Ex Parte Russell et alDownload PDFPatent Trial and Appeal BoardOct 1, 201812795011 (P.T.A.B. Oct. 1, 2018) Copy Citation UNITED STA TES p A TENT AND TRADEMARK OFFICE APPLICATION NO. FILING DATE 12/795,011 06/07/2010 63759 7590 10/03/2018 DUKEW. YEE YEE & AS SOCIA TES, P.C. P.O. BOX 802333 DALLAS, TX 75380 FIRST NAMED INVENTOR James C. Russell UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www .uspto.gov ATTORNEY DOCKET NO. CONFIRMATION NO. 10-0065-US-NP 1138 EXAMINER HUANG, CHENG YUAN ART UNIT PAPER NUMBER 1787 NOTIFICATION DATE DELIVERY MODE 10/03/2018 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): ptonotifs@yeeiplaw.com mgamez@yeeiplaw.com patentadmin@boeing.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte JAMES C. RUSSELL, TRESHA L. WHITE, BRYAN SHIFLETT, PAZION CHERINET, SCOTT WADLEY, CAROL BARNHART, VYACHESLA V KHOZIKOV, and KYLE NAKAMOT0 1 Appeal 2017-011141 Application 12/795,011 Technology Center 1700 Before TERRY J. OWENS, ROMULO H. DELMENDO, and CHRISTOPHER C. KENNEDY, Administrative Patent Judges. KENNEDY, Administrative Patent Judge. DECISION ON APPEAL This is an appeal under 35 U.S.C. § 134(a) from the Examiner's decision rejecting claims 1-9, 11-14, 29-33, 61---64, and 66-72. We have jurisdiction under 35 U.S.C. § 6(b ). We AFFIRM. Pursuant to our authority under 37 C.F.R. § 41.50(b), we also enter a NEW GROUND OF REJECTION under 35 U.S.C. § 103(a). 1 According to the Appellants, the Real Party in Interest is The Boeing Company. App. Br. 2. Appeal 2017-011141 Application 12/795,011 BACKGROUND The subject matter on appeal relates to thermal barrier coatings comprising nanoparticles and a glassy matrix material. E.g., Spec. ,r 1; Claim 1. Claim 1 is reproduced below from page 23 ( Claims Appendix) of the Appeal Brief ( some paragraph breaks added): 1. A coating on a substrate, wherein the coating is configured to manage flow of heat in a preselected range of temperatures, the coating comprising: a glassy matrix material; and an array comprising a plurality of metal nano-particles, the array held in the glassy matrix material, a distance between each of the plurality of metal nano- particles in the array being substantially equal to wavelength of phonons transporting heat through the coating, wherein particle size of the plurality of nano-particles is configured based on the preselected range of temperatures, and wherein the glassy matrix material is configured to exhibit phonon mean free path lengths at least as long as the wavelength of phonons transporting heat through the coating. REJECTIONS ON APPEAL The claims stand rejected as follows: 1. Claims 1--4, 8, 13, 14, 62---64, and 66---69 under 35 U.S.C. § I02(b) as anticipated by Ganti (EP 1 844 863 Al, published Oct. 17, 2007); 2. Claims 5, 29--32, 61, and 70-72 under 35 U.S.C. § I03(a) as unpatentable over Ganti and Burton (WO 2008/060699 A2, published May 22, 2008); 3. Claims 6 and 7 under 35 U.S.C. § I03(a) as unpatentable over Ganti and Murray (US 3,380,846, issued Apr. 30, 1968); 2 Appeal 2017-011141 Application 12/795,011 4. Claim 9 under 35 U.S.C. § I03(a) as unpatentable over Ganti and Gray (US 2005/0112399 Al, published May 26, 2005); 5. Claims 11 and 12 under 35 U.S.C. § I03(a) as unpatentable over Ganti, Murray, and Burton; 6. Claim 33 under 35 U.S.C. § I03(a) as unpatentable over Ganti, Burton, and Murray. ANALYSIS After review of the cited evidence in the appeal briefs and the opposing positions of the Appellants and the Examiner, we determine that the Appellants have not identified reversible error in the Examiner's rejections. Accordingly, we affirm the rejections for reasons set forth below, in the Final Action, and in the Examiner's Answer. See generally Final Act. 2-16; Ans. 2-25. Pursuant to our authority under 37 C.F.R. § 4I.50(b ), we also enter a new ground of rejection under 35 U.S.C. § I03(a). Rejection 1 The Appellants separately address claims 1, 66, 67, 68, and 69. See App. Br. 7-13. We address those claims below. The remaining claims subject to Rejection 1 will stand or fall with the claim from which they depend. See 37 C.F.R. § 4I.37(c)(l)(iv). Claim 1. The Examiner finds that Ganti discloses a coating on a substrate in which the coating comprises a glassy matrix material with metal nano-particles dispersed therein. Final Act. 2. Concerning the limitation that "a distance between each of the plurality of metal nano-particles" is "substantially equal to wavelength of phonons transporting heat through the coating," the Examiner finds that, 3 Appeal 2017-011141 Application 12/795,011 because Ganti discloses an embodiment in which nanoparticles have the same spacing (100 nm) as an embodiment disclosed by the Specification, " [that] embodiment of Gan ti necessarily discloses the particle spacing limitation, because 100nm spacing inherently is 'substantially equal to wavelength of phonons transporting heat through the coating."' Id. at 2-3. Concerning the limitations that "particle size of the plurality of nano- particles is configured based on the preselected range of temperatures," and "the glassy matrix material is configured to exhibit phonon mean free path lengths at least as long as the wavelength of phonons transporting heat through the coating," the Examiner finds that Ganti's coating "compris[es] structure and materials identical to those as presently claimed" and necessarily meets those limitations. Id. at 3. The Appellants raise several arguments in opposition to the rejection, which we address in tum below. 1. In the Appeal Brief, the Appellants first argue that Ganti does not disclose a glassy matrix material. 