UNITED TECHNOLOGIES CORPORATIONDownload PDFPatent Trials and Appeals BoardOct 28, 20202019005677 (P.T.A.B. Oct. 28, 2020) Copy Citation UNITED STATES PATENT AND TRADEMARK OFFICE UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 14/726,947 06/01/2015 James W Neal 80954US01(15-186) 5237 52237 7590 10/28/2020 Bachman & LaPointe, P.C. 900 Chapel St., Suite 1201 New Haven, CT 06510 EXAMINER KHAN, TAHSEEN ART UNIT PAPER NUMBER 1781 MAIL DATE DELIVERY MODE 10/28/2020 PAPER Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE ____________________ BEFORE THE PATENT TRIAL AND APPEAL BOARD ____________________ Ex parte JAMES W. NEAL, DAVID A. LITTON, KEVIN W. SCHLICHTING, ERIC JORZIK, BRIAN T. HAZEL, and MICHAEL J. MALONEY ____________________ Appeal 2019-005677 Application 14/726,9471 Technology Center 1700 ____________________ Before JAMES C. HOUSEL, MICHELLE N. ANKENBRAND, and JULIA HEANEY, Administrative Patent Judges. HOUSEL, Administrative Patent Judge. DECISION ON APPEAL A. STATEMENT OF THE CASE Appellant filed an appeal under 35 U.S.C. § 134(a) from the Examiner’s final decision rejecting claims 1–8, 15–20, and 22–28.2 We have jurisdiction under 35 U.S.C. § 6(b).3 1 Appellant is the Applicant, United Technologies Corporation, which, according to Appeal Brief, is the real party in interest. Appeal Brief (“Appeal Br.”) 2, filed February 6, 2019. 2 Claim 21 has been withdrawn from consideration. Appeal Br. 4. 3 Our Decision additionally refers to the Specification (“Spec.”) filed June 1, 2015, the Final Office Action (“Final Act.”) dated June 29, 2018, the Examiner’s Answer (“Ans.”) dated May 17, 2019, and the Reply Brief (“Reply Br.”) filed July 17, 2019. Appeal 2019-005677 Application 14/726,947 2 We AFFIRM. The subject matter on appeal relates to coated components and methods of electron beam physical vapor deposition (see, e.g., claims 1 and 15). The Specification discloses that electron beam physical vapor deposition causes a portion of a workpiece within a Line of Sight (LOS) to be coated with a thin layer of material. Spec. ¶ 2. However, some workpieces, such as contemporary airfoil components, have complex geometries that have reduced LOS or Non Line of Sight (NLOS) areas with respect to an electron beam physical vapor deposition process. Id. ¶ 3. To address both LOS and NLOS areas, the Specification discloses a coated component with a coating applied by electron beam physical vapor deposition, wherein the component includes at least one NLOS area and at least one LOS area and the coating defines a ratio greater than about 10% NLOS/LOS. Id. ¶ 4. The Specification further discloses a method of electron beam physical vapor deposition in which a deposition chamber is maintained at a pressure between about 4–20 Pa, a workpiece is positioned within the deposition chamber to define at least one NLOS area and at least one LOS area, and a coating is applied to the workpiece at a ratio greater than about 10% NLOS/LOS. Id. ¶ 18. Independent claims 1 and 15 are illustrative and are reproduced below from the Claims Appendix of the Appeal Brief. 1. A coated component with a coating applied by Electron Beam Physical Vapor Deposition (EB-PVD), comprising: at least one Non Line of Sight (NLOS) area and at least one Line of Sight (LOS) area, a coating on a workpiece defines a thickness ratio greater than about 10% NLOS/LOS such that for every 1 unit of thickness in the LOS area, an at least 0.1 unit of thickness is in the NLOS area. Appeal 2019-005677 Application 14/726,947 3 15. A method of Electron Beam Physical Vapor Deposition, comprising: maintaining a deposition chamber at a pressure between about 4-20 Pa; directing an electron beam at between 40kV -50kV at an ingot within the deposition chamber; and positioning a workpiece with a part manipulator to position a workpiece within the deposition chamber and respect to the ingot to define at least one Non Line of Sight (NLOS) area and at least one Line of Sight (LOS) area, wherein the coating applied to the workpiece is at a thickness ratio greater than about 10% NLOS/LOS. REJECTIONS ON APPEAL The Examiner maintains, and Appellant requests our review of, the following grounds of rejection under 35 U.S.C. § 103: I. Claims 1–8 and 22–26 as unpatentable over Greenberg;4 II. Claims 1–6 and 26 as unpatentable over Hass;5 III. Claims 15–20, 27, and 20 as unpatentable over Greenberg in view of Hazel;6 and IV. Claims 15–17, 20, 27, and 28 as unpatentable over Hass in view of Hazel. B. DISCUSSION Rejection I Claims 1–8 and 22–26 are rejected under 35 U.S.C. § 103 as being unpatentable over Greenberg. 