Ex Parte MalikDownload PDFPatent Trial and Appeal BoardOct 30, 201813745037 (P.T.A.B. Oct. 30, 2018) Copy Citation UNITED STA TES p A TENT AND TRADEMARK OFFICE APPLICATION NO. FILING DATE 13/745,037 01/18/2013 20411 7590 10/30/2018 The Linde Group 200 Somerset Corporate Blvd. Suite 7000 Bridgewater, NJ 08807 FIRST NAMED INVENTOR Zaheer I. Malik UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www .uspto.gov ATTORNEY DOCKET NO. CONFIRMATION NO. Pl3A002 4081 EXAMINER RAYMOND, KEITH MICHAEL ART UNIT PAPER NUMBER 3763 MAIL DATE DELIVERY MODE 10/30/2018 PAPER Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte ZAHEER I. MALIK Appeal2017-004545 Application 13/745,037 1 Technology Center 3700 Before LINDA E. HORNER, LISA M. GUIJT, and ERIC C. JESCHKE, Administrative Patent Judges. JESCHKE, Administrative Patent Judge. DECISION ON APPEAL STATEMENT OF THE CASE Zaheer I. Malik ("Appellant") seeks review under 35 U.S.C. § 134(a) of the Examiner's decision, as set forth in the Final Office Action dated January 13, 2016 ("Final Act."), and as further explained in the Advisory Action dated July 6, 2016 ("Adv. Act."), rejecting claims 1-32. We have jurisdiction under 35 U.S.C. § 6(b ). We affirm. 1 Appellant identifies Linde AG, Munich, Germany as the real party in interest. Br. 3. Appeal2017-004545 Application 13/745,037 BACKGROUND The disclosed subject matter "relates to a method and apparatus for the improved recovery of C2 or C3 and heavier components from hydrocarbon gases." Spec. ,r 1.2 Claims 1, 12, 17, and 28 are independent. Claim 1 is reproduced below: 1. In a process for separating a hydrocarbon gas containing at least ethane and C3 and heavier components into a fraction containing a predominant portion of the ethane and lighter components and a fraction containing a predominant portion of the C3 and heavier components in which process (a) the hydrocarbon gas is treated in one or more heat exchangers, and expansion steps to provide at least one partly condensed hydrocarbon gas, providing thereby at least one first residue vapor and at least one C3-containing liquid which liquid also contains lighter hydrocarbons; and (b) at least one of the C3-containing liquids is directed into a distillation column wherein said liquid is separated into a second residue containing lighter hydrocarbons and a C3-containing product; the improvement comprising ( 1) cooling said second residue to partially condense said second residue; (2) intimately contacting at least part of one of said first residue vapors with at least part of a liquid portion of the partially condensed second residue in at least one contacting stage and 2 Citations to the Specification refer to the version filed on April 24, 2013. 2 Appeal2017-004545 Application 13/745,037 thereafter separating vapors and liquids from said contacting stage; (3) supplying the liquids from said contacting stage thereby recovered to the distillation column as a liquid feed thereto; and ( 4) directing the vapors thereby recovered into heat exchange relation with said second residue from the distillation column, thereby to supply the cooling of step (1 ), and thereafter discharging said vapor from the contacting stage; the improvement further comprising: ( 5) recovering a recycle gas stream from an expander-compressor or residue gas compressor; (6) cooling and partially condensing the recycle stream in said one or more heat exchangers whereby the recycle stream is heat exchanged in a subcooler with gases from top of a light-ends fractionation column; (7) expanding and feeding a cold reflux stream from the subcooler into the light ends fractionation column, wherein colder temperatures realized by the cold reflux stream improves the yield of ethane and heavier components. REJECTIONS 1. Claims 1-32 stand rejected under 35 U.S.C. § 112, second paragraph, as failing to particularly point out and distinctly claim the subject matter regarded as the invention. 2. Claims 1-8, 10, 12-24, 26, and 28-32 stand rejected under 35 U.S.C. § I03(a) as unpatentable over Foglietta (US 6,712,880 B2, issued Mar. 30, 2004) and Finn (US 2001/0008073 Al, published July 19, 2001). 3 Appeal2017-004545 Application 13/745,037 3. Claims 9 and 25 stand rejected under 35 U.S.C. § 103(a) as unpatentable over Foglietta, Finn, and Campbell (US 4,171,964, issued Oct. 23, 1979). 