MOMENTIVE PERFORMANCE MATERIALS JAPAN LLCDownload PDFPatent Trials and Appeals BoardDec 2, 20202019006968 (P.T.A.B. Dec. 2, 2020) Copy Citation UNITED STATES PATENT AND TRADEMARK OFFICE UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 14/438,447 04/24/2015 Hideo Takahashi 3400.P1486US 1003 23474 7590 12/02/2020 FLYNN THIEL, P.C. 2026 RAMBLING ROAD KALAMAZOO, MI 49008-1631 EXAMINER ZIMMER, MARC S ART UNIT PAPER NUMBER 1765 NOTIFICATION DATE DELIVERY MODE 12/02/2020 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): DOCKET@FLYNNTHIEL.COM PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE ____________ BEFORE THE PATENT TRIAL AND APPEAL BOARD ____________ Ex parte HIDEO TAKAHASHI, HIROYOSHI IIJIMA, and HIDEFUMI TAGAI Appeal 2019-006968 Application 14/438,447 Technology Center 1700 ____________ Before BEVERLY A. FRANKLIN, JEFFREY R. SNAY, and MICHAEL G. McMANUS, Administrative Patent Judges. McMANUS, Administrative Patent Judge. DECISION ON APPEAL Pursuant to 35 U.S.C. § 134(a), Appellant1 seeks review of the Examiner’s decision to reject claims 1–11. We have jurisdiction under 35 U.S.C. § 6(b). We affirm. 1 We use the word “Appellant” to refer to “applicant” as defined in 37 C.F.R. § 1.42. Appellant identifies the real party in interest as Momentive Performance Materials Japan LLC. Appeal Brief dated May 22, 2019 (“Appeal Br.”) 1. Appeal 2019-006968 Application 14/438,447 2 STATEMENT OF THE CASE The present application was filed April 24, 2015 claiming priority to JP2013/079694, filed Nov. 1, 2013. The Examiner issued a non-final rejection on November 4, 2015. On February 4, 2016, Appellant submitted a response to the non-final rejection. On March 16, 2016, the Examiner issued a final rejection. On June 16, 2016, Appellant submitted a response after final action. By advisory action dated July 7, 2016, the Examiner determined that the response after final did not place the application in condition for allowance. A notice of appeal was filed July 15, 2016, followed by an appeal brief dated September 12, 2016. In the Examiner’s answer dated December 2, 2016, the Examiner incorporated the statement of rejection dated November 4, 2015. On March 1, 2018, the Board affirmed the Examiner’s rejection. On May 1, 2018, Appellant submitted additional evidence, argument, and claim amendments in support of patentability. Appellant narrowed limitation (E) of claim 1 from “30 to 3000 ppm of an ionic liquid” to “40 to 2000 ppm of an ionic liquid.” Request for Continued Examination (RCE Amendment) dated May 1, 2018. Appellant additionally added new dependent claim 11. Id. On May 23, 2018, the Examiner issued a non-final rejection. On September 19, 2018, Appellant submitted additional evidence and argument. On November 23, 2018, the Examiner issued a final rejection. Appellant submitted a request for reconsideration dated February 22, 2019. By advisory action dated March 15, 2019, the Examiner determined that the request for reconsideration did not place the application in condition for Appeal 2019-006968 Application 14/438,447 3 allowance. On March 22, 2015 Appellant filed a Notice of Appeal for the presently pending appeal followed by an Appeal Brief dated May 22, 2019. CLAIMED SUBJECT MATTER The present application generally relates to a heat-curable silicone rubber composition exhibiting high transparency and antistatic property. Spec. ¶ 1. Claim 1 is representative of the pending claims and is reproduced below: 1. A heat-curable silicone rubber composition comprising: (A) 100 parts by mass of an organopolysiloxane having an average polymerization degree of 50 to 10000 and containing at least two alkenyl groups bonded to a silicon atom in one molecule; (B) 10 to 400 parts by mass of a silicone resin which includes units selected from a R3SiO1/2 unit as unit M, SiO4/2 unit as unit Q, R2SiO2/2 unit as unit D, and RSiO3/2 unit as unit T, whereas R is a monovalent hydrocarbon group having 1 to 6 carbon atoms and at least two in one molecule are alkenyl groups and in which a sum of the unit M, unit Q and unit T in all of the