Ex Parte Matzdorf et alDownload PDFBoard of Patent Appeals and InterferencesApr 30, 201011116165 (B.P.A.I. Apr. 30, 2010) Copy Citation UNITED STATES PATENT AND TRADEMARK OFFICE ____________________ BEFORE THE BOARD OF PATENT APPEALS AND INTERFERENCES ____________________ Ex parte CRAIG A. MATZDORF and WILLIAM C. JR., NICKERSON ____________________ Appeal 2009-009912 Application 11/116,1651 Technology Center 1700 ____________________ Decided: April 30, 2010 ____________________ 1 As Appellants point out at page 4 of the Appeal Brief, the subject matter in this appeal is related to the subject matter in U.S. Patent Application Nos. 11/058,533 (filed Feb. 15, 2005), 11/058,715 (filed Feb. 15, 2005), 11/116,166 (filed Apr. 21, 2005), and 11/076,106 (filed Feb. 15, 2005). Before: MICHAEL P. COLAIANNI, CATHERINE Q. TIMM, and JEFFREY T. SMITH, Administrative Patent Judges. COLAIANNI, Administrative Patent Judge. Appeal 2009-009912 Application 11/116,165 2 DECISION ON APPEAL This is a decision on an appeal under 35 U.S.C. § 134 from the Examiner's final rejection of claims 17 through 40. Claims 1 through 16, the other claims pending in this application, stand withdrawn from consideration by the Examiner. We have jurisdiction pursuant to 35 U.S.C. § 6. We AFFIRM-IN-PART. STATEMENT OF THE CASE The subject matter on appeal is directed to compositions for coating metal substrates. Claim 17 is illustrative: 17. Compositions for coating metal substrates to improve the corrosion protection and adhesion bonding strength of said metal which comprise an acidic aqueous solution having a pH ranging from about 1.0 to 5.5 and per liter of said solution from about 0.01 to 100 grams of at least one trivalent chromium compound, from about 0.01 to 24 grams of at least one fluorozirconate, an effective amount of at least one water-soluble corrosion inhibitor selected from the group consisting of triazobes, benzimidazoles, benzazoles, benzoxazoles and mixtures of said inhibitors, from about 0.0 to 20 grams of divalent zinc compounds, from about 0.0 to 20 grams of surfactants, from about 0.0 to 20 grams of thickeners, and effective amounts of a stabilizing compound selected from the group consisting of polyhydroxy compounds, carboxylic compounds and mixtures of polyhydroxy and carboxylic compounds. As evidence of unpatentability of the claimed subject matter, the Examiner relies upon the following references: Lipinski US 4,138,353 Feb. 6, 1979 Redmore US 4,235,838 Nov. 25, 1980 Appeal 2009-009912 Application 11/116,165 3 Crotty US 4,359,348 Nov. 16, 1982 Palmer US 4,719,035 Jan. 12, 1988 Guhde US 4,971,635 Nov. 20, 1990 Komiyama US 6,447,620 B1 Sep. 10, 2002 Gonzalez '427 US 2005/0126427 A1 Jun. 16, 2005 Gonzalez '062 WO 03/056062 Jul. 10, 2003 Claims 17-40 of copending U.S. Patent Application No. 11/116,166, filed April 21, 2005. The Examiner maintains the following rejections: 1) Claims 17-20, 23, 24, 29, 31, 32, 38, and 39 under 35 U.S.C. § 103(a) as unpatentable over Gonzalez '062, whose English equivalent is Gonzalez '4272; 2) Claims 33 and 40 under 35 U.S.C. § 103(a) as unpatentable over Gonzalez '062, and further in view of Palmer; 3) Claims 34 and 35 under 35 U.S.C. § 103(a) as unpatentable over Gonzalez '062, and further in view of Redmore; 4) Claims 36 and 37 under 35 U.S.C. § 103(a) as unpatentable over Gonzalez '062, and further in view of Lipinski; 5) Claims 21, 22, 25-28 and 30 under 35 U.S.C. § 103(a) as unpatentable over Gonzalez '062, and further in view of Guhde as evidenced by Crotty or Komiyama3; 2 With respect to rejection (1), Appellants do not dispute or question the Examiner's statement at page 3 of the Answer that Gonzalez '427 (US 2005/0126427 A1) is the "English equivalent" or translation of Gonzalez '062 (WO 03/056062). Thus, our reference to Gonzalez '062 is to the translation thereof (i.e., Gonzalez '427). 