HALLIBURTON ENERGY SERVICES, INC.Download PDFPatent Trials and Appeals BoardApr 20, 202014906511 - (D) (P.T.A.B. Apr. 20, 2020) Copy Citation UNITED STATES PATENT AND TRADEMARK OFFICE UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 14/906,511 01/20/2016 Mathew Dennis Rowe 2013-IP-069218P1 US 6171 15604 7590 04/20/2020 Baker Botts L.L.P. 910 Louisiana Street, One Shell Plaza Houston, TX 77002 EXAMINER MCCORMACK, JASON L ART UNIT PAPER NUMBER 2881 NOTIFICATION DATE DELIVERY MODE 04/20/2020 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): debie.hernandez@bakerbotts.com susan.stewart@bakerbotts.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE ____________ BEFORE THE PATENT TRIAL AND APPEAL BOARD ____________ Ex parte MATHEW DENNIS ROWE and DAVID KIRKPATRICK MUIRHEAD ____________ Appeal 2019-003703 Application 14/906,511 Technology Center 2800 ____________ Before KAREN M. HASTINGS, DEBRA L. DENNETT, and JANE E. INGLESE, Administrative Patent Judges. INGLESE, Administrative Patent Judge. DECISION ON APPEAL Appellant1 requests our review under 35 U.S.C. § 134(a) of the Examiner’s decision to finally reject claims 1, 3–5, 9–11, 13, 14, and 17– 20.2 We have jurisdiction over this appeal under 35 U.S.C. § 6(b). We REVERSE. 1 We use the word “Appellant” to refer to the “applicant” as defined in 37 C.F.R. § 1.42. Appellant identifies Halliburton Energy Services, Inc. as the real party in interest. Appeal Brief filed January 17, 2019 (“Appeal Br.”) at 2. 2 Final Office Action entered August 13, 2018 (“Final Act.”) at 1. Appeal 2019-003703 Application 14/906,511 2 CLAIMED SUBJECT MATTER Appellant claims a method and system for analyzing drilling fluid used in a drilling operation within a subterranean formation. Appeal Br. 2– 3. Independent claims 1 and 11 illustrate the subject matter on appeal, and are reproduced below: 1. A method for analyzing drilling fluid used in a drilling operation within a subterranean formation, comprising: receiving a drilling fluid sample from a flow of drilling fluid at a surface of the subterranean formation; determining a chemical composition of the drilling fluid sample using a mass spectrometer, wherein determining a chemical composition of the drilling fluid sample further comprises measuring the chemical composition of an extracted gas from the drilling fluid sample and measuring the chemical composition of a liquid portion of the drilling fluid sample; altering the liquid portion of the drilling fluid sample by performing pyrolysis on the liquid portion; and determining a formation characteristic of the subterranean formation using the determined chemical composition wherein determining the formation characteristic using the determined chemical composition comprises comparing the determined chemical composition to known chemical compositions of subterranean formations. 11. A system for analyzing drilling fluid used in a drilling operation within a subterranean formation, comprising: a fluid circulation system positioned at the surface of the subterranean formation and configured to pump a flow of drilling fluid into and receive the flow of drilling fluid from a borehole in the subterranean formation; a drilling fluid analyzer in fluid communication with the fluid circulation system to receive and analyze a drilling fluid sample from the flow of drilling fluid; and an information handling system comprising a processor and a memory device containing a set of instructions that, when executed by the processor, cause the processor to receive an output from the drilling fluid analyzer; Appeal 2019-003703 Application 14/906,511 3 determine a chemical composition of the drilling fluid sample, wherein the drilling fluid analyzer analyzes both an extracted gas from the drilling fluid sample and a liquid portion of the drilling fluid sample; and the set of instructions that causes the processor to determine the chemical composition of the drilling fluid sample further causes the processor to measure the chemical composition of the extracted gas and measure the chemical composition of the liquid portion; wherein the drilling fluid analyzer comprises a sample preparation unit that performs pyrolysis on the liquid portion; and determine a formation characteristic of the subterranean formation based, at least in part, on the determined chemical composition of the drilling fluid sample, wherein the set of instructions that causes the processor to determine the formation characteristic based, at least in part, on the determined chemical composition further causes the processor to compare the determined chemical composition to known chemical compositions of subterranean formations. Appeal Br. 12–14 (Claims Appendix) (emphasis added). REJECTIONS The Examiner maintains the following rejections in the Examiner’s Answer entered March 4, 2019 (“Ans.”): I. Claims 1, 9–11, and 17–20 under 35 U.S.C. § 103 as unpatentable over Pop3 in view of Vinegar;4 II. Claims 3 and 13 under 35 U.S.C. § 103 as unpatentable over Pop in view of Vinegar and Kumar;5 3 Pop et al., US 2007/0137293 A1, published June 21, 2007. 4 Vinegar et al., US 2003/0173072 A1, published September 18, 2003. 