(f): 55-38-9

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

0.2 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Ferbam

CAS NO(f): 14484-64-1

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

Final Rule Limits**:

TWA

-

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Ferrovanadium dust

CAS NO(f): 12604-58-9

Transitional Limits:

PEL*

-

1 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

1 mg/m(3)(b)

STEL

-

3 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Fluorides (as F)

CAS NO(f): Varies with Compound

Transitional Limits:

PEL*

-

2.5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

2.5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Fluorine

CAS NO(f): 77821-41-4

Transitional Limits:

PEL*

0.1 ppm(a)

0.2 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

0.1 ppm(a)

0.2 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Fluorotrichloro-methane (Trichloro-fluoromethane)

CAS NO(f): 75-69-4

Transitional Limits:

PEL*

1000 ppm(a)

5600 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

1000 ppm(a)

5600 mg/m(3)(b)

Skin Designation

-

Fononfos

CAS NO(f): 944-22-9

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

0.1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

* Formaldehyde;

CAS NO(f): 50-00-0

see 1910.1048

Formamide

CAS NO(f): 75-12-7

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

20 ppm(a)

30 mg/m(3)(b)

STEL(c)

30 ppm(a)

45 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Formic acid

CAS NO(f): 64-18-6

Transitional Limits:

PEL*

5 ppm(a)

9 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

5 ppm(a)

9 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Furfural

CAS NO(f): 98-01-1

Transitional Limits:

PEL*

5 ppm(a)

20 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

2 ppm(a)

8 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Furfuryl alcohol

CAS NO(f): 98-00-0

Transitional Limits:

PEL*

50 ppm(a)

200 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

10 ppm(a)

40 mg/m(3)(b)

STEL(c)

15 ppm(a)

60 mg/m(3)(b)

CEILING

-

-

Skin Designation

X

Gasoline

CAS NO(f): 8006-61-9

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

300 ppm(a)

900 mg/m(3)(b)

STEL(c)

500 ppm(a)

1500 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Germanium tetrahydride

CAS NO(f): 7782-65-2

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

0.2 ppm(a)

0.6 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Glutaraldehyde

CAS NO(f): 111-30-8

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

0.2 ppm(a)

0.8 mg/m(3)(b)

Skin Designation

-

Glycerin (Mist)

CAS NO(f): 56-81-5

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Glycidol

CAS NO(f): 556-52-5

Transitional Limits:

PEL*

50 ppm(a)

150 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

25 ppm(a)

75 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Glycol monoethyl ether;

see 2-Ethoxyethanol

Grain dust (oat, wheat, barley)

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Graphite, natural respirable dust

CAS NO(f): 7782-42-5

Transitional Limits:

PEL*

-

Tbl. Z-3

Skin Designation

-

Final Rule Limits**:

TWA

-

2.5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Graphite, synthetic

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Guthion (R);

see Azinphos methyl

Gypsum

CAS NO(f): 13397-24-5

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

15 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Hafnium

CAS NO(f): 7440-58-6

Transitional Limits:

PEL*

-

0.5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

0.5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Heptachlor

CAS NO(f): 76-44-8

Transitional Limits:

PEL*

-

0.5 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

0.5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Heptane (n-Heptane)

CAS NO(f): 142-82-5

Transitional Limits:

PEL*

500 ppm(a)

2000 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

400 ppm(a)

1600 mg/m(3)(b)

STEL(c)

500 ppm(a)

2000 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Hexachlorobutadiene

CAS NO(f): 87-68-3

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

0.02 ppm(a)

0.24 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Hexachlorocyclo-pentadiene

CAS NO(f): 77-47-4

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

0.01 ppm(a)

0.1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Hexachloroethane

CAS NO(f); 67-72-1

Transitional Limits:

PEL*

1 ppm(a)

10 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

1 ppm(a)

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Hexachloronaphthalene

CAS NO(f): 1335-87-1

Transitional Limits:

PEL*

-

0.2 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

0.2 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Hexafluoracetone

CAS NO(f): 684-16-2

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

0.1 ppm(a)

0.7 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

n-Hexane

CAS NO(f): 110-54-3

Transitional Limits:

PEL*

500 ppm(a)

1800 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

50 ppm(a)

180 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Hexane isomers

CAS NO(f): Varies With Compound

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

500 ppm(a)

1800 mg/m(3)(b)

STEL(c)

1000 ppm(a)

3600 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

2-Hexanone (Methyl n-butyl ketone)

CAS NO(f): 591-78-6

Transitional Limits:

PEL*

100 ppm(a)

410 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

5 ppm(a)

20 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Hexone (Methyl isobutyl ketone)

CAS NO(f): 108-10-1

Transitional Limits:

PEL*

100 ppm(a)

410 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

50 ppm(a)

205 mg/m(3)(b)

STEL(c)

75 ppm(a)

300 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

sec-Hexyl acetate

CAS NO(f): 108-84-9

Transitional Limits:

PEL*

50 ppm(a)

300 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

50 ppm(a)

300 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Hexylene glycol

CAS NO(f): 107-41-5

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

25 ppm(a)

125 mg/m(3)(b)

Skin Designation

-

Hydrazine

CAS NO(f): 302-01-2

Transitional Limits:

PEL*

1 ppm(a)

1.3 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

0.1 ppm(a)

0.1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Hydrogenated terphenyls

CAS NO(f): 61788-32-7

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

0.5 ppm(a)

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Hydrogen bromide

CAS NO(f): 10035-10-6

Transitional Limits:

PEL*

3 ppm(a)

10 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

3 mg/m(3)(b)

10 mg/m(3)(b)

Skin Designation

-

Hydrogen chloride

CAS NO(f): 7647-01-0

Transitional Limits:

PEL*

(C) 5 ppm(a)

(C) 7 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

5 ppm(a)

7 mg/m(3)(b)

Skin Designation

-

Footnote (C) denotes a ceiling limit.

Hydrogen cyanide

CAS NO(f): 74-90-8

Transitional Limits:

PEL*

10 ppm(a)

11 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

-

STEL(c)

4.7 ppm(a)

5 mg/m(3)(b)

CEILING

-

-

Skin Designation

X

Hydrogen fluoride (as F)

CAS NO(f): 7664-39-3

Transitional Limits:

PEL*

Tbl. Z-2

Skin Designation

-

Final Rule Limits**:

TWA

3 ppm(a)

-

STEL(c)

6 ppm(a)

-

CEILING

-

-

Skin Designation

-

Hydrogen peroxide

CAS NO(f): 7722-84-1

Transitional Limits:

PEL*

1 ppm(a)

1.4 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

1 ppm(a)

1.4 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Hydrogen selenide (as Se)

CAS NO(f): 7783-07-5

Transitional Limits:

PEL*

0.05 ppm(a)

0.2 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

0.05 ppm(a)

0.2 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Hydrogen sulfide

CAS NO(f): 7783-06-4

Transitional Limits:

PEL*

Tbl. Z-2

Tbl. Z-2

Skin Designation

-

Final Rule Limits**:

TWA

10 ppm(a)

14 mg/m(3)(b)

STEL(c)

15 ppm(a)

21 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Hydroquinone

CAS NO(f): 123-31-9

Transitional Limits:

PEL*

-

2 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

2 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

2-Hydroxypropyl acrylate

CAS NO(f): 999-61-1

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

0.5 ppm(a)

3 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Indene

CAS NO(f): 95-13-6

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

10 ppm(a)

45 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Indium and compounds (as in)

CAS NO(f): 7440-74-6

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

0.1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Iodine

CAS NO(f): 7553-56-2

Transitional Limits:

PEL*

(C) 0.1 ppm(a)

(C) 1 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

0.1 ppm(a)

1 mg/m(3)(b)

Skin Designation

-

Footnote (C) denotes a ceiling limit.

