Ex Parte Valentine et alDownload PDFBoard of Patent Appeals and InterferencesJun 16, 200911038288 (B.P.A.I. Jun. 16, 2009) Copy Citation UNITED STATES PATENT AND TRADEMARK OFFICE ____________________ BEFORE THE BOARD OF PATENT APPEALS AND INTERFERENCES ____________________ Ex parte JAMES M. VALENTINE and BARRY N. SPRAGUE ____________________ Appeal 2009-001095 Application 11/038,288 Technology Center 3700 ____________________ Decided:1 June 16, 2009 ____________________ Before: JENNIFER D. BAHR, STEVEN D.A. McCARTHY and KEN B. BARRETT, Administrative Patent Judges. McCARTHY, Administrative Patent Judge. DECISION ON APPEAL 1 The two month time period for filing an appeal or commencing a civil action, as recited in 37 C.F.R. § 1.304 (2008), begins to run from the Decided Date shown on this page of the decision. The time period does not run from the Mail Date (paper delivery) or the Notification Date (electronic delivery). Appeal 2009-001095 Application 11/038,288 2 STATEMENT OF THE CASE 1 The Appellants appeal under 35 U.S.C. § 134 (2002) from the final 2 rejection of claims 1-4 and 6-10 under 35 U.S.C. § 103(a) (2002) as being 3 unpatentable over Peter-Hoblyn (US 6,051,040, issued Apr. 18, 2000) and 4 Dettling (US 5,100,632, issued Mar. 31, 1992); from the final rejection of 5 claims 5 and 13 under § 103(a) as being unpatentable over Peter-Hoblyn, 6 Dettling and Schäfer-Sindlinger (US 6,516,611 B1, issued Feb. 11, 2003); 7 and from the final rejection of claims 11 and 12 under § 103(a) as being 8 unpatentable over Peter-Hoblyn, Dettling and Rao (US 4,562,695, issued 9 Jan. 7, 1986).2 An oral hearing was held on June 10, 2009. We have 10 jurisdiction under 35 U.S.C. § 6(b) (2002). 11 We AFFIRM. 12 Claim 1 is typical of the claims on appeal: 13 14 1. A method for reducing particulate 15 emissions from a diesel engine while also 16 2 The Examiner in the Answer states that claims 5 and 13 are rejected under § 103(a) as being unpatentable over Peter-Hoblyn and Schäfer- Sindlinger only; and that claims 11 and 12 are rejected under § 103(a) as being unpatentable over Peter-Hoblyn and Rao only. (Ans. 6 and 7). When articulating the reasoning supporting the rejections, however, the Examiner relies on the “modified Peter-Hoblyn,” that is, the device of Peter-Hoblyn as modified in view of the teachings of Dettling, and cites passages from Dettling. (See id.) Therefore, Dettling is properly included amongst the evidence cited by the Examiner in support of the rejection of claims 5 and 13; and of claims 11 and 12. Since the Appellants’ sole argument directed against the rejection of claims 5 and 13; and against the rejection of claims 11 and 12 is directed against the combination of Peter-Hoblyn and Dettling (see App. Br. 11-12), including Dettling in the evidence relied on in support of the rejections of these claims does not prejudice the Appellants. Appeal 2009-001095 Application 11/038,288 3 controlling emissions of NO2 as a percent of 1 exhaust total nitrogen oxides, comprising: adding 2 a fuel borne catalyst comprising platinum and 3 cerium and/or iron at a total metal concentration of 4 from 2 to 15 ppm in the fuel to a diesel fuel; and 5 passing exhaust produced by the combustion 6 through a diesel particulate filter having substrate 7 with a precious metal catalyst thereon, the catalyst 8 be present on the substrate in an amount of less 9 than 15 grams per cubic foot of substrate. 10 11 ISSUES 12 The Appellants argue the rejections of claims 1-4 and 6-10 under 13 § 103(a) as a group. Independent claim 1 is representative of the group. 37 14 C.F.R. § 41.37(c)(1)(vii) (2007). With respect to the rejection of 15 representative claim 1, the Appellants argue that neither Peter-Hoblyn nor 16 Dettling discloses or suggests controlling emission of NO2 as a percent of 17 exhaust total nitrogen oxides. (App. Br. 7). Following up on this argument, 18 the Appellants contend one of ordinary skill in the art would not have found 19 obvious a method which added a fuel borne catalyst comprising platinum 20 and cerium or iron at a total metal concentration at the low end of the range 21 disclosed in Peter-Hoblyn or which passed diesel exhaust through a 22 particulate filter having a precious metal catalyst present in an amount at the 23 low end of the range disclosed in Dettling. (App. Br. 9-10). Finally, the 24 Appellants contend that the capacity to reduce particulate emissions from a 25 diesel engine while also controlling emissions of NO2 as a percent of 26 exhaust total nitrogen oxides is an unexpected result of the claimed method. 