Hongfei Jia et al.Download PDFPatent Trials and Appeals BoardAug 29, 201914068291 - (D) (P.T.A.B. Aug. 29, 2019) Copy Citation UNITED STATES PATENT AND TRADEMARK OFFICE UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 14/068,291 10/31/2013 Hongfei Jia TTC13-13802/08 7021 63796 7590 08/29/2019 DINSMORE & SHOHL LLP 900 Wilshire Drive Suite 300 TROY, MI 48084 EXAMINER KEELING, ALEXANDER W ART UNIT PAPER NUMBER 1795 NOTIFICATION DATE DELIVERY MODE 08/29/2019 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): MichiganPatTM@dinsmore.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE ____________ BEFORE THE PATENT TRIAL AND APPEAL BOARD ____________ Ex parte HONGFEI JIA and KENNETH JAMES MCDONALD ____________ Appeal 2018-002074 Application 14/068,291 Technology Center 1700 ____________ Before KAREN M. HASTINGS, MICHAEL P. COLAIANNI, and JANE E. INGLESE, Administrative Patent Judges. INGLESE, Administrative Patent Judge. DECISION ON APPEAL Appellant1 requests our review under 35 U.S.C. § 134(a) of the Examiner’s decision to reject claims 1, 3, and 5–20.2 We have jurisdiction over this appeal under 35 U.S.C. § 6(b). We heard oral arguments from Appellant’s representative on August 20, 2019. We AFFIRM. 1 Appellant is the Applicant, Toyota Motor Engineering & Manufacturing North America, Inc., which, according to the Appeal Brief, is also the real party in interest. Appeal Brief filed November 28, 2016 (“App. Br.”), 2. 2 Non-Final Office Action entered May 13, 2016 (“Office Act”), 1. Appeal 2018-002074 Application 14/068,291 2 STATEMENT OF THE CASE Appellant claims an electrode for electrochemical reduction of carbon dioxide and water to form carbon monoxide and hydrogen. Claim 1 illustrates the subject matter on appeal, and is reproduced below with contested language italicized: 1. An electrode for electrochemical reduction of carbon dioxide and water forming carbon monoxide and hydrogen comprising: a metal substrate formed of a metal having a low carbon monoxide bonding strength, the metal substrate electrochemically reducing carbon dioxide and water; a self-assembled monolayer bonded to the metal substrate wherein the self-assembled monolayer includes an organic ligand having a surface end having a reactive group bonded to the metal substrate and an opposing end including an organic functional group regulating a ratio of reaction products; wherein a selectivity of reaction products of carbon monoxide and hydrogen produced by the electrode is regulated relative to a bare metal substrate. App. Br. 14–16 (Claims Appendix) (emphasis added). Independent claim 9 is essentially identical to claim 1, while independent claim 13, like claim 1, recites an electrode for electrochemical reduction of carbon dioxide and water that comprises a self-assembled monolayer bonded to a metal substrate, in which a selectivity of reaction products of carbon monoxide and hydrogen produced by the electrode is regulated relative to a bare metal substrate. The Examiner maintains the rejection of claims 1, 3, and 5–20 under Appeal 2018-002074 Application 14/068,291 3 35 U.S.C. § 102(a)(1) as anticipated by Love3 as evidenced by Sperling4 (for claims 6 and 18) in the Examiner’s Answer entered October 19, 2017 (“Ans.”). DISCUSSION Upon consideration of the evidence relied upon in this appeal and each of Appellant’s contentions, we affirm the Examiner’s rejection of claims 1, 3, and 5–20 under 35 U.S.C. § 102(a)(1), for the reasons set forth in the Office Action, the Answer, and below. We review appealed rejections for reversible error based on the arguments and evidence the appellant provides for each issue the appellant identifies. 37 C.F.R. § 41.37(c)(1)(iv); Ex parte Frye, 94 USPQ2d 1072, 1075 (BPAI 2010) (precedential) (cited with approval in In re Jung, 637 F.3d 1356, 1365 (Fed. Cir. 2011) (Explaining that even if the Examiner had failed to make a prima facie case, “it has long been the Board’s practice to require an applicant to identify the alleged error in the examiner’s rejections.”)). For purposes of this appeal, we address claims separately to the extent they are so argued by Appellant. 