Iodoform

CAS NO(f): 75-47-8

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

0.6 ppm(a)

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Iron oxide fume (as Fe)

CAS NO(f): 1309-37-1

Total Particulate

Transitional Limits:

PEL*

-

10 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Iron pentacarbonyl (as Fe)

CAS NO(f): 13463-40-6

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

0.1 ppm(a)

0.8 mg/m(3)(b)

STEL(c)

0.2 ppm(a)

1.6 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Iron salts (Soluable) (as Fe)

CAS NO(f): Varies With Compound

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Isomyl acetate

CAS NO(f): 123-92-2

Transitional Limits:

PEL*

100 ppm(a)

525 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

100 ppm(a)

525 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Isomyl alcohol (primary and secondary)

CAS NO(f): 123-51-3

Transitional Limits:

PEL*

100 ppm(a)

360 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

100 ppm(a)

360 mg/m(3)(b)

STEL(c)

125 ppm(a)

450 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Isobutyl acetate

CAS NO(f): 110-19-0

Transitional Limits:

PEL*

150 ppm(a)

700 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

150 ppm(a)

700 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Isobutyl alcohol

CAS NO(f): 78-83-1

Transitional Limits:

PEL*

100 ppm(a)

300 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

50 ppm(a)

150 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Isooctyl alcohol

CAS NO(f): 26952-21-6

Transitional Limits:

PEL*

-

-

Skin Designation

Final Rule Limits**:

TWA

50 ppm(a)

270 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Isophorone

CAS NO(f): 78-59-1

Transitional Limits:

PEL*

25 ppm(a)

140 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

4 ppm(a)

23 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Isophorone diisocyanate

CAS NO(f): 4098-71-9

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

0.005 ppm(a)

-

STEL(c)

0.02 ppm(a)

-

CEILING

-

-

Skin Designation

X

2-Isopropoxyethanol

CAS NO(f): 109-59-1

Transitional Limits:

PEL*

Skin Designation

-

Final Rule Limits**:

TWA

25 ppm(a)

105 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Isopropyl acetate

CAS NO(f): 108-21-4

Transitional Limits:

PEL*

250 ppm(a)

950 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

250 ppm(a)

950 mg/m(3)(b)

STEL(c)

310 ppm(a)

1185 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Isopropyl alcohol

CAS NO(f): 67-63-0

Transitional Limits:

PEL*

400 ppm(a)

980 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

400 ppm(a)

980 mg/m(3)(b)

STEL(c)

500 ppm(a)

1225 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Isopropylamine

CAS NO(f): 75-31-0

Transitional Limits:

PEL*

5 ppm(a)

12 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

5 ppm(a)

12 mg/m(3)(b)

STEL(c)

10 ppm(a)

24 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

N-Isopropylaniline

CAS NO(f): 768-52-5

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

2 ppm(a)

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Isopropyl ether

CAS NO(f): 108-20-3

Transitional Limits:

PEL*

500 ppm(a)

2100 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

500 ppm(a)

2100 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Isopropyl glycidyl ether (IGE)

CAS NO(f): 4016-14-2

Transitional Limits:

PEL*

50 ppm(a)

240 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

50 ppm(a)

240 mg/m(3)(b)

STEL(c)

75 ppm(a)

360 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Kaolin

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Ketene

CAS NO(f): 463-51-4

Transitional Limits:

PEL*

0.5 ppm(a)

0.9 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

0.5 ppm(a)

0.9 mg/m(3)(b)

STEL(c)

1.5 ppm(a)

3 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Lead inorganic (as Pb)

CAS NO(f): 7439-92-1

see 1910.1025

Limestone

CAS NO(f): 1317-65-3

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

15 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Lindane

CAS NO(f): 58-89-9

Transitional Limits:

PEL*

-

0.5 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

0.5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Lithium hydride

CAS NO(f): 7580-67-8

Transitional Limits:

PEL*

-

0.025 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

0.025 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

L.P.G. (Liquified petroleum gas)

CAS NO(f): 68476-85-7

Transitional Limits:

PEL*

1000 ppm(a)

1800 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

1000 ppm(a)

1800 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Magnesite

CAS NO(f): 546-93-0

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

15 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Magnesium oxide fume

CAS NO(f): 1309-48-4

Total Particulate

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Malathion

CAS NO(f): 121-75-5

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Maleic anhydride

CAS NO(f): 108-31-6

Transitional Limits:

PEL*

0.25 ppm(a)

1 mg/m(3)(b)

Final Rule Limits**:

TWA

0.25 ppm(a)

1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Manganese compounds (as Mn)

CAS NO(f): 7439-96-5

Transitional Limits:

PEL*

-

(C) 5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

-

5 mg/m(3)(b)

Skin Designation

-

Footnote (C) denotes a ceiling limit.

Manganese fume (as Mn)

CAS NO(f): 7439-96-5

Transitional Limits:

PEL*

-

(C) 5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

1 mg/m(3)(b)

STEL(c)

-

3 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Footnote (C) denotes a ceiling limit.

Manganese cyclopetadienyl tricarbonyl (as Mn)

CAS NO(f): 12079-65-1

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

0.1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Manganese tetroxide (as Mn)

CAS NO(f): 1317-35-7

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Marble

CAS NO(f): 1317-65-3

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

15 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Mercury (aryl and inorganic) (as Hg)

CAS NO(f): 7439-97-6

Transitional Limits:

PEL*

Tbl. Z-2

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

-

0.1 mg/m(3)(b)

Skin Designation

X

Mercury (organo) alkyl compounds (as Hg)

CAS NO(f): 7439-97-6

Transitional Limits:

PEL*

Tbl. Z-2

Skin Designation

-

Final Rule Limits**:

TWA

-

0.01 mg/m(3)(b)

STEL(c)

-

0.03 mg/m(3)(b)

CEILING

-

-

Skin Designation

X

Mercury (vapor) (as Hg)

CAS NO(f): 7439-97-6

Transitional Limits:

PEL*

Tbl. Z-2

Skin Designation

-

Final Rule Limits**:

TWA

-

0.05 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Mesityl oxide

CAS NO(f): 141-79-7

Transitional Limits:

PEL*

25 ppm(a)

100 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

15 ppm(a)

60 mg/m(3)(b)

STEL(c)

25 ppm(a)

100 mg/m(3)(b)

CEILING

-

-

Skin Designation

X

Methacrylic acid

CAS NO(f): 79-41-4

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

20 ppm(a)

70 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Methanethiol;

see Methyl mercaptan

Methomyl (Lannate)

CAS NO(f): 16752-77-5

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

2.5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Methoxychlor

CAS NO(f): 72-43-5

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

2-Methoxyethanol;

see Methyl cellosolve

4-Methoxyphenol

CAS NO(f): 150-76-5

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Methyl acetate

CAS NO(f): 79-20-9

Transitional Limits:

PEL*

200 ppm(a)

610 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

200 ppm(a)

610 mg/m(3)(b)

STEL(c)

250 ppm(a)

760 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Methyl acetylene (Propyne)

CAS NO(f): 74-99-7

Transitional Limits:

PEL*

1000 ppm(a)

1650 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

1000 ppm(a)

1650 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Methyl acetylene propadiene mixture (MAPP)

Transitional Limits:

PEL*

1000 ppm(a)

1800 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

1000 ppm(a)

1800 mg/m(3)(b)

STEL(c)

1250 ppm(a)

2250 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Methyl acrylate

CAS NO(f): 96-33-3

Transitional Limits:

PEL*

10 ppm(a)

35 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

10 ppm(a)

35 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Methylacrylonitrile

CAS NO(f): 126-98-7

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

1 ppm(a)

3 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Methyial (Dimethoxy-methane)

CAS NO(f): 109-87-5

Transitional Limits:

PEL*

1000 ppm(a)

3100 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

1000 ppm(a)

3100 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Methyl alcohol

CAS NO(f): 67-56-1

Transitional Limits:

PEL*

200 ppm(a)

260 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

200 ppm(a)

260 mg/m(3)(b)

STEL(c)

250 ppm(a)

325 mg/m(3)(b)

CEILING

-

-

Skin Designation

X

Methylamine

CAS NO(f): 74-89-5

Transitional Limits:

PEL*

10 ppm(a)

12 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

10 ppm(a)

12 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Methyl amyl alcohol;

see Methyl Isobutyl carbinol

Methyl n-amyl ketone

CAS NO(f): 110-43-0

Transitional Limits:

PEL*

100 ppm(a)

465 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

100 ppm(a)

465 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Methyl bromide

CAS NO(f): 74-83-9

Transitional Limits:

PEL*

(C) 20 ppm(a)

(C) 80 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

5 ppm(a)

20 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Footnote (C) denotes a ceiling limit.