5 Kumar, US 2012/0285680 A1, published November 15, 2012. Appeal 2019-003703 Application 14/906,511 4 III. Claims 4 and 14 under 35 U.S.C. § 103 as unpatentable over Pop in view of Vinegar, Kumar, and Evans;6 and IV. Claim 5 under 35 U.S.C. § 103 as unpatentable over Pop in view of Vinegar, Kumar, and Crownover.7 FACTUAL FINDINGS AND ANALYSIS Upon consideration of the evidence relied upon in this appeal and each of Appellant’s contentions, we reverse the Examiner’s rejections of claims 1, 3–5, 9–11, 13, 14, and 17–20 under 35 U.S.C. § 103, for reasons set forth in the Appeal and Reply Briefs, and below. Claim 1 requires the recited method for analyzing drilling fluid used in a drilling operation within a subterranean formation to comprise, in part, receiving a drilling fluid sample from a flow of drilling fluid at a surface of a subterranean formation, and altering a liquid portion of the drilling fluid sample by performing pyrolysis on the liquid portion. Claim 11 requires the recited system for analyzing drilling fluid used in a drilling operation within a subterranean formation to comprise, in part, a fluid circulation system positioned at the surface of a subterranean formation and configured to pump a flow of drilling fluid into, and receive the flow of drilling fluid from, a borehole in the subterranean formation, and a drilling fluid analyzer in fluid communication with the fluid circulation system to receive and analyze a drilling fluid sample from the flow of drilling fluid, the drilling fluid analyzer comprising a sample preparation unit that performs pyrolysis on a liquid portion of the drilling fluid sample. 6 Evans, US 4,287,957, issued September 8, 1981. 7 Crownover, US 4,635,735, issued January 13, 1987. Appeal 2019-003703 Application 14/906,511 5 The Examiner finds that Pop discloses a method and system for analyzing drilling fluid used in a drilling operation within a subterranean formation having all the features recited in claims 1 and 11, except that Pop does not disclose altering a liquid portion of a drilling fluid sample by performing pyrolysis on the liquid portion of the sample. Final Act. 2–4, 6– 8 (citing Pop ¶¶ 19–22). The Examiner finds, however, that Vinegar discloses that liquid hydrocarbons in a formation may be low grade hydrocarbons such as heavy hydrocarbons, and heat from heat sources may mobilize and/or pyrolyze the low grade hydrocarbons. Final Act. 4, 8 (citing Vinegar ¶ 2599). The Examiner finds that Vinegar discloses that “[p]yrolyzation and removal of pyrolyzation products may increase the permeability of the selected section of the formation. The increased permeability may facilitate flow of liquid hydrocarbons originally in the formation towards the production wells.” Final Act. 4, 8 (citing Vinegar ¶ 2598). In view of these disclosures in Vinegar, the Examiner concludes that it would have been obvious to one of ordinary skill in the art at the time of Appellant’s invention to modify Pop’s method and system “with the pyrolyzation step of Vinegar in order to improve the flow of the liquid portion of the sample in Pop [] towards an analysis location, thereby preventing clogging and improving the reliability of measurements in the device by stabilizing flow rate to the analyzer.” Final Act. 5, 8–9. On the record before us, however, the Examiner does not articulate reasoning having rational underpinning that explains why one of ordinary skill in the art would have combined the relied-upon disclosures of Pop and Appeal 2019-003703 Application 14/906,511 6 Vinegar to arrive at the method and system of claims 1 and 11, for reasons expressed by Appellant and discussed below. Pop discloses a method for determining a property of one or more formations surrounding an earth borehole being drilled with a drill bit at the end of a drill string, using drilling fluid that flows downward through the drill string, exits through the drill bit, and returns toward the earth’s surface in an annulus between the drill string and the borehole. Pop ¶ 19. Pop discloses that the method involves obtaining, downhole near the drill bit, a pre-bit sample of the mud in the drill string as it approaches the drill bit, and obtaining, downhole near the drill bit, a post-bit sample of the mud in the annulus, entrained with drilled earth formation, after its egression from the drill bit. Id. Pop discloses performing a first extraction step on the pre-bit and post-bit samples that “comprises extracting, from the sample[s], gases which are present, and volatile hydrocarbon components as a gas.” Pop ¶ 53; Fig. 4. Pop discloses performing “one or more subsequent extraction steps” on the pre-bit and post-bit samples that involve heating the samples to extract volatile components, and extracting non-volatile liquids from the samples by “boiling the liquids off.” Id. Pop discloses performing compositional analysis on the extracted components of the pre-bit and post- bit samples. Pop ¶¶ 21, 54. Vinegar discloses an in situ process for heating a formation containing kerogen and liquid hydrocarbons that involves providing heat from one or more heat sources installed in the formation to a selected section of the formation. Vinegar ¶¶ 41, 42, 2596, 2600. Vinegar