37 C.F.R. § 41.37(c)(1)(iv). Claims 1, 6, 7, 9, 13, 14, 16, 18, and 19 Although Appellant provides separate arguments for independent 3 Love et al., Self-Assembled Monolayers of Thiolates on Metals as a Form of Nanotechnology, American Chemical Society, Vol. 105, 1103–1169 (2005). 4 Sperling et al., Surface modification, functionalization and bioconjugation of colloidal inorganic nanoparticles, Philosophical Transactions of the Royal Society A, Vol. 368, 1333–1383 (2010). Appeal 2018-002074 Application 14/068,291 4 claims 1, 9, and 13, Appellant’s arguments for each of these claims are essentially the same. Compare App. Br. 13–16, with App. Br. 17–20 and 22–24. We accordingly select claim 1 as representative, and decide the appeal as to claims 1, 6, 7, 9, 13, 14, 16, 18, and 19 based on claim 1 alone, keeping in mind that in so doing, we address Appellant’s arguments for claims 9 and 13, by virtue of addressing Appellant’s arguments for claim 1. 37 C.F.R. § 41.37(c)(1)(iv). Love discloses a self-assembled monolayer bound to the surface of a substrate formed of a metal such as gold, silver, palladium, copper, platinum, or mercury. Love pg. 1106. Love discloses that the self- assembled monolayer is comprised of ligands that include a chemical functionality on one end, such as a thiol moiety, having specific affinity for the surface of the metal substrate, and a functional group on the opposite end, such as –OH, –COOH, –CH3, or –NH2. Love pp. 1106, 1123–24, 1145, 1156, Fig. 22. Love discloses that the functional groups on the ligand ends are separated by a carbon chain, and discloses ligands having a carbon chain length of 6, 8, 10, 12, and 14 carbons. Love pp. 1132–1133, Fig. 10. The Examiner finds that because Love discloses a metal substrate- bound self-assembled monolayer having all the structural features of the electrode recited in claim 1, Love’s metal substrate-bound self-assembled monolayer “would be capable of reducing carbon dioxide and water electrochemically” to form carbon monoxide and water, and would be capable of regulating a selectivity of the carbon monoxide and hydrogen reaction products produced by the electrode, as recited in claim 1. Final Act. 4; Ans. 13, 15. The Examiner also finds that in view of the disclosure in Appellant’s Specification that –OH, –COOH, –CH3, or –NH2 organic Appeal 2018-002074 Application 14/068,291 5 functional groups may affect various properties of an electrode as recited in claim 1, and disclosure that the changes in the electrode properties may be utilized to regulate or modify the selectivity and activity of the electrode, the –OH, –COOH, –CH3, or –NH2 functional groups disclosed in Love would be capable of regulating a ratio of reaction products, as recited in claim 1. Ans. 12–13 (citing Spec. ¶ 21). Appellant argues that Love does not disclose “the type of metal used as a substrate, specifically that it is a metal having a low carbon monoxide bonding strength.” App. Br. 13–14. Appellant argues that Love also does not disclose reducing carbon dioxide and water as recited in the preamble of claim 1, which Appellant argues “should be included in the claim limitations.” App. Br. 14–15. Nor does Love disclose, Appellant argues, an organic functional group regulating a ratio of reaction products of carbon monoxide and hydrogen, and does not disclose the ability to selectively produce differing amounts of the reaction products. App. Br. 14–16. Appellant’s arguments are unpersuasive of reversible error in the Examiner’s rejection, however, because the claim recitations at issue are directed to functional language and an intended use, which do not patentably distinguish the claimed electrode from the metal substrate-bound self- assembled monolayer disclosed Love, for reasons that follow. It has long been held that “apparatus claims cover what a device is, not what a device does.” Hewlett-Packard Co. v. Bausch & Lomb Inc., 909 F.2d 1464, 1468 (Fed. Cir. 1990). Nonetheless, a patent applicant is free to claim elements of a device either structurally or functionally, or claim characteristics or properties of elements of a device. In re Swinehart, 439 F.2d 210, 212 (CCPA 1971); In re Schreiber, 128 F.3d 