Franz, CharleneDownload PDFPatent Trials and Appeals BoardAug 6, 202013401216 - (D) (P.T.A.B. Aug. 6, 2020) Copy Citation UNITED STATES PATENT AND TRADEMARK OFFICE UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 13/401,216 02/21/2012 James J. Strohm 17088-G 2414 21567 7590 08/06/2020 Wells St. John P.S. 601 W. Main Avenue Suite 600 Spokane, WA 99201 EXAMINER STEIN, MICHELLE ART UNIT PAPER NUMBER 1771 NOTIFICATION DATE DELIVERY MODE 08/06/2020 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): docketing@wellsip.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte JAMES J. STROHM, JOHN C. LINEHAN, BENJAMIN Q. ROBERTS, DOUGLAS L. MCMAKIN, DAVID M. SHEEN, JEFFREY W. GRIFFIN, and JAMES A. FRANZ Appeal 2019-005870 Application 13/401,216 Technology Center 1700 Before LINDA M. GAUDETTE, FRANCISCO C. PRATS, and LILAN REN, Administrative Patent Judges. GAUDETTE, Administrative Patent Judge. Appeal 2019-005870 Application 13/401,216 2 DECISION ON APPEAL1 The Appellant2 appeals under 35 U.S.C. § 134(a) from the Examiner’s decision finally rejecting claims 58–66 and 68–72.3, 4 We REVERSE. CLAIMED SUBJECT MATTER The invention relates to a method of using microwave (MW) and/or radiofrequency (RF) energies to convert heavy fossil hydrocarbons (HFH) to a variety of value-added chemicals or fuels. Spec. ¶ 3. Claim 58, reproduced below, is illustrative of the claimed subject matter: 58. A method for continuous flash conversion of heavy fossil hydrocarbons (HFH), the method comprising: simultaneously providing both a continuous HFH feed and hydrogen-containing process gas feed to a reaction zone, wherein a mass ratio of the HFH feed to the hydrogen- containing process gas is greater than 3:1; dispersing the HFH feed in the process gas while maintaining a pressure of greater than 0.9 atm within the reaction zone; and concentrating microwave or RF energy in the reaction zone using a microwave or RF energy source to generate 1 This Decision includes citations to the following documents: Specification filed February 21, 2012 (“Spec.”); Appeal Brief filed March 2, 2019 (“Appeal Br.”); Examiner’s Answer dated May 30, 2019 (“Ans.”); and Reply Brief filed July 30, 2019 (“Reply Br.”). 2 We use the word “Appellant” to refer to “applicant” as defined in 37 C.F.R. § 1.42. The Appellant identifies the real party in interest as Battelle Memorial Institute. Appeal Br. 3. 3 We have jurisdiction under 35 U.S.C. § 6(b). 4 The Examiner entered the Appellant’s After-Final Amendment cancelling claim 67, and withdrew the rejection of claim 67 under 35 U.S.C. § 112 as indefinite. See Advisory Action dated December 6, 2018; Ans. 7. Appeal 2019-005870 Application 13/401,216 3 dielectric discharges within the reaction zone to flash convert the HFH. Appeal Br. 16 (Claims App.). REFERENCES The Examiner relies on the following prior art as evidence of unpatentability: Name Reference Date Murphy US 5,328,577 July 12, 1994 Medoff US 2010/0105119 A1 Apr. 29, 2010 REJECTIONS The Examiner states that the prior rejections under 35 U.S.C. § 103(a) have been withdrawn and are replaced by the following new grounds (Ans. 7): 1. Claims 58, 59, 62–66, 68–70, and 72 are rejected under 35 U.S.C. § 103(a) as unpatentable over Murphy. 2. Claims 60, 61, and 71 are rejected under 35 U.S.C. § 103(a) as unpatentable over Murphy in view of Medoff. OPINION Independent claims 58 and 68 recite methods for continuous flash conversion of heavy fossil hydrocarbons (HFH). See Appeal Br. 16, 18 (Claims App.). Independent claim 58 requires that “a mass ratio of the HFH feed to the hydrogen-containing process gas is greater than 3:1.” Independent claim 68 includes a similar limitation. The Specification defines the term “HFH” as referring to “bitumen, coal of any rank (i.e., bituminous, sub-bituminous, lignite, etc.), oil sands (i.e., bitumen containing ores), oil shale, petroleum resids, asphaltenes and pre-asphaltenes, and any other Appeal 2019-005870 Application 13/401,216 4 kerogen-containing materials[,] . . . biomass, plastics, municipal waste, sludge, or other carbon-rich materials.” Spec. ¶ 10. The Specification discloses that “[e]xamples of suitable process gases include, but are not