3 As is apparent from page 3 of the Final Rejection (mailed on April 8, 2008) and pages 2-9 of the Answer, the Examiner has withdrawn the §103(a) rejection of claims 21, 22, 25-28 and 30 over "Gonzalez, and further in view of Guhde" and replaced it with this new ground of rejection. Appeal 2009-009912 Application 11/116,165 4 6) Claims 17-32 and 38-39 are provisionally rejected under nonstatutory obviousness-type double patenting over claims 17-40 of copending U.S. Patent Application No. 11/116,166 and Gonzalez '062; 7) Claims 33 and 40 are provisionally rejected under nonstatutory obviousness-type double patenting over claims 17-40 of copending U.S. Patent Application No. 11/116,166 and Gonzalez '062, and further in view of Palmer; 8) Claims 34 and 35 are provisionally rejected under nonstatutory obviousness-type double patenting as unpatentable over claims 17-40 of copending U.S. Patent Application No. 11/116,166 and Gonzalez '062, and further in view of Redmore; and 9) Claims 36 and 37 are provisionally rejected under nonstatutory obviousness-type double patenting as unpatentable over claims 17-40 of copending U.S. Patent Application No. 11/116,166 and Gonzalez '062, and further in view of Lipinski.4 REJECTION (1) With respect to rejection (1), Appellants' arguments focus on claims 17. Accordingly, we address Appellants' arguments regarding the rejection with respect to claim 17 only. See 37 C.F.R. § 41.37(c)(1)(vii). 4 With respect to rejections (2) through (9), we note that the Examiner's statements of the rejections made at pages 5 through 9 of the Answer applying "Gonzalez" (i.e., Gonzalez '427 as defined by the Examiner at page 3 of the Answer) as a reference is harmless error since it is apparent from pages 3 through 9 of the Answer that the rejections apply Gonzalez '062 (WO 03/056062) and merely employ Gonzalez '427 (US 2005/0126427 A1) in the bodies of these rejections as the "English equivalent" or translation thereof. Appeal 2009-009912 Application 11/116,165 5 ISSUE Did the Examiner reversibly err in determining that Gonzalez '062 would have suggested compositions for coating metal substrates comprising, inter alia, a trivalent chromium compound and a fluorozirconate as required by claim 17 within the meaning of § 103? We decide this issue in the negative. FINDINGS OF FACT 1. The Examiner finds that "Gonzalez teaches using trivalent chromium in paragraph [0046] and fluorozirconate in paragraph [0075]." (Ans. 11). 2. Gonzalez '062 teaches compositions for treating metal surfaces for, inter alia, corrosion protection comprising a) at least one polymer as component A, composed of aa) at least one amino-containing polymer as component Aa; ab) at least one aromatic compound as component Ab, being a phenol or quinone or containing a phenolic or quinonoid structural unit; ac) if desired, an aldehyde as component Ac; b) water or another solvent suitable for dissolving, dispersing, suspending or emulsifying the polymer (component A), as component B; c) if desired, surface-active compounds, dispersants, suspension media and/or emulsifiers as component C. (Gonzalez '427, ¶¶ [0001] and [0021]-[0027]). Gonzalez '062 teaches that one of the ingredients of component Ab may be a "M+ [having] . . . a cation with a valence of two or more, preferably . . . Cr(III)." (Gonzalez '427, ¶ [0046], see also ¶¶ [0040]-[0045]). 3. Gonzalez '062 teaches that Appeal 2009-009912 Application 11/116,165 6 In one preferred embodiment, the composition of the invention is used for the treatment of metal surfaces and comprises further to components A, B and, where appropriate, C: d) at least one salt, acid or base based on transition metal cations, transition metal oxo anions, fluorometallates or lanthanoids as component D, and/or e) at least one acid selected from the group consisting of phosphoric acid, sulfuric acid, sulfonic acids, nitric acid, hydrofluoric acid, and hydrochloric acid, as component E, and/or f ) at least one further corrosion inhibitor as component F, and/or g) compounds of Ce, Ni, Co, V, Fe, Zn, Zr, Ca, Mn, Mo, W, Cr and/or Bi as component G, and/or h) further auxiliaries and additives as component H. (Gonzalez '427, ¶¶ [0067]-[0072]). In this regard, Gonzalez '062 teaches that "[s]uitable components D are salts, acids, and bases based on transition metal cations, transition metal oxo anions, fluorometallates or lanthanoids. Suitable transition metal cations are, in particular, fluorometallates of Ti(IV), Zr(IV), Hf(IV) and/or Si(IV), and a particularly suitable lanthanoid is Ce. Also suitable are tungstates