4 Greenberg et al., US 2012/0258256 A1, published Oct. 11, 2012 (“Greenberg”). 5 Hass et al., US 2005/0255242 A1, published Nov. 17, 2005 (“Hass”). 6 Hazel et al., WO 2014/144189 A1, published Sept. 18, 2014 (“Hazel”). Appeal 2019-005677 Application 14/726,947 4 Appellant presents separate arguments for claims 1, 2, 5, 7, and 8. Appeal Br. 9–10. Appellant does not present separate arguments for claims 3, 4, 6, and 22–26. Id. at 18. Therefore, claims 3, 4, 6, and 24–26 stand or fall with claim 1, and claims 22 and 23 stand or fall with claims 7 and 8, respectively. See 37 C.F.R. § 41.37(c)(1)(iv). Claims 1, 3, 4, 6, and 24–26 The Examiner finds that Greenberg discloses a method for applying a coating onto a substrate, such as a workpiece having an NLOS region and an LOS region, via electron beam physical vapor deposition. Ans. 4. With regard to the thickness ratio of claim 1, the Examiner finds that Greenberg discloses a vapor cloud modifier that may be used to thicken a coating on an NLOS area or to reduce the coating on an LOS area and finds Greenberg expresses a desire for a uniform coating. Id. at 4–5. The Examiner further finds that although Greenberg does not explicitly disclose the claimed thickness ratio, Greenberg shows how different ratios can be obtained. Id. at 5. The Examiner concludes that “it would be expected for one of ordinary skill in the art to know how to obtain different thicknesses in respective areas based upon end-user specifications of the product.” Id. Appellant contends that “Greenberg simply does not show how different ratios can be obtained and, in fact, does not even utilize the word ‘ratio.’” Appeal Br. 9. Appellant argues that Greenberg’s vapor cloud modifier “is actually a physical object that disrupts the flow of the vapor cloud which inherently limits how different ratios can be obtained.” Id. at 9–10. Appellant makes similar arguments in its Reply Brief and asserts “[t]he Examiner is apparently relying upon routine optimization,” but “Greenberg does not require only a change of form, proportions, or degree of the substitution of equivalents doing the same thing as the original Appeal 2019-005677 Application 14/726,947 5 invention as apparently argued by the Examiner.” Reply Br. 1–2 (citing In re Williams, 36 F.2d 436, 438 (CCPA 1929)). Appellant’s arguments are unpersuasive. Greenberg discloses that electron beam physical vapor deposition can be used to deposit coatings but the depositing vapor is transported along an LOS during the process and, therefore, such “processes often fail to create uniform coating thicknesses on difficult to coat locations of a substrate, i.e., non-line of sight and limited line of sight areas.” Greenberg ¶ 8. In view of this, Greenberg discloses a method for applying a coating to a substrate to more uniformly coat a product including NLOS areas. Id. ¶ 1. Greenberg’s Figure 1 is reproduced below. Figure 1 is a perspective view of a multi-airfoil vane segment Appeal 2019-005677 Application 14/726,947 6 Figure 1 depicts multi-airfoil vane segment 107 that includes airfoils 12 between inner shroud 14 and outer shroud 16. Id. ¶ 18. Greenberg discloses that a thermal barrier coating (TBC) is coated onto the surfaces of airfoils 12 and inner surfaces 18, 20 of shrouds 14, 16. Id. Greenberg teaches that “shrouds 14 and 16 prevent direct line of sight of the entire part during TBC application” and thus the geometry of the part “results in a non- line of sight area 13 of multi-airfoil vane segment 