2 App. Br. 8. The Appellants' argument focuses on whether substrate 110 of Ganti constitutes a glassy matrix, and the Appellants argue that it does not because substrate 110 is "rough or uneven, and thus not glassy." Id. The Appellants further argue: 2 In a previous appeal involving this application, the Appellants did not contest the Examiner's finding that Ganti discloses a glassy matrix. See generally Appeal Brief dated March 18, 2013. Although the Examiner's rejections were reversed for other reasons as a result of that appeal, the Board entered a new ground of rejection. See Decision dated August 28, 2015, at 16-18. In entering the new ground, the Board adopted the Examiner's findings (which, at that time, had not been contested) concerning Ganti's disclosure of a glassy matrix material. Id. at 16. 4 Appeal 2017-011141 Application 12/795,011 Furthermore, paragraph 19 of Ganti only discloses that "Substrate 110 may comprise at least one of a metal, an alloy, a plastic, a ceramic, or any combination thereof' and "may take the form of a film, a sheet, or a bulk shape." However, Ganti gives no indication that the surface is a "glassy matrix," as claimed. Id. Although the Appellants acknowledge that the Examiner relies on Ganti' s "coating structure" and "materials identical to those presently claimed" (i.e., ceramic), the Appellants argue the Examiner's findings are incorrect "for the reasons given above," i.e., the arguments concerning Ganti's substrate. See id. Those arguments are not persuasive because they do not meaningfully address the Examiner's rejection. See In re Jung, 637 F.3d 1356, 1365 (Fed. Cir. 2011) ("[I]t has long been the Board's practice to require an applicant to identify the alleged error in the examiner's rejections .... "); In re Lovin, 652 F.3d 1349, 1357 (Fed. Cir. 2011) ("[T]he Board reasonably interpreted Rule 41.37 to require more substantive arguments in an appeal brief than a mere recitation of the claim elements and a naked assertion that the corresponding elements were not found in the prior art."). The paragraphs cited by the Examiner do not solely concern Ganti's substrate, and the most reasonable understanding of the Examiner's rejection is that the Examiner is not relying on Ganti' s substrate as corresponding to the claimed glassy matrix. See Final Act. 2-3. Rather, the rejection cites paragraphs 18, 21, 24, and 31 of Ganti, which describe "[s]urface 120" that may be a polymer or a ceramic, and substrate 110 that may also be ceramic. Ganti ,r,r 18, 19. Paragraph 20 discloses that surface 120 may be integral with the substrate or "may comprise a layer that is disposed or deposited onto" the substrate. Id. ,r 20. 5 Appeal 2017-011141 Application 12/795,011 Paragraph 21 discloses that the surface includes a "plurality of features," which may be "substantially spherical features," and it specifically discloses an embodiment in which "spherical or sphere-like features, each having a diameter of about 100 nm, are spaced about 100 nm apart." Id. ,r 21. Paragraph 24 references Figure 5 and discloses that the features may be "a plurality of nanoparticles ... deposited on" a substrate, over which a coating of polymer is applied. Id. ,r 24. Paragraph 31 describes an embodiment in which a plurality of nanoparticles is combined with a ceramic precursor to form a slurry, which is then applied to a substrate and "heated to convert the ceramic precursor into a ceramic, such as, but not limited to an oxide, carbide, nitride, silicide, or combinations thereof, thereby forming a textured, low-wettability surface comprising the plurality of nanoparticles embedded in a ceramic coating." Id. ,r 31. In view of the Examiner's findings and citations to Ganti, the most reasonable understanding of the Examiner's rejection is that the Examiner was relying on Ganti's ceramic coating (in which nanoparticles are embedded) as Ganti's glassy matrix. See Final Act. 2-3. In focusing their arguments on Gan ti's substrate, and failing to meaningfully address the disclosures of Ganti discussed above, the Appellants fail to identify reversible error in the Examiner's determination that Ganti's ceramic coating in which nanoparticles are embedded corresponds to the claimed glassy matrix. See Jung, 637 F.3d at 1365. Additionally, although the Appellants assert that if something is "rough or uneven," it is "not glassy," they provide no evidence in support of that assertion. See App. Br. 8; see also In re Pearson, 494 F.2d 1399, 1405 (CCPA 1974) ("Attorney's argument in a brief cannot take the place of 6 Appeal 2017-011141 Application 12/795,011 evidence."). And, although the Appellants assert that "Ganti gives no indication that the surface is a 'glassy matrix,"' id., that naked assertion fails to address the Examiner's finding that, because Ganti discloses ceramic coatings in which nanoparticles are embedded, and the Appellants' claim 8 recites that "the glassy matrix material is a ceramic," Gan ti's ceramic coating falls within the scope of the term "glassy matrix material." See Final Act. 3 (finding that the materials of Ganti are "identical to those as presently claimed" and that "Ganti teaches glassy matrix material identical to that presently claimed"); see Lovin, 652 F.3d at 1357. Accordingly, the arguments presented in the Appeal Brief fail to show reversible error in the Examiner's determination that Ganti teaches a glassy matrix material. In view of Ganti' s disclosures, a person of ordinary skill in the art would have at once envisaged a ceramic coating in which metal nanoparticles are embedded, the nanoparticles being about 100 nm in diameter and being spaced apart by about 100 nm. See Ganti ,r,r 