(1)Oxides of Sulfur (sulfur dioxide).(a)Primary Ambient Air Quality Standards for Oxides of Sulfur (sulfur dioxide). 1. The level of the primary one hour ambient air quality standard for oxides of sulfur is 75 parts per billion (ppb, which is 1 part in 1,000,000,000), measured in the ambient air as sulfur dioxide (SO2).2. The one hour primary standard is met at an ambient air quality monitoring site when the three-year average of the annual (99th percentile) of the daily maximum one hour average concentrations is less than or equal to 75 ppb, as determined in accordance with 40 CFR Part 50, Appendix T.3. The level of the standard shall be measured by a reference method based on 40 CFR Part 50, Appendix A or A-1 or by a federal equivalent method (FEM) designated in accordance with 40 CFR Part 53.(b)Secondary Ambient Air Quality Standards for Oxides of Sulfur (sulfur dioxide).1. The level of the secondary three-hour ambient air quality standard for oxides of sulfur is 0.5 parts per million (ppm), not to be exceeded more than once per calendar year. The three-hour averages shall be determined from successive non-overlapping three-hour blocks starting at midnight each calendar day and shall be rounded to one decimal place (fractional parts equal to or greater than 0.05 ppm shall be rounded up).2. Oxides of sulfur shall be measured in the ambient air as sulfur dioxide by the reference method described in 40 CFR Part 50, Appendix A or by a federal equivalent method designated in accordance with 40 CFR Part 53.3. To demonstrate attainment, the second-highest three-hour average must be based upon hourly data that are at least 75% complete in each calendar quarter. A three hour block average shall be considered valid only if all three hourly averages for the three hour period are available. If only one or two hourly averages are available, but the three hour average would exceed the level of the standard when zeros are substituted for the missing values, subject to the rounding rule of 310 CMR 6.04(1), then this shall be considered a valid three-hour average. In all cases, the three-hour block average shall be computed as the sum of the hourly averages divided by three.(2)Particulate Matter.(a)Primary and Secondary Ambient Air Quality Standards for PM10:1. The level of the primary and secondary 24-hour ambient air quality standards for particulate matter is 150 micrograms per cubic meter (µg/m3), 24-hour average concentration. The standards are attained when the expected number of days per calendar year with a 24-hour average concentration above 150 µg/m3, as determined in accordance with 40 CFR Part 50, Appendix K is equal to or less than one.2. For the purpose of determining attainment of the primary and secondary standards, particulate matter shall be measured in the ambient air as PM10 (particles with an aerodynamic diameter less than or equal to a nominal 10 micrometers) by:a. A reference method based on 40 CFR Part 50, Appendix J and designated in accordance with 40 CFR Part 53, orb. An equivalent method designated in accordance with 40 CFR Part 53. (b)Primary Ambient Air Quality Standards for PM2.5 : 1. The primary ambient air quality standards for PM2.5 are 12.0 micrograms per cubic meter (µg/m3) annual arithmetic mean concentration and 35 µg/m3 24-hour average concentration measured in the ambient air as PM2.5 (particles with an aerodynamic diameter less than or equal to a nominal 2.5 micrometers) by either: a. A reference method based on 40 CFR Part 50, Appendix L and designated in accordance with 40 CFR Part 53; orb. An equivalent method designated in accordance with 40 CFR Part 53.2. The primary annual PM2.5 standard is met when the annual arithmetic mean concentration, as determined in accordance with 40 CFR Part 50, Appendix N is less than or equal to 12.0 µg/m3.3. The primary 24-hour PM2.5 standard is met when the 98th percentile 24-hour concentration, as determined in accordance with 40 CFR Part 50, Appendix N is less than or equal to 35 µg/m3.(c)Secondary Ambient Air Quality Standards for PM2.5:1. The secondary ambient air quality standards for PM2.5 are 15.0 micrograms per cubic meter (µg/m3) annual arithmetic mean concentration, and 35 µg/m3 24-hour average concentration measured in the ambient air as PM2.5 (particles with an aerodynamic diameter less than or equal to a nominal 2.5 micrometers) by either: a. A reference method based on 40 CFR Part 50, Appendix L and designated in accordance with 40 CFR Part 53; orb. An equivalent method designated in accordance with 40 CFR Part 53.2. The annual secondary PM2.5 standard is met when the annual arithmetic mean concentration, as determined in accordance with 40 CFR Part 50, Appendix N is less than or equal to 15.0 µg/m3.3. The 24-hour secondary PM2.5 standard is met when the 98th percentile 24-hour concentration, as determined in accordance with 40 CFR Part 50, Appendix N is less than or equal to 35 µg/m3.(3)Carbon Monoxide. (a)The primary ambient air quality standards for carbon monoxide are: 1. 