N.Y. Comp. Codes R. & Regs. tit. 12, Appendices, app A-12

Current through Register Vol. 46, No. 45, November 2, 2024
Appendix A-12

A1 AND A2 VALUES FOR RADIONUCLIDES

(cf. Part 38)

For a given radionuclide, the A1 or A2 value is defined as the maximum activity permitted in a Type A package. The A1 value applies for special form radioactive material, while the A2 value applies for radioactive material in other than special form. (See section 38.3 Definitions.)

I. Single Radionuclides

(1) For a single radionuclide of known identity, the values of A1 and A2 are taken from Table 1 if listed there. The values A1 and A2 in Table 1 are also applicable for the radionuclide contained in (±,n) or (³,n) neutron sources.

(2) For any single radionuclide whose identity is known but which is not listed in Table 1, the value of A1 and A2 are determined according to the following procedure:

(2) (a) If the radionuclide emits only one type of radiation, A1 is determined according to the following method. For radionuclides emitting different kinds of radiation, A1 is the most restrictive value of those determined for each kind of radiation. However, in either case, A1 is restricted to a maximum of 1000 curies (37 TBq). If a parent nuclide decays into a shorter lived daughter with a half-life not greater than 10 days, A1 is calculated for both the parent and the daughter, and the more limiting of the two values is assigned to the parent nuclide.

(1) For gamma emitters, A1 is determined by the expression: A1 = 9 curies [GAMMA]

Where [GAMMA] is the gamma-ray constant, corresponding to the dose in roentgens per curie-hour at 1 meter, and the number 9 results from the choice of 1 rem per hour at a distance of 3 meters as the reference dose-equivalent rate.

(2) For x-ray emitters, A1 is determined by the atomic number of the nuclide:

for Z <= 55, A1 = 1000 Ci (37 TBq); and for Z > 55, A1 = 200 Ci (7.4 TBq) .......

where Z is the atomic number of the nuclide.

(3) For beta emitters, A1 is determined by the maximum beta energy (E max) according to Table 2; and

(4) For alpha emitters, A1 is determined by the expression:

A1 = 1000 A3

where A3 is the value listed in Table 3;

(2) (b) A2 is the more restrictive of the following two values:

(2) (1) the corresponding A1; and

(2) (2) the value A3 obtained from Table 3.

(3) For any single radionuclide whose identity is unknown, the value of A1 is taken to be 2 Ci (74 GBq) and the value of A2 is taken to be 0.002 Ci (74 MBq). However, if the atomic number of the radionuclide is known to be less than 82, the value of A1 is taken to be 10 Ci (370 GBq) and the value of A2 is taken to be 0.4 Ci (14.8 GBq).

II. Mixtures of Radionuclides, Including Radioactive Decay Chains

1. For mixed fission products, the activity limit may be assuned if a detailed analysis of the mixture is not carried out,

A1 = 10 Ci (370 GBq)

A2 = 0.4 Ci (14.8 GBq)

2 A single radioactive decay chain is considered to be a single radionuclide when the radionuclides are present in their naturally occurring proportions and no daughter nuclide has a half-life either longer than 10 days or longer than that of the parent nuclide. The activity to be taken into account and the A1 or A2 value from Table 1 to be applied are those corresponding to the parent nuclide of that chain. When calculating A1 or A2 values, radiation emitted by daughters must be considered. However, in the case of radioactive decay chains in which any daughter nuclide has a half-life either longer than 10 days or greater than that of the parent nuclide, the parent and daughter nuclides are considered to be mixtures of different nuclides.

3. In the case of a mixture of different radionuclides, where the identity and activity of each radionuclide are known, the permissible activity of each radionuclide R1, R2. . . Rn is such that F1 + F2 +. . . Fn is not greater than unity, where:

F1 = Total activity of R1 .......

A1(R1) .......

F

2 = Total activity of R2 .......

A1(R2) .......

Fn = Total activity of Rn and .......

A1(Rn) .......

A1 (R1, R2. . . Rn is the value of A1 or A2 as appropriate for the nuclide R1, R2. . . Rn.