structural units is 80% by mole or more; (C) an organohydrogenpolysiloxane containing at least two hydrogen atoms bonded to a silicon atom in one molecule, in an amount such that the number of the hydrogen atoms bonded to a silicon atom per one alkenyl group bonded to a silicon atom in the component (A) and the component (B) is 1.0 to 10.0; (D) a hydrosilylation reaction catalyst, and (E) 40 to 2000 ppm of an ionic liquid serving as an antistatic agent, wherein the ionic liquid of the component (E) has a difference in refractive index from the refractive index of a Appeal 2019-006968 Application 14/438,447 4 cured product formed of a base silicone rubber mixture of the components (A), (B), (C) and (D) within a range of ± 0.04. Appeal Br. (Claims App. 1) (reformatted for clarity; emphasis added). REFERENCES The Examiner relies upon the following prior art: Name Reference Date Hardman et al. (“Hardman”) US 4,329,273 May 11, 1982 Lai et al. (“Lai”) US 2005/0038219 A1 Feb. 17, 2005 Mogi US 2009/0062499 A1 Mar. 5, 2009 Iijima et al. (“Iijima”) US 2011/0039991 A1 Feb. 17, 2011 DISCUSSION The Examiner rejects claims 1–11 under pre-AIA 35 U.S.C. § 103(a) as obvious over Iijima in view of Lai and further in view of Hardman and Mogi. Final Office Action dated November 23, 2018 (“Final Act.”) 2–3. The Examiner, however, does not set forth a description of where each claim element is taught by the prior art, nor propose any rationale for combination of the teachings of the references in the November 2018 Office Action. Id. In the Examiner’s Answer dated July 29, 2019 (“Ans.”), the Examiner states that “[e]very ground of rejection set forth in the Office action dated November 4, 2015 from which the appeal is taken is being maintained by the examiner.” Ans. 3. The November 4, 2015 Office Action provides a basis for the rejection of claims 1–10 over the cited references but does not address (later added) claim 11. See November 4, 2015 Office Action 2–5. The Appeal 2019-006968 Application 14/438,447 5 Examiner’s May 23, 2018 Office Action includes some analysis of claim 11. We will interpret that analysis as applicable to the present rejection. In our prior decision, we summarized the November 4, 2015 rejection as follows: [T]he Examiner found that the primary reference, Iijima, teaches each element of claim 1 other than element B, an alkenyl functional silicone resin. [November 4, 2015] Non- Final Act. 3. Iijima further teaches that the composition may include silica as an additive. Iijima ¶¶ 14–15. The Examiner additionally found that Lai and Hardman teach that alkenyl-functional silicone resins (such as those required by element B of claim 1) are functionally equivalent to silica “when employed in the capacity of a reinforcing agent in a hydrosilylation-curable organopolysiloxane.” [November 4, 2015] Non-Final Act. 3. Accordingly, the Examiner determines that it would have been obvious to one of skill in the art to modify the composition of Iijima to include an alkenyl- functional silicone resin as a reinforcing agent/filler rather than silica. Id. at 3–4; [March 16, 2016] Final Act. 4. In re Takahashi, Appeal No. 2017-005025 (PTAB March 1, 2018) 3–4. The Examiner finds that favorable light transmittance properties would be inherent to such a composition. Ans. 5. Claim 11 depends from claim 1 and further specifies the range of components that may satisfy limitations (A) through (D). Appeal Br. (Claims App. 3). The Examiner addresses claim 11 in the May 23, 2018 Non-Final Rejection. In this regard, the Examiner finds as follows: The Examples [from Iijima], for instance, disclose the employment of a dimethylsiloxane/methylvinylsiloxane copolymer for which the end groups are not specified but the broader description contemplates linear polysiloxanes bearing Appeal 2019-006968 Application 14/438,447 6 methyl groups and vinyl groups of which a vinyl-terminated polydimethylsiloxane would be immediately obvious. May 23, 2018 Non-Final Rejection 2–3. The Examiner additionally determines that a difference in the haze and transmittance properties