Ex Parte Mohajeri et alDownload PDFPatent Trial and Appeal BoardJun 17, 201612629835 (P.T.A.B. Jun. 17, 2016) Copy Citation UNITED STA TES p A TENT AND TRADEMARK OFFICE APPLICATION NO. FILING DATE FIRST NAMED INVENTOR 12/629,835 12/02/2009 Ali Mohajeri 60769 7590 06/21/2016 ARASH BEHRA VESH MANNA VA & KANG, P.C. 3201 Jermantown Road Suite 525 Fairfax, VA 22030 UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www .uspto.gov ATTORNEY DOCKET NO. CONFIRMATION NO. 5000.1001 8576 EXAMINER NGUYEN, COLETTE B ART UNIT PAPER NUMBER 1732 NOTIFICATION DATE DELIVERY MODE 06/21/2016 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address( es): abehravesh@mannavakang.com docketing@mannavakang.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte ALI MOHAJERI, ALIMORAD RASHIDI,KHEIROLLAHJAF ARI JOZANI, PA YMAN KHO MARI, BARMAN AMINI, DORSA PARVIZ and MANSOUR KALBASI Appeal2015-001620 Application 12/629,835 Technology Center 1700 Before JEFFREY T. SMITH, KAREN M. HASTINGS, and MICHAEL P. COLAIANNI, Administrative Patent Judges. SMITH, Administrative Patent Judge. DECISION ON APPEAL STATEMENT OF THE CASE This is an appeal under 35 U.S.C. § 134 from a final rejection of claims 1, 4, and 7-17. We have jurisdiction under 35 U.S.C. § 6. Claim 1 is illustrative of the subject matter on appeal and is reproduced below: Appeal2015-001620 Application 12/629,835 1. A hydrodesulphurization nanocatalyst, comprising: a nano-structured porous carbonaceous support material, comprising carbon nanotubes; a first active metal selected from sulfides of the group 8B of the periodic table of elements, which sulfides are formed during the sulphurization reaction from nitrate, acetate, carbonate, sulfate, or thiocyanate salts of the group 8B metal of the periodic table of elements; and a second active metal selected from sulfides of the group 6B of the periodic table of elements, which metal is molybdenum, which sulfides are formed during the sulphurization reaction from ammonium heptamolybdate, ammonium molybdate, sodium molybdate and molybdenum oxide; wherein the molar ratio of the group 8B metal to group 6B metal is from about 0.2 to about 0.5, wherein the group 8B active metal is cobalt, and wherein the active metals in the nanocatalyst are present in an amount from about 3 to about 15 percent by weight. Appellants (App. Br. 6) request review of the following rejections from the Examiner's Final Action: 1 I. Claims 1, 7, 9, 11-14 and 17 rejected under 35 U.S.C. § 103(a) as unpatentable over Ma (US 2006/0142149 Al, published June 29, 2006) and Sudhakar (US 5,770,046, issued June 23, 1998). II. Claim 4 rejected under 35 U.S.C. § 103(a) as unpatentable over Ma, Sudhakar, and Bronner (US 6,623,628 Bl, issued September 23, 2003). 1 The Examiner withdrew the rejection under 35 U.S.C. § 112, second paragraph. Final Act. 2, Ans. 8. Accordingly, this rejection is not before us for review on appeal. 2 Appeal2015-001620 Application 12/629,835 Ill. Claim 8 rejected under 35 U.S.C. § 103(a) as unpatentable over Ma, Sudhakar, and Lin (US 7,871,592 B2, issued January 18, 2011). IV. Claim 10 rejected under 35 U.S.C. § 103(a) as unpatentable over Ma, Sudhakar, and Bening (US 5,965,470, issued October 12, 1999). V. Claims 15-17 rejected under 35 U.S.C. § 103(a) as unpatentable over Ma, Sudhakar, and Eijsbouts-Spickova (US 8,476,184 B2, issued July 2, 2013). OPINION We AFFIRM. Prior Art Rejections Rejection I (claims 1, 11 and 12)2 After review of the respective positions provided by Appellants and the Examiner, we AFFIRM the Examiner's prior art rejection of claims 1, 7, 9, 11-14 and 17 under 35 U.S.C. § 103(a) for the reasons presented by the Examiner and add the following for emphasis. Claim 1 Independent claim 1 is directed to a hydrodesulphurization nanocatalyst comprising a carbon nanotube support having as active metals a Co sulfide and a Mo sulfide where the Co to Mo molar ratio is from about 0.2 to about 0.5. 2 Appellants present separate arguments for independent claims 1, 12 and dependent claim 11 but do not present separate arguments for dependent claims 7, 9, 13, 14 and 17. See Appeal Brief, generally. Accordingly, we select independent claim 1 as representative of the subject matter before us on appeal. Claims argued separately will be addressed separately. However, claims 7, 9, 13, 14 and 17 will stand or fall with their respective independent claim. 