limited to, nitrogen, carbon dioxide, methane, natural gas, recycle gas, carbon monoxide, argon, helium, water vapor, oxygen, and combinations thereof.” Id. ¶ 7. Claims 58 and 68 require that the process gas, or mixture of HFH feed and process gas, contain hydrogen. Murphy is directed to a method of upgrading low value hydrocarbons. Murphy, Abstract. Murphy discloses that “[s]uitable low value hydrocarbons include whole crude as well as any of its fractions . . . . The low value hydrocarbon may be derived from petroleum sources or from shale oil kerogen, tar sands, bitumen processing, synthetic oils, coal hydrogenation, and the like.” Id. at 2:50–58. Murphy discloses that, in addition to the low value hydrocarbon, the feed stream to the reaction zone includes a hydrogen donor. Id. at 1:54–55. Murphy defines “hydrogen donor” as “any chemical species having a donatable hydrogen.” Id. at 2:61–62. Murphy further discloses that “[o]ther gases such as N2 may be present as well.” Id. at 2:66. Murphy teaches that “[t]he amount of hydrogen in the reaction zone during upgrading should be sufficient to maintain a carbon (based on carbon in the molecules in contact with the plasma initiators) to hydrogen weight ratio less than 6:1, . . . most preferably less than 1.5:1.” Murphy 4:42–48. The Examiner determined that although “the claims are drawn to hydrocarbon to hydrogen mass ratios[, it] would have been obvious to the person having ordinary skill in the art to have converted the Murphy carbon to hydrogen ratios by using the molecular weight of hydrocarbon, in order to obtain the ratio of hydrocarbon to hydrogen.” Ans. 4. Appeal 2019-005870 Application 13/401,216 5 The Appellant argues that Murphy discusses ratios of elements within a molecule, which “is wholly different than the ratios of the two reactants (HFH and process gas) presently claimed in the independent claims.” Reply Br. 9. The Appellant argues that “[i]t is unreasonable to expand the C:H molecule suggestions to claims reciting reactant to reactant ratios because there simply is no rational basis to do so.” Id. The Appellant’s argument is persuasive of reversible error in the Examiner’s rejections. The Examiner has not explained persuasively why Murphy’s disclosure of a carbon to hydrogen weight ratio of less than 6:1 suggests formulating an HFH feed to hydrogen-containing process gas mass ratio of greater than 3:1. As explained by the Appellant, [t]he claimed reactants are much more than just hydrocarbon, the HFH feed can include, but is not limited to for example, coal, coal/biomass blends, oil sands, coke, and/or char recycle for example. These materials are not just hydrocarbons; hence they are claimed as HFH feed. It follows that the conversion the Examiner refers to in the Answer would not be obvious to a person having ordinary skill in the art because that conversion would only be accounting for carbon within the HFH feed and not the additional components of the HFH feed. The same is true for the hydrogen-containing process gas reactant; while this can be hydrogen alone, it also can include, but is not limited to for example, nitrogen, carbon dioxide, methane, natural gas, recycle gas, carbon monoxide, argon, helium, water vapor, and/or oxygen. Again, the conversion the Examiner refers to in the Answer would only account for hydrogen and not any of these other components. Reply Br. 14–15. As further pointed out by the Appellant (Reply Br. 8), the claims recite a minimum HFH feed to hydrogen-containing process gas ratio, whereas Murphy suggests decreasing the weight ratio of carbon to hydrogen (Murphy 4:42–52). Appeal 2019-005870 Application 13/401,216 6 Because the Appellant has argued persuasively that the record evidence fails to support the Examiner’s finding that Murphy discloses or suggests the claimed HFH feed to process gas mass ratio, we do not sustain the rejections under 35 U.S.C. § 103(a). DECISION SUMMARY Claims Rejected 35 U.S.C. § Reference(s)/Basis Affirmed Reversed 58, 59, 62–66, 68–70, 72 103(a) Murphy 58, 59, 62–66, 68–70, 72 60, 61, 71 103(a) Murphy, Medoff 60, 61, 71 Overall Outcome: 58–66, 68–72 REVERSED Copy with citationCopy as parenthetical citation