18-21, 24, 31. In the Reply Brief, the Appellants raise the following new arguments: ( 1) "Just because Ganti discloses a ceramic does not mean that it is a glassy matrix" because, according to the Appellants, "most ceramics [are] not glassy," (2) "Ganti discloses many materials for its coating. However, none of those materials is necessarily a glassy matrix." Reply Br. 8-10; see also Reply Br. 13, 15-16 ("[O]ne cannot logically conclude that the ceramics in Ganti necessarily match the ceramic in claim 8 (because the claim 8 ceramic is a glassy matrix) .... "), 20, 25, 28. Those arguments are untimely because they were not presented in the Appeal Brief, and the Appellants have not attempted to show good cause for presenting them for the first time in the Reply Brief. See 37 C.F.R. § 41.41(b)(2). Accordingly, those 7 Appeal 2017-011141 Application 12/795,011 arguments are waived and do not provide a basis for reversal of the Examiner's rejection. 2. The Appellants also assert that Ganti does not disclose particle spacing "substantially equal to wavelength of phonons transporting heat through the coating," as required by claim 1. App. Br. 9. They argue that "even if the spacing as in claim 1 is possible from the disclosure of Ganti, a disputed point, mere probabilities or possibilities may not establish inherency." Id. They further argue that "the materials in Ganti may create different phonons relative to what is claimed." Id. at 10. Those arguments are not persuasive. Ganti does not merely disclose the "possib[ility ]" of 100 nm particle spacing; Ganti specifically discloses 100 nm nanoparticles spaced about 100 nm apart. Ganti ,r 21. The Appellants' Specification discloses that "[t]he size of the nano-particles is substantially similar to the wavelength of the phonons transporting heat through the coating at a preselected temperature," and the Appellants' Specification discloses an embodiment in which nanoparticles are spaced at "approximately 50nm to 100nm." With regards to materials, as set forth above, Ganti discloses metal nanoparticles, and it discloses ceramic coatings in which the nanoparticles are embedded. The Appellants disclose that the glassy matrix may be ceramic. Spec. ,r 9; see also Claim 8. On this record, Ganti' s disclosure of materials and particle spacing that fall within the scope of the Appellants' disclosure was sufficient to shift the burden to the Appellants to show that Ganti' s compositions would not inherently possess the disputed limitation. See In re Spada, 911 F.2d 705, 708 (Fed. Cir. 1990) ("[W]hen the PTO shows sound basis for believing that the products of the applicant and the prior art are the same, the applicant has 8 Appeal 2017-011141 Application 12/795,011 the burden of showing that they are not."); In re Best, 562 F.2d 1252, 1255- 56 (CCPA 1977) ("Where, as here, the claimed and prior art products are identical or substantially identical, or are produced by identical or substantially identical processes, the PTO can require an applicant to prove that the prior art products do not necessarily or inherently possess the characteristics of his claimed product."). As set forth above, in view of Ganti' s disclosures a person of ordinary skill in the art would have at once envisaged compositions in which 100 nm metal nanoparticles, spaced 100 nm apart, are embedded in a ceramic coating. The Appellants have not carried their burden of showing that such an embodiment would not inherently possess the disputed limitation. The fact that Ganti is not strictly limited to 100 nm particle spacing, and therefore also contemplates embodiments that may not fall within the scope of claim 1, does not detract from the disclosures discussed above and relied on by the Examiner. In the Reply Brief, the Appellants argue for the first time that paragraph 43 of their Specification indicates that "phonon dispersion and scattering depend on more than just the spacing of the particles." Reply Br. 4. The Appellants point out that paragraph 43 (which was not cited or discussed in the Appeal Brief) describes mass ratio, effective matrix spring constant, and other properties. Id.; see also id. at 11, 13-14, 15, 19. As explained above, arguments raised for the first time in the Reply Brief are untimely and waived. However, we observe that, even assuming that the properties of the matrix and nanoparticles influence the wavelength of the phonon, Ganti discloses both materials ( metal nanoparticles embedded in ceramic coatings) and spacing (100 nm) that fall within the scope of the Appellants' disclosure. 9 Appeal 2017-011141 Application 12/795,011 That is sufficient to shift the burden to the Appellants to show that Ganti's composition comprising 100 nm metal nanoparticles, spaced 100 nm apart and embedded in a ceramic matrix, does not possess the recited particle distance substantially equal to the wavelength of phonons transporting heat through the coating. See Spada, 911 F.2d at 708; Best, 562 F.2d at 1255-56. The Appellants have not carried that burden. The Appellants have not persuasively identified any "variable" in Ganti that supports their arguments. See Reply Br. 5 ("[W]hat is likely is that the phonons in Ganti's coating have a wavelength different than 100 nm because of the other variables that affect phonon wavelength and reflections." ( emphasis added)). 