of the composition of the claims relative to the composition of Iijima would not have been surprising to one of ordinary skill in the art. November 23, 2018 Final Rejection 2–3. The Examiner finds that such differences would be expected because the refractive properties of silica particles (which exist as a discontinuous phase) were known to differ from those of silicone resin. May 23, 2018 Non-Final Rejection 3–5. Appellant argues that the rejection should be reversed. Appeal Br. 3– 7. Appellant argues that none of the cited references recognize the need to employ an ionic liquid having a refractive index similar to the remainder of the composition. Id. at 3–5. Appellant further argues that it has proffered data in the Specification showing that the inventive composition exhibits superior haze and transmittance properties relative to the closest prior art (Iijima). Id. at 6. Appellant additionally refers to data submitted in Declarations indicating that compositions including silica (as taught by Iijima) had poor transmittance and haze characteristics. Id. at 6–7 (citing Declarations of Hiroyoshi Iijima dated June 8, 2016 and August 28, 2018). In the Answer, the Examiner contends that Appellant has not offered sufficient evidence to rebut the prima facie case of obviousness. Ans. 5–6. The Examiner asserts that it was well known that differences in refractive index have a negative effect on transmittance and haze. Id. at 6–7. The Examiner further finds that the several of the ionic liquids taught by Iijima Appeal 2019-006968 Application 14/438,447 7 (¶ 19) are enumerated in pending dependent claim 5. Accordingly, the Examiner reasons, they would exhibit the claimed refractive index. Id. at 7. The Examiner further indicates that the degree of transmittance/haze of a composition is affected by the compatibility of the materials and the resulting (lack of) uniformity of the composition. Id. at 8. The Examiner additionally directs us to the Board’s determination in the prior decision that Appellant’s showing is not commensurate in scope with the breadth of the claims. Id. at 10. Analysis A prima facie case of obviousness may be rebutted by evidence of “secondary considerations,” such as “commercial success, long felt but unsolved needs, [and] failure of others.” Graham v. John Deere Co., 383 U.S. 1, 17 (1966). Rebuttal evidence may also include evidence that the claimed invention yields unexpectedly improved properties not present in the prior art. In re Fenn, 639 F.2d 762, 765 (CCPA 1981). When such evidence is submitted, we begin anew and evaluate the rebuttal evidence along with the evidence upon which the conclusion of obviousness was based. In re Rinehart, 531 F.2d 1048, 1052 (CCPA 1976). Unexpected Results The Federal Circuit has held that “[w]hat is important regarding properties that may be inherent, but unknown, is whether they are unexpected. All properties of a composition are inherent in that composition, but unexpected properties may cause what may appear to be an Appeal 2019-006968 Application 14/438,447 8 obvious composition to be nonobvious.” Honeywell Int’l Inc. v. Mexichem Amanco Holding, 865 F.3d 1348, 1355 (Fed. Cir. 2017). Here, Appellant offers declaratory evidence from an inventor that “the heat-curable silicone rubber composition of the present invention has unexpectedly superior properties with respect to transmittance and haze when compared to the comparative compositions which did not use the claimed silicone resin.” Iijima Declaration dated August 28, 2018, 2. The Examiner has consistently maintained that the observed optical properties of the claimed composition are not surprising. See Ans. 5–10; Final Rejection dated November 23, 2018, 2–3; Non-Final Rejection dated May 23, 2018, 3–5. The Examiner makes findings that the three factors that are known to affect light scattering in a composition are i) similarity of refractive indices, ii) compatibility, and iii) particle size. Non-Final Rejection dated May 23, 2018, 4–5. As persons of scientific competence in the fields in which they work, examiners