Ill. Admin. Code tit. 8, pt. 259, subpt. E, app E

Current through Register Vol. 48, No. 49, December 6, 2024
Appendix E - Pesticide Organic Carbon Partition Coefficients and Henry's Law Constants

Pesticide Name

CAS No.a

Organic Carbon Partition Coefficients Koc(L/kg)b

Henry's Law Constant H' (unitless)c

acetochlor

34256-82-1

952d

9.14 E-07f

acifluorfen sodium

62476-59-9

113

8.10 E-13

alachlor

15972-60-8

124

1.32 E-06

aldicarb

116-06-3

26

5.07 E-09

aldrin

309-00-2

17500

1.65 E-02

atrazine

1912-24-9

147

1.01 E-07

bentazon sodium

50723-80-3

35

4.63 E-14

bromacil

314-40-9

15h

4.57 E-09

bromoxynil(o)

1689-99-2

190

1.31 E-03

butylate

2008-41-5

304

3.46 E-03

carbofuran

1563-66-2

46

2.10 E-08

chlordane

57-74-9

60000

3.86 E-03

chlorimuron-ethyl

90982-32-4

91h

7.48 E-14

chlorpyrifos

2921-88-2

9930

3.02 E-04

cyanazine

21725-46-2

218

1.34 E-10

2,4-D

94-75-7

48

7.35 E-11

4,4'-DDD

72-54-8

231000

3.64 E-04

4,4'-DDE

72-55-9

883000

4.15 E-03

4,4'-DDT

50-29-3

921000h

3.65 E-04

diazinon

333-41-5

1520

2.90 E-05

dicamba

1918-00-9

13

1.79 E-08

dieldrin

60-57-1

12000

2.65 E-05

dimethoate

60-51-5

20

5.61 E-10

dinoseb

88-85-7

30g

2.44 E-07

disulfoton

298-04-4

1345

6.68 E-05

endosulfan

115-29-7

12400

1.19 E-05

endothall

145-73-3

85

1.56 E-14i

endrin

72-20-8

10000

5.99 E-05

EPTC

759-94-4

223

6.56 E-04

glyphosate

1071-83-6

2100

5.732 -11

HCH-alpha

319-84-6

5440d

3.53 E-04e

heptachlor

76-44-8

24000

1.43 E-01

heptachlor epoxide

1024-57-3

78600d

2.05 E-03e

lindane

58-89-9

1355

7.42 E-05

linuron

330-55-2

496

2.56 E-07

malathion

121-75-5

1200

4.64 E-07

methoxychlor

72-43-5

76000

4.80 E-04i

metolachlor

51218-45-2

70

9.91 E-07

metribuzin

21087-64-9

52

1.48 E-09

parathion, ethyl

56-38-2

7660

9.57 E-06

parathion, methyl

298-00-0

6300

3.88 E-07

pendimethalin

40487-42-1

12400

4.98 E-04

permethrin

52645-53-1

39300

7.68 E-05

phorate

298-02-2

1057

4.07 E-04

simazine

122-34-9

140

3.96 E-08

2,4,5-TP

93-72-1

5440d

2.04 E-06e

terbufos

13071-79-9

650

1.09 E-03

toxaphene

8001-35-2

100000

2.97 E-05

trifluralin

1582-09-8

7200

6.21 E-03

Notes:

a Chemical Abstract Service (CAS).

b Selected values from U.S. Department of Agriculture, Agriculture Research Service, Pesticide Properties Database (PPD), Alternate Crops & Systems Laboratory, Beltsville, Maryland, http://wizard.arsusda.gov/acsl/ppdb3.html, unless otherwise noted.

c H' = KH as atm-m3/mol {vapor pressure x molecular weight / solubility in water} x {R (gas constant) x T (temperature as degrees Kelvin)} = KH x 41 at 25° C. Values from the ARS Pesticide Properties Database (PPD), unless otherwise noted.

d Koc = 10((0.983 x log Kow) + 0.00028), log Kow linear relationship with Koc by Di Toro, 1985 (Technical Background Document, p. 140, incorporated by reference at Section 259.150 ), log Kow values from Syracuse Research Corporation, Physical Properties Database (PHYSPROP), http://esc.syrres.com/interkow/physprop.htm.

e Estimated KH values using data from the SRC Physical Properties Database (PHYSPROP) then converted to H' as noted in c above.

f KH values from the SRC Physical Properties Database (PHYSPROP) then converted to H' as noted in c above.

g Low Koc based on anionic nature (high solubility, low vapor pressure and above pH 5).

h Mean of values listed in ARS Pesticide Properties Database (PPD).

i Estimated using vapor pressure from SRC Physical Properties Database (PHYSPROP).

Ill. Admin. Code tit. 8, pt. 259, subpt. E, app E

Amended at 32 Ill. Reg. 1308, effective January 21, 2008