3. The Appellants argue that Ganti does not disclose "wherein particle size of the plurality of nano-particles is configured3 based on the preselected range of temperatures, and wherein the glassy matrix material is configured to exhibit phonon mean free path lengths at least as long as the wavelength of phonons transporting heat through the coating." App. Br. 10. The argument is based on the same arguments discussed above and found unpersuasive. Id. (arguing that "Ganti does not disclose identical materials 3 It is unclear what it means for a "particle size" to be "configured," and the Appellants have not cited any portion of the Specification clarifying the meaning of that term. The Specification does not appear to use the word "configured" in association with the term "particle size." See generally Spec. Consistent with the Specification, we interpret "configured" to be synonymous with "selected." See Spec. ,r 45 (describing "selections" of matrix and nano-particle materials "based at least in part on the temperature ranges" that have been preselected); see also original claim 3 8 ("selecting the size of the metal nano-particles based on the selected temperature range"). In the event of further examination of the application on appeal, the Appellants and Examiner may wish to clarify that. 10 Appeal 2017-011141 Application 12/795,011 to those claimed" and that "mere similar spacing of particles does not necessarily result in the claimed configuration"). The Appellants also assert that the Examiner's rejection does not show that Ganti's composition "necessarily" possesses the recited properties sufficient to establish inherency. Id. at 11. Those arguments are not persuasive essentially for reasons stated above. With regards to the limitation that "particle size of the plurality of nano-particles is configured based on the preselected range of temperatures," we further observe that claim 1 is directed to a composition, not a method. Thus, if the structural components or features (such as materials, particle size, and spacing) of Ganti' s composition fall within the scope of the claim, the reason for the selection of those components or features (i.e., whether or not a given feature such as particle size is selected "based on the preselected range of temperatures") is not relevant to whether the claimed composition is structurally distinguishable from the composition of the prior art. Cf In re Schreiber, 128 F.3d 1473, 1477-78 (Fed. Cir. 1997); In re Gardiner, 171 F.2d 313, 315-16 (CCPA 1948) ("It is trite to state that the patentability of apparatus claims must be shown in the structure claimed and not merely upon a use, function, or result thereof."). Given that Ganti discloses 100 nm particles with 100 nm spacing, and the Specification discloses that spacing of 50 nm to 100 nm corresponds to a temperature range of 100-250°F, Spec. ,r 44, the Appellants fail to distinguish the claimed composition from the composition of Ganti on the basis of the "particle size of the plurality of nano-particles is configured based on the preselected range of temperatures" recitation of claim 1. It is irrelevant whether Ganti' s particle spacing would have been selected in view of a preselected temperature range. 11 Appeal 2017-011141 Application 12/795,011 Additionally, the Examiner does not rely on probabilities. As set forth above, in view of Ganti's disclosures a person of ordinary skill in the art would have at once envisaged compositions in which 100 nm metal nanoparticles, with 100 nm spacing, are embedded in a ceramic matrix. The similarity, if not identity, of that composition to the claimed compositions, is sufficient to shift the burden to the Appellants to show that Ganti' s composition does not possess a "glassy matrix material ... configured to exhibit phonon mean free path lengths at least as long as the wavelength of phonons transporting heat through the coating." See Spada, 911 F.2d at 708; Best, 562 F.2d at 1255-56. That some of Ganti's compositions may not inherently fall within the scope of claim 1 does not defeat Ganti's disclosure of compositions that do fall within the scope of claim 1. We have carefully considered the Appellants' arguments concerning claim 1, but we are not persuaded of reversible error in the rejection. See Jung, 637 F.3d at 1365. Claim 66. Claim 66 depends from claim 1 and further recites "wherein [the] coefficient of thermal expansion of the glassy matrix material substantially matches [the] coefficient of thermal expansion of the substrate." The Examiner finds that because "Ganti teaches that the glassy matrix material and the substrate may comprise identical material, i.e. ceramic and absent evidence to the contrary, it is clear that the coefficient of thermal expansion of the glassy matrix material of Ganti would substantially match [the] coefficient of thermal expansion of the substrate." Final Act. 5 ( citation omitted). 12 Appeal 2017-011141 Application 12/795,011 The Appellants argue that "Ganti discloses several different materials which may make up the surface and the substrate," and "[t]he Office Action is relying on a mere possibility that the same type of material may be selected for both the substrate and the coating." App. Br. 12-13. That argument is not persuasive. Ganti expressly discloses that the surface material may be a ceramic or a polymer. Ganti ,r 18. Ganti expressly discloses that the substrate may be a ceramic, a metal, an alloy, a plastic, or a combination of those materials. Id. ,r 19. In view of those disclosures, a person of ordinary skill in the art would have at once envisaged an embodiment in which both the surface coating and the substrate are the same ceramic material. The Appellants do not meaningfully assert otherwise. The Appellants do not assert that a composition in which the substrate and surface coating are the same material would fall beyond the scope of claim 66. As explained above, the fact that