are responsible for making findings, informed by their scientific knowledge, as to the meaning of prior art references to persons of ordinary skill in the art. In re Berg, 320 F.3d 1310, 1315 (Fed. Cir. 2003). Absent legal error or contrary factual evidence, those findings can establish a prima facie case of obviousness. Id. Here, Appellant addresses the Examiner’s findings regarding similarity of refractive indices. Reply Br. 2. Appellant does not, however, squarely address the Examiner’s findings regarding compatibility and particle size. Accordingly, we accept the Examiner’s findings. Appeal 2019-006968 Application 14/438,447 9 As a result, we determine that Appellant has not shown adequate evidence that one of skill in the art would have found the optical properties of the claimed composition to be surprising or unexpected. Commensurate in Scope “It is the established rule that ‘objective evidence of non-obviousness must be commensurate in scope with the claims which the evidence is offered to support.’” Allergan, Inc. v. Apotex Inc., 754 F.3d 952, 965 (Fed. Cir. 2014) (quoting In re Tiffin, 448 F.2d 791, 792 (CCPA 1971)). This is as true for evidence of unexpected results as it is for any other type of objective evidence of non-obviousness. See In re Peterson, 315 F.3d 1325, 1329 (Fed. Cir. 2003) (“the applicant’s showing of unexpected results must be commensurate in scope with the claimed range”); In re Clemens, 622 F.2d 1029, 1035 (CCPA 1980) (“In order to establish unexpected results for a claimed invention, objective evidence of non-obviousness must be commensurate in scope with the claims which the evidence is offered to support.”). Here, claim 1 includes 5 separate limitations (A–E). Appeal Br. (Claims App. 1). Limitation (A) requires, in part, “an organopolysiloxane having an average polymerization degree of 50 to 10000.” Id. The Specification describes the structure of the organopolysiloxanes of limitation (A) as follows: A group bonded to silicon atom other than alkenyl group can include a monovalent hydrocarbon group. Examples of the monovalent hydrocarbon group can include an alkyl group such as methyl, ethyl, propyl or butyl; an aryl group such as phenyl or tryl; a cycloalkyl group such as Appeal 2019-006968 Application 14/438,447 10 cyclohexyl; an aralkyl group such as benzyl or 13-phenylethyl; or chrolomethyl, cyanoethyl or the like in which a part or the whole of hydrogen atoms bonded to carbon atoms of those groups is substituted by a halogen atom (excluding fluorine atom), cyano group and the like, and methyl is preferable. The alkenyl group bonded to silicon atom includes vinyl, allyl, and the like, and vinyl is preferable. Spec. ¶ 8. Appellant offers test results for two organopolysiloxanes having a polymerization degree of 200 and 940. Spec. ¶ 29; Iijima Declaration dated August 28, 2018, 2. Limitation (B) requires, in part, “10 to 400 parts by mass of a silicone resin.” Appeal Br. (Claims App. 1). The Specification describes exemplary silicone resins of limitation (B) as follows: Examples of the silicone resin of the component (B) can include a copolymer of vinyldimethylsiloxy group and the unit Q, a copolymer of vinyldimethylsiloxy group trimethylsiloxy group and the unit Q, a copolymer of vinyldimethylsiloxy group dimethylsiloxane unit and the unit Q, a copolymer of vinyldimethylsiloxy group phenylsilsesquioxane unit and the unit Q, a copolymer of vinyldimethylsiloxy group dimethyl siloxane unit phenylsilsesquioxane unit and the unit Q, a copolymer of trimethylsiloxy group vinylmethylsiloxane unit and the unit Q, and the like. Spec. ¶ 12. Appellant appears to provide test data for a single silicone resin. Id. ¶ 30. The tested compositions described in the Specification and the Iijima Declaration include amounts of silicone resin ranging from 10 parts to 400 parts. Spec. ¶ 38, Tables 1 and 2; Iijima Declaration, dated August 28, 2018, 2. We have not been directed to any tested compositions having a quantity of silicone resin falling outside the claimed range. Appeal 2019-006968 Application 