1473, 1478 (Fed. Cir. Appeal 2018-002074 Application 14/068,291 6 1997). But choosing to claim an element of a device functionally—by what the element does rather than what it is—carries a risk, as does claiming an element by its characteristics or properties rather than its structure. Swinehart, 439 F.2d at 212–213 (“[I]t is elementary that the mere recitation of a newly discovered function or property, inherently possessed by things in the prior art, does not cause a claim drawn to those things to distinguish over the prior art.”). Where the Patent Office has reason to believe that claimed and prior art devices are the same or substantially the same, or are produced by the same or substantially the same processes, the Patent Office can require an applicant to prove that the prior art device is not capable of performing a claimed function, or does not possess a claimed characteristic or property. In re Best, 562 F.2d 1252, 1255 (CCPA 1977) (“Where . . . the claimed and prior art products are identical or substantially identical, or are produced by identical or substantially identical processes, the PTO can require an applicant to prove that the prior art products do not necessarily or inherently possess the characteristics of his claimed product. []Whether the rejection is based on ‘inherency’ under 35 U.S.C. § 102, on ‘prima facie obviousness’ under 35 U.S.C. § 103, jointly or alternatively, the burden of proof is the same, and its fairness is evidenced by the PTO’s inability to manufacture products or to obtain and compare prior art products.”). It is also well-established that “a statement of intended use . . . does not qualify or distinguish the structural apparatus claimed over the [prior art] reference.” In re Sinex, 309 F.2d 488, 492 (CCPA 1962); see also Schreiber, 128 F.3d at 1477–79 (“Schreiber’s contention that his structure will be used to dispense popcorn does not have patentable weight if the Appeal 2018-002074 Application 14/068,291 7 structure is already known” and “the Board [correctly] found that the Harz dispenser [for dispensing lubricating oil] would be capable of dispensing popcorn in the manner set forth in claim 1 of Schreiber’s application.”). Although Appellant argues that Love does not disclose “the type of metal used as a substrate, specifically that it is a metal having a low carbon monoxide bonding strength” (App. Br. 14), as discussed above, Love discloses a metal substrate that can be formed of gold, silver, or palladium to which a self-assembled monolayer is bound. Love pg. 1106. Appellant’s Specification indicates that gold, silver, and palladium are metals having a low carbon monoxide bonding strength. Spec. ¶ 18. Consequently, a reasonable basis exists for finding that a metal substrate formed of gold, silver, or palladium as disclosed in Love has a low carbon monoxide bonding strength, and the burden therefore shifts to Appellant to show otherwise. Best, 562 F.2d at 1255. On the record before us, Appellant does not meet this burden because Appellant does not argue, much less provide objective evidence to demonstrate, that a metal substrate formed of gold, silver, or palladium as disclosed in Love does not have a low carbon monoxide bonding strength. App. Br. 13–26. Similarly, although Appellant argues that Love does not disclose reducing carbon dioxide and water to form carbon monoxide and hydrogen reaction products, does not disclose an organic functional group regulating a ratio of such reaction products, and does not disclose the ability to selectively produce differing amounts of carbon monoxide and hydrogen reaction products (App. Br. 14–16), Love discloses all the structural features of the electrode recited in claim 1. In particular, as discussed above, Love discloses a self-assembled monolayer comprised of ligands having thiol Appeal 2018-002074 Application 14/068,291 8 groups on one end that bind to the surface of a substrate, which Love discloses can be gold, silver, or palladium. Love pg. 1106. Love discloses that the ligands can include –OH, –COOH, –CH3, or –NH2 functional groups on the free end opposite the end bound to the substrate, and Love discloses ligands