Ex Parte Morita et alDownload PDFPatent Trials and Appeals BoardApr 12, 201913636255 - (D) (P.T.A.B. Apr. 12, 2019) Copy Citation UNITED STA TES p A TENT AND TRADEMARK OFFICE APPLICATION NO. FILING DATE FIRST NAMED INVENTOR 13/636,255 09/20/2012 Shin ya Morita 22850 7590 04/16/2019 OBLON, MCCLELLAND, MAIER & NEUSTADT, L.L.P. 1940 DUKE STREET ALEXANDRIA, VA 22314 UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www .uspto.gov ATTORNEY DOCKET NO. CONFIRMATION NO. 404419US99PCT 7750 EXAMINER MCDONALD, RODNEY GLENN ART UNIT PAPER NUMBER 1794 NOTIFICATION DATE DELIVERY MODE 04/16/2019 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): patentdocket@oblon.com OBLONPAT@OBLON.COM iahmadi@oblon.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte SHINY AMORITA, 1 Toshihiro Kugiyama, Takeaki Maeda, Satoshi Yasuno, Yasuaki Terao, and Aya Miki Appeal2017-008223 2 Application 13/636,255 Technology Center 1700 Before MARK NAGUMO, JEFFREY R. SNAY, and JENNIFER R. GUPTA, Administrative Patent Judges. NAGUMO, Administrative Patent Judge. DECISION ON APPEAL Shinya Morita, Toshihiro Kugiyama, Takeaki Maeda, Satoshi Yasuno, Yasuaki Terao, and Aya Miki ("Morita") timely appeal under 35 U.S.C. 1 The real party in interest is identified as Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.). (Appeal Brief, filed 11 August 2016 ("Br."), 2.) 2 Heard 2 April 2019. The Official Transcript will be made of record in due course. Appeal2017-008223 Application 13/636,255 § 134(a) from the Final Rejection3 of claims 7, 12, 13, and 15-17. 4 We have jurisdiction. 35 U.S.C. § 6. We reverse. OPINION A. Introduction 5 The subject matter on appeal relates to an oxide for a semiconductor layer of a thin film transistor ("TFT") used in a display device, especially an organic electroluminescent ("EL") display. (Spec. 1, 1st para.) The '255 Specification teaches that, for conventional TFTs based on silicon, amorphous silicon (a-Si) provides the high carrier mobility and high optical bandgap required for good TFT switching characteristics. 6 However, a-Si must be deposited at high temperatures that are incompatible with resin substrates and organic light emitting diode ("OLED") displays characteristic of the large, high resolution, high speed, next-generation displays. (Id. at 1, 11. 7-11.) Amorphous oxide semiconductors composed of indium, gallium, 3 Office Action mailed 11 March 2016 ("Final Rejection"; cited as "FR"). 4 Remaining copending independent claim 1 and dependent claims 3---6 have been withdrawn from consideration by the Examiner (FR 1, § 5A), and are not before us. 5 Application 13/636,255, Oxide for semiconductor layer of thin film transistor, sputtering target, and thin film transistor, filed 20 September 2012, as the national stage under 35 U.S.C. § 371 of PCT/JPl 1/58847, filed 07 April 2011. We refer to the '"255 Specification," which we cite as "Spec." 6 Such characteristics are said to include high on-state current, low off-state current, low subthreshold swing ("SS") value (the gate voltage required for increasing the drain current by one order of magnitude), and a stable threshold voltage. (Spec., para. bridging 1-2.) 2 Appeal2017-008223 Application 13/636,255 zinc, and oxygen ("IGZO"), further doped with molybdenum (Mo), are regarded as strong candidates to replace a-Si, as they exhibit high carrier mobilities and can be formed, e.g., by sputtering, at much lower temperatures. (Id. at 1, 11. 17-21.) However, the Mo-doped IGZO are said to exhibit decreased on-state current and increased subthreshold swing values. (Id. at 2, 11. 9-10.) Moreover, TFTs comprising amorphous IGZO semiconductors must exhibit higher resistance to stress induced by the application of voltages to the gate of the transistor, or by exposure to light leaking from the liquid crystal cell, both of which can shift the threshold voltage markedly. (Id. at 11. 