Ex Parte Xue et alDownload PDFPatent Trial and Appeal BoardJul 15, 201310910371 (P.T.A.B. Jul. 15, 2013) Copy Citation UNITED STATES PATENT AND TRADEMARK OFFICE UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 10/910,371 08/04/2004 Jiangeng Xue Y3422-91302 7798 111687 7590 07/15/2013 Duane Morris LLP (UDC) 30 South 17th Street Philadelphia, PA 19103 EXAMINER DICKEY, THOMAS L ART UNIT PAPER NUMBER 2826 MAIL DATE DELIVERY MODE 07/15/2013 PAPER Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE ____________ BEFORE THE PATENT TRIAL AND APPEAL BOARD ____________ Ex parte JIANGENG XUE, SOICHI UCHIDA, BARRY P. RAND, and STEPHEN FORREST ___________ Appeal 2010-011610 Application 10/910,371 Technology Center 2800 ____________ Before JOSEPH F. RUGGIERO, ERIC B. CHEN, and DANIEL N. FISHMAN, Administrative Patent Judges. FISHMAN, Administrative Patent Judge. DECISION ON APPEAL This is an appeal under 35 U.S.C. § 134(a) from the final rejection of claims 1-12, 14-18, 21-23, 32-35, 42, and 43. 1 App. Br. 2. Claim 13 is objected to as dependent on rejected claim but is deemed otherwise 1 Claim 13 was rejected under 35 U.S.C. § 101 and § 112 in the Final Office Action mailed Sept. 25, 2009 from which this appeal was taken. However, the Examiner withdrew the rejections of claim 13 in the Answer leaving claim 13 merely objected to as dependent from rejected claim 1. Ans. 2-3. Appeal 2010-011610 Application 10/910,371 2 allowable. Ans. 2. Claims 19, 20, 24-31, and 36-41 are cancelled. We have jurisdiction under 35 U.S.C. § 6(b). We reverse. STATEMENT OF THE CASE Appellants’ invention relates to a device having a photoactive region disposed between two electrodes. The photoactive region includes a first organic photoactive layer having a thickness not greater than 0.8 characteristic charge transport lengths and a second organic photoactive layer having a thickness not less than about 0.1 optical absorption lengths. See generally Abstract. Claim 1 is illustrative, with disputed limitations in italics: 1. A device for generating photocurrent by absorbing photons, comprising: a first electrode; a second electrode; a photoactive region disposed between the first electrode and the second electrode, the photoactive region further comprising: a first photoactive organic layer for generating excitons by absorbing photons comprising a mixture of a small molecule organic acceptor material and a small molecule organic donor material, wherein the first organic layer has a thickness not greater than 0.8 characteristic charge transport lengths; and a second photoactive organic layer for generating excitons by absorbing photons in direct contact with the first photoactive organic layer, wherein: the second photoactive organic layer comprises an unmixed layer of the small molecule organic acceptor material of the first photoactive organic layer, and the second photoactive organic layer has a thickness not less than about 0.1 optical absorption lengths, Appeal 2010-011610 Application 10/910,371 3 wherein excitons generated by absorption of photons by the first and second photoactive organic layers dissociate into electrons and holes that contribute to the photocurrent. THE REJECTIONS Claims 1-12, 17, 22, 23, 32, 34, 35, and 42 are rejected under 35 U.S.C. § 102(b) as anticipated by Drechsel (High Efficiency Organic Solar Cells Based On Single Or Multiple PIN Structures; Thin Solid Films 451- 453, pp. 515-517 (2004)). Ans. 4-11. Claim 18 is rejected under 35 U.S.C. § 103(a) as unpatentable over Drechsel and Uchida (U.S. Patent No. 5,587,444; issued Dec. 24, 1996). Ans. 11-16. Claims 14-16 and 21 are rejected under 35 U.S.C. § 103(a) as unpatentable over Drechsel and Forrest (U.S. Patent Publication No. 2003/0042846 A1; published Mar. 6, 2003). Ans. 17. Claims 1-12, 14-18, 21-23, 32-35, 42, and 43 are rejected under 35 U.S.C. § 112, first paragraph, as failing to provide enablement commensurate with the scope of the claims. Ans. 17-24. Claims 1-12, 14-18, 21-23, 32-35, 42, and 43 are rejected under 35 U.S.C. § 101 as directed to non-statutory subject matter. Ans. 25-27. THE § 102 REJECTION The Examiner finds that Drechsel teaches all elements of claim 1 and specifically cites Drechsel’s layer labeled “n-C60 30nm” of Figure 3 as showing the recited “second photoactive organic layer.” Ans. 