Ex Parte MatuszDownload PDFPatent Trial and Appeal BoardSep 25, 201712865021 (P.T.A.B. Sep. 25, 2017) Copy Citation United States Patent and Trademark Office UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O.Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 12/865,021 10/25/2010 Marek Matusz TH2905 US 9730 23632 7590 09/27/2017 SHF! T OH miUPANY EXAMINER P 0 BOX 576 NGUYEN, COLETTE B HOUSTON, TX 77001-0576 ART UNIT PAPER NUMBER 1732 NOTIFICATION DATE DELIVERY MODE 09/27/2017 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): USPatents@Shell.com Shelldocketing@cpaglobal.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte MAREK MATUSZ Appeal 2016-008482 Application 12/865,021 Technology Center 1700 Before JULIA HEANEY, MONTE T. SQUIRE, and JENNIFER R. GUPTA, Administrative Patent Judges. GUPTA, Administrative Patent Judge. DECISION ON APPEAL1 Appellant2 appeals under 35 U.S.C. § 134(a) from the Examiner’s final decision rejecting claims 1—12 and 16—23.3 We have jurisdiction under 35 U.S.C. § 6(b). We AFFIRM. 1 In this decision, we refer to Appellant’s Specification filed July 28, 2010 (“Spec.”), the Final Office Action mailed December 2, 2014 (“Final Act.”), the Appeal Brief filed May 1, 2015 (“Br.”), and the Examiner’s Answer mailed September 11, 2015 (“Ans.”). 2 Appellant identifies the real party in interest as Shell Oil Company. Br. 2. 3 Claims 13—15 stand withdrawn from consideration by the Examiner pursuant to 35 U.S.C. § 1.142(b) as being drawn to a non-elected invention. Non-Final Office Action mailed April 8, 2013. Appeal 2016-008482 Application 12/865,021 The subject matter on appeal is directed to an epoxidation catalyst and a process for preparing the catalyst. Spec. 1,11. 5—8. Independent claim 1, reproduced below from the Claims Appendix of the Appeal Brief, is illustrative of the claims on appeal. 1. A catalyst for the epoxidation of an olefin comprising a carrier and, deposited on the carrier, silver, a rhenium promoter, a first co-promoter, and a second co-promoter; wherein the molar ratio of the first co-promoter to the second co promoter is greater than 1 and at most 20; the first co-promoter is selected from sulfur, phosphorus, boron, and mixtures thereof; and the second co-promoter is selected from tungsten, molybdenum, chromium, and mixtures thereof. Br. 10 (Claims Appendix). Independent claim 12 is directed to preparing a catalyst for the epoxidation of an olefin and includes all the same components in the same molar ratios as the catalyst as recited in independent claim 1. DISCUSSION Rejection 3 — Obviousness The Examiner maintains the rejection of claims 1—12 and 16—23 under 35 U.S.C. § 103(a) as unpatentable over Matusz et al. (US 2004/0198992 Al, published October 7, 2004) (“Matusz”) or Remus et al. (WO 2007/095453 Al, published August 23, 2007) (“Remus”). Final Act. 2—5. We review the appealed rejections for error based upon the issues identified by Appellant and in light of the arguments and evidence produced 2 Appeal 2016-008482 Application 12/865,021 thereon. Cf. Ex parte Frye, 94 USPQ2d 1072, 1075 (BPAI 2010) (precedential) (cited with approval in In re Jung, 637 F.3d 1356, 1365 (Fed. Cir. 2011) (“it has long been the Board’s practice to require an applicant to identify the alleged error in the examiner’s rejections”)). After considering each of Appellant’s contentions, we are not persuaded that Appellant identifies reversible error. Thus, we sustain the Examiner’s rejections for the reasons expressed in the Final Office Action, the Answer, and below. The Examiner finds that Matusz discloses a catalyst for the epoxidation of ethylene (an olefin) where the catalyst comprises a support, and deposited on the support, a silver metal, rhenium, a co-promoter selected from one or more of sulfur, phosphorus, and boron in an amount of 0.1 to 30 mmole/kg each (corresponding to the recited “first co-promoter”), and one or more of rhenium, molybdenum, tungsten, and nitrate- or nitrite forming compounds, where tungsten, for example, may preferably be present in an amount ranging from 0.5 to 20 mmole/kg (corresponding to the “second co-promoter”). Final Act. 2-4; Matusz H 1, 7, 9, 27, and 38. The Examiner finds that the molar ratios of the “first co-promoter” to the “second co-promoter,” 0.1—30:0.5—20, overlap with the ratio of “greater than 1 and at most 20,” recited in claims 1 and 12. Final Act. 2—3. The Examiner