Methyl butyl ketone;

see 2-Hexanone

Methyl cellosolve (2-Methoxyethanol)

CAS NO(f): 109-86-4

Transitional Limits:

PEL*

25 ppm(a)

80 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

25 ppm(a)

80 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Methyl cellosolve acetate (2-Methoxyethyl acetate)

CAS NO(f): 110-49-6

Transitional Limits:

PEL*

25 ppm(a)

120 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

25 ppm(a)

120 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Methyl chloride

CAS NO(f): 74-87-3

Transitional Limits:

PEL*

Tbl. Z-2

Final Rule Limits**:

TWA

50 ppm(a)

105 mg/m(3)(b)

STEL(c)

100 ppm(a)

210 mg/m(3)(b)

CEILING

-

Skin Designation

Methyl chloroform (1,1,1-Trichloroethane)

CAS NO(f): 71-55-6

Transitional Limits:

PEL*

350 ppm(a)

1900 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

350 ppm(a)

1900 mg/m(3)(b)

STEL(c)

450 ppm(a)

2450 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Methyl 2-cyanoacrylate

CAS NO(f): 137-05-3

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

2 ppm(a)

8 mg/m(3)(b)

STEL(c)

4 ppm(a)

16 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Methylcyclohexane

CAS NO(f): 108-87-2

Transitional Limits:

PEL*

500 ppm(a)

2000 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

400 ppm(a)

1600 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Methylcyclohexanol

CAS NO(f): 25639-42-3

Transitional Limits:

PEL*

100 ppm(a)

470 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

50 ppm(a)

235 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

o-Methylcyclohexanone

CAS NO(f): 583-60-8

Transitional Limits:

PEL*

100 ppm(a)

460 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

50 ppm(a)

230 mg/m(3)(b)

STEL(c)

75 ppm(a)

345 mg/m(3)(b)

CEILING

-

-

Skin Designation

X

Methylcyclopentiadienyl manganese tricarbonyl (as Mn)

CAS NO(f): 12108-13-3

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

0.2 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Methyl demeton

CAS NO(f): 8022-00-2

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

0.5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

4,42-Methylene bis (2-chloroaniline) (MBOCA)

CAS NO(f): 101-14-4

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

0.02 ppm(a)

0.22 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

Skin Designation

X

Methylene bis (4-cyclohexylisocyanate)

CAS NO(f): 5124-30-1

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

0.01 ppm(a)

0.11 mg/m(3)(b)

Skin Designation

X

Methylene chloride

CAS NO(f): 75-09-2

Transitional Limits:

PEL*

Tbl. Z-2

-

Skin Designation

-

Final Rule Limits**:

TWA

Tbl. Z-2

-

STEL(c)

Tbl. Z-2

-

CEILING

Tbl. Z-2

-

Skin Designation

-

Methyl ethyl ketone peroxide (MEKP)

CAS NO(f): 1338-23-4

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

0.7 ppm(a)

5 mg/m(3)(b)

Skin Designation

-

Methyl formate

CAS NO(f): 107-31-3

Transitional Limits:

PEL*

100 ppm(a)

250 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

100 ppm(a)

250 mg/m(3)(b)

STEL(c)

150 ppm(a)

375 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Methyl hydrazine (Monomethyl hydrazine)

CAS NO(f): 60-34-4

Transitional Limits:

PEL*

(C) 0.2 ppm(a)

(C) 0.35 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

0.2 ppm(a)

0.35 mg/m(3)(b)

Skin Designation

X

Footnote (C) denotes a ceiling limit.

Methyl iodide

CAS NO(f): 74-88-4

Transitional Limits:

PEL*

5 ppm(a)

28 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

2 ppm(a)

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Methyl isoamyl ketone

CAS NO(f): 110-12-3

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

50 ppm(a)

240 mg/m(3)(b)

STEL(c)

-

CEILING

-

Skin Designation

-

Methyl isobutyl carbinol

CAS NO(f): 108-11-2

Transitional Limits:

PEL*

25 ppm(a)

100 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

25 ppm(a)

100 mg/m(3)(b)

STEL(c)

40 ppm(a)

165 mg/m(3)(b)

CEILING

-

-

Skin Designation

X

Methyl isobutyl ketone; see Hexone

Methyl isocyanate

CAS NO(f): 624-83-9

Transitional Limits:

PEL*

0.02 ppm(a)

0.05 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

0.02 ppm(a)

0.05 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Methyl isopropyl ketone

CAS NO(f): 563-80-4

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

200 ppm(a)

705 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Methyl mercaptan

CAS NO(f): 74-93-1

Transitional Limits:

PEL*

(C) 10 ppm(a)

(C) 20 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

0.5 ppm(a)

1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Footnote (C) denotes a ceiling limit.

Methyl methacrylate

CAS NO(f): 80-62-2

Transitional Limits:

PEL*

100 ppm(a)

410 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

100 ppm(a)

410 mg/m(3)(b)

STEL(c)

-

CEILING

-

-

Skin Designation

-

Methyl parathion

CAS NO(f): 298-00-0

Transitional Limits:

PEL*

-

Skin Designation

-

Final Rule Limits**:

TWA

-

STEL(c)

-

CEILING

-

Skin Designation

X

Methyl propyl ketone;

see 2-Pentanone

Methyl silicate

CAS NO(f): 681-84-5

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

1 ppm(a)

6 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

alpha-Methyl styrene

CAS NO(f): 98-83-9

Transitional Limits:

PEL*

(C) 100 ppm(a)

(C) 480 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

50 ppm(a)

240 mg/m(3)(b)

STEL(c)

100 ppm(a)

485 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Footnote (C) denotes a ceiling limit.

Methylene bisphenyl isocyanate (MDI)

CAS NO(f): 101-68-8

Transitional Limits:

PEL*

(C) 0.02 ppm(a)

(C) 0.2 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

0.02 ppm(a)

0.2 mg/m(3)(b)

Skin Designation

-

Footnote (C) denotes a ceiling limit.

Metribuzin

CAS NO(f): 21087-64-9

Transitional Limits:

PEL*

-

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Mica;

see Silicates

Molybdenum (as Mo)

CAS NO(f): 7439-98-7

Soluble compounds

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Insoluble Compounds-total dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Monocrotophos (Azodrin (R))

CAS NO(f): 6923-22-4

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

0.25 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Monomethyl aniline

CAS NO(f): 100-61-8

Transitional Limits:

PEL*

2 ppm(a)

9 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

0.5 ppm(a)

2 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Morpholine

CAS NO(f): 110-91-8

Transitional Limits:

PEL*

20 ppm(a)

70 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

20 ppm(a)

70 mg/m(3)(b)

STEL(c)

30 ppm(a)

105 mg/m(3)(b)

CEILING

-

-

Skin Designation

X

Naphtha (Coal tar)

CAS NO(f): 8030-30-6

Transitional Limits:

PEL*

100 ppm(a)

400 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

100 ppm(a)

400 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Naphthalene

CAS NO(f): 91-20-3

Transitional Limits:

PEL*

10 ppm(a)

50 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

10 ppm(a)

50 mg/m(3)(b)

STEL(c)

15 ppm(a)

75 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

alpha-Naphthylamine;

CAS NO(f): 134-32-7

see 1910.1004

beta-Naphthylamine;

CAS NO(f): 91-59-8

see 1910.1009

Nickel carbonyl (as Ni)

CAS NO(f): 13463-39-3

Transitional Limits:

PEL*

0.001 ppm(a)

0.007 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

0.001 ppm(a)

0.007 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Nickel, metal and insoluble compounds (as Ni)

CAS NO(f): 7440-02-0

Transitional Limits:

PEL*

-

1 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Nickel, insoluble compounds (as Ni)

CAS NO(f): 7440-02-0

Transitional Limits:

PEL*

-

1 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

0.1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Nicotine

CAS NO(f): 54-11-5

Transitional Limits:

PEL*

-

0.5 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

0.5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Nitric acid

CAS NO(f): 7697-37-2

Transitional Limits:

PEL*

2 ppm(a)

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

2 ppm(a)

5 mg/m(3)(b)

STEL(c)

4 ppm(a)

10 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Nitric oxide

CAS NO(f): 10102-43-9

Transitional Limits:

PEL*

25 ppm(a)

30 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

25 ppm(a)

30 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

p-Nitroaniline

CAS NO(f): 100-01-6

Transitional Limits:

PEL*

1 ppm(a)

6 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

3 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Nitrobenzene

CAS NO(f): 98-95-3

Transitional Limits:

PEL*

1 ppm(a)

5 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

1 ppm(a)

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

Skin Designation

X

p-Nitrochlorobenzene

CAS NO(f): 100-00-5

Transitional Limits:

PEL*

-

1 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

Skin Designation

X

4-Nitrodiphenyl;

CAS NO(f): 92-93-3

see 1910.1003

Nitroethane

CAS NO(f): 79-24-3

Transitional Limits:

PEL*

100 ppm(a)

310 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

100 ppm(a)

310 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Nitrogen dioxide

CAS NO(f): 10102-44-0

Transitional Limits:

PEL*

(C) 5 ppm(a)

(C) 9 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

1 ppm(a)

1.8 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Footnote (C) denotes a ceiling limit.

Nitrogen trifluoride

CAS NO(f): 7783-54-1

Transitional Limits:

PEL*

10 ppm(a)

29 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

10 ppm(a)

29 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Nitroglycerin(1)

CAS NO(f): 55-63-0

Transitional Limits:

PEL*

(C) 0.2 ppm(a)

(C) 2 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

-

STEL(c)

-

0.1 mg/m(3)(b)(l)

CEILING

-

-

Skin Designation

X

Footnote (C) denotes a ceiling limit.
Footnote (1) The Final Rule Limit STEL of 0.1 mg/m(3) is not in effect as a result of reconsideration for the industrial sector of civilian manufacture and distribution of explosives and propellants for civilian use. The Final rule limits skin designation and the Transitional limits ceiling limit of 2 mg/m(3) remains in effect for this sector until completion of the reconsideration.

Nitromethane

CAS NO(f): 75-52-5

Transitional Limits:

PEL*

100 ppm(a)

250 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

100 ppm(a)

250 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

1-Nitropropane

CAS NO(f): 108-03-2

Transitional Limits:

PEL*

25 ppm(a)

90 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

25 ppm(a)

90 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

2-Nitropropane

CAS NO(f): 79-46-9

Transitional Limits:

PEL*

25 ppm(a)

90 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

10 ppm(a)

35 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

N-Nitrosodimethylamine;

CAS NO(f): 62-79-9

see 1910.1016

Nitrotoluene

CAS NO(f): o-isomer 88-72-2; m-isomer 99-08-1; p-isomer 99-99-0

Transitional Limits:

PEL*

5 ppm(a)

30 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

2 ppm(a)

11 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Nitrotrichloromethane; see Chloropicrin

Nonane

CAS NO(f): 111-84-2

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

200 ppm(a)

1050 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Octachloronaphthalene

CAS NO(f): 2234-13-1

Transitional Limits:

PEL*

-

0.1 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

0.1 mg/m(3)(b)

STEL(c)

-

0.3 mg/m(3)(b)

CEILING

-

-

Skin Designation

X

Octane

CAS NO(f): 111-65-9

Transitional Limits:

PEL*

500 ppm(a)

2350 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

300 ppm(a)

1450 mg/m(3)(b)

STEL(c)

375 ppm(a)

1800 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Oil mist, mineral

CAS NO(f): 8012-95-1

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Osmium tetroxide (as Os)

CAS NO(f): 20816-12-0

Transitional Limits:

PEL*

-

0.002 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

0.0002 ppm(a)

0.002 mg/m(3)(b)

STEL(c)

0.0006 ppm(a)

0.006 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Oxalic acid

CAS NO(f): 144-62-7

Transitional Limits:

PEL*

-

1 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

1 mg/m(3)(b)

STEL(c)

-

2 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Oxygen difluoride

CAS NO(f): 7783-41-7

Transitional Limits:

PEL*

0.05 ppm(a)

0.1 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

0.05 ppm(a)

0.1 mg/m(3)(b)

Skin Designation

-

Ozone

CAS NO(f): 10028-15-6

Transitional Limits:

PEL*

0.1 ppm(a)

0.2 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

0.1 ppm(a)

0.2 mg/m(3)(b)

STEL(c)

0.3 ppm(a)

0.6 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Paraffin wax fume

CAS NO(f): 8002-74-2

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

2 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Paraquat, respirable dust

CAS NO(f): 1910-42-5; 2074-50-2; 4685-14-7

Transitional Limits:

PEL*

-

0.5 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

0.1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Parathion

CAS NO(f): 56-38-2

Transitional Limits:

PEL*

-

0.1 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

0.1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Particulates not otherwise regulated

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

15 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

Skin Designation

-

Pentaborane

CAS NO(f): 19624-22-7

Transitional Limits:

PEL*

0.005 ppm(a)

0.01 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

0.005 ppm(a)

0.01 mg/m(3)(b)

STEL(c)

0.015 ppm(a)

0.03 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Pentachloronaphthalene

CAS NO(f): 1321-64-8

Transitional Limits:

PEL*

-

0.5 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

0.5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Pentachlorophenol

CAS NO(f): 87-86-5

Transitional Limits:

PEL*

-

0.5 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

0.5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Pentaerythritol

CAS NO(f): 115-77-5

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Pentane

CAS NO(f): 109-66-0

Transitional Limits:

PEL*

1000 ppm(a)

2950 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

600 ppm(a)

1800 mg/m(3)(b)

STEL(c)

750 ppm(a)

2250 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

2-Pentanone (Methyl propyl ketone)

CAS NO(f): 107-87-9

Transitional Limits:

PEL*

200 ppm(a)

700 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

200 ppm(a)

700 mg/m(3)(b)

STEL(c)

250 ppm(a)

875 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Pentachloronaphthalene (Tetrachloroethylene)

CAS NO(f): 127-18-4

Transitional Limits:

PEL*

Tbl. Z-2

-

Skin Designation

-

Final Rule Limits**:

TWA

25 ppm(a)

170 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Perchloromethyl mercaptan

CAS NO(f): 594-42-3

Transitional Limits:

PEL*

0.1 ppm(a)

0.8 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

0.1 ppm(a)

0.8 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Perchloryl fluoride

CAS NO(f): 7616-94-6

Transitional Limits:

PEL*

3 ppm(a)

13.5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

3 ppm(a)

14 mg/m(3)(B)

STEL(c)

6 ppm(a)

28 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Perlite

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

15 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

* Petroleum distillates (Naphtha) (Rubber Solvent)

Transitional Limits:

PEL*

500 ppm(a)

2000 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

400 ppm(a)

1600 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Phenol

CAS NO(f): 108-95-2

Transitional Limits:

PEL*

5 ppm(a)

19 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

5 ppm(a)

19 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Phenothiazine

CAS NO(f): 92-84-2

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

p-Phenylene diamine

CAS NO(f): 106-50-3

Transitional Limits:

PEL*

-

0.1 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

0.1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Phenyl ether, vapor

CAS NO(f): 101-84-8

Transitional Limits:

PEL*

1 ppm(a)

7 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

1 ppm(a)

7 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Phenyl ether-biphenyl mixture, vapor

Transitional Limits:

PEL*

1 ppm(a)

7 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

1 ppm(a)

7 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Phenylethylene;

see Styrene

Phenyl glycidyl ether (PGE)

CAS NO(f): 122-60-1

Transitional Limits:

PEL*

10 ppm(a)

60 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

1 ppm(a)

6 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Phenylhydrazine

CAS NO(f): 100-63-0

Transitional Limits:

PEL*

5 ppm(a)