having a carbon chain with a length of 6, 10, 12, or 14 carbons. Love pp. 1123–24, 1132–1133, 1145, 1156, Figs. 10 and 22. In view of these disclosures in Love, one of ordinary skill in the art would “at once envisage” a self-assembled monolayer comprised of organic ligands having a reactive group on one end that bonds to a metal substrate, and an organic functional group on the opposite end of the ligands, as recited in claim 1, in which the metal substrate, reactive group, and organic functional group correspond to those described in Appellant’s Specification as providing the functionality recited in claim 1. Kennametal, Inc. v. Ingersoll Cutting Tool Co., 780 F.3d 1376, 1381 (Fed. Cir. 2015) (“[A] reference can anticipate a claim even if it ‘d[oes] not expressly spell out’ all the limitations arranged or combined as in the claim, if a person of skill in the art, reading the reference, would ‘at once envisage’ the claimed arrangement or combination.”) (alteration in original) (quoting In re Petering, 301 F.2d 676, 681 (CCPA 1962)); see also Blue Calypso, LLC v. Groupon, Inc., 815 F.3d 1331, 1344 (Fed. Cir. 2016) ([A] reference may still anticipate if that reference teaches that the disclosed components or functionalities may be combined and one of skill in the art would be able to implement the combination.”) (citing Kennametal, 780 F.3d at 1383)). More specifically, claim 1 recites a self-assembled monolayer comprised of organic ligands having a reactive group on one end that bonds to a metal substrate, and an organic functional group on the opposite end of Appeal 2018-002074 Application 14/068,291 9 the ligands. Appellant’s Specification discloses that thiol groups as disclosed in Love are suitable reactive groups for bonding organic ligands as recited in claim 1 to a metal substrate, and discloses using gold, silver, and palladium to form a substrate as recited in claim 1, which Love also discloses. Spec. ¶¶ 18, 20. Appellant’s Specification discloses that organic ligands as recited in claim 1 may have from 2 to 20 carbon units, and Love discloses ligands having carbon chains with a length of 6, 10, 12, or 14 carbons. Spec. ¶ 19. Like Love’s disclosure of –OH, –COOH, –CH3, or –NH2 functional groups on the free end of ligands opposite the end bound to a substrate, Appellant’s Specification discloses including –OH, –COOH, – CH3, or –NH2 groups as organic functional groups on the free end of ligands as recited in claim 1, and discloses that such functional groups may affect various properties of an electrode comprised of a metal substrate-bound self- assembled monolayer as recited in claim 1. Spec. ¶¶ 21. Appellant’s Specification further indicates that such changes in the electrode properties may be utilized to regulate or modify the selectivity and activity of the electrode. Id. The Examiner, therefore, has a reasonable basis for finding that a metal substrate-bound self-assembled monolayer as disclosed in Love would be capable of reducing carbon dioxide and water electrochemically to form carbon monoxide and water. Schreiber, 128 F.3d at 1478. The Examiner also has a reasonable basis for finding that the –OH, –COOH, –CH3, or – NH2 functional groups disclosed in Love would be capable of regulating a ratio of the carbon monoxide and hydrogen reaction products produced by Love’s metal substrate-bound self-assembled monolayer. Id. The burden therefore shifts to Appellant to demonstrate otherwise. Best, 562 F.2d at Appeal 2018-002074 Application 14/068,291 10 1255. On the record before us, however, Appellant does not meet this burden because Appellant does not argue, much less provide objective evidence demonstrating, that a metal substrate-bound self-assembled monolayer as disclosed in Love having the structural features recited in claim 1 is not capable of reducing carbon dioxide and water electrochemically to form carbon monoxide and water, and is not capable of regulating a selectivity of such carbon monoxide and hydrogen reaction products. App. Br. 13–26. Nor does Appellant provide objective evidence demonstrating that the –OH, –COOH, –CH3, or –NH2 functional groups of a self-assembled monolayer as disclosed