9 parts per million (10 milligrams per cubic meter) for an eight-hour average concentration not to be exceeded more than once per year; and2. 35 parts per million (40 milligrams per cubic meter) for a one hour average concentration not to be exceeded more than once per year.(b)The levels of carbon monoxide in the ambient air shall be measured by: 1. A reference method based on 40 CFR Part 50, Appendix C and designated in accordance with 40 CFR Part 53; or2. An equivalent method designated in accordance with 40 CFR Part 53.(c)An eight-hour average shall be considered valid if at least 75% of the hourly average for the eight-hour period are available. In the event that only six (or seven) hourly averages are available, the eight-hour average shall be computed on the basis of the hours available using six (or seven) as the divisor.(d)When summarizing data for comparison with the standards, averages shall be stated to one decimal place. Comparison of the data with the levels of the standards in parts per million shall be made in terms of integers with fractional parts of 0.5 or greater rounding up.(4)Ozone. Primary and Secondary Ambient Air Quality Standards for Ozone: (a) The level of the eight hour primary ambient air quality standard for ozone (O3) is 0.070 parts per million (ppm), daily maximum eight-hour average, measured by a reference method based on 40 CFR Part 50, Appendix D and designated in accordance with 40 CFR Part 53 or an equivalent method designated in accordance with 40 CFR Part 53.(b) The eight-hour primary O3 ambient air quality standard is met at an ambient air quality monitoring site when the three-year average of the annual fourth-highest daily maximum eight-hour average O3 concentration is less than or equal to 0.070 ppm, as determined in accordance with 40 CFR Part 50, Appendix U.(c) The level of the secondary ambient air quality standard for O3 is 0.070 ppm, daily maximum eight-hour average, measured by a reference method based on 40 CFR Part 50, Appendix D and designated in accordance with 40 CFR Part 53 or an equivalent method designated in accordance with 40 CFR Part 53.(d) The eight-hour secondary O3 ambient air quality standard is met at an ambient air quality monitoring site when the three-year average of the annual fourth-highest daily maximum eight-hour average O3 concentration is less than or equal to 0.070 ppm, as determined in accordance with 40 CFR Part 50, Appendix U.(5)Oxides of Nitrogen (nitrogen dioxide). Primary and Secondary Ambient Air Quality Standards for Oxides of Nitrogen:(a) The level of the primary annual ambient air quality standard for oxides of nitrogen is 53 parts per billion (ppb, which is 1 part in 1,000,000,000), annual average concentration, measured in the ambient air as nitrogen dioxide.(b) The level of the primary one hour ambient air quality standard for oxides of nitrogen is 100 ppb, one hour average concentration, measured in the ambient air as nitrogen dioxide.(c) The level of the secondary ambient air quality standard for nitrogen dioxide is 0.053 parts per million (100 micrograms per cubic meter), annual arithmetic mean concentration.(d) The levels of the standards shall be measured by:1. A reference method based on 40 CFR Part 50, Appendix F; or2. By a Federal equivalent method (FEM) designated in accordance with 40 CFR Part 53.(e) The annual primary standard is met when the annual average concentration in a calendar year is less than or equal to 53 ppb, as determined in accordance with 50 CFR Part 50, Appendix S for the annual standard.(f) The one hour primary standard is met when the three-year average of the annual 98th percentile of the daily maximum one hour average concentration is less than or equal to 100 ppb, as determined in accordance with 40 CFR Part 50, Appendix S for the one hour standard.(g) The secondary standard is attained when the annual arithmetic mean concentration in a calendar year is less than or equal to 0.053 ppm, rounded to three decimal places (fractional parts equal to or greater than 0.0005 ppm must be rounded up). To demonstrate attainment, an annual mean must be based upon hourly data that are at least 75% complete or upon data derived from manual methods that are at least 75% complete for the scheduled sampling days in each calendar quarter.(6)Lead.(a) The primary and secondary ambient air quality standards for lead (Pb) and its compounds are 0.15 micrograms per cubic meter, arithmetic mean concentration over a three-month period, measured in the ambient air as Pb either by: 1. A reference method based on 40 CFR Part 50, Appendix G and designated in accordance with 40 CFR Part 53 or;2. An equivalent method designated in accordance with 40 CFR Part 53.(b) The primary and secondary ambient air quality standards for Pb are met when the maximum arithmetic three-month mean concentration for a three-year period, as determined in accordance with 40 CFR Part 50, Appendix R is less than or equal to 0.15 micrograms per cubic meter.Amended by Mass Register Issue 1393, eff. 6/14/2019.Amended by Mass Register Issue 1394, eff. 6/14/2019.