finds that Remus discloses a process for preparing an epoxidation catalyst comprising a carrier with silver, a promoter component that may be one or more of rhenium, tungsten, molybdenum, chromium, and mixtures thereof in an amount of at least 0.01 mmole/kg to at most 50 mmole/kg (corresponding to the recited “rhenium promoter” and “second co-promoter”), and a co-promoter component that may be one or more of tungsten, chromium, molybdenum, sulfur, phosphorus, boron and mixtures 3 Appeal 2016-008482 Application 12/865,021 thereof in an amount of at least 0.1 mmole/kg to at most 40 mmole/kg (corresponding to the recited “first co-promoter”), deposited thereon. Final Act. 4—5; Remus, 1,11. 7—9, and 11. 20-21, 14,11. 22—25, 15,11. 11—21, and 15,1. 31—16,1. 11. The Examiner finds that the molar ratios of the “first co promoter” to the “second co-promoter,” 0.1—40:0.01—50, overlap with the ratio of “greater than 1 and at most 20,” recited in claims 1 and 12. Final Act. 4. First, Appellant argues that neither Matusz nor Remus provides any teaching that would have led one of ordinary skill in the art to select the specific combination of promoters and co-promoters with the claimed molar ratio. Br. 4. According to Appellant, the skilled person would be left to “pick and choose” from many possible combinations of various promoters and co-promoters, in a broad range of amounts, with no reasonable expectation of success whether any particular combination would improve the performance of the catalyst compositions at all. Id. Appellant’s argument is not persuasive of reversible error. Matusz’s and Remus’ disclosures would have indicated to one of ordinary skill in the art that any combination of the disclosed promoters and co-promoters, in any of the disclosed amounts, including the combination and molar ratios recited in Appellant’s claims, is suitable. See Merck & Co., Inc. v. Biocraft Labs., Inc., 874 F.2d 804, 807 (Fed. Cir. 1989) (The fact that a reference “discloses a multitude of effective combinations does not render any particular formulation less obvious.”). Thus, we discern no reversible error in the Examiner’s conclusion that the claimed catalyst and process for preparing the catalyst would have been prima facie obvious to one of ordinary skill in the art based on Matusz or Remus. 4 Appeal 2016-008482 Application 12/865,021 Second, Appellant argues that the evidence of record, in particular the Declaration under 37 C.F.R. § 1.132 executed by Dr. Marek Matusz on January 15, 2014 (“Dr. Matusz’s Declaration”), provides data that demonstrates unexpected results of the claimed catalyst. Br. 4—5. We have reviewed Appellant’s evidence, but do not find it persuasive. Claims 1 and 12 recite that “the molar ratio of the first co-promoter to the second co-promoter is greater than 1 and at most 20.” The data presented in Dr. Matusz’s Declaration demonstrates that an inventive catalyst that includes a first co-promoter and a second co-promoter in a molar ratio of 3 or 5 has improved initial selectivity as compared to a similar catalyst that includes the first co-promoter and the second co-promoter in a molar ratio of 1. Dr. Matusz’s Declaration at 4 (Table 1). Dr. Matusz’s Declaration, however, fails to include inventive examples of catalysts that include the first co-promoter and the second co-promoter in other molar ratios within the claimed range, e.g., a molar ratio closer to 20. On this record, Appellant has not established that the results obtained when using a catalyst within the scope of claims 1 and 12 that includes the first co-promoter and second co promoter in a molar ratio of 3 or 5 would be obtained over the entire range of ratios covered by the claims. In re Grasselli, 713 F.2d 731, 743 (Fed. Cir. 1983) (concluding that unexpected results “limited to sodium only” were not commensurate in scope with claims to a catalyst having “‘an alkali metal’”); see also In re Kao, 639 F.3d 1057, 1068 (Fed. Cir. 2011). Therefore, as the Examiner finds, Appellant’s evidence fails to establish unexpected results over the entire claimed range of “greater than 1 and at most 20” recited in claims 1 and 12. 5 Appeal 2016-008482 Application 12/865,021 DECISION For the above reasons, the Examiner’s decision to reject claims 1—12 and 16—23 is affirmed. No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a). AFFIRMED 6 Copy with citationCopy as parenthetical citation