3 Appeal2015-001620 Application 12/629,835 We refer to the Examiner's Answer for a statement of the rejection. Final Act. 3--4. Appellants argue Ma does not suggest a catalyst having a first active metal of only Co and a second active metal of only Mo because Ma's catalyst requires the presence of other metals. App. Br. 10-11; Ma i-f 74. Appellants additionally argue Sudhakar does not disclose the claimed Co to Mo molar ratio. App. Br. 11. We are unpersuaded by Appellants' arguments and agree with the Examiner's determination of obviousness for the reasons provided by the Examiner. Ans. 8-9. First, we agree with the Examiner's determination that the use of the transitional open language "comprising" in claim 1 does not limit the metals present in the catalyst to just Co and Mo. Id. at 8. With respect to the molar ratio of Co to Mo, the Examiner found Ma discloses a hydrodesulfurisation nanocatalyst comprising a nano-structured support and sulfides of Co and Mo. Final Act. 3--4, Ma Abstract i-fi-1 14, 15, 24, 31, 92. While Ma is silent as to the molar ratio of Co to Mo, the Examiner found Sudhakar teaches a hydrodesulfurisation catalyst having a carbonaceous support comprising 0.1-15% Co and 0.5-30% Mo as catalytic metals .. Final Act. 4; Sudhakar col. 9, 11. 10-65. The Examiner determined these disclosed amounts result in Co to Mo molar ratios that overlap the claimed Co to Mo molar ratio. Final Act. 4. Moreover, Appellants acknowledge that Sudhakar' s amounts for Co and Mo result in a broad Co to Mo molar ratio range that encompasses the claimed molar ratio for the same elements. App. Br. 12. Thus, since the amounts of Co and Mo and, thus, a ratio representing these amounts, are result effective variables, the Examiner provided a reasonable basis to combine the cited art to arrive to the claimed invention. 4 Appeal2015-001620 Application 12/629,835 It is well settled that it would have been obvious for an artisan with ordinary skill to develop workable or even optimum ranges for result-effective parameters. In re Boesch, 617 F.2d 272, 276 (CCPA 1980); In re Aller, 220 F.2d 454, 456 (CCPA 1955); In re Woodruff, 919 F.2d 1575, 1577-78 (Fed. Cir. 1990)(where the difference between the claimed invention and the prior art is some range, the applicant must show that the particular range is critical, generally by showing that the claimed range achieves unexpected results relative to the prior art range). Thus, Appellants have not adequately explained why one skilled in the art would not have been capable of arriving to the claimed catalysts from the teachings of the cited references. In addition, Appellants principally assert the data in Table 3 of the Specification shows unexpected results by the claimed Co to Mo molar ratio in the form of improved hydrodesulfurisation performance when compared against the hydrodesulfurisation performance of Sudhakar's catalysts. App. Br. 12; Spec. i-fi-170-73 (Table 3 appears after i173). The burden of establishing unexpected results rests on the person who asserts them. Appellants may meet their burden by establishing that the difference between the claimed invention and the closest prior art was an unexpected difference. See In re Klosak, 455 F.2d 1077, 1080 (CCPA 1972). The unexpected results must be established by factual evidence, and attorney statements are insufficient to establish unexpected results. See In re Geisler, 116 F.3d 1465, 1470-71 (Fed. Cir. 1997). Further, a showing of unexpected results supported by factual evidence must be reasonably commensurate in scope with the degree of protection sought by the claims on appeal. In re Grasselli, 713 F.2d 731, 743 (Fed. Cir. 1983); In re Clemens, 622 F.2d 1029, 1035(CCPA1980). 