5. Appellants argue that Drechsel fails to show the recited second photoactive organic Appeal 2010-011610 Application 10/910,371 4 layer because the layer of Drechsel relied upon by the Examiner is not “photoactive” as recited in claim 1. App. Br. 15. Issue Has the Examiner erred in finding that Drechsel teaches “a second photoactive organic layer for generating excitons by absorbing photons . . . wherein excitons generated by absorption of photons by the first and second photoactive organic layers dissociate into electrons and holes that contribute to the photocurrent” as recited in claim 1? Analysis We are persuaded by Appellants’ argument that Drechsel fails to show the second layer as recited in claim 1. Appellants contend that the “n-C60” layer relied upon by the Examiner to show the recited second layer is not a photoactive layer as recited in the claim. App. Br. 15. Claim 1 recites “wherein excitons generated by absorption of photons by the first and second photoactive organic layers dissociate into electrons and holes that contribute to the photocurrent.” To meet this limitation, both the recited first and second layers must absorb photons such that they both contribute to the photocurrent of the device. The Examiner and Appellants engage is a detailed technical exchange regarding characteristics of “C60” and “n-C60.” See, e.g., Ans. 30-41; Reply Br. 1-5; Declaration of Co-Inventor Dr. Xue (App. Br. Evidence Appendix). While we have reviewed the detailed positions presented by the Examiner and Appellants regarding various properties of “C60” and “n-C60”, we find that Drechsel explicitly teaches a device having only a single photoactive layer: Appeal 2010-011610 Application 10/910,371 5 We show that the performance of organic solar cells can be strongly improved using PIN structures with doped wide-gap transport layers and a phthalocyanine-fullerene blend as a photoactive layer. Such cells only absorb light in the photoactive region and thus avoid recombination losses at the contacts and make optimum use of the light reflected at the top contact. Drechsel Abstract (emphasis added). Figure 1(a) of Drechsel (reproduced below) shows an abstraction of the “photoactive region” in the device of Drechsel as discussed in the quoted portion of the Abstract: Drechsel Figure 1(a) Showing a Device with a Single “Active Area” The “n-C60” layer relied upon by the Examiner as showing the recited second layer (shown Drechsel Figure 3) corresponds to the “wide-gap n-type electron transport” layer of Drechsel’s Figure 1(a) and is not taught by Drechsel to be an “active” layer that absorbs photons to thereby contribute to the photocurrent as required of the second layer of claim 1. Rather, Drechsel’s Abstract as quoted above makes clear that only the photoactive region (“active areas, absorption” if Figure 1(a)) absorbs light and thus only the single active area (i.e., single photoactive region) contributes to photocurrent—not the “wide-gap n-type electron transport” layer relied upon by the Examiner to teach the recited second photoactive organic layer. We Appeal 2010-011610 Application 10/910,371 6 therefore find that Drechsel does not teach, explicitly or inherently, a second photoactive organic layer that absorbs photons and thereby contributes to the photocurrent as required by claim 1. Whether the recited second layer of claim 1 is obvious in view of Drechsel alone or in combination with other references is not before us on this appeal. 2 In view of the above discussion we are persuaded that the Examiner erred in finding that Drechsel teaches “a second photoactive organic layer for generating excitons by absorbing photons . . . wherein excitons generated by absorption of photons by the first and second photoactive organic layers dissociate into electrons and holes that contribute to the photocurrent” as recited in claim 1. We therefore do not sustain the rejection of claim 1 under § 102 and claims 2-12, 17, 22, 23, 32, 34, 35, and 42 dependent from claim 1 (directly or indirectly). THE § 103 REJECTIONS Claims 14-16, 18, and 21 depend from claim 1 (directly or indirectly) and are rejected as unpatentable over Drechsel in combination with other references. The additional references relied upon in the § 103 rejections are not relied upon by the Examiner to overcome