11-16.) Morita describes IGZOs containing certain additional elements in certain amounts (see withdrawn sole independent claim 1 ), that are said to overcome these problems. Morita claims a sputtering target used to deposit the oxide (dependent claims 7, 12, 13, and 15-17). Claim 7 is representative and reads: A sputtering target for forming the oxide according to Claim 1, the sputtering target comprising In, Ga, and Zn; and at least one element selected from the group X consisting of Si, Ni, Hf, Ta, and W, wherein the sputtering target does not comprise Sn, when the oxide[7J comprises Si as the element of the group X, Si/(In +Ga+ Zn+ Si) x 100 = 2.0 to 15 at%; 7 The recitation of the term "oxide," which replaces the recitation of the term "sputtering target," formerly used in claims 8-10, was introduced in the amendment filed 3 August 2015; which also canceled claims 8-10. In the Remarks/ Arguments section of that submission, Morita cites original claim 9 for support of the amendment to claim 7. ( Amendment and Request for Continued Examination, 6, 11. 8-9 (3 August 2015).) Original claim 9 reads in relevant part, "when the sputtering target contains Al as the element of 3 Appeal2017-008223 Application 13/636,255 when the oxide[7J comprises Ni as the element of the group X, Ni/(In + Ga + Zn + Ni) x 100 = 0.1 to 5 at%; when the oxide[7J comprises Hf as the element of the group X, Hf/(In +Ga+ Zn+ Hf) x 100 = 2.0 to 10 at%; when the oxide[7J comprises Ta as the element of the group X, Ta/(In +Ga+ Zn+ Ta) x 100 = 2.0 to 10 at%; and when the oxide[7J comprises W as the element of the group X, W/(In +Ga+ Zn+ W) x 100 = 2.0 to 10 at%. (Claims App., Br. 20-21; some formatting added.) Independent claim 1, which is not before us, is drawn to an oxide comprising the elements in the amounts recited in claim 7. The Examiner maintains the following ground of rejection: s, 9, 10 Claims 7, 12, 13, and 15-17 stand rejected under 35 U.S.C. § 103(a) in view of Orita. 11 the group X" (Spec. 21, 11. 6-7 (emphasis added); similarly for other elements of group X). It appears that the term --oxide- in this context is an inadvertent substitution for the term "sputtering target." 8 Examiner's Answer mailed 10 March 2017 ("Ans."). 9 Because this application was filed before the 16 March 2013, effective date of the America Invents Act, we refer to the pre-AIA version of the statute. 10 The Examiner has withdrawn an obviousness-type double patenting rejection over U.S. Patent No. 9,184,298 B2 (10 November 2015) (issued to Shinya Morita et al., and assigned to Kobe Steel, Ltd.). (Advisory Action entered 6 June 2016.) 11 Masahiro Orita et al., Electro-conductive oxides and electrodes using the same, U.S. Patent No. 5,622,653 (1997). 4 Appeal2017-008223 Application 13/636,255 B. Discussion The Board's findings of fact throughout this Opinion are supported by a preponderance of the evidence of record. The Examiner finds that Orita discloses sputtering targets (Orita col. 13, 11. 4--23) for forming oxides comprising In, Ga, and Zn, as well as elements from group X (Orita col. 7, 11. 1-38; and col. 14, 11. 4--51) 12. (FR 2-3.) In particular, the Examiner finds that Orita discloses, in Example 4-7 [Orita col. 29, 1. 36], that "Al is present at about 2 atomic%." (FR 3, 1. 15.) The Examiner concludes that, because Si, Ni, Ge 13, Hf, Ta, and Ware equivalents to Al 12, they can all be substituted at the value of 2% exemplified for aluminum. (Id. at 11. 15-17.) In the Response to Arguments section of the Final Rejection, the Examiner explains that the substitution at 2 atomic% would have been selected because "[t]he metals are believed to be equivalent." (Id. at 8, 11. 6-7). Morita argues that the Examiner errs harmfully in finding that the ordinary worker would have understood Orita to disclose that the members of Group X are equivalents that could be substituted for one another in the same or similar amounts. (Br. 9, 2d full para.) In particular, Morita urges the Examiner takes improper Official Notice of the supposed equivalence of 12 Orita teaches, at cols. 7 and 14, conductive crystalline metal oxides and sputtering targets, respectively, both having the formula M(l )xM(2)yinzOcx + 3y/2 + 3z/2)-d, where M(l) can be Mg and Zn, M(2) can be Al and Ga, and a host of other elements, including the elements in Group X, can replace parts of M(l ), M(2), and In. 13 The elements germanium (Ge) and aluminum (Al) were canceled from group X by the amendment filed 17 December 2015. 