27 (App. Br. 5-6 and 9). 28 Appeal 2009-001095 Application 11/038,288 4 The Appellants argue the rejections of claims 5 and 13; and of claim 1 11 and 12 in separately sub-headed paragraphs of the Appeal Br. (See App. 2 Br. 11-12). In the case of both the rejection of claims 5 and 13; and the 3 rejection of claims 11 and 12, the Appellants refer back to the same 4 arguments directed against the combined teachings of Peter-Hoblyn and 5 Dettling in opposition to the rejection of claims 1-4 and 6-10. Therefore, the 6 Appellants’ contentions in connection with the rejections of claims 5, 11, 12 7 and 13 raise no issues not already raised in connection with the rejections of 8 claims 1-4 and 6-10. 9 This appeal turns on two issues: 10 Have the Appellants shown that the Examiner erred in 11 concluding that the teachings of Peter-Hoblyn and Dettling 12 support a prima facie conclusion of obviousness of the subject 13 matter of representative claim 1? 14 Have the Appellants shown that the Examiner erred in 15 concluding that the evidentiary value of the teachings of Peter-16 Hoblyn and Dettling outweighs the evidentiary value of the 17 working examples in the Specification such that the evidence as 18 a whole supports the conclusion of obviousness of the subject 19 matter of representative claim 1? 20 21 FINDINGS OF FACT 22 The record supports the following findings of fact (“FF”) by a 23 preponderance of the evidence. 24 Appeal 2009-001095 Application 11/038,288 5 1. Peter-Hoblyn discloses a method for improving the operation of 1 a diesel engine with reduced emissions of particulates and nitrogen oxides. 2 (Peter-Hoblyn, col. 4, ll. 38-40). 3 2. Peter-Hoblyn’s method includes the steps of adding a fuel-4 soluble composition to the diesel fuel and passing the combustion gases 5 through a particulate trap to reduce the level of particulates. (Peter-Hoblyn, 6 col. 4, ll. 40-56). 7 3. Peter-Hoblyn’s fuel-soluble composition includes a platinum 8 group metal and a useful salt of a metal such as iron or cerium. (Peter-9 Hoblyn, col. 8, ll. 14-25 and 50-55). 10 4. Peter-Hoblyn discloses adding from about 5 to 100 ppm and 11 preferably 30 to 60 ppm of the catalyst metal in combination with the 12 platinum group metal composition to the diesel fuel. (Peter-Hoblyn, col. 8, 13 ll. 50-55). 14 5. In other words, Peter-Hoblyn teaches adding to a diesel fuel a 15 fuel borne catalyst comprising platinum and cerium or iron at a total metal 16 concentration of from 5 to 100 ppm in the fuel. 17 6. Peter-Hoblyn teaches adding to a diesel fuel a fuel borne 18 catalyst comprising platinum and cerium or iron at a total metal 19 concentration in a range which overlaps the range of 2 to 15 ppm in the fuel 20 recited in claim 1. 21 7. Peter-Hoblyn teaches that the particulate trap may be coated 22 with a catalytic material to facilitate regeneration. (Peter-Hoblyn, col. 7, ll. 23 32-34). 24 Appeal 2009-001095 Application 11/038,288 6 8. Dettling discloses a particulate filter. (Dettling, col. 2, ll. 49-1 54). 2 9. The surfaces of the walls of the filter are coated with a coating 3 or film layer including one or more platinum group metals. (Dettling, col. 2, 4 ll. 49-62 and col. 4, ll. 59-63). 5 10. Platinum group metals are precious metals. (Cf. 16 C.F.R. 6 § 23.0(a) (2008)(listing “precious metals”)). 7 11. The amount of platinum group metal or metals in the coating is 8 about 2 to about 200 g/ft3. (Dettling, col 4, l. 63 – col. 5, l. 3). 9 12. Dettling discloses passing exhaust from the combustion of 10 diesel fuel through a diesel particulate filter having substrate with a precious 11 metal catalyst present on the substrate in an amount of 2 to 200 grams per 12 cubic foot of substrate. 13 13. In other words, Dettling discloses passing exhaust from the 14 combustion of diesel fuel through a diesel particulate filter having substrate 15 with a precious metal catalyst present on the substrate in an amount in a 16 range which overlaps the range of less than 15 grams per cubic foot of 17 substrate recited in claim 1. 18 14. Dettling’s coating serves to lower the temperature at which the 19 collected particulates are ignited during regeneration. (Dettling, col. 2, ll. 20 62-66). 