in Love are not capable of regulating a ratio of reaction products. Id. Although Appellant argues that Love also does not disclose reducing carbon dioxide and water as recited in the preamble of claim 1, which Appellant urges “should be included in the claim limitations” (App. Br. 14– 15), the preamble of claim 1 states “an electrode for electrochemical reduction of carbon dioxide and water forming carbon monoxide and hydrogen,” which is an intended use for the claimed electrode. As discussed above, it is well-established that statements of an intended use for a claimed apparatus do not patentably distinguish the claimed apparatus from a prior art apparatus. Sinex, 309 F.2d at 492. Nonetheless, in view of the disclosures of Love discussed above, Appellant does not meet its burden of demonstrating that a metal substrate- bound self-assembled monolayer as disclosed in Love is not capable of electrochemically reducing carbon dioxide and water to form carbon monoxide and hydrogen. Best, 562 F.2d at 1255. We, accordingly, sustain the Examiner’s rejection of independent Appeal 2018-002074 Application 14/068,291 11 claims 1, 9, and 13, and claims 6, 7, 14, 16, 18, and 19, which each depend from either claim 1, 9, or 13, under 35 U.S.C. § 102(a)(1). Claims 3, 10, and 15 Each of claims 3, 10, and 15, which depend from independent claims 1, 9, and 13, respectively, recite that the metal substrate is selected from Au, Ag, Zn, Pd, and Ga. Although Appellant provides separate arguments for claims 3, 10, and 15, Appellant’s arguments for each claim are substantially the same. Compare App. Br. 16–17, with App. Br. 21 and 25. We accordingly address Appellant’s arguments for claim 3, keeping in mind that in so doing, we also address Appellant’s arguments for claims 10 and 15. Appellant argues that although the Examiner relies on Love’s disclosure of a substrate formed of gold, silver, palladium, copper, platinum, or mercury, “[t]his listing of metals does not teach the limitation of a metal having a low carbon monoxide bonding strength and electrochemically reducing carbon dioxide and water” because use of mercury as a substrate results production of formate ion, platinum has a strong CO adsorption and results in production of hydrogen, and copper further reacts with CO to form CH3 and C2H4. App. Br. 16–17. Appellant further argues that “[t]here is no teaching in the Love reference of the metals Zinc and Gallium.” App. Br. 17. It is well-established, however, that a single species disclosed in the prior art that falls within a claimed genus anticipates the claimed genus, regardless of how many additional species are disclosed in the prior art. In re Slayter, 276 F.2d 408, 411 (CCPA 1960) (Explaining that “[i]t is well settled that a generic claim cannot be allowed to an applicant if the prior art Appeal 2018-002074 Application 14/068,291 12 discloses a species falling within the claimed genus.”); In re Sivaramakrishnan, 673 F.2d 1383, 1385 (CCPA 1982) (a prior art reference specifically naming a claimed salt compound as a suitable salt amongst a list of many salts for inclusion in a polycarbonate resin held to anticipate a claim to a composition including the salt and a polycarbonate resin). Although Love may disclose forming the substrate described in the reference of mercury, platinum, or copper, which are not recited in claim 3, Love nonetheless also discloses forming the substrate of gold, silver, or palladium, which are each included in the Markush group recited in the claim. Love pg. 1106. Accordingly, Love’s disclosure of a gold, silver, or palladium substrate anticipates the genus recited in claim 3, regardless of whether Love may not also disclose zinc and gallium. Furthermore, as discussed above, a reasonable basis exists on this appeal record for finding that a metal substrate formed of gold, silver, or palladium as disclosed in Love has a low carbon monoxide bonding strength. The burden therefore shifts to Appellant to show otherwise, which burden Appellant does not meet on the record before us, for reasons discussed above. Best, 562 F.2d at 1255. We accordingly sustain the Examiner’s rejection of claims 3, 