10.” Id. ¶ 19. Therefore, Greenberg recognizes the problem of insufficient coating of NLOS areas of a workpiece during electron beam physical vapor deposition, including NLOS areas of airfoil workpieces. To address the issue of coating NLOS areas, Greenberg discloses a process that “comprehensively” applies a thermal barrier coating to a workpiece. Id. ¶ 20. In Greenberg’s process, a vapor source introduces vapor cloud 44 toward the LOS regions of a part and a gas is introduced via a plurality of nozzles to cause particle-to-particle collisions that randomize and push vapor cloud 44 toward the workpiece. Id. ¶¶ 20, 28. Greenberg teaches that vapor cloud 44 coats LOS regions in the path of the introduced gas but, “[a]lthough some of the vapor cloud will contact the non-line of sight areas, the thickness of the resultant coating will not be the same as the thickness of the coating applied to the line of sight areas.” Id. ¶ 20. Greenberg’s Figure 3 is reproduced below. 7 Throughout this Decision, for clarity, we present labels to elements in figures in unbolded font, regardless of their presentation in the original document. Appeal 2019-005677 Application 14/726,947 7 Figure 3 depicts Greenberg’s workpiece and vapor cloud modifiers Greenberg further discloses the use of vapor cloud modifier 36 in the process chamber (not depicted in Figure 3), which “is a physical object that disrupts the flow of the vapor cloud” and thus deposition of a coating on the workpiece, such as by thickening the coating on an NLOS area of the workpiece. Id. ¶ 27. Greenberg also discloses the use of flow modifier 46a that directs the flow of vapor cloud 44 to the gap between airfoils 12a and 12b and towards another flow modifier 46b, which in turn redirects flows 44b and 44c to enhance the coating of inner side 50 of airfoil 12a. Id. ¶ 29. According to Greenberg, some of the flow will continue through the gap between airfoils 12a and 12b and contact flow inhibitor 48, which will impede the flow and redirect it back towards outer side 52 of airfoil 12b. Id. Greenberg teaches that as a result of this process, “the application of the coating being deposited by vapor cloud 44 will be more uniformly dispersed on workpiece 32.” Id. Thus, Greenberg also expresses a desire for more uniform coatings. Appeal 2019-005677 Application 14/726,947 8 As Appellant states, the Examiner appears to rely upon routine optimization. Reply Br. 1. “[D]iscovery of an optimum value of a result effective variable in a known process is ordinarily within the skill of the art.” In re Boesch, 617 F.2d 272, 276 (CCPA 1980). Greenberg teaches that vapor cloud modifiers 36, including flow modifiers 46 and flow inhibitor 48, “may be of any dimension so long as the resultant flow of the carrier gas that creates vapor cloud 44 is disrupted to achieve the desire[d] result.” Greenberg ¶ 31. In other words, Greenberg recognizes that the dimensions of flow modifiers 46 and flow inhibitor 48 are variables that can be altered to achieve a desired result (e.g., a uniform coating thickness) in an electron beam physical vapor deposition process. Therefore, in view of Greenberg’s teachings regarding the problem of coating NLOS areas, Greenberg’s desire for a uniform coating, and Greenberg’s process, it would have been obvious to modify the dimensions of Greenberg’s flow modifiers 46 and flow inhibitor 48 by determining workable or optimal dimensions for the flow modifiers 46 and flow inhibitor 48, as a matter of routine experimentation and design within the level of the ordinary skill, to achieve a more uniform coating of NLOS areas and LOS areas of a workpiece. As the Examiner finds, a uniform coating suggests a coating thickness ratio of 1:1 for NLOS and LOS areas. Ans. 4–5. As a result, the routine experimentation to provide the more uniform coating Greenberg desires would result in a coated product that falls within the scope of claim 1 (i.e., “a thickness ratio greater than about 10% NLOS/LOS”). Appellant also presents new arguments for claims 24 and 25 in Appellant’s Reply Brief. Reply Br. 2–3. Appellant has failed to show good cause why these arguments could not have been presented in the Appeal Appeal 2019-005677 Application 14/726,947 9 Brief. Therefore, we will not consider the separate arguments for claims 24 and 25 newly raised in the Reply Brief. 