Ganti also discloses embodiments in which the substrate and surface coating are not necessarily the same material ( and thus may not fall within the scope of claim 66) does not detract from Gan ti's disclosures that would have enabled a person of ordinary skill in the art to at once envisage compositions in which the substrate and surface coating are the same material and, therefore, have the same coefficient of thermal expansion. The Appellants have not identified reversible error in the Examiner's rejection of claim 66. See Jung, 637 F.3d at 1365. Claim 67. Independent claim 67 is similar to claim 1 but additionally requires, inter alia, that the array of nanoparticles is "configured to produce interfering reflections of phonons." For reasons essentially the same as those set forth above in the discussion of claim 1, the Examiner finds that 13 Appeal 2017-011141 Application 12/795,011 Ganti' s composition comprising 100 nm metal nanoparticles, spaced 100 nm apart and embedded in a ceramic matrix, would necessarily produce interfering reflections of phonons. Final Act. 5-6. The Appellants disagree for reasons similar to those discussed above. App. Br. 12. Additionally, the Appellants describe a scientific article that "describes forming nanocrystalline silicon," which allegedly shows that "by changing one of the temperature and the hold time, the resultant grain size and/or density of the resulting silicon may be changed," and that "the resultant grain size and density may affect the thermal properties of the silicon." Id. at 12. We understand the purpose of the Appellants' discussion of that article to be to abstractly suggest that the specific method by which Ganti's composition is formed might influence the thermal properties of Ganti' s composition. Even assuming everything the Appellants say about the article is true, that discussion is insufficient to carry the Appellants' burden of showing that Ganti's embodiment relied upon by the Examiner (i.e., 100 nm metal nanoparticles spaced apart by 100 nm and embedded in a ceramic matrix) would not inherently produce interfering reflections of phonons. See Spada, 911 F.2d at 708; Best, 562 F.2d at 1255-56. As set forth above, those particle sizes, spacing, and materials fall within the scope of the Appellants' disclosure, and the Appellants have given no persuasive reason a person of ordinary skill in the art would not have expected them to fall within the scope of claim 67. Even assuming that the specific method by which Ganti' s composition is formed may have some influence on the thermal properties of Ganti' s composition, the Appellants' discussion of the article provides no basis to believe that the effect would be such as to 14 Appeal 2017-011141 Application 12/795,011 remove Ganti's composition from the scope of the claim. In that regard, we observe that the Appellants identify no relevant disclosure in either their own Specification, or in Ganti, that would suggest the methods by which the compositions are produced affects whether the compositions are "configured to produce interfering reflections of phonons," as recited by claim 67. The Appellants have not identified reversible error in the Examiner's rejection of claim 67. See Jung, 637 F.3d at 1365. Claim 68. Claim 68 depends from claim 67 and further recites that "the plurality of nano-particles have a thermal conductivity substantially greater than [the] thermal conductivity of the glassy matrix material." The Examiner finds that because "Ganti teaches plurality of nano- particles and glassy matrix material identical to those presently claimed and absent evidence to the contrary, it is clear that the thermal conductivity of the plurality of the nano-particles are substantially greater than the thermal conductivity of the glassy matrix material." Final Act. 6. The Appellants argue that "Ganti is silent as to a 'thermal conductivity."' App. Br. 13. The Appellants further argue that "Ganti discloses that the nano-particles may be metallic or non-metallic, coated or uncoated, and may have a low wettability or not. With a variety of types of possible nano-particles and a variety of types of polymers or ceramics it is not true that Ganti necessarily have [sic] the feature of claim 68." Id. That argument fails to identify reversible error in the rejection. As the Appellants concede, Ganti expressly discloses that the nanoparticles may be metallic or nonmetallic. Ganti ,r 24. In view of that disclosure, a person of ordinary skill in the art would at once envisage a composition in which the nanoparticles are metal nanoparticles. As set forth above, a person of 15 Appeal 2017-011141 Application 12/795,011 ordinary skill would also at once envisage a composition in which the metal nanoparticles are embedded in a ceramic matrix. Id. ,r 31. As set forth above, and as the Examiner explains in the Answer, see Ans. 21, the fact that some of Ganti' s compositions may not fall within the scope of claim 68 does not detract from Ganti's disclosure of compositions that do fall within the scope of claim 68. The Appellants do not assert that a composition with metal nanoparticles embedded in a ceramic matrix would not meet the additional requirement of claim 68. On this record, the Appellants have not identified reversible error in the Examiner's rejection of claim 68. See Jung, 637 F.3d at 1365. Claim 69. Claim 69 depends from claim 67 and further recites "wherein: particle size of the plurality of nano-particles is configured based on the preselected range of temperatures." The Appellants argue that because Ganti is concerned with surface qualities of its substrate, and with textures