4. Claims 11 and 27 stand rejected under 35 U.S.C. § 103(a) as unpatentable over Foglietta, Finn, and Pitman (US 9,080,810 B2, issued July 14, 2015). DISCUSSION Rejection I -The rejection of claims 1-32 under 35 US. C. § 112, second paragraph In rejecting claims 1-32 under 35 U.S.C. § 112, second paragraph, the Examiner identified (1) language in claims 1, 2, 12, 17, and 28 as lacking antecedent basis and (2) language rendering claim 13 "unclear." See Final Act. 2-3. The Examiner rejected the remaining claims based on their dependence from rejected claims. Id. at 3. Appellant states to have "proposed amendments" to claims 1, 2, 12, 13, 17, and 28 "per the Examiner's suggestions in [a] response to the Final Office Action," and Appellant "contends that the claims would be definite if these amendments were entered." Br. 24, 25. Appellant has not identified error in this Rejection because, as noted by the Examiner, the relied-on proposed amendments-filed with the Notice of Appeal on June 13, 2016--were not entered for purposes of this Appeal. Ans. 2; see also Adv. Act. 1 (boxes 3 and 7), 2 ("The proposed amendments will NOT be entered because they raise new issues that would require further search and consideration including the addition of the new limitation 'wherein the pressure of the light ends fractionation column is lower than the heavy ends fractionation column' to claims 1 and 17."). 4 Appeal2017-004545 Application 13/745,037 To the extent Appellant requests the Patent Trial and Appeal Board to direct the Examiner to enter the proposed amendments, we cannot grant the requested relief. The refusal by an examiner to enter a proposed amendment filed after a final rejection is a petitionable matter, not one for appeal. See In re Berger, 279 F.3d 975, 984 (Fed. Cir. 2002) (citing In re Mindick, 371 F.2d 892, 894 (CCPA 1967) (stating that the predecessor to the PTAB "does not consider the issue of whether the examiner's refusal to enter the proposed amendment after final rejection constituted an abuse of discretion")); see also 37 C.F.R. § 1.127 (2015) ("From the refusal of the primary examiner to admit an amendment, in whole or in part, a petition will lie to the Director under § 1.181. "). Because Appellant has not identified error in the Examiner's bases to reject claims 1-32 in their current form as indefinite, we sustain this rejection. Rejection 2 - The rejection of claims 1---8, 10, 12-2 4, 26, and 28-32 under 35 US.C. § 103(a) Appellant argues the claims in this rejection as a group. Br. 26-36. We select claim 1 as representative, with the remaining claims standing or falling with claim 1. 37 C.F.R. § 4I.37(c)(l)(iv). For claim 1, the Examiner relied on Foglietta for certain limitations (Final Act. 5-6) but stated that "Foglietta does not explicitly disclose the improvement further comprising: steps ( 5), ( 6), and (7)" (id. at 6). The Examiner found, however, that steps (5), (6), and (7) are "disclosed by Finn." Id. According to the Examiner, it would have been obvious for one of ordinary skill in the art at the time of the invention to provide a cold column reflux stream from a residue gas as disclosed by Finn with the absorber, residue stream, and process of Foglietta in order to help improve recoveries of C2 5 Appeal2017-004545 Application 13/745,037 or C3 and heavier hydrocarbons by providing additional reflux contact liquids within the absorber that can help condense a greater proportion of the C2+ hydrocarbons from rising vapors. Id. at 7. First, Appellant argues that "[i]ncorporating the teachings of Finn into [Foglietta] will not result in [the claimed] invention." Br. 34. According to Appellant, "Foglietta takes the overhead from the fractionation column and feeds it to an overhead condenser/ exchanger before feeding it to a separator" and Foglietta teaches that "[t]he separated stream can either be fed back to the fractionation column or back to the overhead condenser for feed into the adsorber and ultimately production as a product stream." Id. at 34--35. Appellant argues that [ t ]aking this overhead feed from the fractionation column of Foglietta and feeding it into the system of Finn will result in a feed that proceeds through two heat exchangers and two expanders before being either separated as product gas or returned back through the heat exchangers to the top of the fractionation column. Id. at 35. We are not apprised of error based on this argument because, for the reasons stated by the Examiner (Ans. 3--4), the argument does not address the rejection as articulated. Specifically, as noted by the Examiner, in the proposed modification, "the overhead feed from the fractionation column of Foglietta is not being fed into the system of Finn."3 Ans. 3; see also Foglietta, 8:44---62 (discussing overhead stream 60 from fractionation column 22 shown in Figure 1 ). 3 Throughout this Decision, we remove any underlining from quotations from the Answer. 