discloses that the heat mobilizes liquid hydrocarbons originally present in the selected section of the formation to facilitate flow of the liquid hydrocarbons towards Appeal 2019-003703 Application 14/906,511 7 production wells. Vinegar ¶ 2596. Vinegar discloses that the heat provided to the selected portion of the formation may pyrolyze a portion of kerogen in the formation, and may also pyrolyze low grade hydrocarbons, such as heavy hydrocarbons, within the formation. Vinegar ¶¶ 2596, 2599. Vinegar discloses that pyrolyzation and removal of pyrolyzation products may increase the permeability of the selected section of the formation, which may facilitate the flow of liquid hydrocarbons originally present in the formation towards production wells. Vinegar ¶ 2598. Appellant argues that, absent hindsight, one of ordinary skill in the art would not have been motivated to use Vinegar’s in-situ downhole pyrolysis process in Pop’s method of analyzing a drilling fluid, because Vinegar teaches using pyrolysis to increase the permeability of a formation to facilitate the flow of liquid hydrocarbons originally present in the formation towards production wells. Appeal Br. 8–10. The Examiner responds to Appellant’s arguments in the Answer by asserting that “Pop and Vinegar are each concerned with improving the mobility of hydrocarbons through a formation for extraction.” Ans. 6. The Examiner contends that “Pop specifically references heating to perform ‘extraction,’” and Vinegar explicitly teaches that “[p]yrolyzation and removal of pyrolyzation products may increase the permeability of the selected section of the formation. The increased permeability may facilitate flow of liquid hydrocarbons originally in the formation towards the production wells.” Ans. 6 (citing Pop ¶ 64; Vinegar ¶ 2598). The Examiner determines that “[o]ne of ordinary skill in the art would have recognized the desire for increased mobility of the drilling fluid flow, expressed in Pop, and Appeal 2019-003703 Application 14/906,511 8 would have recognized the teachings of Vinegar as enhancing the mobility of fluid flow.” Ans. 6. Contrary to the Examiner’s assertions, however, as discussed above, Pop discloses obtaining samples from a drill string near a drill bit in a borehole (pre-bit samples), and obtaining samples from an annulus between the drill string and the borehole (post-bit samples). The paragraph of Pop cited by the Examiner in the Answer as expressing a “desire for increased mobility of the drilling fluid flow” (¶ 64) discloses heating the pre-bit and post-bit samples to extract gases, volatile components, and non-volatile liquids from samples. We find no disclosure in this paragraph expressing a “desire for increased mobility of the drilling fluid flow” as the Examiner contends. The Examiner, therefore, does not identify any actual disclosure in Pop that describes or would have suggested improving the mobility of hydrocarbons in a formation for extraction. Consequently, the Examiner’s assertion that Vinegar’s disclosure of heating a formation in situ using heat sources installed in the formation to pyrolyze kerogen and heavy hydrocarbons, and removing the pyrolyzation products, to increase the permeability of the formation to facilitate the flow of liquid hydrocarbons towards production wells, would have led one of ordinary skill in the art to modify Pop’s method and system “with the pyrolyzation step of Vinegar in order to improve the flow of the liquid portion of the sample in Pop [] towards an analysis location” lacks rational underpinning, and appears to be based on hindsight, as Appellant argues. Accordingly, the Examiner does not establish that the combined disclosures of Pop and Vinegar would have suggested receiving a drilling fluid sample from a flow of drilling fluid at a surface of a subterranean Appeal 2019-003703 Application 14/906,511 9 formation, and altering a liquid portion of the drilling fluid sample by performing pyrolysis on the liquid portion, as required by claim 1. Nor does the Examiner establish that that the combined disclosures of Pop and Vinegar would have suggested a fluid circulation system positioned at the surface of a subterranean formation and configured to pump a flow of drilling fluid into, and receive the flow of drilling fluid from, a borehole in the subterranean formation, and a drilling fluid analyzer in fluid communication with the fluid circulation system to receive and analyze a drilling fluid sample from the flow of drilling fluid, the drilling fluid analyzer comprising a sample preparation unit that performs pyrolysis on a liquid portion of the drilling fluid sample, as required by claim 11. We, therefore, do not sustain the Examiner’s rejection of claims 1 and 11, and claims 3–5, 9, 10, 13, 14, and 17–20, which each depend from either claim 1 or claim 11, under 35 U.S.C. § 103. CONCLUSION Claims 35 U.S.C. § Reference(s)/Basis Affirmed Reversed 1, 9–11, 17–20 103 Pop, Vinegar 1, 9–11, 17–20 3, 13 103 Pop, Vinegar, Kumar 3, 13 4, 14 103 Pop, Vinegar, Kumar, Evans 4, 14 5 103 Pop, Vinegar, Kumar, Crownover 5 Overall Outcome 1, 3–5, 9–11, 13, 14, 17–20 REVERSED Copy with citationCopy as parenthetical citation