4. When the identity of each radionuclide is known but the individual activities of some of the radionuclides are not known, the formula given in paragraph 3. is applied to establish the values of A1 or A2 as appropriate. All the radionuclides whose individual activities are not known their total activity will however, be known) are classed in a single group and the most restrictive value of A1 and A2 applicable to any one of them is used as the value of A1 or A2 in the denominator of the fraction.

5. Where the identity of each radionuclide is known but the individual activity of none of the radionuclides is known, the most restrictive value of A1 or A2 applicable to any one of the radionuclides present is adopted as the applicable value.

6. When the identity of none of the nuclides is known, the value of A1 is taken to be 2 Ci (74 GBq) and the value of A2 is taken to be 0.002 Ci (74 MBq). However, if alpha emitters are known to be absent, the value of A2 is taken to be 0.4 Ci (14.8 GBq).

TABLE 1

A1 AND A2 VALUES FOR RADIONUCLIDES

(See footnotes at end of Table)

Symbol of Radionuclide

Element and Atomic Number

A1 (Ci)

A2 (Ci)

Specific Activity (Ci/g)

Ac-227Actinium (89)10000.0037.2 E + 01
Ac-2281042.2 E + 06
Ag-105Silver (47)40403.9 E + 07
Ag-110m774.7 E + 03
Ag-111100201.5 E + 05
Am-241Americium (95)80.0083.2
Am-24380.0081.9 E 01
Ar-37 (compressed or Uncompressed)*Argon (18)100010001.0 E + 05
Ar-41 (uncompressed)*20204.3 E + 07
Ar-41 (compressed)*114.3 E.+ 07
As-73Arsenic (33)10004002.4 E + 04
As-7420201.0 E + 05
As-7610101.6 E + 06
As-77300201.1 E + 06
At-211Astatine (85)20072.1 E + 06
Au-193Gold (79)2002009.3 E + 05
Au-19630301.2 E + 05
Au-19840202.5 E + 05
Au-199200252.1 E + 05
Ba-131Barium (56)40408.7 E + 04
Ba-13340404.0 E + 03
Ba-14020207.3 E + 04
Be-7Beryllium (4)3003003.5 E + 05
Bi-206Bismuth (83)559.9 E + 04
Bi-20710102.2 E + 02
Bi-210 (RaE)10041.2 E + 05
Bi-212661.5 E + 07
Bk-249Berkelium (97)100011.9 E + 03
Br-77Bromine (35)70257.1 E + 03
Br-82661.1 E + 06
C-11Carbon (6)20208.4 E + 08
C-141000604.6
Ca-45Calcium (20)1000251.9 E + 04
Ca-4720205.9 E + 05
Cd-109Cadmium (48)1000702.6 E + 03
Cd-115m30302.6 E + 04
Cd-11580205.1 E + 05
Ce-139Cerium (58)1001006.5 E + 03
Ce-141300252.8 E + 04
Ce-14360206.6 E + 05
Ce-1441073.2 E + 03
Cf-249Californium (98)20.0023.1
Cf-25070.0071.3 E + 02
Cf-25220.0096.5 E + 02
Cl-36Chlorine (17)300103.2 E. 02
Cl-3810101.3 E + 08
Cm-242Curium (96)2000.23.3 E + 03
Cm-24390.0094.2 E + 01
Cm-244100.018.2 E + 01
Cm-24560.0061.0 E 01
Cm-24660.0063.6 E 01
Co-56Cobalt (27)553.0 E + 04
Co-5790908.5 E + 03
Co-58m100010005.9 E + 06
Co-5820203.1 E + 05
Co-60771.1 E + 03
Cr-51Chromium (24)6006009.2 E + 04
Cs-129Cesium (55)40407.6 E + 05
Cs-131100010001.1 E + 05
Cs-134m1000107.4 E + 06
Cs-13410101.2 E + 03
Cs-1351000258.8 E 04
Cs-136777.4 E + 04
Cs-13730109.8 E + 01
Cu-64Copper (29)80253.8 E + 06
Cu-67200257.9 E + 05