6 Appeal2017-004545 Application 13/745,037 Instead, in the Examiner's proposed modification of Foglietta based on Finn, "Finn is merely being utilized to disclose subcooling and expanding of a compressed residue stream which can easily be applied to residue streams 50 or 68 [ of F oglietta] to provide reflux to absorber 18" in F oglietta. Ans. 3; see also id. (stating that "Finn (figure 2) is merely being utilized to disclose recovering of a recycle gas stream 52 from a residue gas compressor ... , cooling/condensing in a subcooler against overhead gases ... , and then expanding ... and feeding the reflux into the same column" and that "[t]his process of recycling a subcooled and expanded residue stream as disclosed by Finn can easily be applied to the residue gas stream 50 from residue gas compressor 28 in Foglietta (Figure 1 )"); Final Act. 5-7 ( addressing claim 1 ). Second, Appellant argues that "[ t ]here is no expansion of the cold reflux stream from the subcooler that would result from this combination." Br. 3 5. According to Appellant, "[ w Ji th out this expansion after the subcooler, the yield of ethane and heavier components does not improve" and, thus, "it would not be obvious to combine these two references as there would be no improvement as realized by the present invention." Id. Step (7) of claim 1 recites "expanding and feeding a cold reflux stream from the subcooler into the light ends fractionation column, wherein colder temperatures realized by the cold reflux stream improves the yield of ethane and heavier components." Br. 43 (Claims App.). With this argument, Appellant contends that the prior art does not disclose this limitation but Appellant does not adequately explain the alleged error in the relevant findings. See 3 7 C.F .R. § 41.3 7 ( c )(1 )(iv) ("The arguments shall 7 Appeal2017-004545 Application 13/745,037 explain why the examiner erred as to each ground of rejection contested by appellant."). In the Office Action, the Examiner relied on Finn to address step (7), the Examiner stating "expanding (in valve 60) and feeding a cold reflux stream 62 from the subcooler 20 into the same column (16)" and quoting portions of paragraphs 30 and 71 of Finn. See Final Act. 6-7 (emphasis omitted); see also Finn, Fig. 2. In the Answer, the Examiner states that "clearly Finn provides the utilization of expansion ( expansion valve 60, see figure 2) as Finn further states 'subcooled liquid 58 is expanded across valve 60 to the demethaniser pressure giving a two phase stream 62 which is fed to the top of the demethaniser 16."' Ans. 4--5 (quoting Finn ,r 71). 4 The record here supports the Examiner's findings that Finn discloses step (7). Third, Appellant argues that "both Foglietta and Finn operate the light ends fractionation column at a higher pressure than the heavy ends fractionation column," which "is opposite of ... step (7) of the proposed amended claims 1 and 17 made ... in ... response to the Final Office Action." Br. 35 (emphasis added). This argument does not apprise us of error because, as noted by the Examiner (and as discussed above regarding Rejection 1), the proposed amendments at issue were not entered for purposes of this Appeal. See Ans. 5; Adv. Act. 1-2. Thus, the current claims do not recite the limitations relied on for patentability. See In re Self, 671 F.2d 1344, 1348 (CCPA 1982) (rejecting arguments "not based on limitations appearing in the claims"). 4 The Examiner mistakenly attributes this passage to paragraph 72 of Finn. See Ans. 5. 8 Appeal2017-004545 Application 13/745,037 Fourth, Appellant argues that "[ n ]either F oglietta nor Finn teach[] that the liquid product stream passes through the inlet heat exchanger for heat integration purposes." Br. 3 6. As noted by the Examiner, however, the feature relied on by Appellant is not recited in the claims. See Ans. 5; see also Self, 671 F.2d at 1348 (rejecting arguments "not based on limitations appearing in the claims"). Further, the specific language of claim 1 ( or any other claim) that Appellant intends to rely upon for patentability is not readily apparent based on our independent review of the claims. Fifth, Appellant contends that based on "[c]alculations [that] were performed," Appellant "discovered that Foglietta employs a very lean inlet gas composition such that it is reasonable to assume that no liquids are leaving the bottoms of the cold separator." Br. 36. Although Appellant does not precisely identify the claim language at issue with this argument, we understand Appellant to address step (a) of claim 1, which recites "providing ... at least one first residue vapor and at least one C3-containing liquid." Br. 42 (Claims App.) ( emphasis added). In the Office Action, the Examiner stated that Foglietta teaches "providing ... at least one first residue vapor 42 and at least one C3-containing liquid 44."5 Final Act. 5 (emphasis added); see Foglietta, Fig. 1. In the Answer, the Examiner takes the same position, stating that "Foglietta clearly provides for a liquid steam 44 coming from the bottom of the cold separator" 14, as shown in Figure 1. Ans. 6. 5 Throughout this Decision, we omit any bolding of reference numerals from prior art references. 