37 C.F.R. § 41.41(b)(2). Claims 2 and 5 Although Appellant argues claims 2 and 5 separately, we address claims 2 and 5 together for purposes of efficiency. Claim 2 depends from claim 1 and requires the thickness ratio of NLOS/LOS area to “between about 10% – 50%,” and claim 5, which also depends from claim 1, requires a coating thickness of “about 5–15 mil . . . at the LOS area and about 4–11 mil . . . at the NLOS area.” Appeal Br. 13. Appellant asserts that Greenberg cannot achieve the limitations of claims 2 and 5. Appeal Br. 10. However, these “separate” arguments amount to no more than a recitation of the additional limitations of the dependent claims and a generic denial that the applied reference teaches or suggests the additional limitations. We and our reviewing court have long held that such “argument” does not merit separate consideration. See, e.g., In re Lovin, 652 F.3d 1349, 1357 (Fed. Cir. 2011) (“[W]e hold that the Board reasonably interpreted Rule 41.37 to require more substantive arguments in an appeal brief than a mere recitation of the claim elements and a naked assertion that the corresponding elements were not found in the prior art.”). Claims 7, 8, 22, and 23 Claim 7 depends from claim 1, and further recites “wherein the LOS area includes a leading edge of an airfoil.” Appeal Br. 14. Claim 22 depends from claim 7. Id. at 15. Claim 8 depends from claim 1, and further recites “wherein the NLOS area includes an area between two airfoils.” Id. at 14. Claim 23 depends from claim 8. Id. at 15. Appeal 2019-005677 Application 14/726,947 10 As an initial matter, we note that claims 7 and 8 are product claims that result from how a workpiece, an airfoil in the case of claims 7 and 8, is positioned within an electron beam physical vapor deposition process chamber relative to the source of coating material and the vapor cloud that is produced from that source. Therefore, the naming of certain areas of a workpiece as LOS areas and others as NLOS areas are artifacts of the process design and would have been an obvious matter of design choice, given the lack of evidence demonstrating a difference in function or unexpected result when different areas of an airfoil product are presented as LOS or NLOS areas, as the Examiner seems to indicate (e.g., as a matter of selecting how a workpiece is positioned within a process chamber). Ans. 11–12. Moreover, Greenberg discloses the limitations of claims 7 and 8. As discussed above, Greenberg discloses NLOS area 13 between airfoils 12 depicted in Greenberg’s Figure 1. Greenberg ¶¶ 19–20. Greenberg’s Figure 3 also depicts the leading edges of airfoils 12a, 12b as facing vapor cloud 44, and thus being in line-of-sight with vapor cloud 44. For these reasons and those set forth in the Examiner’s Answer, we sustain the Examiner’s § 103 rejection of claims 1–8 and 22–26 over Greenberg. Rejection II Claims 1–6 and 26 are rejected as being unpatentable under 35 U.S.C. § 103 over Hass. Final Act. 4–5; Ans. 5–6. Appellant does not address this ground in the Appeal Brief. See Appeal Br. 8. We, therefore, summarily affirm the Examiner’s § 103 rejection of claims 1–6 and 26 over Hass. Appeal 2019-005677 Application 14/726,947 11 Rejection III Claims 15–20, 27, and 28 are rejected as being unpatentable under 35 U.S.C. § 103 over Greenberg in view of Hazel. Appellant argues the claims together as a group. Therefore, we select claim 15 to address Appellant’s arguments and remaining claims 16–20, 27, and 28 stand or fall with claim 15. 