5 Appeal2015-001620 Application 12/629,835 We find the evidence is insutlicient to establish unexpected results. First of all, Table 3 does not include any information about the Co to Mo molar ratio of the claimed catalysts tested and Appellants provide no explanation or direct us to any portion of the Specification discussing this feature with respect to the proffered comparison. Thus, one skilled in the art is unable to ascertain if this proffered showing, in fact, demonstrates the unexpected results asserted by Appellants. Secondly, Appellants asserted focus of the showing is the Co to Mo molar ratio. App. Br. 12. However, the comparison is between catalysts having different carbonaceous supports (claimed nano-based v. Sudhakar' s non-nano based supports)). Appellants have not adequately explained what impact, if any, the different type of supports has in the effectiveness of the dehydrosulfurisation process. Lastly, Appellants have tested only two catalysts having combined active metal contents of 5 and 10% while the claimed invention requires from about 3 to about 15 percent by weight combined active metals. Appellants have not adequately explained why the two tested catalysts are representative of the entire range of combined active metal contents claimed for the catalyst. On this record, Appellants have not adequately shown, much less explained, why the evidence relied upon would have been unexpected by one of ordinary skill in the art or is reasonably commensurate in the scope with the claims. See, e.g., In re Harris, 409 F.3d 1339, 1344 (Fed. Cir. 2005) ("Even assuming that the results were unexpected, Harris needed to show results covering the scope of the claimed range. Alternatively Harris 6 Appeal2015-001620 Application 12/629,835 needed to narrow the claims."); Jn re Greenfield, 571 F .2d 1185, 1189 (CCP A 1978). Claim 11 Claim 11 is directed a hydrodesulphurization process using the catalyst of claim 1 where the hydrodesulphurization reaction is conducted at a pressure of about 15 bar or less. We have considered Appellants' arguments with respect to claim 11 and find them unavailing. App. Br. 13; Reply Br. 4. In the Reply Brief, Appellants acknowledge that Sudhakar discloses a reaction pressure range of between 200 and 1000 psig that encompasses the claimed reaction pressure range of about 15 bar or less (217 psig or less). Reply Br. 4. While Appellants argue that Sudhakar's preferred range of reaction pressures does not overlap the claimed range, it is well settled that a reference may be relied upon for all that it would have reasonably suggested to one having ordinary skill in the art, including non-preferred embodiments. Reply Br. 4; Merck & Co. v. Biocraft Labs., Inc., 874 F.2d 804, 807 (Fed. Cir. 1989) ("all disclosures of the prior art, including unpreferred embodiments, must be considered") (quoting In re Lamberti, 545 F.2d 747, 750 (CCPA 1976)). Given Appellants' acknowledgement, Appellants have not adequately distinguished the claimed process from the process of the prior art. Claim 12 Claim 12 is directed a method of making a nanocatalyst comprising a specific drying step. 7 Appeal2015-001620 Application 12/629,835 Appellants argue Ma's Example 13 discloses temperature and time combination (130° C for 20 hours) valid for specific CrCh catalysts and cannot be simply generalized to other catalysts. Reply Br. 5.; Ma i-f 145. We are unpersuaded by this argument because claim 12 is not limited to a particular catalyst. Accordingly, we affirm the Examiner's prior art rejection of claims 1, 7, 9, 11-14 and 17 for the reasons presented by the Examiner and given above. Rejections 11-V In addition, the Examiner separately rejected dependent claims 4, 8, 10 and 15-17 under 35 U.S.C. § 103(a) as unpatentable over Ma and Sudhakar in combination with a number of additional references (Rejections II-V). Final Act. 5-8. In addressing these separate rejections, Appellants rely primarily on the arguments presented when discussing Rejection I. App. Br. 14--16. Appellants did not substantially address or further distinguish the respectively cited secondary references based on the additional limitations of the dependent claims. Id. Accordingly, we sustain the Examiner's Rejections II-V for the reasons presented by the Examiner and given above. ORDER The Examiner's prior art rejections of claims 1, 4, and 7-17 are affirmed. TIME PERIOD 8 Appeal2015-001620 Application 12/629,835 No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a)(l). AFFIRMED 9 Copy with citationCopy as parenthetical citation