the above deficiencies of 2 The Examiner notes that there is disagreement with Appellants as regards a definition of “photoactive” as required for the second layer recited in claim 1. Ans. 6. The Examiner adopts a broad dictionary definition that photoactive means “[c]apable of responding to light photoelectrically.” Id. Though not an aspect of our decision, we suggest that the Examiner’s definition is unreasonably broad in view of the narrower recitation of claim 1 that specifically requires the first and second photoactive layers absorb photons and thereby contribute to photocurrent of the device. The Specification supports this narrower construction of “photoactive.” See, e.g., Spec. ¶¶ 0029, 0030, 0036, and 0037. Appeal 2010-011610 Application 10/910,371 7 Drechsel with respect to claim 1. Thus, for the same reasons as claim 1, we are persuaded of error in the Examiner’s rejections of claims 14-16, 18, and 21 under § 103 and do not sustain the rejections of claims 14-16, 18, and 21 under § 103. THE § 112 REJECTION The Examiner rejected claims 1-12, 14-18, 21-23, 32-35, 42, and 43 because the Specification “does not reasonably provide enablement for an embodiment including a mixed C60/titanyl phthalocyanine [1:1] first organic layer in a thickness not greater than 0.8 characteristic charge transport lengths.” Ans. 18. The Examiner acknowledges that the Specification is enabling for a device comprising a first layer including a variety of mixed organic acceptor/donor materials. Id. (citing table 1 of the Spec.). Specifically, with regard to the Examiner’s suggested “a mixed C60/titanyl phthalocyanine [1:1] first organic layer”, the Examiner finds: Specifically, the characteristic transport length of a combination of C60 and titanyl phthalocyanine combined in a ratio of 1:1 (C60/TiOPC [1:1] in the nomenclature commonly used to describe the sort of "mixed", "blended", or "bulk heterojunction" layers Appellants claim as their "first photoactive layer") was unknown as of the filing date. Such a combination, in such a ratio, meets the limitations of the claimed "first photoactive layer", but one skilled in the art would have no idea how thick (in measurable units) to build said layer in order to meet claim 1. For this reason the specification does not enable any person skilled in the art to which it pertains, or with which it is most nearly connected, to make the invention commensurate with the full scope of these claims. Ans. 19. Appellants argue that a skilled artisan would know how to determine the characteristic charge transport length of any suitable material Appeal 2010-011610 Application 10/910,371 8 based on the disclosure of the application—specifically based on equation (3) of the Specification as discussed in ¶ 0086. App. Br. 6-13. More specifically, Appellants argue: Moreover, the characteristic charge transport length L is a measurable property for any and all organic acceptor/donor materials as determined by equation (3), As such, a person of ordinary skill in the art can measure 0.8 characteristic charge transport length for any suitable combination of organic acceptor/donor materials, as described in the specification, without the "preknowledge" the Examiner erroneously asserts. Such a measurement can be made prior to assembling the components of Claim 1 using known methods. App. Br. 8. Issue Has the Examiner erred in finding that the Specification fails to enable the skilled artisan to practice the invention without undue experimentation? Analysis We are persuaded that the Examiner erred in finding that the Specification fails to enable the skilled artisan to practice the invention without undue experimentation. Appellants argue that the Specification discloses two methods for determining the characteristic charge transport length (“CTL”) using equation (3) and further argue that the Examiner does not indicate why these methods of the Specification fail to enable the skilled artisan to determine the CTL of organic materials. App. Br. 8-9. We agree. Although the Examiner discusses various factors (the “Wands factors”) that the Examiner asserts indicate that undue experimentation is required (Ans. 21-23), the Examiner’s analysis appears to ignore the specific methods discussed in the Specification that Appellants assert teaches the skilled