37 C.F.R. § 41.37(c)(1)(iv). For the rejection of claim 15, the Examiner repeats many of the findings made with regard to claim 1 above, and also finds that Greenberg discloses a deposition pressure range of 1 x 10-8 to 101 kPa and that this overlaps the pressure range of claim 15. Ans. 6–7 (citing Greenberg ¶ 24).8 The Examiner concludes it would have been obvious to achieve claim 15’s thickness ratio for essentially the same reasons provided in the rejection of claim 1 over Greenberg. Id. at 7–8. The Examiner further finds that Greenberg does not disclose claim 15’s electron beam voltage. Id. at 8. However, the Examiner finds Hazel discloses a deposition process that uses electron beam guns to produce thermal barrier coatings on workpieces that have LOS and NLOS areas and that Hazel discloses a voltage of 20–90 kV. Id. The Examiner concludes it would have been obvious to use Hazel’s electron beam voltage in Greenberg’s process as a suitable voltage for a process in the same field of endeavor. Id. 8 See E.I. DuPont de Nemours & Co. v. Synvina C.V., 904 F.3d 996 (Fed. Cir. 2018) (“[A] prima facie case of obviousness typically exists when the ranges of a claimed composition overlap the ranges disclosed in the prior art.” (quoting In re Peterson, 315 F.3d 1325, 1329 (Fed. Cir. 2003))). Thus, it would have been obvious to determine a workable pressure for Greenberg’s process and arrive at a pressure value that encompasses claim 15’s range as a matter of routine experimentation. Appeal 2019-005677 Application 14/726,947 12 Appellant cites the arguments asserted for the rejection of claim 1 over Greenberg, contending “the vapor cloud modifier of Greenberg is actually a physical object that disrupts the flow of the vapor cloud” and “[t]his defeats the proposed combination with Hazel.” Appeal Br. 10–11. These arguments do not sufficiently explain why Greenberg’s vapor cloud modifier would defeat the Examiner’s proposed modification, which is to use Hazel’s electron beam voltage in Greenberg’s process. In addition, for the reasons discussed above with regard to the rejection of claim 1 over Greenberg, Appellant’s arguments do not identify a reversible error in the Examiner’s proposed modification of Greenberg’s process to arrive at the claimed thickness ratio. For these reasons and those set forth in the Examiner’s Answer, we sustain the Examiner’s § 103 rejection of claims 15–20, 27, and 28 over Greenberg in view of Hazel. Rejection IV Claims 15–17, 20, 27, and 28 are rejected as being unpatentable under 35 U.S.C. § 103 over Hass in view of Hazel. Appellant argues the claims together as a group. Therefore, we select claim 15 to address Appellant’s arguments and remaining claims 16, 17, 20, 27, and 28 stand or fall with claim 15. 37 C.F.R. § 41.37(c)(1)(iv). The Examiner finds that Hass discloses a process of coating NLOS and LOS regions of a substrate via electron beam physical vapor deposition. Ans. 8–9. The Examiner finds that Hass discloses a thickness range of 2–30 microns for a LOS region and a thickness range of 0.2–2 microns for an NLOS region. Id. at 9. The Examiner further finds that Hass discloses adjusting a coating thickness and its degree of uniformity. Id. Appeal 2019-005677 Application 14/726,947 13 The Examiner finds that Hass does not disclose claim 15’s electron beam voltage. Id. at 10. However, the Examiner finds Hazel discloses a deposition process that uses electron beam guns to produce thermal barrier coatings on workpieces that have LOS and NLOS areas and that Hazel discloses a voltage of 20–90 kV. Id. The Examiner concludes it would have been obvious to use Hazel’s electron beam voltage in Hass’s process as a suitable voltage for a process in the same field of endeavor. Id. Appellant argues that Hass discloses altering a pressure ratio used to create a carrier gas jet, but does not disclose or suggest maintaining the claimed deposition chamber pressure. Appeal Br. 11; Reply Br. 3. This argument is unpersuasive because the Examiner cites Hass’s teaching of a 16 Pa chamber pressure. Ans. 8–9, 13; Hass ¶¶ 24–25. Appellant contends that Hass’s thickness range of 0.2 to 2 microns for an NLOS region “is completely outside the 4–11 mil thickness in the NLOS coverage area as recited and claimed by Appellant.” Appeal Br. 