Ill. Admin. Code tit. 35 § 302.504

Current through Register Vol. 48, No. 45, November 8, 2024
Section 302.504 - Chemical Constituents

The following concentrations of chemical constituents must not be exceeded, except as provided in Sections 302.102 and 302.530:

a) The following standards must be met in all waters of the Lake Michigan Basin. Acute aquatic life standards (AS) must not be exceeded at any time except for those waters for which the Agency has approved a zone of initial dilution (ZID) under Sections 302.102 and 302.530. Chronic aquatic life standards (CS) and human health standards (HHS) must not be exceeded outside of waters in which mixing is allowed under Sections 302.102 and 302.530 by the arithmetic average of at least four consecutive samples collected over at least four days. The samples used to demonstrate compliance with the CS or HHS must be collected in a manner that assures an average representation of the sampling period.

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b) The following water quality standards must not be exceeded at any time in any waters of the Lake Michigan Basin unless a different standard is specified under subsection (c).

Constituent

Unit

Water Quality Standard

Barium (total) 01007

mg/L

5.0

Chloride (total)

mg/L

500

Iron (dissolved)

mg/L

1.0

Phenols

mg/L

0.1

Sulfate

mg/L

500

Total Dissolved Solids

mg/L

1000

c) In addition to the standards specified in subsections (a) and (b), the following standards must not be exceeded at any time in the Open Waters of Lake Michigan as defined in Section 302.501.

Constituent

Unit

Water Quality Standard

Arsenic (total)

µg/L

50.0

Boron (total)

mg/L

1.0

Barium (total)

mg/L

1.0

Chloride (total)

mg/L

12.0

Fluoride (total)

mg/L

1.4

Iron (dissolved)

mg/L

0.30

Lead (total)

µg/L

50.0

Manganese (total)

mg/L

0.15

Nitrate-Nitrogen

mg/L

10.0

Phosphorus

µg/L

7.0

Selenium (total)

µg/L

10.0

Sulfate

mg/L

24.0

Total Dissolved Solids

mg/L

180.0

Oil (hexane solubles or equivalent)

mg/L

0.10

Phenols

µg/L

1.0

d) In addition to the standards specified in subsections (a), (b), and (c), the following human health standards (HHS) must not be exceeded in the Open Waters of Lake Michigan as defined in Section 302.501 by the arithmetic average of at least four consecutive samples collected over at least four days. The samples used to demonstrate compliance with the HHS must be collected in a manner that assures an average representation of the sampling period.

Constituent

Unit

Water Quality Standard

Benzene

µg/L

12.0

Chlorobenzene

µg/L

470.0

2,4-Dimethylphenol

µg/L

450.0

2,4-Dinitrophenol

µg/L

55.0

Hexachloroethane (total)

µg/L

5.30

Lindane

µg/L

0.47

Methylene chloride

µg/L

47.0

Trichloroethylene

µg/L

29.0

e) For the following bioaccumulative chemicals of concern (BCCs), acute aquatic life standards (AS) must not be exceeded at any time in any waters of the Lake Michigan Basin and chronic aquatic life standards (CS), human health standards (HHS), and wildlife standards (WS) must not be exceeded in any waters of the Lake Michigan Basin by the arithmetic average of at least four consecutive samples collected over at least four days subject to the limitations of Sections 302.520 and 302.530. The samples used to demonstrate compliance with the HHS and WS must be collected in a manner that assures an average representation of the sampling period.

Constituent

Unit

AS

CS

HHS

WS

Mercury (total)

ng/L

1,700

910

3.1

1.3

Chlordane

ng/L

NA

NA

0.25

NA

DDT and metabolites

pg/L

NA

NA

150

11.0

Dieldrin

ng/L

240

56

0.0065

NA

Hexachlorobenzene

ng/L

NA

NA

0.45

NA

Lindane

µg/L

0.95

NA

0.5

NA

PCBs (class)

pg/L

NA

NA

26

120

2,3,7,8-TCDD

fg/L

NA

NA

8.6

3.1

Toxaphene

pg/L

NA

NA

68

NA

where:

mg/L

=

milligrams per liter (10-3 grams per liter)

µg/L

=

micrograms per liter (10-6 grams per liter)

ng/L

=

nanograms per liter (10-9 grams per liter)

pg/L

=

picograms per liter (10-12 grams per liter)

fg/L

=

femtograms per liter (10-15 grams per liter)

NA

=

Not Applied

Ill. Admin. Code tit. 35, § 302.504

Amended at 36 Ill. Reg. 18871, effective December 12, 2012

Amended at 47 Ill. Reg. 4437, effective 3/23/2023