21 15. In Examples 1-4 of the Appellants’ Specification, the 22 Appellants measured and tabulated average emissions for NOx, NO, NO2 23 and particulates obtained by combusting No. 2D diesel fuel or ultra-low 24 sulfur [“ULSD”] diesel fuel with or without fuel-borne catalyst. The 25 Appeal 2009-001095 Application 11/038,288 7 Appellants have not identified any data in Examples 1-4 relating to any test 1 using a diesel fuel formulation to which was added a fuel borne catalyst 2 comprising platinum and cerium or iron at a total metal concentration 3 exceeding 15 ppm in the fuel. The Appellants also have not identified any 4 data in Examples 1-4 relating to any test in which exhaust produced by the 5 combustion of the fuel passed through a diesel particulate filter having a 6 precious metal catalyst present on a substrate of the filter in an amount 7 greater than 15 grams per cubic foot of substrate. 8 16. The Appellants provide no evidence sufficient to show that any 9 superior results obtained in Examples 1-4 would have been unexpected by 10 one of ordinary skill in the art. 11 12 PRINCIPLES OF LAW 13 A claim is unpatentable for obviousness under section 103(a) if “the 14 differences between the subject matter sought to be patented and the prior art 15 are such that the subject matter as a whole would have been obvious at the 16 time the invention was made to a person having ordinary skill in the art to 17 which said subject matter pertains.” Id. In Graham v. John Deere Co., 383 18 U.S. 1 (1966), the Supreme Court set out factual inquiries to be considered 19 in determining whether claimed subject matter would have been obvious: 20 21 Under § 103, the scope and content of the prior art 22 are to be determined; differences between the prior 23 art and the claims at issue are to be ascertained; 24 and the level of ordinary skill in the pertinent art 25 resolved. Against this background, the 26 obviousness or nonobviousness of the subject 27 matter is determined. Such secondary 28 Appeal 2009-001095 Application 11/038,288 8 considerations as commercial success, long felt but 1 unsolved needs, failure of others, etc., might be 2 utilized to give light to the circumstances 3 surrounding the origin of the subject matter sought 4 to be patented. As indicia of obviousness or 5 nonobviousness, these inquiries may have 6 relevancy. 7 8 Id., 383 U.S. at 17-18. 9 In order to reject a claim under section 103(a), an examiner must 10 establish at least a “prima facie” case that the claimed subject matter would 11 have been obvious. Once the examiner produces prima facie evidence that 12 the claimed subject matter would have been obvious, the applicant may 13 present additional evidence tending to rebut the examiner’s conclusion that 14 the claimed subject matter would have been obvious. If the applicant 15 presents additional evidence to rebut the examiner’s conclusion, the 16 examiner must consider all of the evidence anew. If the evidence presented 17 by the examiner and any evidence presented by the applicant, considered 18 anew, demonstrate that the claimed subject matter would have been obvious 19 to one of ordinary skill in the art, the claim is properly rejected under section 20 103(a). In re Piasecki, 745 F.2d 1468, 1472 (Fed. Cir. 1984). “On appeal to 21 the Board, an applicant can overcome a rejection [under § 103(a)] by 22 showing insufficient evidence of prima facie obviousness or by rebutting the 23 prima facie case with evidence of secondary indicia of obviousness.” In re 24 Kahn, 441 F.3d 977, 985-86 (Fed. Cir. 2006)(emphasis omitted). 25 Appeal 2009-001095 Application 11/038,288 9 ANALYSIS 1 Representative claim 1 recites a “method for reducing particulate 2 emissions from a diesel engine while also controlling emissions of NO2 as a 3 percent of exhaust total nitrogen oxides.” Peter-Hoblyn discloses a method 4 for reducing particulate emissions from a diesel engine which includes the 5 steps of adding to a diesel fuel a fuel borne catalyst comprising platinum and 6 cerium and/or iron at a total metal concentration of from 5 to 100 ppm in the 7 fuel; and passing exhaust produced by the combustion of the fuel through a 8 diesel particulate filter having substrate with a catalyst thereon. (FF 2-5). 