14/438,447 11 Limitation (C) requires organohydrogenpolysiloxane. Appeal Br. (Claims App. 1). The Specification describes the scope of limitation (C) as follows: Examples of the component (C) can include a diorganopolysiloxane blocked with a dimethylhydrogensilyl group, a copolymer of a dimethylsiloxane unit and a methylhydrogensiloxane unit and end trimethylsiloxane unit, a low-viscosity fluid of a dimethylhydrogensiloxane unit and SiO2 unit, 1,3,5,7-tetrahydrogen-1,3,5,7- tetramethylcyclotetrasiloxane, 1-propyl-3,5,7-trihydrogen- 1,3,5,7-tetramethylcyclotetrasiloxane, 1,5-dihydrogen-3,7- dihexyl-1,3,5,7tetramethylcyclotetrasiloxane, and the like. Spec. ¶ 14. Appellant appears to provide test data for a single exemplary organohydrogenpolysiloxane. Id. ¶ 31. Limitation (D) requires a hydrosilylation reaction catalyst in any quantity. Appeal Br. (Claims App. 1). The Specification describes the scope of limitation (D) as follows: A platinum element, a platinum compound, and a platinum complex can be used as the hydrosilylation reaction catalyst as the component (D), and specific examples thereof can include a platinic acid chloride such as platinic primary acid chloride or platinic secondary acid chloride; a platinum--based complex such as a complex of a platinic acid chloride with an alcohol compound, aldehyde compound, ether compound or various olefins; a platinum-vinylsiloxane complex, and the like. The content of the component (D) in the composition is preferably 0.1 to 200 ppm as a platinum atom relative to the component (A), more preferably 1 to 50 ppm. Spec. ¶¶ 16–17. The Specification and Declarations appear to provide test data for a single exemplary catalyst. Id. ¶ 31; Iijima Declaration, dated August 28, 2018. Appeal 2019-006968 Application 14/438,447 12 Limitation (E) requires from “40 to 2000 ppm of an ionic liquid.” Appeal Br. (Claims App. 1). The Specification teaches that “[e]xamples of the anion are an alkyl sulfate-based anion, a tosylate anion, a sulfonate-based anion, bis(trifluoromethanesulfonyl)imide anion, bis(fluorosulfonyl)imide anion, hexafluorophosphate anion, tetrafluoroborate anion, a halide anion, and the like.” Spec. ¶ 20. The Specification teaches additional exemplary ionic liquids. Id. ¶¶ 20–22. The Specification provides test data for a number of different ionic liquids. Spec. ¶ 38, Tables 1 and 2. Most of the ionic liquids are present in an amount of 1000 ppm but Examples 9–12 include an ionic liquid at 50 ppm, 3000 ppm, 700 ppm, and 2700 ppm, respectively. Id. Given the broad scope of limitations (A) through (D) and the limited quantity of testing data in the Specification and Declarations, we cannot conclude that Appellant has supplied evidence of unexpected results that is commensurate with the scope of claim 1. We do not address whether the evidence of unexpected results is commensurate with scope of the dependent claims at this time. In view of the foregoing, we determine that Appellant has not shown that the compositions of claims 1–11 have properties that would have been surprising or unexpected to those of skill in the art. We further determine that Appellant has not proffered evidence of unexpected properties commensurate with the scope of claim 1. We understand Appellant’s arguments to be limited to rebuttal of the prima facie case of obviousness on the basis of criticality. To the extent that Appellant alleges error in the prima facie case, such argument is not Appeal 2019-006968 Application 14/438,447 13 persuasive for the reasons set forth in our prior decision. See In re Herr, 377 F.2d 610, 611–612 (CCPA 1967). CONCLUSION For the reasons set forth in the Office Actions dated November 4, 2015, May 23, 2018, and November 23, 2018, and the Advisory Action dated March 15, 2019, as well as the Examiner’s Answer, the Examiner’s rejection is affirmed. In summary: Claims Rejected 35 U.S.C. § Reference(s)/Basis Affirmed Reversed 1–11 103(a) Iijima, Lai, Hardman, Mogi 1–11 No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a). AFFIRMED Copy with citationCopy as parenthetical citation