of its surfaces, the features of claim 69 "are not inherent in the material of Ganti." App. Br. 13. Essentially for reasons stated above, that argument fails to carry the Appellants' burden of showing that Ganti' s embodiments that have particle sizes, spacing, and materials that fall within the scope of the claims and the Appellants' disclosure, would not have inherently possessed the additional limitations of claim 69. See Spada, 911 F.2d at 708; Best, 562 F.2d at 1255- 56. The Appellants have not identified reversible error in the Examiner's rejection of claim 69. See Jung, 637 F.3d at 1365. Rejection 2 Although the Appellants quote claim language from certain claims subject to Rejection 2 and allege that those limitations are missing from 16 Appeal 2017-011141 Application 12/795,011 Ganti and Burton, the Appellants do not address the Examiner's specific findings and conclusions concerning those claim limitations. See App. Br. 15. Quotations of claim language accompanied by naked assertions that the limitations are missing from the prior art do not comply with the Board's rules and fail to identify reversible error in the Examiner's rejection. Lovin, 652 F.3d at 1357; see also 37 C.F.R. § 4I.31(c)(l)(iv). Beyond the naked assertions regarding certain quoted limitations, the Appellants also argue that Burton teaches away from claim 1 because Burton teaches "packing smaller nano-particles into spaces between larger particles to decrease the total amount of binder between particles," and that is "different than what is claimed." App. Br. 15 ("Burton's teachings are actually contrary to the features of claim 1." (emphasis omitted)). That argument is unpersuasive. The Examiner relies on Ganti for the particle spacing and on Burton for other disclosures. "The prior art's mere disclosure of more than one alternative does not constitute a teaching away from any of these alternatives because such disclosure does not criticize, discredit, or otherwise discourage the solution claimed .... " In re Fulton, 391 F.3d 1195, 1201 (Fed. Cir. 2004). Even assuming that Burton discloses a different particle spacing than that of claim 1, the Appellants identify no disclosure in Burton that criticizes, discredits, or otherwise discourages the claimed particle spacing or the particle spacing of Ganti. Nor do the Appellants provide any basis to doubt the Examiner's proposal of combining Ganti and Burton. See App. Br. 15. On this record, we are not persuaded that "Burton's teachings are actually contrary to the features of claim 1" merely because they are different from the features of claim 1. 17 Appeal 2017-011141 Application 12/795,011 In the Reply Brief, the Appellants argue for the first time that "Burton provides no explanation that cobalt or tungsten particles could be used in Ganti' s process. Ganti provides no explanation that cobalt or tungsten could be used in his process." Reply Br. 21-22. Those arguments are untimely and waived because they were not presented in the Appeal Brief, and the Appellants have not attempted to show good cause for presenting them for the first time in the Reply Brief. See 37 C.F.R. § 4I.41(b)(2). The Appellants also argue that Ganti is nonanalogous art. App. Br. 15. Specifically, they argue that Ganti is not from the same field of endeavor as the claimed invention because Ganti "is in the field of liquid wettability of solid surfaces and coating the same," whereas "[t]he claims relate[] to thermal barriers." Id. Art is analogous to the claimed invention if ( 1) the art is "from the same field of endeavor, regardless of the problem addressed," or (2) the art is "reasonably pertinent to the particular problem with which the inventor is involved." In re Bigio, 381 F.3d 1320, 1325 (Fed. Cir. 2004). "The Supreme Court's decision in KSR International Co. v. Teleflex, Inc. directs us to construe the scope of analogous art broadly .... " Wyers v. Master Lock Co., 616 F.3d 1231, 1237 (Fed. Cir. 2010) (internal citation omitted). Particularly in view of the Federal Circuit's instruction to "construe the scope of analogous art broadly," we are not persuaded by the Appellants' argument. Some of the appealed claims are directed to "a coating on a substrate," e.g., Claim 1, whereas others recite in the preamble "[a] thermal barrier coating," e.g., Claim 29. The structural elements of both sets of claims are essentially the same (i.e., metal nanoparticles embedded in a glassy matrix). Compare Claim 1, with Claim 29. More specifically, all of 18 Appeal 2017-011141 Application 12/795,011 the appealed claims concern coatings comprising nanoparticles. As described above, Ganti likewise describes coatings comprising nanoparticles. Even were we to focus on the thermal aspects of the Appellants' coatings, Ganti specifically describes applications for its coatings in which "stability at high temperature is desired." Ganti ,r 31. Even more specifically, both Ganti and the Appellants' Specification describe aircraft applications for their coatings. Compare Ganti ,r 31 ( aircraft turbines), with Spec. ,r 11 ("a thermal barrier coating is provided for an aircraft part"). On this record, we determine that both Ganti and the claimed invention are from the field of endeavor of nanoparticle coatings. However, even were we to more narrowly construe the field of endeavor ( e.g., metal nanoparticle coatings with desirable thermal characteristics for use with aircraft), we would still determine that Ganti and the claimed invention are from the same field of endeavor. Rejection 3 In the Appeal Brief, the Appellants simply argue that Murray does not teach features of the claims that are allegedly missing from Ganti. See App. Br. 16. However, as set forth above, we determine that Ganti teaches each of those features. The Appellants' arguments concerning Murray alone are not persuasive. See In re Keller, 642 F.2d 413,426 (CCPA 1981) ("[O]ne cannot show non-obviousness by attacking references individually where, as here, the rejections are based on combinations of references."). The Appellants do not challenge the Examiner's combination of Murray with Ganti. App. Br. 16. On this record, the Appellants have not identified reversible error in Rejection 3. See Jung, 637 F.3d at 1365. 