and molybdates." (Gonzalez '427, ¶ [0075]). ANALYSIS AND CONCLUSION Appellants argue that There is no teaching in the Gonzalez reference, for example, to use a zirconate in combination with trivalent chromium. The Examiner can not [sic] pick and choose certain compounds from an unrelated reference to anticipate or suggest the claims after having the benefit of applicants [sic] disclosure. The Examiner uses a selective combination of compounds from the Gonzalez et al. disclosure to suggest that the claimed invention is Appeal 2009-009912 Application 11/116,165 7 obvious without any reason other than hindsight taken from applicants specification. (App. Br. 16). Contrary to Appellants' arguments, however, the Examiner correctly finds that "Gonzalez teaches using trivalent chromium in paragraph [0046] and fluorozirconate in paragraph [0075]." (FF 1). In this regard, Gonzalez '062 teaches that its composition may comprise, inter alia, Cr(III) (i.e., trivalent chromium), and fluorometallates such as Zr(IV) (i.e., fluorozirconate). (FF 2 and 3). In addition, Appellants argue that "Applicants are not using a polymeric media or composition as taught by Gonzalez" but instead uses an inorganic composition as required by the claims. (App. Br. 16-17). We find this argument unpersuasive of reversible error because this "inorganic" feature is not claimed and thus is not required by claim 17. As the Examiner indicates, the claim uses the open-ended claim language “comprising†which would not exclude polymeric media in addition to the features claimed. Thus, it follows that the Examiner did not reversibly err in determining that Gonzalez '062 would have suggested compositions for coating metal substrates comprising, inter alia, a trivalent chromium compound and a fluorozirconate as required by claim 17 within the meaning of § 103. Accordingly, we sustain the Examiner's rejection (1). Appeal 2009-009912 Application 11/116,165 8 REJECTIONS (2) through (4) With respect to rejections (2) through (4), Appellants argue that the combination of the applied prior art references is improper because "[t]he Examiner is attempting to pick and choose various components from a number of unrelated secondary references of Palmer, Redmore and Lipinski, and combining the teachings of these patents with the primary reference of Gonzalez." (App. Br. 19). Appellants, however, do not specifically dispute the Examiner's findings or reasons stated at pages 5 and 6 in the Answer to combine the teachings of Palmer, Redmore, or Lipinski with the teachings of Gonzalez '062 to arrive the inventions recited in the rejected dependent claims of rejections (2) through (4). Compare Ans. 5-6 with App. Br. 18-20 and Reply Br. 12-15. In addition, Appellants repeat arguments made in connection with rejection (1). (App. Br. 18-20). For the reasons discussed above, we find these arguments unpersuasive of reversible error. Accordingly, we sustain the Examiner's rejections (2) through (4). REJECTION (5) With respect to rejection (5), Appellants focus their arguments on claims 21 and 22. (Reply Br. 6-11). Accordingly, we address Appellants’ arguments with respect to claims 21 and 22. See 37 C.F.R. § 41.37(c)(1)(vii). For reasons evident below, we also address the rejection of claims 25-28 and 30. See 37 C.F.R. § 41.37(c)(1)(vii). Appeal 2009-009912 Application 11/116,165 9 Claims 21 and 22 We begin by noting that claims 21 and 22 require, inter alia, glycolic acid and lactic acid, respectively. The Examiner states that [r]egarding claims 21-22, since the coating solution of Gonzalez already contain citric acid, one of ordinary skill in the art would have found it obvious to have substituted the citric acid in the coating solution of Gonzalez with other carboxylic acid such as glycolic and lactic acids of Guhde with expected success since Guhde teach that citric, glycolic and lactic acids are functionally equivalent carboxylic acids in a chromium containing coating composition. (Ans. 10) (emphasis added). We disagree. While Gonzalez at paragraph [0106] teaches the use of citric acid, the Examiner neither persuasively explains nor directs us to any credible teaching that this citric acid is functionally equivalent to glycolic