9 Appeal2017-004545 Application 13/745,037 The record here supports the finding that stream 44 in Foglietta is liquid. As noted by the Examiner, Foglietta expressly describes stream 44 as "liquid." See Foglietta 7:24--27 ("The high pressure cooled inlet gas stream 40 is supplied to cold separator 14 where a first vapor stream 42 is separated from a first liquid stream 44." (emphasis added)); see also id. at 7:31 and 8:5 (both referring to "first liquid stream 44"). Moreover, Appellant has not provided evidence of the "[ c ]alculations" (Br. 3 6) that allegedly support the position that Foglietta's description of stream 44 as liquid is incorrect. See In re Pearson, 494 F.2d 1399, 1405 (CCPA 1974) ("Attorney's argument in a brief cannot take the place of evidence."). Sixth, Appellant contends that "[ t ]here are further impurities in the final product specification such as too much methane and carbon dioxide." Br. 36. This argument does not apprise us of error because, as noted by the Examiner, claim 1 does not recite limits on the amount of methane or carbon dioxide. See Ans. 6 (stating that "the features upon which [A]ppellant relies (i.e., having too much methane and carbon dioxide) are not recited in the rejected claim(s)"); see also Self, 671 F.2d at 1348 (rejecting arguments "not based on limitations appearing in the claims"). For the reasons above, we sustain the rejection of claim 1 under 35 U.S.C. § 103(a). Claims 2-8, 10, 12-24, 26, and 28-32 fall with claim 1. Rejection 3 -The rejection of claims 9 and 25 under 35 USC§ 103(a) Claims 9 and 25 depend from claims 1 and 17, respectively, with both claims adding the limitation: "wherein said one or more heat exchangers is a plate-fin exchanger, shell and tube heat exchanger or coil wound heat 10 Appeal2017-004545 Application 13/745,037 exchanger." Br. 44--45 (claim 9), 50 (claim 25) (Claims App.). The Examiner rejected claims 9 and 25 together, relying on column 21, lines 7- 17 of Campbell to address the additional limitations. See Final Act. 14--15. According to the Examiner, it would have been obvious for one of ordinary skill in the art at the time of the invention to utilize a plate-fin heat exchanger as disclosed by Campbell as the one or more heat exchangers of Finn and Foglietta in order to have improved heat transfer characteristics which may permit closer temperature approaches in the heat exchangers, lower cost, and also permit flow arrangements to accommodate heat exchange of several streams concurrently. Id. at 15. First, Appellant relies on the arguments for Rejection 2, contending that the "addition of Campbell further to this teaching does not teach or suggest the type of heat exchanger that should be employed in the process of claims 9 and 25." Br. 37. For the reasons above, we are not apprised of error in the rejection of parent claims 1 and 17 based on Foglietta and Finn. Thus, this argument does not identify error in the rejection of claims 9 and 25. Second, Appellant argues that "[i]rrespective of the benefits that a specially crafted heat exchanger [provide], in the absence of any teaching to combine Foglietta and Finn, the choice of heat exchanger is purely [Appellant's] and there is no reason to look to Campbell as to the particular heat exchanger to choose." Br. 37. As to the reference to an "absence of any teaching to combine Foglietta and Finn" (id. (emphasis added)), we first note that an express teaching, suggestion, or motivation in the prior art is not a requirement for an obviousness determination. See KSR Int 'l Co. v. Teleflex Inc., 550 U.S. 11 Appeal2017-004545 Application 13/745,037 398, 418-19 (2007) (holding that when the teaching-suggestion-motivation test is applied as a rigid formula, it is incompatible with Supreme Court precedent); see also Ans. 7 (discussing In re Fine, 837 F.2d 1071 (Fed. Cir. 1988), and KSR). Moreover, Appellant generally contends there is no reason either to modify Foglietta with Finn (as proposed for Rejection 2) or to further modify Foglietta/Finn with Campbell (as proposed for Rejection 3), but Appellant does not substantively address either reasoning statement provided. See Final Act. 7 and Ans. 3--4 ( discussing the reason to modify Foglietta with Finn); Final Act. 15 and Ans. 7-8 (discussing the reason to modify Foglietta/Finn with Campbell). We determine that the Examiner's reasoning supports a prima facie case of obviousness as to the claims at issue. See In re Oetiker, 977 F.2d 1443, 1445 (Fed. Cir. 1992). By not addressing the reasoning provided, Appellant has not shown error in the relevant findings or the conclusion as to obviousness, which we determine to be supported by rational underpinnings. See id. (discussing how, if an examiner presents a prima facie case, "the burden of coming forward with evidence or argument shifts to the applicant"). For these reasons, we sustain the rejection of claims 9 and 25 under 35 U.S.C. § 103(a). Rejection 4-The