9 Peter-Hoblyn further teaches coating the diesel particulate filter with a 10 catalytic material to facilitate regeneration (FF 7), that is, burning-off of 11 particulates trapped by the filter 12 Dettling discloses passing exhaust from the combustion of diesel fuel 13 through a diesel particulate filter having substrate with a precious metal 14 catalyst present on the substrate in an amount of 2 to 200 grams per cubic 15 foot of substrate. (FF 8-12). Dettling teaches that the coating serves to 16 lower the temperature at which the collected particulates are ignited during 17 regeneration. (FF 14). The Examiner correctly concludes (see Ans. 4) that 18 it would have been obvious from the teachings of Dettling to coat the diesel 19 particle filter through which the exhaust is passed in the method disclosed by 20 Peter-Hoblyn with a precious metal catalyst present on a substrate of the 21 filter in an amount of 2 to 200 g/ft3 in order to lower the temperature at 22 which the particles collected by the filter ignite and incinerate. 23 The use of the word “for” in the preamble of representative claim 1 24 indicates that reducing particulate emissions and controlling emissions of 25 Appeal 2009-001095 Application 11/038,288 10 NO2 as a percent of exhaust total nitrogen oxides are properties or benefits 1 of the claimed method and not method steps limiting the scope of the claim. 2 Even assuming for purposes of this appeal only that that neither Peter-3 Hoblyn nor Dettling discloses or suggests controlling emission of NO2 as a 4 percent of exhaust total nitrogen oxides as recited in the preamble of claim 5 1, this deficiency would not establish the patentability of claim 1. See In re 6 Woodruff, 919 F.2d 1575, 1578 (Fed. Cir. 1990). 7 The Appellants contend that one of ordinary skill in the art would not 8 have found obvious a method which added a fuel borne catalyst comprising 9 platinum and cerium or iron at a total metal concentration at the low end of 10 the range disclosed in Peter-Hoblyn or which passed diesel exhaust through 11 a particulate filter having a precious metal catalyst present in an amount at 12 the low end of the range disclosed in Dettling. (App. Br. 9-10). Our 13 reviewing court has established that “even a slight overlap in range 14 establishes a prima facie case of obviousness.” In re Peterson, 313 F.3d 15 1325, 1329 (Fed. Cir. 2003)(emphasis omitted); see also In re Woodruff, 919 16 F.2d 1575, 1577-78 (Fed. Cir. 1990). 17 It would have been obvious from the combined teachings of Peter-18 Hoblyn and Dettling to have added to a diesel fuel a fuel borne catalyst 19 comprising platinum and cerium or iron at a total metal concentration in a 20 range overlapping the range of 2 to 15 ppm in the fuel recited in claim 1. 21 (See FF 6). It also would have been obvious from the combined teachings of 22 Peter-Hoblyn and Dettling to have passed exhaust produced by the 23 combustion of the fuel through a diesel particulate filter having substrate 24 with a precious metal catalyst thereon, the catalyst being present on the 25 Appeal 2009-001095 Application 11/038,288 11 substrate in an amount in a range overlapping the range of less than 15 1 grams per cubic foot of substrate recited in claim 1. (See FF 13). Therefore, 2 the subject matter of claim 1 would have been prima facie obvious. 3 The Appellants advance comparative data in the Specification as 4 objective evidence tending to prove a secondary indicium of 5 nonobviousness, namely, unexpected results. (See App. Br. 5-6 and 10). 6 When an Appellant advances objective evidence in rebuttal of obviousness, 7 the evidence as a whole must be considered anew. See, e.g., In re Eli Lilly & 8 Co., 902 F.2d 943, 945 (Fed. Cir. 1990); see also In re Soni, 54 F.3d 746, 9 750 (Fed. Cir. 1995)(“[T]he PTO must consider comparative data in the 10 specification in determining whether the claimed invention provides 11 unexpected results.”). The Appellant provides no evidence in the form of 12 declarations (see App. Br. 16) and we give no weight to unsupported 13 allegations of fact made in the Appeal Brief or at oral argument, In re 14 Geisler, 116 F.3d 1465, 1470 (Fed. Cir. 1997). Objective evidence of 15 secondary indicia of nonobviousness may be entitled to more or less weight 16 in any given case depending on the nature of the objective evidence and the 17 relationship of the objective evidence with the merits of the invention. 18 Stratoflex Inc. v. Aeroquip Corp., 713 F.2d 1530, 1539 (Fed. Cir. 1983). 