and lactic acids as required by claims 21 and 22. In this regard, Gonzalez teaches at paragraph [0106] that citric acid is used as a complexing agent, which is known to form a complex with another ingredient. Guhde teaches at column 4, lines 25-63 using an acid such as citric, glycolic, and lactic as a reducing agent, which is known to function as an electron donor in order to reduce another species. Indeed, Appellants correctly state that [t]he examiner states that since the coating of Gonzalez contains citric acid, one of ordinary skill in the art would have found it obvious to have substituted the citric acid in the coating of Gonzalez with other carboxylic acid such as lacitic acids of Guhde with expected success, since Guhde teaches that lactic acids are functionally equivalent to carboxylic acids in a chromium-containing coating composition. . . . [a]n examination of the Guhde reference fails to disclose that Appeal 2009-009912 Application 11/116,165 10 carboxylic acids and polyhydric alcohols are chemical [i.e., functional] equivalents. (Reply Br. 9). Accordingly, we reverse the Examiner's rejection of claims 21 and 22 under 35 U.S.C. § 103(a) over Gonzalez '062, and further in view of Guhde as evidenced by Crotty or Komiyama. Claims 25-28 and 30 ISSUE Did the Examiner reversibly err in determining that the applied prior art references would have suggested the inventions recited in claims 25-28 and 30 within the meaning of § 103? We decide this issue in the negative. ADDITIONAL FINDING OF FACT 4. Appellants do not specifically dispute the Examiner's determination that Gonzalez does not teach the claimed glyconic . . . acid. . . . Guhde teach a corrosion inhibiting coating composition comprising Cr(VI). Guhde further teaches using a combination of carboxylic acid, such as citric, glycolic and lactic acids, and polyhydric alcohol such as glycerol, to produce a low-cure coating(abstract, col. 3 lines 55-58 and 62-63, col. 4 lines 26-29 and 57-59). It is widely known and used in the chromium containing reactive coating art that trivalent chromium and hexavalent chromium are both corrosion inhibitors and can be used interchangeably in a coating composition to form a protective coating a metal surface for corrosion inhibition. Evidence of such well known facts can be found in background teachings of Crotty or Komiyama. The toxic nature of hexavalent chromium is also well known as admitted by the instant specification. Replacing hexavalent chromium with trivalent chromium in a chromium Appeal 2009-009912 Application 11/116,165 11 coating composition is also well known and widely practiced with success as evidence by Crotty or Komiyama. Therefore, one of ordinary skill in the art would have known to incorporate the same coating components and additives for a hexavalent chromium containing coating solution into a trivalent chromium containing coating solution with expected success. . . . . Regarding claims 25-28 and 30, it would have been obvious to one of ordinary skill in the art to have incorporated the combination of carboxylic acids, such as citric, glycolic, and lactic acids, and polyhydric alcohol such as glycerol as taught by Guhde into the coating solution of Gonzalez in order to produce a low- cure coating as taught by Guhde. (Compare Ans. 9-10 with App. Br. 18-20 and Reply Br. 12-15). ADDITIONAL PRINCIPLE OF LAW “[T]he law does not require that the references be combined for the reasons contemplated by the inventor.†In re Beattie, 974 F.2d 1309, 1312 (Fed. Cir. 1992). ANALYSIS AND CONCLUSION We begin by noting that the Examiner's rejection of claims 25-28 and 30 stands on a different footing than the Examiner's rejection of claims 21 and 22 because the Examiner articulates a different reason for combining the applied prior art references to arrive at the inventions recited in claims 25-28 and 30. (See FF 4). Turning our attention to the merits of the Examiner's rejection of claims 25-28 and 30, Appellants argue that "[b]efore combining four unrelated prior art patents to reach a conclusion that the claimed subject matter is obvious, there should be some teaching or suggestion to one skilled in the art to combine each of these references." (Reply