22 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

5 ppm(a)

20 mg/m(3)(b)

STEL(c)

10 ppm(a)

45 mg/m(3)(b)

CEILING

-

-

Skin Designation

X

Phenyl mercaptan

CAS NO(f): 108-98-5

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

0.5 ppm(a)

2 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Phenylphosphine

CAS NO(f): 638-21-1

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

0.05 ppm(a)

0.25 mg/m(3)(b)

Skin Designation

-

Phorate

CAS NO(f): 298-02-2

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

0.05 mg/m(3)(b)

STEL(c)

-

0.2 mg/m(3)(b)

CEILING

-

-

Skin Designation

X

Phosdrin (Mevinphos (R))

CAS NO(f): 7786-34-7

Transitional Limits:

PEL*

-

0.1 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

0.01 ppm(a)

0.1 mg/m(3)(b)

STEL(c)

0.03 ppm(a)

0.3 mg/m(3)(b)

CEILING

-

-

Skin Designation

X

Phosgene (Carbonyl chloride)

CAS NO(f): 75-44-5

Transitional Limits:

PEL*

0.1 ppm(a)

0.4 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

0.1 ppm(a)

0.4 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Phosphine

CAS NO(f): 7803-51-2

Transitional Limits:

PEL*

0.3 ppm(a)

0.4 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

0.3 ppm(a)

0.4 mg/m(3)(b)

STEL(c)

1 ppm(a)

1 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Phosphoric acid

CAS NO(f): 7664-38-2

Transitional Limits:

PEL*

-

1 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

1 mg/m(3)(b)

STEL(c)

-

3 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Phosphorus (yellow)

CAS NO(f): 7723-14-0

Transitional Limits:

PEL*

-

0.1 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

0.1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Phosphorous oxychloride

CAS NO(f): 10025-87-3

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

0.1 ppm(a)

0.6 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Phosphorus pentachloride

CAS NO(f): 10026-13-8

Transitional Limits:

PEL*

-

1 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Phosphorus pentasulfide

CAS NO(f): 1314-80-3

Transitional Limits:

PEL*

1 mg/m(3)(b)

Skin designation

-

Final Rule Limits**:

TWA

-

1 mg/m(3)(b)

STEL(c)

-

3 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Phosphorus trichloride

CAS NO(f): 7719-12-2

Transitional Limits:

PEL*

0.5 ppm(a)

3 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

0.2 ppm(a)

1.5 mg/m(3)(b)

STEL(c)

0.5 ppm(a)

3 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Phthalic anhydride

CAS NO(f): 85-44-9

Transitional Limits:

PEL*

2 ppm(a)

12 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

1 ppm(a)

6 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

m-Phthalodinitrile

CAS NO(f): 626-17-5

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Pictoram

CAS NO(f): 1918-02-1

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Picric acid

CAS NO(f): 88-89-1

Transitional Limits:

PEL*

-

0.1 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

0.1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Piperazine dihydro-chloride

CAS NO(f): 142-64-3

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Pindone (2-Pivalyl-1,3-indandione)

CAS NO(f): 83-26-1

Transitional Limits:

PEL*

-

0.1 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

0.1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Plaster of paris

CAS NO(f): 26499-65-0

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

15 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Platinum (as Pt)

CAS NO(f): 7440-06-4

Metal

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Soluble Salts

Transitional Limits:

PEL*

-

0.002 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

0.002 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Portland cement

CAS NO(f): 65997-15-1

Total Dust

Transitional Limits:

PEL*

-

Tbl. Z-3

Skin Designation

-

Final Rule Limits**:

TWA

-

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

-

Tbl. Z-3

Skin Designation

-

Final Rule Limits **:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Potassium hydroxide

CAS NO(f): 1310-58-3

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

-

2 mg/m(3)(b)

Skin Designation

-

Propane

CAS NO(f): 74-98-6

Transitional Limits:

PEL*

1000 ppm(a)

1800 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

1000 ppm(a)

1800 mg/m(3)(b)

STEL(c)

-

-

CEILING

Skin Designation

-

Propargyl alcohol

CAS NO(f): 107-19-7

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

1 ppm(a)

2 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

beta-Propriolactone;

CAS NO(f): 57-57-8

see 1910.1013

Propionic acid

CAS NO(f): 79-09-4

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

10 ppm(a)

30 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Propoxur (Baygon)

CAS NO(f): 114-26-1

Transitonal Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

0.5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

n-Propyl acetate

CAS NO(f): 109-60-4

Transitional Limits:

PEL*

200 ppm(a)

840 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

200 ppm(a)

840 mg/m(3)(b)

STEL(c)

250 ppm(a)

1050 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

n-Propyl alcohol

CAS NO(f): 71-23-8

Transitional Limits:

PEL*

200 ppm(a)

500 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

200 ppm(a)

500 mg/m(3)(b)

STEL(c)

250 ppm(a)

625 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

n-Propyl nitrate

CAS NO(f): 627-13-4

Transitional Limits:

PEL*

25 ppm(a)

110 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

25 ppm(a)

105 mg/m(3)(b)

STEL(c)

40 ppm(a)

170 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Propylene dichloride

CAS NO(f): 78-87-5

Transitional Limits:

PEL*

75 ppm(a)

350 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

75 ppm(a)

350 mg/m(3)(b)

STEL(c)

110 ppm(a)

510 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Propylene glycol dinitrate

CAS NO(f): 6423-43-4

Transitional Limits:

PEL*

-

Skin Designation

-

Final Rule Limits**:

TWA

0.05 ppm(a)

0.8 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Propylene glycol monomethyl ether

CAS NO(f): 107-98-2

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

100 ppm(a)

360 mg/m(3)(b)

STEL(c)

150 ppm(a)

540 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Propylene imine

CAS NO(f): 75-55-8

Transitional Limits:

PEL*

2 ppm(a)

5 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

2 ppm(a)

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Propylene oxide

CAS NO(f): 75-56-9

Transitional Limits:

PEL*

100 ppm(a)

240 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

20 ppm(a)

50 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Propyne;

see Methyl acetylene

Pyrethrum

CAS NO(f): 8003-34-7

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

5 ppm(a)

-

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Pyridine

CAS NO(f): 110-86-1

Transitional Limits:

PEL*

5 ppm(a)

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

5 ppm(a)

15 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Quinone

CAS NO(f): 106-51-4

Transitional Limits:

PEL*

0.1 ppm(a)

0.4 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

0.1 ppm(a)

0.4 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Resorcinol

CAS NO(f): 108-46-3

Transitional Limits:

PEL*

Skin Designation

-

Final Rule Limits**:

TWA

10 ppm(a)

45 mg/m(3)(b)

STEL(c)

20 ppm(a)

90 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Rhodium (as Rh), metal fume and insoluble compounds

CAS NO(f): 7440-16-6

Transitional Limits:

PEL*

0.1 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

0.1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

Skin Designation

-

Rhodium (as Rh), soluble compounds

CAS NO(f): 7440-16-6

Transitional Limits:

PEL*

-

0.001 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

0.001 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Ronnel

CAS NO(f): 299-84-3

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Rosin core solder pyrolysis products, as formaldehyde

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

0.1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Rotenone

CAS NO(f): 83-79-4

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Rouge

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Selenium compounds (as Se)

CAS NO(f): 7782-49-2

Transitional Limits:

PEL*

-

0.2 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

0.2 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Selenium hexafluoride (as Se)

CAS NO(f): 7783-79-1

Transitional Limits:

PEL*

0.05 ppm(a)

0.4 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

0.05 ppm(a)

0.4 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Silica, amorphous, precipitated and gel

CAS NO(f): 112926-00-8

Transitional Limits:

PEL*

-

Tbl. Z-3

Skin Designation

-

Final Rule Limits**:

TWA

-

6 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Silica, amorpous, diatomaceous earth, containing less than 1% cyrstalline silica

CAS NO(f): 61790-53-2

Transitional Limits:

PEL*

-

Tbl. Z-3

Skin Designation

-

Final Rule Limits**:

TWA

-

6 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

* Silica, crystalline cristobalite, respirable dust

CAS NO(f): 14464-46-1

Transitional Limits:

PEL*

-

Tbl. Z-3

Skin Designation

-

Final Rule Limits**:

TWA

-

0.05 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

* Silica, crystalline quartz, respirable dust

CAS NO(f): 14808-60-7

Transitional Limits:

PEL*

-

Tbl. Z-3

Skin Designation

-

Final Rule Limits**:

TWA

-

0.1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Silica, crystalline tripoli (as quartz), respirable dust

CAS NO(f): 1317-95-9

Transitional Limits:

PEL*

-

Tbl. Z-3

Skin Designation

-

Final Rule Limits**:

TWA

-

0.1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

* Silica, crystalline tridymite, respirable dust

CAS NO(f): 15468-32-3

Transitional Limits:

PEL*

-

Tbl. Z-3

Skin Designation

-

Final Rule Limits**:

TWA

-

0.05 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Silica, fused, respirable dust

CAS NO(f): 60676-86-0

Transitional Limits:

PEL*

-

Tbl. Z-3

Skin Designation

-

Final Rule Limits**:

TWA

-

0.1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Silicates (less than 1% crystalline silica CAS NO(f): 12001-26-2

Mica (respirable dust)

Transitional Limits:

PEL*

-

Tbl. Z-3

Skin Designation

-

Final Rule Limits**:

TWA

-

3 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Soapstone, Total Dust

Transitional Limits:

PEL*

-

Tbl. Z-3

Skin Designation

-

Final Rule Limits**:

TWA

-

6 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Soapstone, Respirable Dust

Transitional Limits:

PEL*

-

Tbl. Z-3

Skin Designation

-

Final Rule Limits**:

TWA

-

3 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

Talc (containing asbestos): use asbestos limit: See 29 CRF 1910.1001

Transitional Limits:

PEL*

-

Tbl. Z-3

Skin Designation

-

Final Rule Limits**:

Talc (containing no asbestos), respirable dust CAS NO(f): 14807-96-6

Transitional Limits:

PEL*

-

Tbl. Z-3

Skin Designation

-

Final Rule Limits**:

TWA

-

2 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Tremolite

Transitional Limits:

See 29 CFR 1010.1101

PEL*

-

Tbl. Z-3

Skin Designation

-

Final Rule Limits**:

Silicon

CAS NO(f): 7440-21-3

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Silicon carbide

CAS NO(f): 409-21-2

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Silicon tetrahydride

CAS NO(f): 7803-62-5

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

5 ppm(a)

7 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Silver, metal and soluble compounds (as Ag)

CAS NO(f): 7440-22-4

Transitional Limits:

PEL*

-

0.01 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

0.01 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Soapstone;

see Silicates

Sodium azide (as HN (3)):

CAS NO(f): 26628-22-8

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

0.1 ppm(a)

-

Skin Designation

X

(as NaN (3)):

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

-

0.3 mg/m(3)(b)

Skin Designation

X

Sodium bisulfite

CAS NO(f): 7631-90-5

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Sodium fluoroacetate

CAS NO(f): 62-74-8

Transitional Limits:

PEL*

-

0.05 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

0.05 mg/m(3)(b)

STEL(c)

-

0.15 mg/m(3)(b)

CEILING

-

-

Skin Designation

X

Sodium hydroxide

CAS NO(f): 1310-73-2

Transitional Limits:

PEL*

-

2 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

-

2 mg/m(3)(b)

Skin Designation

-

Sodium metabisulfite

CAS NO(f): 7681-57-4

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Starch

CAS NO(f): 9005-25-8

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

15 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Stibine CAS

NO(f): 7803-52-3

Transitional Limits:

PEL*

0.1 ppm(a)

0.5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

0.1 ppm(a)

0.5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Stoddard solvent

CAS NO(f): 8052-41-3

Transitional Limits:

PEL*

500 ppm(a)

2900 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

100 ppm(a)

525 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Strychnine

CAS NO(f): 57-24-9

Transitional Limits:

PEL*

-

0.15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

0.15 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Styrene

CAS NO(f): 100-42-5

Transitional Limits:

PEL*

Tbl. Z-2

-

Skin Designation

-

Final Rule Limits**:

TWA

50 ppm(a)

215 mg/m(3)(b)

STEL(c)

100 ppm(a)

425 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Subtilisins (Proteolytic enzymes)

CAS NO(f): 9014-01-1

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

0.00006 mg/m(3)(b) (60 min.) (g)

CEILING

-

-

Skin Designation

Footnote (g) Compliance with the subtilisins PEL is assessed by sampling with a high volume sampler (600-800 liters per minute) for at least 60 minutes.

Sucrose

CAS NO(f): 57-50-1

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

15 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Sulfur dioxide

CAS NO(f): 7446-09-5

Transitional Limits:

PEL*

5 ppm(a)

13 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

2 ppm(a)

5 mg/m(3)(b)

*STEL(c)

5 ppm(a)

13 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Sulfur hexafluoride

CAS NO(f): 2551-62-4

Transitional Limits:

PEL*

1000 ppm(a)

6000 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

1000 ppm(a)

6000 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Sulfuric acid

CAS NO(f): 7664-93-9

Transitional Limits:

PEL*

-

1 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Sulfur monochloride

CAS NO(f): 10025-67-9

Transitional Limits:

PEL*

1 ppm(a)

6 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

1 ppm(a)

6 mg/m(3)(b)

Skin Designation

-

Sulfur pentafluoride

CAS NO(f): 5714-22-7

Transitional Limits:

PEL*

0.025 ppm(a)

0.25 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

0.01 ppm(a)

0.1 mg/m(3)(b)

Skin Designation

-

Sulfur tetrafluoride

CAS NO(f): 7783-60-0

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

0.1 ppm(a)

0.4 mg/m(3)(b)

Skin Designation

-

Sulfuryl fluoride

CAS NO(f): 2699-79-8

Transitional Limits:

PEL*

5 ppm(a)

20 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

5 ppm(a)

20 mg/m(3)(b)

STEL(c)

10 ppm(a)

40 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Sulprofos

CAS NO(f): 35400-43-2

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Systox (R);

see Demeton

2,4,5-T

CAS NO(f): 93-76-5

Transitional Limits:

PEL*

-

10 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Talc;

see Silicates

Tantalum, metal and oxide dust

CAS NO(f): 7440-25-7

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

TEDP (Sulfotep)

CAS NO(f): 3689-24-5

Transitional Limits:

PEL*

-

0.2 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

0.2 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Tellurium and compounds (as Te)

CAS NO(f): 13494-80-9

Transitional Limits:

PEL*

-

0.1 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

0.1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Tellurium hexafluoride (as Te)

CAS NO(f): 7783-80-4

Transitional Limits:

PEL*

0.02 ppm(a)

0.2 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

0.02 ppm(a)

0.2 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Temephos

CAS NO(f): 3383-96-8

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

TEPP

CAS NO(f): 107-49-3

Transitional Limits:

PEL*

-

0.05 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

0.05 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Terphenylis

CAS NO(f): 26140-60-3

Transitional Limits:

PEL*

(C) 1 ppm(a)

(C) 9 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

0.5 ppm(a)

5 mg/m(3)(b)

Skin Designation

-

Footnote (C) denotes a ceiling limit.