artisan how to determine the CTL for any material. Rather, the Appeal 2010-011610 Application 10/910,371 9 Examiner “Wands factors” analysis (Ans. 21-23) focuses on a specific mixed organic material (“C60/TiOPc”) that the Examiner finds is not specifically discussed in the Specification and requires undue experimentation to determine the material’s CTL. Appellants acknowledge that their claimed invention is material- independent but argue that the Specification teaches the skilled artisan methods to determine the CTL for any suitable combination of organic acceptor/donor materials. App. Br. 7-8. The Examiner has not shown that the disclosed methods for determining CTL for any suitable combination of organic acceptor/donor materials are incorrect. Appellants’ Specification is not required to specifically recite enabling parameters/values for each possible embodiment (i.e., each species) of the broad claim (i.e., a genus). See, e.g., Utter v. Hiraga, 845 F.2d 993, 998 (Fed. Cir. 1988) (“A specification may, within the meaning of 35 U.S.C. § 112 ¶ 1, contain a written description of a broadly claimed invention without describing all species that claim encompasses.”); see also Manual of Patent Examining Procedures (“MPEP”) § 2164 (“However, to comply with 35 U.S.C. 112, first paragraph, it is not necessary to ‘enable one of ordinary skill in the art to make and use a perfected, commercially viable embodiment absent a claim limitation to that effect.’ CFMT, Inc. v. Yieldup Int’l Corp., 349 F.3d 1333, 1338, 68 USPQ2d 1940, 1944 (Fed. Cir. 2003)”); see also MPEP § 2164.02 (“For a claimed genus, representative examples together with a statement applicable to the genus as a whole will ordinarily be sufficient if one skilled in the art (in view of level of skill, state of the art and the information in the specification) would expect the claimed genus could be used in that manner without undue experimentation”). Appeal 2010-011610 Application 10/910,371 10 In view of the above discussion, we are persuaded of error in the Examiner’s finding that the Specification fails to enable the skilled artisan to practice the invention without undue experimentation. We therefore do not sustain the Examiner’s rejection of claims 1-12, 14-18, 21-23, 32-35, 42, and 43 under § 112. THE § 101 REJECTION The Examiner finds that the claims are directed to non-statutory subject matter because they recite an abstract idea (i.e., equation (3) of the Specification is used by the apparatus of the claims) and finds that claims “cover every practical application of the abstract idea.” Ans. 25-27. Appellants argue that the claims do not recite an abstract idea and thus do not pre-empt all possible applications of the idea. App. Br. 3-6. Issue Does claim 1 recite an abstract idea so as to pre-empt all practical applications of the abstract idea? Analysis We are persuaded by Appellants’ argument that claim 1 does not pre- empt all practical applications of equation (3) of the Specification. Claim 1 recites a specific structure—a device for generating photocurrent comprising two electrodes and a photoactive region disposed between the two electrodes. In other words, claim 1 clearly recites a specific useful application of the idea expressed by equation (3) (for determining the “characteristic charge transport lengths” of any organic material suitable for the recited photoactive application in the structure recited by claim 1). Appeal 2010-011610 Application 10/910,371 11 In view of the above discussion, we are persuaded that the Examiner erred in finding that claim 1 recites an abstract idea so as to pre-empt all practical applications of the idea. DECISION For the reasons discussed above, the Examiner’s decision rejecting claims 1-12, 17, 22, 23, 32, 34, 35, and 42 under 35 U.S.C. § 102(b) is reversed. For the reasons discussed above, the Examiner’s decisions rejecting claims 14-16, 18, and 21 under 35 U.S.C. § 103(a) are reversed. For the reasons discussed above, the Examiner’s decision rejecting claims 1-12, 14-18, 21-23, 32-35, 42, and 43 under 35 U.S.C. § 112, first paragraph, is reversed. For the reasons discussed above, the Examiner’s decision rejecting claims 1-12, 14-18, 21-23, 32-35, 42, and 43 under 35 U.S.C. § 101 is reversed. REVERSED kis Copy with citationCopy as parenthetical citation