Dy-165Dysprosium (66)100208.2 E + 06
Dy-16610002002.3 E + 05
Er-169Erbium (68)1000258.2 E + 04
Er-17150202.4 E + 06
Eu-152mEuropium (63)30302.2 E + 06
Eu-15220101.9 E + 02
Eu-1541051.5 E + 02
Eu-155400601.4 E + 03
F-18Fluorine (9)20209.3 E + 07
Fe-52Iron (26)557.3 E + 06
Fe-55100010002.2 E + 03
Fe-5910104.9 E + 04
Ga-67Gallium (31)1001006.0 E + 03
Ga-6820204.0 E + 07
Ga-72773.1 E + 06
Gd-153Gadolinium (64)2001003.6 E + 03
Gd-159300201.1 E + 06
Ge-68Gernanium (32)20107.0 E + 03
Ge-71100010001.6 E + 05
H-3Hydrogen (1)See Tritium
Hf-181Hafnium (72)30251.6 E + 04
Hg-197mMercury (80)2002006.6 E + 05
Hg-1972002002.5 E + 05
Hg-20380251.4 E + 04
Ho-166Holmium (67)30306.9 E + 05
I-123Iodine (53)50506.9 E + 04
I-1251000701.7 E + 04
I-12640107.8 E + 04
I-129100021.6 E 04
I-1314011.2 E + 05
I-132771.1 E + 07
I-13330101.1 E + 06
I-134882.7 E + 07
I-13510103.5 E + 06
In-111Indium (49)30254.2 E + 05
In-113m60601.6 E + 07
In-114m30202.3 E + 04
In-115m100206.1 E + 06
Ir-190Iridium (77)10106.2 E + 04
Ir-19220109.1 E + 03
Ir-19410108.5 E + 05
K-42Potassium (19)10106.0 E + 06
K-4320103.3 E + 06
Kr-85m (uncompressed)*Krypton (36)1001008.4 E + 06
Kr-85m (compressed)*338.4 E + 06
Kr-85 (uncompressed)*100010004.0 E + 02
Kr-85 (compressed)*554.0 E + 02
Kr-87 (uncompressed)*20202.8 E + 07
Kr-87 (compressed)*0.60.62.8 E + 07
La-140Lanthanum (57)30305.6 E + 05
Lu-177Lutetium (71)300251.1 E + 05
MFPMixed Fission Products100.4---
Mg-28Magnesium (12)665.2 E + 06
Mn-52Manganese (25)554.4 E + 05
Mn-5420208.3 E + 03
Mn-56552.2 E + 07
Mo-99Molybdenum (42)100204.7 E + 05
N-13Nitrogen (7)20101.5 E + 09
Na-22Sodium (11)886.3 E + 03
Na-24558.7 E + 06
Nb-93mNiobium (41)10002004.1 E + 02
Nb-9520203.9 E + 07
Nb-9720202.6 E + 07
Nd-147Neodymium (60)100208.0 E + 04
Nd-14930201.1 E + 07
Ni-59Nickel (28)10009008.1 E 02
Ni-6310001004.6 E + 01
Ni-6510101.9 E + 07
Np-237Neptunium (93)50.0056.9 E 04
Np-239200252.3 E + 05
Os-185Osmium (76)20207.3 E + 03
Os-1916002004.6 E + 04
Os-191m2002001.2 E + 06
Os-193100205.3 E + 05
P-32Phosphorus (15)30302.9 E + 05
Pa-230Protactinium (91)200.83.2 E + 04
Pa-23120.0024.5 E 02
Pa-2331001002.1 E + 04
Pb-201Lead (82)20201.7 E + 06
Pb-2101000.28.8 E + 01
Pb-212651.4 E + 06
Pd-103Palladium (46)10007007.5 E + 04
Pd-109100202.1 E + 06
Pm-147Promethium (61)1000259.4 E + 02
Pm-149100204.2 E + 05
Po-210Polonium (84)2000.24.5 E + 03
Pr-142Praseodymium (59)10101.2 E + 06
Pr-143300206.6 E + 04
Pt-191Platinum (78)1001002.3 E + 05
Pt-193m2002002.0 E + 05
Pt-197m300201.2 E + 07
Pt-197300208.8 E + 05
Pu-238Plutonium (94)30.0031.7 E + 01
Pu-23920.0026.2 E 02
Pu-24020.0022.3 E 01
Pu-24110000.11.1 E + 02
Pu-24230.0033.9 E 03
Ra-223Radium (88)500.25.0 E + 04
Ra-22460.51.6 E + 05
Ra-226100.051.0
Ra-228100.052.3 E + 02
Rb-81Rubidium (37)30248.2 E + 04
Rb-8630308.1 E + 04
Rb-87UnlimitedUnlimited6.6 E 08
Rb (natural)UnlimitedUnlimited1.8 E 08
Re-186Rhenium (75)100201.9 E + 05
Re-187UnlimitedUnlimited3.8 E 08