19 Objective evidence, “to be effective, must compare the claimed 20 subject matter with the closest prior art.” In re Burckel, 592 F.2d 1175, 21 1179 (CCPA 1979). The Appellants contend one of ordinary skill in the art 22 would not have found obvious a method which added a fuel borne catalyst 23 comprising platinum and cerium or iron at a total metal concentration at the 24 low end of the range disclosed in Peter-Hoblyn or which passed diesel 25 Appeal 2009-001095 Application 11/038,288 12 exhaust through a particulate filter having a precious metal catalyst present 1 in an amount at the low end of the range disclosed in Dettling. (App. Br. 9-2 10). Despite this, the Appellants have not identified any data in Examples 1-3 4 relating to any test using a diesel fuel formulation to which was added a 4 fuel borne catalyst comprising platinum and cerium or iron at a total metal 5 concentration exceeding 15 ppm in the fuel. The Appellants also have not 6 identified any data in Examples 1-4 relating to any test in which exhaust 7 produced by the combustion of the fuel passed through a diesel particulate 8 filter having a precious metal catalyst present on a substrate of the filter in 9 an amount greater than 15 grams per cubic foot of substrate. (FF 15). The 10 comparative data provided by the Appellants in Examples 1-4 is entitled to 11 little weight in determining whether the Examiner erred in reaching the 12 conclusion of obviousness because Examples 1-4 do not compare the subject 13 matter of representative claim 1 with Peter-Hoblyn and Dettling. 14 Apart from this, the Appellants failed to introduce any evidence that 15 any superior results attributable to the claimed method would not have been 16 expected by one of ordinary skill in the art. (See FF 16). This failure 17 provides an additional reason why the comparative data provided by the 18 Appellants in Examples 1-4 is entitled to little weight in determining 19 whether the Examiner erred in reaching the conclusion of obviousness. See 20 Geisler, 116 F.3d at 1470. 21 Weighing the probative value of the comparative data provided by the 22 Appellants in Examples 1-4 anew against the probative value of the 23 teachings of Peter-Hoblyn and Dettling, the evidence of obviousness on 24 Appeal 2009-001095 Application 11/038,288 13 which the Examiner relies outweighs the objective evidence identified by the 1 Appellants. 2 3 CONCLUSIONS 4 The Appellants have not shown that the Examiner erred in concluding 5 that the teachings of Peter-Hoblyn and Dettling support a prima facie 6 conclusion of obviousness of the subject matter of representative claim 1. 7 The Appellants have not shown that the Examiner erred in concluding 8 that the evidentiary value of the teachings of Peter-Hoblyn and Dettling 9 outweighs the evidentiary value of the working examples in the 10 Specification such that the evidence as a whole supports the conclusion of 11 obviousness of the subject matter of representative claim 1. 12 Therefore, the Appellants have not shown that the Examiner erred in 13 rejecting claims 1-4 and 6-10 under § 103(a) as being unpatentable over 14 Peter-Hoblyn and Dettling. Since the Appellants only contest the rejections 15 of claims 5 and 13 by referring back to the same arguments directed against 16 the combined teachings of Peter-Hoblyn and Dettling in opposition to the 17 rejection of claims 1-4 and 6-10, the Appellants have not shown that the 18 Examiner erred in rejecting claims 5 and 13 under § 103(a) as being 19 unpatentable over Peter-Hoblyn, Dettling and Schäfer-Sindlinger. Since the 20 Appellants only contest the rejections of claims 11 and 12 by referring back 21 to the same arguments directed against the combined teachings of Peter-22 Hoblyn and Dettling in opposition to the rejection of claims 1-4 and 6-10, 23 the Appellants have not shown that the Examiner erred in rejecting claims 24 Appeal 2009-001095 Application 11/038,288 14 11 and 12 under § 103(a) as being unpatentable over Peter-Hoblyn, Dettling 1 and Rao. 2 3 DECISION 4 We AFFIRM the rejections of claims 1-13. 5 No time period for taking any subsequent action in connection with 6 this appeal may be extended under 37 C.F.R. § 1.136(a) (2007). See 37 7 C.F.R. § 1.136(a)(1)(iv) (2007). 8 9 AFFIRMED 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 Appeal 2009-001095 Application 11/038,288 15 1 2 3 4 5 LV 6 7 THADDIUS J. CARVIS 8 102 NORTH KING STREET 9 LEESBURG, VA 20176 10 Copy with citationCopy as parenthetical citation