11. We note that claim 15 does not recite a specific coating thickness range for an NLOS area, but instead recites a thickness ratio between an NLOS area and an LOS area. The Examiner finds that Hass discloses coating thickness ranges for these two areas that provide thickness ratios that fall within the claimed range. Ans. 8–9. To the extent Appellant is arguing the NLOS thickness range of claim 17, the Examiner also finds that Hass discloses adjusting coating thickness and the degree of coating uniformity. Ans. 9. Based on this teaching, the Examiner concludes it would have been obvious to modify Hass’s coating thickness based on an end-user’s specification. Id. at 9–10, 13. Hass discloses an electron beam vapor deposition process and that altering the pressure ratio and gas velocity of a carrier gas jet changes coating thickness Appeal 2019-005677 Application 14/726,947 14 uniformity between LOS and NLOS areas of a workpiece. Hass ¶¶ 3, 56, 58, 61–63, 71, 73. Therefore, Hass recognizes that the pressure ratio and velocity of a carrier gas jet are variables that affect the uniformity of a coating applied to a workpiece having LOS and NLOS regions. As a result, it would have been a matter of routine experimentation and design within the level of the ordinary skill in the art to determine the workable or optimal pressure ratio and velocity for a carrier gas jet of Hass’s process that provides a more uniform coating of NLOS and LOS workpiece areas. As a result, if an end user desires a uniform coating thickness of 4 or 5 micrometers, which is within the LOS range of 2–30 micrometers suggested in Hass’s paragraph 61, it would have been obvious to optimize Hass’s process to also achieve a similar thickness on NLOS areas to achieve the uniform thickness Hass desires. See Hass ¶ 47. Appellant argues that Hass does not address the NLOS/LOS thickness ratio. Appeal Br. 11–12. This argument is unpersuasive in view of Hass’s thickness range disclosures and desire to achieve a more uniform coating between LOS and NLOS areas of a workpiece. In addition, Appellant asserts a lack of reason to modify Hass in view of Hazel because “Hazel discloses a different voltage range within a different system” and “the Examiner has only selected Hazel to attempt to correct the noted deficiency of Hass without any proper motivation,” and further argues impermissible hindsight. Appeal Br. 12; Reply Br. 3. These arguments are also unpersuasive. The Examiner explains that Hass and Hazel are both directed to electron beam deposition processes for workpieces that have LOS and NLOS areas. Ans. 10, 14. Therefore, the substitution of Hazel’s electron beam voltage in Hass’s process would merely have been the use of a known electron beam voltage to achieve a Appeal 2019-005677 Application 14/726,947 15 predictable result (e.g., produce a coating in an electron beam deposition process). KSR Int’l Co. v. Teleflex Inc., 550 U.S. 398, 416–417 (2007) (The substitution of one known element for another is obvious when the combination yields no more than a predictable result or is the mere application of a known technique to prior art that is ready for improvement). For these reasons and those set forth in the Examiner’s Answer, we sustain the Examiner’s § 103 rejection of claims 15–17, 20, 27, and 28 over Hass in view of Hazel. CONCLUSION Upon consideration of the record and for the reasons set forth above and in the Final Office Action and the Examiner’s Answer, the Examiner’s decision to reject claims 1–8, 15–20, and 22–28 under 35 U.S.C. § 103 is affirmed. In summary: Claims Rejected 35 U.S.C. § References/Basis Affirmed Reversed 1–8, 22–26 103 Greenberg 1–8, 22–26 1–6, 26 103 Hass 1–6, 26 15–20, 27, 28 103 Greenberg, Hazel 15–20, 27, 28 15–17, 20, 27, 28 103 Hass, Hazel 15–17, 20, 27, 28 Overall Outcome 1–8, 15–20, 22–28 Appeal 2019-005677 Application 14/726,947 16 TIME PERIOD FOR RESPONSE No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a). See 37 C.F.R. § 1.136(a)(1)(iv). AFFIRMED Copy with citationCopy as parenthetical citation