Re (natural)UnlimitedUnlimited2.4 E 08
Rh-103mRhodium (45)100010003.2 E + 07
Rh-105200258.2 E + 05
Rn-222Radon (86)1021.5 E + 05
Ru-97Ruthenium (44)80805.5 E + 05
Ru-10330253.2 E + 04
Ru-10520206.6 E + 06
Ru-1061073.4 E + 03
S-35Sulphur (16)1000604.3 E + 04
Sb-122Antimony (51)30303.9 E + 05
Sb-124551.8 E + 04
Sb-12540251.4 E + 03
Sc-46Scandium (21)883.4 E + 04
Sc-47200208.2 E + 05
Sc-48551.5 E + 06
Se-75Selenium (34)40401.4 E + 04
Si-31Silicon (14)100203.9 E + 07
Sm-147Samarium (62)UnlimitedUnlimited2.0 E 08
Sm-1511000902.6 E + 01
Sm-153300204.4 E + 05
Sn-113Tin (50)60601.0 E + 04
Sn-119m1001004.4 E + 03
Sn-12510101.1 E + 05
Sr-85mStrontium (38)80803.2 E + 07
Sr-8530302.4 E + 04
Sr-89100102.9 E + 04
Sr-90100.41.5 E + 02
Sr-9110103.6 E + 06
Sr-9210101.3 E + 07
T (uncompressed)*Tritium (1)100010009.7 E + 03
T (compressed)*100010009.7 E + 03
T (activated luminous paint)100010009.7 E + 03
T (absorbed on solid carrier)100010009.7 E + 03
T (tritiated water)100010009.7 E + 03
T (other forms)20209.7 E + 03
Ta-182Tantalum (73)20206.2 E + 03
Tb-182Terbium (65)20101.1 E + 05
Tc-96mTechnetium (43)100010003.8 E + 07
Tc-96663.2 E + 05
Tc-97m10002001.5 E + 04
Tc-9710004001.4 E + 04
Tc-99m1001005.2 E + 06
Tc-991000251.7 E 02
Te-125mTellurium (52)10001001.8 E + 04
Te-127m300204.0 E + 04
Te-127300202.6 E + 06
Te-129m30102.5 E + 04
Te-129100202.0 E + 07
Te-131m10108.0 E + 05
Te-132773.1 E + 05
Th-227Thorium (90)2000.23.2 E + 04
Th-22860.0088.3 E + 02
Th-23030.0031.9 E 02
Th-2311000255.3 E + 05
Th-232UnlimitedUnlimited1.1 E 07
Th-23410102.3 E + 04
Th (natural)UnlimitedUnlimited2.2 E 07
Th (irradiated)**---------
Tl-200Thallium (81)20205.8 E + 05
Tl-2012002002.2 E + 05
Tl-20240405.4 E + 04
Tl-204300104.3 E + 02
Tm-170Thulium (69)300106.0 E + 03
Tm-17110001001.1 E + 03
U-230Uranium (92)1000.12.7 E + 04
U-232300.032.1 E + 01
U-2331000.19.5 E 03
U-2341000.16.2 E 03
U-2351000.22.1 E 06
U-2362000.26.3 E 05
U-238UnlimitedUnlimited3.3 E 07
U (natural)UnlimitedUnlimited(see Table 4)
U (enriched) < 20 percentUnlimitedUnlimited(see Table 4)
U (enriched) 20 percent or greaterUnlimitedUnlimited(see Table 4)
U (depleted)UnlimitedUnlimited(see Table 4)
U (irradiated)***---------
V-48Vanadium (23)661.7 E + 05
W-181Tungsten (74)2001005.0 E + 03
W-1851000259.7 E + 03
W-18740207.0 E + 05
Xe-127 (uncompressed)*Xenon (54)70702.8 E + 04
Xe-127 (compressed)*552.8 E + 04
Xe-131m (compressed)*10101.0 E + 05
Xe-131m1001001.0 E + 05
Xe-133 (uncompressed)*100010001.9 E + 05
Xe-133 (compressed)*551.9 E + 05
Xe-135 (uncompressed)*70702.5 E + 06
Xe-135 (compressed)*222.5 E + 06
Y-87Yttrium (39)20204.5 E + 05
Y-9010105.4 E + 05
Y-91m30304.1 E + 07
Y-9130302.5 E + 04
Y-9210109.5 E + 06
Y-9310103.2 E + 06
Yb-169Ytterbium (70)80802.3 E + 05
Yb-175400251.8 E + 05
Zn-65Zinc (30)30308.0 E + 03
Zn-69m40203.3 E + 06
Zn-69300205.3 E + 07
Zr-93Zirconium (40)10002003.5 E 03
Zr-9520202.1 E + 04
Zr-9720202.0 E + 06