1,1,1,2-Tetrachloro-2,2-difluoroethane

CAS NO(f): 76-11-9

Transitional Limits:

PEL*

500 ppm(a)

4170 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

500 ppm(a)

4170 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

1,1,2,2-Tetrachloro-1,2-difluoroethane

CAS NO(f): 76-12-0

Transitional Limits:

PEL*

500 ppm(a)

4170 mg/mm(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

500 ppm(a)

4170 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

1,1,2,2-Tetrachloroethane

CAS NO(f): 79-34-5

Transitional Limits:

PEL*

5 ppm(a)

35 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

1 ppm(a)

7 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Tetrachlorethylene;

see Perchloroethylene

Tetrachloromethane;

see Carbon tetrachloride

Tetrachloronaphthalene

CAS NO(f): 1335-88-2

Transitional Limits:

PEL*

-

2 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

2 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Tetraethyl lead (as Pb)

CAS NO(f): 78-00-2

Transitional Limits:

PEL*

-

0.075 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

0.075 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Tetrahydrofuran

CAS NO(f): 109-99-9

Transitional Limits:

PEL*

200 ppm(a)

590 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

200 ppm(a)

590 mg/m(3)(b)

STEL(c)

250 ppm(a)

735 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Tetramethyl lead, (as Pb)

CAS NO (f): 75-74-1

Transitional Limits:

PEL*

-

0.075 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

0.075 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Tetramethyl succinonitrile

CAS NO (f): 3333-52-6

Transitional Limits:

PEL*

0.5 ppm(a)

3 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

0.5 ppm(a)

3 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Tetranitromethane

CAS NO (f): 509-14-8

Transitional Limits:

PEL*

1 ppm(a)

8 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

1 ppm(a)

8 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Tetrasodium pyrophosphate

CAS NO (f): 7722-88-5

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Tetryl (2,4,6-Trinitro-phenyl-methyl-nitramine)

CAS NO (f): 479-45-8

Transitional Limits:

PEL*

-

1.5 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

1.5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Thallium, soluble compounds (as Tl)

CAS NO (f): 7440-28-0

Transitional Limits:

PEL*

-

0.1 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

0.1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

4,42-Thiobis (6-tert, Butyl-m-cresol)

CAS NO (f): 96-69-5

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Thioglycolic acid

CAS NO (f): 68-11-1

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

1 ppm(a)

4 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Thionyl chloride

CAS NO (f): 7719-09-7

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

1 ppm(a)

5 mg/m(3)(b)

Skin Designation

-

Thiram

CAS NO (f): 137-26-8

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Tin, inorganic compounds (except oxides) (as Sn)

CAS NO (f): 7440-31-5

Transitional Limits:

PEL*

-

2 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

2 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Tin, organic compounds (as Sn)

CAS NO (f): 7440-31-5

Transitional Limits:

PEL*

-

0.1 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

0.1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Tin oxide (as Sn)

CAS NO (f): 21651-19-4

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

2 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Titanium dioxide

CAS NO (f): 13463-67-7

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Toluene

CAS NO (f): 108-88-3

Transitional Limits:

PEL*

Tbl. Z-2

Skin Designation

-

Final Rule Limits**:

TWA

100 ppm(a)

375 mg/m(3)(b)

STEL(c)

150 ppm(a)

560 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Toluene-2,4-diisocyanate (TDI)

CAS NO (f): 584-84-9

Transitional Limits:

PEL*

(C) 0.02 ppm(a)

(C) 0.14 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

0.005 ppm(a)

0.04 mg/m(3)(b)

STEL(c)

0.02 ppm(a)

0.15 mg/m(3)(b)

CEILING

-

-

Skin Designation.

Footnote (C) denotes a ceiling limit.

m-Toluidine

CAS NO (f): 108-44-1

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

2 ppm(a)

9 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

o-Toluidine

CAS NO (f): 95-53.4

Transitional Limits:

PEL*

5 ppm(a)

22 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

5 ppm(a)

22 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

p-Toluidine

CAS NO (f): 106-49-0

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

2 ppm(a)

9 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Toxaphene;

see Chlorinated camphene

Tremolite;

see Silicates

Tributyl phosphate

CAS NO (f): 126-73-8

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

0.2 ppm(a)

2.5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Trichloroacetic acid

CAS NO (f): 76-03-9

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

1 ppm(a)

7 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

1,2,4-Trichlorobenzene

CAS NO (f): 120-82-1

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

5 ppm(a)

40 mg/m(3)(b)

Skin Designation

-

1,1,1-Trichloroethane;

see Methyl chloroform

1,1,2-Trichloroethane

CAS NO (f): 79-00-5

Transitional Limits:

PEL*

10 ppm(a)

45 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

10 ppm(a)

45 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Trichloroethylene

CAS NO (f): 79-01-6

Transitional Limits:

PEL*

Tbl. Z-2

Tbl. Z-2

Skin Designation

Thl. Z-2

Final Rule Limits**:

TWA

50 ppm(a)

270 mg/m(3)(b)

STEL(c)

200 ppm(a)

1080 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Trichloromethane;

see Chloroform

Trichloronaphthalene

CAS NO (f): 1321-65-9

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

1,2,3-Trichloropropane

CAS NO (f): 96-18-4

Transitional Limits:

PEL*

50 ppm(a)

300 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

10 ppm(a)

60 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

1,1,2-Trichloro-1,2,2-trifluoroethane

CAS NO (f): 76-13-1

Transitional Limits:

PEL*

1000 ppm(a)

7600 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

1000 ppm(a)

7600 mg/m(3)(b)

STEL(c)

1250 ppm(a)

9500 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Triethylamine

CAS NO (f): 121-44-8

Transitional Limits:

PEL*

25 ppm(a)

100 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

10 ppm(a)

40 mg/m(3)(b)

STEL(c)

15 ppm(a)

60 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Trifluorobromomethane

CAS NO (f): 75-63-8

Transitional Limits:

PEL*

1000 ppm(a)

6100 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

1000 ppm(a)

6100 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Trimellitic anhydride

CAS NO (f): 552-30-7

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

0.005 ppm(a)

0.04 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Trimethylamine

CAS NO (f): 75-50-3

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

10 ppm(a)

24 mg/m(3)(b)

STEL(c)

15 ppm(a)

36 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Trimethyl benzene

CAS NO (f): 25551-13-7

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

25 ppm(a)

125 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Trimethyl phosphite

CAS NO (f): 121-45-9

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

2 ppm(a)

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

2,4,6-Trinitrophenyl;

see Picric acid

2,4,6-Trinitrophenylmethyl nitramine;

see Tetryl

2,4,6-Trinitrotoluene (TNT)

CAS NO (f): 118-96-7

Transitional Limits:

PEL*

-

1.5 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

-

0.5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Triorthocresyl phosphate

CAS NO (f): 78-30-8

Transitional Limits:

PEL*

-

0.1 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

0.1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Triphenyl amine

CAS NO (f): 603-34-9

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Triphenyl phosphate

CAS NO (f): 115-86-6

Transitional Limits:

PEL*

-

3 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

3 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Tungsten (as W)

CAS NO (f): 7440-33-7

Insoluble Compounds

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

10 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Soluble Compounds

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

1 mg/m(3)(b)

STEL(c)

-

3 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Turpentine

CAS NO (f): 8006-64-2

Transitional Limits:

PEL*

100 ppm(a)

560 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

100 ppm(a)

560 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Uranium (as U)

CAS NO (f): 7440-61-1

Soluble Compounds

Transitional Limits:

PEL*

-

0.05 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

0.05 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Insoluble Compounds

Transitional Limits:

PEL*

-

0.25 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

0.2 mg/m(3)(b)

STEL(c)

-

0.6 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

n-Valeraldehyde

CAS NO (f): 110-62-3

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

50 ppm(a)

175 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Vanadium

CAS NO (f): 1314-62-1

Respirable dust (as V(2)O(5))

Transitional Limits:

PEL*

-

(C) 0.5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

0.05 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Fume (as V(2)O(5))

Transitional Limits:

PEL*

-

(C) 0.1 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

0.05 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Footnote (C) denotes a ceiling limit

Vegetable oil mist

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

15 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Vinyl acetate

CAS NO (f): 108-05-4

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

10 ppm(a)

30 mg/m(3)(b)

STEL(c)

20 ppm(a)

60 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Vinyl benzene;

see Styrene

Vinyl bromide

CAS NO (f): 593-60-2

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

5 ppm(a)

20 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Vinyl chloride;

see 1910.1017

CAS NO (f): 75-01-4

Vinyl cyanide*;

see Acrylonitrile

Vinyl cyclohexene dioxide

CAS NO (f): 106-87-6

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

10 ppm(a)

60 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Vinylidene chloride

(1,1-Dichloroethylene)

CAS NO (f): 75-35-4

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

1 ppm(a)

4 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Vinyl toluene

CAS NO (f): 25013-15-4

Transitional Limits:

PEL*

100 ppm(a)

480 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

100 ppm(a)

480 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

VM & P Naphtha

CAS NO (f): 8032-32-4

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

300 ppm(a)

1350 mg/m(3)(b)

STEL(c)

400 ppm(a)

1800 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Warfarin

CAS NO (f): 81-81-2

Transitional Limits:

PEL*

-

0.1 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

0.1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Welding fumes (total particulate***) (As determined from breathing-zone air samples)

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Footnote*** As determined from breathing-zone air samples.
Wood dust, all soft and hard woods, except Western red cedar

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

10 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Wood dust, Western red cedar

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

2.5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Xylenes (o-, m-, p-isomers)

CAS NO(f): 1330-20-7

Transitional Limits:

PEL*

100 ppm(a)

435 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

100 ppm(a)

435 mg/m(3)(b)

STEL(c)

150 ppm(a)

655 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

m-Xylene alpha, alpha2-diamine

CAS NO(f): 1477-55-0

Transitional Limits:

PEL*

-

-

Skin Designation

-

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

-

0.1 mg/m(3)(b)

Skin Designation

X

Xylidine

CAS NO(f): 1300-73-8

Transitional Limits:

PEL*

5 ppm(a)

25 mg/m(3)(b)

Skin Designation

X

Final Rule Limits**:

TWA

2 ppm(a)

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

X

Yttrium

CAS NO(f): 7440-65-5

Transitional Limits:

PEL*

-

1 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

1 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Zinc chloride fume

CAS NO(f): 7646-85-7

Transitional Limits:

PEL*

-

1 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

1 mg/m(3)(b)

STEL(c)

-

2 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Zinc chromate (as CrO (3))

CAS NO(f): Varies with Compound

Transitional Limits:

PEL*

Tbl. Z-2

Tbl. Z-2

Skin Designation

Tbl. Z-2

Final Rule Limits**:

TWA

-

-

STEL(c)

-

-

CEILING

-

0.1 mg/m(3)(b)

Skin Designation

-

Zinc oxide fume

CAS NO (f): 1314-13-2

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

10 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

Zinc oxide

CAS NO (f): 1314-13-2

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Zinc stearate

CAS NO (f): 557-05-1

Total Dust

Transitional Limits:

PEL*

-

15 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

10 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Respirable fraction

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

-

CEILING

-

-

Skin Designation

-

Zirconium compounds (as Zr)

CAS NO (f): 7440-67-7

Transitional Limits:

PEL*

-

5 mg/m(3)(b)

Skin Designation

-

Final Rule Limits**:

TWA

-

5 mg/m(3)(b)

STEL(c)

-

10 mg/m(3)(b)

CEILING

-

-

Skin Designation

-

TABLE Z-2

Acceptable max. peak above the acceptable ceil. concentration for an 8-hr shift
Material8-hour time-wtd AverageAcceptable ceiling concentration
ConcentrationMaximum duration
*Benzene (Z37.40-1969)(a)10 ppm25 ppm50 ppm10 minutes
Beryllium and Berylium compounds (Z37.29-1970)2 ug/m(3)5 ug/m(3)25 ug/m(3)30 minutes
*Cadmium fume (Z37.5-1970)(c)0.1 mg/m(3)0.3 mg/m(3) .......
Cadmium dust (Z37.5-1970)(c)0.2 mg/m(3)0.6 mg/m(3).......
Carbon disulfide (Z37.3-1968)20 ppm30 ppm100 ppm30 minutes
Carbon Tetrachloride (Z37.17-1967)10 ppm25 ppm200 ppm5 min. in any 4 hrs.
Chromic acid and chromates (Z37-7-1971)....... 1 mg/10 m(3).......
Ethylene dibromide (Z37.31-1970)20 ppm30 ppm50 ppm5 minutes
Ethylene dichloride (Z37.21-1969)50 ppm100 ppm200 ppm5 min. in any 3 hrs.
Formaldehyde (Z37.16-1967)(b)3 ppm5 ppm10 ppm30 minutes
Hydrogen fluoride (Z37.28-1969)3 ppm....... .......
Hydrogen sulfide (Z37.2-1966)....... 20 ppm50 ppm10 minutes once only if no other meas. exposure occurs
Fluoride as dust (Z37.38-1969)2.5 mg.m(3)....... .......
Mercury (Z237.8-1971) ....... 1 mg/10 m(3) .......
Methyl chloride (Z37.18-1969)100 ppm200 ppm300 ppm5 min. in any 3 hrs.
Methylene chloride (Z37.23-1969)500 ppm1,000 ppm2,000 ppm5 min. in any 2 hrs.
Organo (alkyl) mercury (Z37.30-1969)0.01 mg/m(3)0.04 mg/m(3) .......
Styrene (Z37.15-1969)100 ppm200 ppm600 ppm5 min. in any 3 hrs.
Tetrachloroethylene (Z37.22-1967)100 ppm200 ppm300 ppm5 min. in any 3 hrs.
Toluene (Z37.12-1967)200 ppm300 ppm500 ppm10 minutes
Trichloroethylene (Z37.19-1967)100 ppm200 ppm300 ppm5 min in any 2 hrs.

*The transitional PELs are 8-hour TWAs unless otherwise noted; a (C) designation denotes a ceiling limit.

** Unless otherwise noted, employers in General Industry (i.e., those covered by 29 CFR 1910) may use any combination of controls to achieve these limits until December 31, 1993 as set forth in 29 CFR 1910.1000(f).

*** As determined from breathing zone air samples.

a Parts of vapor or gas per million parts of contaminated air by volume at 25 degrees C abd 760 torr.

b Milligrams of substance per cubic meter of air. When a numeric entry for a substance is in the mg/m(3) column and not in the ppm column, then the number in the mg/m(3) column is exact. When numerical entries for a substance are in both the ppm and mg/m(3) columns, then the number in the mg/m(3) column may be rounded off.

c Duration is for 15 minutes, unless otherwise noted.

d The final benzene standard in 1910,.1028 applies to all occupational exposures to benzene except some subsegments of industry where exposures are consistenly under the action level (i.e., distribution and sale of fuels, sealed containers and pipelines, coke production, oil and gas drilling and production, natural gas processing, and the percentage exclusion for liquid mixtures); for the excepted subsegments, the benzene limits in Table Z-2 apply.

TABLE Z-3

Mineral Dusts

Substance

mppcf(e)

mg/m(3)

SILICA:250(f)10 mg/
CRYSTALLINEm(3)(m)
QUARTZ (RESPIRABLE) .......
QUARTZ (TOTAL DUST) ....... %SiO(2) +5%SiO(2) +2
30 mg/m(3)
%SiO(2) +2
CRYSTOBALITE: Use 1/2 the value calculated from the count or mass formulae for quartz
TRIDYMITE: Use 1/2 the value calculated from the formulae for quartz
AMORPHOUS, including natural diatomaceous earth ....... 2080 mg/m(3)
%SiO(2)
SILICATES (less than 1% crystaline silica):
Mica ....... 20 .......
Soapstone ....... 20 .......
Talc (not containing asbestos) ....... 20(n) .......
Talc (containing asbestos).
Use asbestos limit
Tremolite (see 29 CFR 1910.1101)
Portland cement ....... 50 .......
GRAPHITE (NATURAL) ....... 15 .......
COAL DUST (respirable fraction less than 5% SiO(2) ....... 2.4 mg/m(3)
or
For more than 5% SiO(2) ....... 10 mg/m(3)
%SiO(2) +2
* INERT OR NUISANCE DUST(G):
Respirable fraction ....... 155 mg/m(3)
Total dust ....... 5015 mg/m(3)

Note - Conversion factors - mppcf X 35.3 = million particles per cubic meter = particles per c.c.

*This standard applies to the industry segments exempt from the 1 ppm 8-hour TWA and 5 ppm STEL of the benzene standard at 1910.1028.

N.Y. Comp. Codes R. & Regs. Tit. 12 § 800.5

Amended New York State Register December 13, 2023/Volume XLV, Issue 50, eff. 12/13/2023