D. Monitoring Requirements Note: References for the parameters required in this Section are listed as follows.
EC-electrical conductivity (millimhos/cm for soil, micromhos/cm for water)
SAR-sodium adsorption ratio
ESP-exchangeable sodium percentage (percent)
CEC-cation exchange capacity (milliequivalents/100 gm soil)
TPH-total petroleum hydrocarbons (ppm)
Total benzene (ppm)
TCLP benzene (Toxicity Characteristic Leaching Procedure-ppm)
Total metals as follows:
As-arsenic
Ba-barium
Cd-cadmium
Cr-chromium
Cu-copper
Pb-lead
Hg-mercury
Mo-molybdenum
Ni-nickel
Se-selenium
Ag-silver
Zn-zinc
TDS-total dissolved solids
TSS-total suspended solids
Soluble cations:
Na-sodium
Ca-calcium
Mg-magnesium
Soluble anions:
CO3-carbonate
HCO3-bicarbonate
C1-chloride
SO4-sulfate
1. Prior to the receipt of E and P Waste in a newly permitted and constructed land treatment system or cell, baseline data must be provided by the following sampling and testing program. a. Soil in the treatment zone (0-24") of each cell must be sampled for the following parameters: pH, EC, SAR, ESP, CEC, TPH, As, barium leachate, Cd, Cr, Cu, Pb, Hg, Mo, Ni, Se, Ag, and Zn.b. Groundwater must be sampled and tested for the following parameters: pH, EC, TDS, TSS, TPH, C1, Total Benzene, Na, As, Ba, Cd, Cr, Cu, Pb, Hg, Mo, Ni, Se, Ag, and Zn.c. Water from land treatment cell underdrain systems must be sampled and tested for the following parameters: TDS, pH, Na, Cl, EC, TPH, total benzene, Ba, Pb, Zn, and reactive sulfides.2. The following monitoring program must be conducted during the active life of a permitted E and P Waste land treatment system.a. Soil in the treatment zone (waste treatment zone- WTZ and upper treatment zone- UTZ) must be sampled and tested quarterly to determine E and P Waste degradation and accumulation of metals and hydrocarbons. Samples must be analyzed for the following: As, barium leachate, Cd, Cr, Cu, Pb, Hg, Mo, Ni, Se, Ag, Zn, and TPH.b. Soil in the treatment zone (waste treatment zone-WTZ and upper treatment zone-UTZ) must be sampled and tested quarterly to determine the accumulation of salts and to provide data for determining necessary soil amendments. Samples must be analyzed for the following: pH, EC, SAR, ESP, CEC, soluble cations (Na, Ca, Mg), and soluble anions (CO3, HCO3, C1, SO4).c. Discharge Water. A copy of each discharge monitoring report made in conformance with any applicable state and/or federal regulatory program shall be furnished to the Office of Conservation on a timely basis.d. Land treatment cell underdrain systems must be sampled and tested quarterly to determine the presence of mobile constituents. Sampling and testing shall be performed on a quarterly basis. A composite of at least three samples per management unit (or cell if applicable) are to be analyzed for the following: TDS, pH, Na, Cl, EC, TPH, total benzene, Ba, Pb, Zn and reactive sulfides. If total benzene exceeds an action level of 0.5 ppm, the commissioner may require further assessment and testing as deemed appropriate.e. Groundwater levels in monitor wells shall be measured monthly for a period of two years to determine seasonal fluctuation in water table. Water level shall be measured quarterly each year thereafter.f. Groundwater from monitor wells shall be sampled quarterly to determine the impact of facility operation on groundwater. Prior to obtaining discreet representative samples, each well must be purged in accordance with EPA guidance. A composite of at least two samples per well shall be tested for the following parameters: TDS, TSS, pH, C1, Na, EC, TPH, total benzene, As, Ba, Cr, Pb, and Zn.g. The original hard copy or original electronic copy quarterly monitoring report(s) must be received by the Office of Conservation on or before the dates listed for each quarter as followed: 1st Quarter - due April 30; 2nd Quarter - due July 31; 3rd Quarter - due October 31; 4th Quarter -due January 31. If delivered on an April 30, July 31, October 31 or January 31, the subject report(s) must be received by the Office of Conservation before the close of business, i.e., no later than 4:30 p.m. In the event that April 30, July 31, October 31, or January 31 falls on a Saturday, Sunday, or state holiday, the reporting deadline shall be the following regularly scheduled business day, before the close of business. Each quarterly report must contain the following information: i. the status of each cell at the time of the sampling event (application phase, treatment phase, inactive, etc.), the date(s) sampling took place, and a diagram indicating sample locations for each cell;ii. the amounts and types of E and P Waste applied to each cell during the application phase, including the beginning and ending dates of application;iii. a brief description of treatment activities undertaken to bring each cell into compliance with the criteria of this Section, including the status of fluids (salts) removal from each cell;iv. a compilation (chart) of test results for the present and past three quarterly sampling events;v. copies of current laboratory test data;vi. the size of each land treatment cell (in acres);vii. a compilation (chart) of water depth measurements of monitor well water levels calculated from the top of casing;viii. a potentiometric surface map contoured with water level elevations from mean sea level.h. The Office of Conservation may approve an alternative monitoring program upon receipt of evidence that such procedure shall provide adequate monitoring during the active life of a facility.3. Sampling and Testing Requirements a. A stratified random sampling system shall be used to determine soil sampling locations in land treatment cells. All cells and monitor wells are to be sampled and tested for all parameters unless otherwise approved by the commissioner. Facilities are required to notify the Office of Conservation at least one week in advance of each quarterly sampling event in order for a representative of this office to be present.b. Soil samples in land treatment cells shall be taken in the waste treatment zone (WTZ) and the upper treatment zone (UTZ). Over time, the depth of the treatment zone sampled may need to be increased due to solids buildup on land treatment cells. The degree of E and P Waste incorporation shall be noted at the time of sampling.c. At least two samples must be taken from WTZ and UTZ for each acre of cell area.d. Soil samples are to be analyzed using standard soil testing procedures as presented in the Laboratory Manual for the Analysis of E and P Waste (Department of Natural Resources, August 9, 1988, or latest revision).e. Water samples are to be analyzed for required parameters according to acceptable EPA guidelines and/or the laboratory procedures as presented in the Laboratory Manual for the Analysis of E and P Waste (Department of Natural Resources, August 9, 1988, or latest revision).f. The soil in an inactive cell may not be required to be tested for certain quarterly monitoring parameters only after two consecutive quarterly tests indicate compliance and upon receipt of written approval of this office.