* For the purpose of Table 1, compressed gas means a gas at a pressure which exceeds the ambient atmospheric pressure at the location where the containment system was closed.

** The value of A1 and A 2 must be calculated in accordance with the procedure specified in paragraph II 3. of this Appendix, taking into account the activity of the fission products and of the uranium-233 in addition to that of the thorium.

*** The values of A1 and A 2 must be calculated in accordance with the procedure specified in paragraph II 3. of this Appendix, taking into account the activity of the fission products and plutonium isotopes in addition to that of the uranium.

TABLE 2

RELATIONSHIP BETWEEN A1 AND E MAX FOR BETA EMITTERS

E max (McV)A1(Ci)
> 0.51000
0.5 - > 1.0300
1.0 - > 1.5100
1.5 - > 2.030
>= 2.010

TABLE 3

RELATIONSHIP BETWEEN A3 AND THE ATOMIC NUMBER OF THE RADIONUCLIDE

Atomic Number

Half-life less than 1000 days

A3Half-life days to 104yearsHalf-life greater than 104years
1 to 813 Ci0.05 Ci3 Ci
82 and above0.002 Ci0.002 Ci3 Ci

TABLE 4

ACTIVITY-MASS RELATIONSHIPS FOR URANIUM/THORIUM

Thorium and Uranium Enrichment*wt % U-235 present

Specific Activity

Ci/gg/Ci
0.455.0 × 10-72.0 × 106
0.72 (natural)7.06 × 10-71.42 × 106
1.07.6 × 10-71.3 × 106
1.51.0 × 10-61.0 × 106
5.02.7 × 10-63.7 × 105
10.04.8 × 10-62.1 × 105
20.01.0 × 10-51.0 × 105
35.02.0 × 10-55.0 × 104
50.02.5 × 10-54.0 × 104
90.05.8 × 10-61.7 × 104
93.07.0 × 10-61.4 × 104
95.09.1 × 10-61.1 × 104
Natural Thorium2.2 × 10-74.6 × 106

* The figures for uranium include representative values for the activity of the uranium-234 which is concentrated during the enrichment process. The activity for thorium includes the equilibrium concentration of thorium-228.

Footnotes

* For the purpose of Table 1, compressed gas means a gas at a pressure which exceeds the ambient atmospheric pressure at the location where the containment system was closed.

** The value of A1 and A 2 must be calculated in accordance with the procedure specified in paragraph II 3. of this Appendix, taking into account the activity of the fission products and of the uranium-233 in addition to that of the thorium.

*** The values of A1 and A 2 must be calculated in accordance with the procedure specified in paragraph II 3. of this Appendix, taking into account the activity of the fission products and plutonium isotopes in addition to that of the uranium.

N.Y. Comp. Codes R. & Regs. tit. 12, Appendices, app A-12