19 Appeal 2017-011141 Application 12/795,011 In the Reply Brief, the Appellants raise new arguments concerning Rejection 3. Because they were not presented in the Appeal Brief, and the Appellants do not assert good cause for presenting them for the first time in the Reply Brief, those arguments are untimely and waived. See 37 C.F.R. § 41.41(b)(2). Rejection 4 The Appellants argue only that "Gray does not remedy the deficiencies of Ganti." App. Br. 1 7. They do not challenge the Examiner's combination of Gray with Ganti. Id. Because no distinct arguments are presented against Rejection 4, we affirm Rejection 4 for reasons set forth above. As above, to the extent new arguments are raised in the Reply Brief, they are untimely and waived. See 37 C.F.R. § 4I.41(b)(2). Rejections 5 and 6 The Appellants argue that Rejections 5 and 6 should be reversed "[fJor at least the reasons above." App. Br. 17-18. The Appellants do not challenge the Examiner's combination of Gray, Murray, and Burton with Ganti. Id. Because no distinct arguments are presented against Rejections 5 and 6, we affirm Rejections 5 and 6 for reasons set forth above. New Ground of Re} ection Independent claims 1 and 67 are rejected under 35 U.S.C. § 103(a) as unpatentable over Ganti. Claim 1. As set forth above, Ganti describes "[s]urface 120" that may be a polymer or a ceramic, and substrate 110 that may also be ceramic. Ganti ,r,r 18, 19. Paragraph 20 discloses that surface 120 may be integral with the substrate or "may comprise a layer that is disposed or deposited 20 Appeal 2017-011141 Application 12/795,011 onto" the substrate." Id. ,r 20. Paragraph 21 discloses that the surface includes a "plurality of features," which may be "substantially spherical features," and it specifically discloses an embodiment in which "spherical or sphere-like features, each having a diameter of about 100 nm, are spaced about 100 nm apart." Id. ,r 21. Paragraph 24 references Figure 5 and discloses that the features may be "a plurality of nanoparticles ... deposited on" a substrate, over which a coating of polymer is applied. Id. ,r 24. Paragraph 31 describes an embodiment in which a plurality of nanoparticles is combined with a ceramic precursor to form a slurry, which is then applied to a substrate and "heated to convert the ceramic precursor into a ceramic, such as, but not limited to an oxide, carbide, nitride, silicide, or combinations thereof, thereby forming a textured, low-wettability surface comprising the plurality of nanoparticles embedded in a ceramic coating." To the extent that those disclosures do not anticipate claim 1 (i.e., even if a person of ordinary skill in the art would not have at once envisaged a composition falling within the scope of claim 1 in view of those disclosures), the subject matter of claim 1 would have been obvious in view of those disclosures. Ganti discloses a coating on a substrate ( e.g., ,r,r 18-20, 24, 31 ). Concerning the claimed "glassy matrix material," Ganti discloses that the coating may be ceramic. E.g., Ganti ,r,r 18, 19, 31. Although Gan ti does not explicitly disclose a "glassy" ceramic, a person of ordinary skill would have understood that ceramics are either glassy or non-glassy, and Ganti does not exclude glassy ceramics. Thus, Ganti' s broad disclosure of ceramic coatings reasonably teaches or suggests both glassy and non-glassy 21 Appeal 2017-011141 Application 12/795,011 ceramics. Additionally, Ganti discloses a variety of"[ s ]uitable ceramic materials," including "inorganic oxides, carbides, nitrides, and combinations thereof." Id. ,r 18. Ganti discloses as a "[n]on-limiting example" silicon carbide. Id. In view of the disclosure of inorganic oxides and carbides, as well as the specific "[ n ]on-limiting" disclosure of silicon carbide, a person of ordinary skill in the art reasonably would have inferred that suitable "inorganic oxides" would include silicon oxide, i.e., silica. The Specification states: "As used herein, 'glass', 'glassy', 'glass compound', 'glass compound' [sic] and 'silica-based compound' refer to compounds containing silica." Spec. ,r 40. Ganti's disclosure reasonably suggests silica- based ceramics and, therefore, reasonably suggests a glassy matrix material. Concerning the claimed "array comprising a plurality of metal nano- particles," Ganti teaches or suggests "features" on its surface or in its coating that may be, e.g., spherical features such as nanoparticles. E.g., Ganti ,r,r 21, 24, 31. Ganti expressly teaches that its nanoparticles may be metal. Id. ,r 24. Ganti teaches that its features "may be arranged in ... an ordered array." Id. ,r 21. Ganti teaches that the "features" are spaced apart from each other by a distance, and Ganti specifically discloses an embodiment in which "spherical or sphere-like features, each having a diameter of about 100 nm, are spaced about 100 nm apart." Id. ,r 21. In view of those disclosures, a nanoparticle coating comprising 100 nm metal nanoparticles spaced 100 nm apart and embedded in a glassy ceramic matrix would