Br. 11). In addition, Appellants argue that "there is no teaching that would suggest the . . . Appeal 2009-009912 Application 11/116,165 12 hydroxy-carboxy compounds claimed by appellants to the primary reference of Gonzalez." (Reply Br. 8). These arguments, however, fail to address and thus fail to identify reversible error in the Examiner's stated findings and reason for combining Gonzalez and Guhde5 to arrive at the claimed inventions. (FF 4). Thus, we agree with the Examiner's determination that, with respect to claims 25-28 and 30, "it would have been obvious . . . to have incorporated the combination of carboxylic acids, such as citric, glycolic, and lactic acids, and polyhydric alcohol such as glycerol as taught by Guhde into the coating solution of Gonzalez in order to produce a low-cure coating as taught by Guhde." (FF 4) (emphasis added). In addition, Appellants also argue that "Guhde reference fails to disclose that carboxylic acids and polyhydric alcohols are chemical equivalents as thought [sic, taught] by applicants for a specific use and therefore would [not] be obvious to add the combination of carboxy and hydroxy compounds to the coating of Gonzalez to produce a low-curing coating." (Reply Br. 9-10) (emphasis added). While it is true that Guhde does not disclose that carboxylic acids and polyhydric alcohols are chemical equivalents for Appellants’ disclosed use, it is well settled that “[t]he law does not require that the references be combined for the reasons contemplated by the inventor.†See Beattie, 974 F.2d at 1312. In this regard, as stated above, Appellants do not specifically dispute the Examiner's reason for combining Gonzalez and Guhde, which is 5 We note that the Examiner relies on Crotty and Komiyama as evidence to show that it is known to "incorporate the same coating components and additives for a hexavalent chromium containing coating solution into a trivalent chromium containing coating solution." (FF 4). Appeal 2009-009912 Application 11/116,165 13 different from Appellants' reason, to arrive at the claimed invention. (See FF 4). In addition, Appellants repeat the arguments made in the above rejections. (Reply Br. 8). For the reasons discussed above, Appellants' arguments are without persuasive merit. Thus, it follows that the Examiner did not reversibly err in determining that the applied prior art references would have suggested the inventions recited in claims 25-28 and 30 within the meaning of § 103. Accordingly, we sustain the Examiner's rejection of claims 25-28 and 30 under 35 U.S.C. § 103(a) over Gonzalez '062, and further in view of Guhde as evidenced by Crotty or Komiyama. REJECTIONS (6) through (9) Appellants argue that it is applicants['] contention that the claims of this application . . . and the claims of SN: 11/116,166 . . . are mutually exclusive in that the claims of this application (SN: 11/116,165) recite the use of inhibitors i.e. the triazoles, benzimidazoles, benazaoles, benzoxazoles and mixtures of these inhibitors together with the other compounds as set forth in the claims. (App. Br. 22). Appellants, however, do not specifically dispute the Examiner's findings or reasons stated at pages 7 through 9 in the Answer that claims 17- 40 would have been an obvious variation of claims 17-40 of copending U.S. Patent Application No. 11/116,116 in light of the disclosures of the applied prior art references. (Compare Ans. 7-9 with App. Br. 21-24 and Reply Br. 12-15). Thus, Appellants' arguments are unpersuasive of reversible error. Accordingly, we sustain the Examiner's rejections (6) through (9). Appeal 2009-009912 Application 11/116,165 14 ORDER In summary, the Examiner's rejections (1) through (4) and (6) through (9) are sustained. With respect to rejection (5), we sustain the Examiner's rejection of claims 25-28 and 30 and reverse the Examiner's rejection of claims 21 and 22. Accordingly, the decision of the Examiner is affirmed-in-part. TIME PERIOD No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a)(1) (2009). AFFIRMED-IN-PART kmm DEPARTMENT OF THE NAVY (NAVAL AIR WARFARE CENTER -AIRCRAFT DIVISION) 47076 LIJENCREANTZ ROAD, B 435 PATUXENT RIVER, MD 20670 Copy with citationCopy as parenthetical citation