10, and 15 under 35 U.S.C. § 102(a)(1). Claims 5, 11, and 17 Each of claims 5, 11, and 17, which depend from independent claims 1, 9, and 13, respectively, recite that the organic ligand has a length of from C2 to C20. Although Appellant provides separate arguments for claims 5, 11, and 17, Appellant’s arguments for each claim are substantially the same. Appeal 2018-002074 Application 14/068,291 13 Compare App. Br. 17, with App. Br. 21–22 and 25–26. We accordingly address Appellant’s arguments for claim 5, keeping in mind that in so doing, we also address Appellant’s arguments for claims 11 and 17. Appellant argues that although the Examiner relies on Love’s disclosure that the ligands forming the self-assembled monolayer described in the reference include a carbon chain having a length of 6, 8, 10, 12, or 14 carbons, “[t]his does not teach the limitations of C2 to C20 lengths as recited in claim 5” because “[t]here is no disclosure of the range including C2–C5 and Cl5–C20 in Love.” App. Br. 17. It is well-established, however, that a prior art disclosure of a specific example falling within a claimed range anticipates the claimed range. Titanium Metals Corp. of America v. Banner, 778 F.2d 775, 782 (Fed. Cir. 1985) (“[W]hen, as by a recitation of ranges or otherwise, a claim covers several compositions, the claim is ‘anticipated’ if one of them is in the prior art.”); In re Petering, 301 F.2d 676, 682 (CCPA 1962). Accordingly, Love’s disclosure of ligands that each have a chain length of 6, 8, 10, 12, or 14 carbons anticipates the organic ligand length range of C2 to C20 recited in claim 5, regardless of whether Love may not disclose ligands having a chain length of 2 to 5 carbons or 15 to 20 carbons. Love pp. 1132–1133, Fig. 10. We, accordingly, sustain the Examiner’s rejection of claims 5, 11, and 17 under 35 U.S.C. § 102(a)(1). Claims 8, 12, and 20 Each of claims 8, 12, and 20, which depend from independent claims 1, 9, and 13, respectively, recite that the organic functional group is selected from CH3, OH, COOH and NH2. Although Appellant provides separate arguments for claims 8, 12, and 20, Appellant’s arguments for each claim Appeal 2018-002074 Application 14/068,291 14 are substantially the same. Compare App. Br. 16, with App. Br. 20 and 24. We accordingly address Appellant’s arguments for claim 8, keeping in mind that in so doing, we also address Appellant’s arguments for claims 12 and 20. As discussed above, Love discloses ligands that have a –OH, –COOH, –CH3, or –NH2 functional group on the free end of the ligands opposite the end bound to a metal substrate. Love pp. 1106, 1123–24, 1145, 1156, Fig. 22. Appellant argues that Love teaches away from use of –OH and –COOH functional groups “for modifying a reaction and does not disclose that use of such functional groups may regulate a ratio of reaction products in a reaction.” App. Br. 16. Appellant argues that Love “only generally refers to NH2 as a polar functional group and does not disclose the use of such functional groups may regulate a ratio of reaction products in a reaction.” Id. Although a showing that the prior art teaches away from a claimed invention may rebut a prima facie case of obviousness, such a showing is irrelevant to anticipation. In re Wiggins, 488 F.2d 538, 543 (CCPA 1973). Furthermore, as discussed above, the Examiner has a reasonable basis for finding that the –OH, –COOH, and –NH2 functional groups disclosed in Love would be capable of regulating a ratio of carbon monoxide and hydrogen reaction products produced by a metal substrate-bound self- assembled monolayer as disclosed in Love. The burden therefore shifts to Appellant to demonstrate otherwise, and on the record before us, Appellant does not meet this burden, for reasons discussed above. Best, 562 F.2d at 1255. We, accordingly, sustain the Examiner’s rejection of claims 8, 12, and Appeal 2018-002074 Application 14/068,291 15 20 under 35 U.S.C. § 102(a)(1). DECISION We affirm the Examiner’s rejection of claims 1, 3, and 5–20 under 35 U.S.C. § 102(a)(1). No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a)(1)(iv). AFFIRMED Copy with citationCopy as parenthetical citation