have been obvious to a person of ordinary skill in the art because Ganti teaches or suggests each element of such a nanoparticle coating. Id. ,r,r 18-20, 24, 31. To the extent making specific selections to 22 Appeal 2017-011141 Application 12/795,011 arrive at such a composition is required, a person of ordinary skill in the art would have understood that specific features of the relevant disclosures could have been selected in order to achieve a coating with the desired properties. Ganti discloses a limited number of options for each selection. For example, Ganti discloses that the nanoparticles "may be metallic, non- metallic; or a combination of both." Id. ,r 24. Selection of metal nanoparticles would have been obvious in view of that disclosure. Similarly, Ganti discloses that its coating may be a polymer or a ceramic. Id. ,r 18. Selection of a ceramic coating would have been obvious in view of that disclosure. As set forth above, a person of ordinary skill in the art would have understood that ceramics may be either glassy or non-glassy, and that Ganti' s broad disclosure of "ceramic" encompasses both. Finally, although Ganti' s compositions are not limited to 100 nm nanoparticles spaced 100 nm apart, selection of such size and spacing would have been obvious in view of Gan ti's express disclosure of such size and spacing. Id. ,r 21. Thus, a nanoparticle coating comprising 100 nm metal nanoparticles spaced 100 nm apart and embedded in a glassy ceramic matrix would have been obvious to a person of ordinary skill in the art in view of Ganti's disclosures. Most of the remaining recitations of claim 1 ("coating is configured to manage flow of heat in a preselected range of temperatures," "distance ... equal to wavelength of phonons," "glassy matrix material is configured to exhibit phonon mean free path lengths") would flow naturally from the composition rendered obvious by Ganti. Cf Ex parte Obiaya, 227 USPQ 58, 60 (BPAI 1985) ("The fact that appellant has recognized another advantage which would flow naturally from following the suggestion of the prior art cannot be the basis for patentability when the differences would 23 Appeal 2017-011141 Application 12/795,011 otherwise be obvious."); In re Kubin, 561 F.3d 1351, 1357 (Fed. Cir. 2009) ("Even if no prior art of record explicitly discusses the [limitation], [applicants'] application itself instructs that [ the limitation] is not an additional requirement imposed by the claims on the [ claimed invention], but rather a property necessarily present in [ the claimed invention]."); cf also Best, 562 F.2d at 1255 ("Where, as here, the claimed and prior art products are identical or substantially identical, or are produced by identical or substantially identical processes, the PTO can require an applicant to prove that the prior art products do not necessarily or inherently possess the characteristics of his claimed product."). A nanoparticle coating comprising 100 nm metal nanoparticles spaced 100 nm apart and embedded in a glassy ceramic matrix appears to fall within the scope of the coating of claim 1 and involves materials and spacing specifically described by the Specification. E.g., Spec. ,r,r 9 (disclosing that "[t]he glass[y] matrix may be in the form of a ceramic"), 44 ( disclosing "nano-particle period of approximately 50nm to 100nm in order to tune it for a temperature range of approximately 250°F to 100°F"). Finally, for reasons stated above, the recitation that "particle size ... is configured based on the preselected range of temperatures" specifies a reason for the selection of particle size and fails to structurally distinguish the coating of claim 1 from the coating taught or suggested by Ganti. Accordingly, the subject matter of claim 1 would have been obvious in view of Ganti. We leave to the Examiner consideration of the dependent claims. Claim 67. The same analysis set forth above for claim 1 applies equally to claim 67. The additional recitations of claim 67 ("array 24 Appeal 2017-011141 Application 12/795,011 configured to produce interfering reflections of phonons," "wavelength of the phonons ... is determined from the preselected range of temperatures") would flow naturally from the composition rendered obvious by Ganti and do not structurally distinguish Ganti's composition from the subject matter of claim 67. Cf Obiaya, 227 USPQ at 60; Kubin, 561 F.3d at 1357; cf also Best, 562 F.2d at 1255. Accordingly, the subject matter of claim 67 would have been obvious in view of Ganti. We leave to the Examiner consideration of the dependent claims. CONCLUSION We AFFIRM the Examiner's rejections of claims 1-9, 11-14, 29-33, 61---64, and 66-72. We enter a NEW GROUND OF REJECTION as set forth above for independent claims 1 and 67. 37 C.F.R. § 4I.50(b) provides that "[a] new ground of rejection pursuant to this paragraph shall not be considered final for judicial review." Section 41.50(b) also provides that the Appellants, WITHIN TWO MONTHS FROM THE DATE OF THE DECISION, must exercise one of the following two options with respect to the new ground of rejection to avoid termination of the appeal as to the rejected claims: ( 1) Reopen prosecution. Submit an appropriate amendment of the claims so rejected or new evidence relating to the claims so rejected, or both, and have the matter reconsidered by the Examiner, in which event the prosecution will be remanded to the Examiner .... 25 Appeal 2017-011141 Application 12/795,011 (2) Request rehearing. Request that the proceeding be reheard under § 41.52 by the Board upon the same record. AFFIRMED 37 C.F.R. § 4I.50(b) 26 Copy with citationCopy as parenthetical citation