5 Appeal2017-008223 Application 13/636,255 the group X elements, and fails to provide persuasive evidence in support of that notice. (Id.) The reason advanced by the Examiner, that the elements are equivalent because "they are listed as materials that can [a]ffect transmission" (Adv. 2, 1. 5), is not persuasive, in Morita's view, because the Examiner has not indicated where Orita teaches that the amounts would have been expected to be similar to one another, and in the range required by claim 7. (Br. 12-13.) In this regard, Morita argues that Orita teaches that the amount of metal used as replacement metal elements depends on the light transmission (more than 70%; Orita col. 7, 11. 54--58) and the carrier electron density (id. at col. 89, 11. 18-22.) (Br. 13, last para.) As evidence that the members of Group X would not have been regarded as equivalents, Morita points to Examples provided by Orita, in which Al is present in amounts ranging from 0.04 to 6 at%. (Br. 14, 11. 1-3, citing Orita Tables 2, 11, and 15 (at cols. 17, 25, and 29, respectively.) In contrast, Morita urges, Si and Ta are present in amounts ranging from 0.2 to 1 at%. (Br. 14, 11. 3-5; 15, 11. 5---6 (Si, citing Orita Tables 2, 7, 12, and 16); 16, 11. 1-2 (Ta, citing Orita Tables 2 and 12).) Thus, Morita concludes, "Orita does not teach or suggest that Al, Si, and Ta can be used in the same or similar amount." (Id. at 14, 11. 6-7.) Morita also urges that "Orita is completely silent regarding a specific content when the replacing element is Ni, Hf, or W" (id. at 10, 11. 18-19), and urges that no prima facie case of obviousness has been established for those elements either. The Examiner acknowledges that "Orita [et al.] suggest using Si and Ta at an amount of 0.2 to 1 at%." (Ans. 4, 1. 12.) "However," the Examiner continues, "one of ordinary skill in the art would readily envisage selecting 6 Appeal2017-008223 Application 13/636,255 higher amounts of Si and Ta because in doing so the transmission properties can be controlled." (Id. at 11. 12-14.) The flaw in the Examiner's argument is that, while the transmission properties will no doubt change, the Examiner has not explained how that change would be "controlled," or why the ordinary worker would have expected the transmission due to two times the amount of Si would remain within values acceptable to Orita. The Examiner responds further that "while there are differences in the various metals[,] Orita suggest ranges for use of the metals and that one of ordinary would select a value in that range to achieve control of transmission." (Ans. 8, 11. 3-5.) The Examiner urges that the ordinary worker "would readily envisage using the same or similar amount of Si, Ni, Hf, Ta, Wat the same amount as Al because control of transmission property is desired." (Id. at 11. 5-8.) The Examiner proceeds to demonstrate that the amounts of Al used as a replacement metal in Tables 2 and 11 range from 0.004 at% to 6 at%. 14 (Id. at 11. 8-16.) This demonstration does not explain, however, why the other elements would have been expected to have the same or similar optical transmission (transparency and absorption edge), and conduction carrier density, as aluminum. As Morita points out, "Orita at most only describes the equivalency of these metals in terms of their function." (Reply 3, 11. 6-7.) The Examiner has not shown that Orita describes or suggests, in Morita's words, "that the metals would be so 14 The calculation based on Example 3-14 in Table 11 shows that the amount of Al used in Example 4-7, which has the same composition, is 6 at%, not 2 at% are the Examiner found earlier (FR 3; Ans. 3.) 7 Appeal2017-008223 Application 13/636,255 equivalent that they could be used in the same or similar amount." (Id. at 11. 8-9.) We conclude that Morita has shown, by a preponderance of the evidence on the present record, that the Examiner erred harmfully in determining that the ordinary worker would have considered the elements of group X to be equivalents such that there would have been a reasonable expectation that those elements would be substituted, at the same atomic percentage, for aluminum in the IGZO sputtering targets taught by Orita. We therefore reverse. C. Order It is ORDERED that the rejection of claims 7, 12, 13, and 15-17 is reversed. REVERSED 8 Copy with citationCopy as parenthetical citation