rejection of claims 11 and 27 under 35 USC§ 103(a) Claims 11 and 27 depend from claims 1 and 17, respectively, with both claims adding the limitation: "wherein said cold reflux stream is from a heavy ends fractionation column." Br. 45 (claim 11), 50 (claim 27) (Claims 12 Appeal2017-004545 Application 13/745,037 App.). The Examiner rejected claims 11 and 27 together, relying on Pitman to address the additional limitations and stating that Pitman discloses utilizing . . . both the overhead from a light ends fractionation column (figure 9, 38 from column 28) and the overhead from a heavy ends fractionation column (53 from column 19) and mixing the two streams (to form stream 50 which is then sent through residue gas compressors, cooled, condensed, and expanded as a reflux stream for the column 28 (reflux 51c). Final Act. 15. Appellant argues that, "[i]n Pit[]man, the cold reflux stream is created from more than just the heavy ends fractionation column but also from a light ends fractionation column" in that "[ t ]hese two streams are mixed together to form a cold reflux stream." Br. 39. According to Appellants, "Pit[]man does not suggest that the cold reflux stream is only from a heavy ends fractionation column but that it is from a mixture of a heavy ends and light ends columns." Id. We are persuaded that the relied-on aspect of Pitman does not fall within the scope of claims 11 and 27. We first note that the Examiner and Appellant do not disagree on the relevant teachings of Pitman; both agree that the identified "cold reflex stream" (beginning at stream 50 in Figure 9 of Pitman) is formed by combining stream 38a (from identified "light ends fractionation column" 28) and stream 43 (from identified "heavy ends fractionation column" 19). See Final Act. 15; Br. 39. We tum now to the construction of the additional limitations in claims 11 and 27. The Examiner proposes that these limitations "can be met by a cold reflux that is in part from a heavy ends fractionation column combined with other streams." Ans. 8. Appellant argues that the limitations require 13 Appeal2017-004545 Application 13/745,037 that "the only source of the cold reflux stream can be from a heavy ends fractionation column." Br. 39. We generally agree with Appellant's position, and we construe the limitations at issue to require at least one point along the "cold reflux stream" in which the entirety of the "stream" originated at (i.e., "is from") a "heavy ends fractionation column." This construction is supported by the claim language, which recites that "said cold reflux stream is from a heavy ends fractionation column" rather than, for example, more broadly reciting that merely at least part of said cold reflux stream is from a heavy ends fractionation column. Further, this construction is supported by the Specification, which provides that "[t]he cold reflux stream that is fed into the light ends fractionation column will come from the top of a heavy ends fractionation column" (Spec. ,r 15) and also provides, in describing "recycle stream 1," that "a portion of the residue gas is cooled and partially liquefied in the subcooler exchanger, 22-E3200, thus increasing the reflux in the light-ends fractionation column, 22-T2000" (id. ,r 44). See also Spec. Fig. lB, ,r,r 44-- 45 (further discussing "recycle stream 1 "). From this, we understand Appellant to have effectively defined the "cold reflex stream" as at least including, for example, the stream within line 36 in Figure lB, through which "cooled hydrocarbon gases leave the subcooler" 22-E3200. Spec. ,r 35. At least at this location, the entirety of the "cold reflux stream" originates at (i.e., "is from") heavy ends fractionation column 22-T2100. See Spec. Fig. lB, ,r 42 ("The tops from the heavy ends fractionation column 22-T2100 will exit through line 34 and pass through a subcooler 22-E3200. Line 3[6] exits the subcooler 22-E3200 and connects to a valve."). 14 Appeal2017-004545 Application 13/745,037 Turning back to Pitman, at no point along the identified "cold reflux stream"-beginning at stream 50 in Figure 9 and ending at stream 51 c- does the entirety of the "stream" originate at identified "heavy ends fractionation column" 19. Thus, the relied-on aspect of Pitman does not fall within the scope of claims 11 and 2 7 under the proper construction. For these reasons, we do not sustain the rejection of claims 11 and 27 under 35 U.S.C. § 103(a). DECISION We affirm the decision to reject claims 1-32 under 35 U.S.C. § 112, second paragraph, we affirm the decision to reject claims 1-10, 12-26, and 28-32 under 35 U.S.C. § 103(a), and we reverse the decision to reject claims 11 and 27 under 35 U.S.C. § 103(a). No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a)(l). See 37 C.F.R. § 1.136(a)(l)(iv); 37 C.F.R. § 4I.50(f). AFFIRMED 15 Copy with citationCopy as parenthetical citation