Ex Parte Krivtsun et alDownload PDFPatent Trial and Appeal BoardJul 15, 201612933668 (P.T.A.B. Jul. 15, 2016) Copy Citation UNITED STA TES p A TENT AND TRADEMARK OFFICE APPLICATION NO. FILING DATE 12/933,668 11/01/2010 909 7590 07119/2016 Pillsbury Winthrop Shaw Pittman, LLP (NV) PO Box 10500 McLean, VA 22102 FIRST NAMED INVENTOR Vladimir Mihailovitc Krivtsun UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www .uspto.gov ATTORNEY DOCKET NO. CONFIRMATION NO. 081468-0388302 1544 EXAMINER PERSAUD, DEORAM ART UNIT PAPER NUMBER 2882 NOTIFICATION DATE DELIVERY MODE 07/19/2016 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address( es): docket_ip@pillsburylaw.com heather.marthers@pillsburylaw.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte VLADIMIR MIHAILOVITC KRIVTSUN, V ADIM YEVGENYEVICH BANINE, ARNO JAN BLEEKER, VLADIMIR VITALEVITCH IVANOV, KONSTANTIN NIKOLAEVITCH KOSHELEV, JOHANNES HUBERTUS JOSEPHINA MOORS, SERGEY CHURILOV, and DENIS GLUSHKOV1 Appeal2015-000885 Application 12/933,668 Technology Center 2800 Before JEFFREY T. SMITH, CHRISTOPHER C. KENNEDY, and JEFFREY R. SNAY, Administrative Patent Judges. KENNEDY, Administrative Patent Judge. DECISION ON APPEAL This is an appeal under 35 U.S.C. § 134(a) from the Examiner's decision to reject claims 1, 3-13, and 20-23. We have jurisdiction under 35 U.S.C. § 6(b). We AFFIRM. 1 According to the Appellants, the Real Party in Interest is ASML Netherlands B.V. App. Br. 2. Appeal2015-000885 Application 12/933,668 BACKGROUND The subject matter on appeal relates to a target material for generating radiation in the extreme ultraviolet (EUV) range, and associated sources and lithographic apparatuses. E.g., Spec. i-fi-12, 7; Claims 1, 7, 8. Claim 1 is reproduced below from page 9 (Claims Appendix) of the Appeal Brief: 1. A target material for use in a source constructed and arranged to generate a radiation beam having a wavelength in an extreme ultraviolet range, said target material comprising a Gd-based composition configured to decrease a melting temperature of Gd. REJECTIONS ON APPEAL2 1. Claims 1, 3-8, and 20 stand rejected under 35 U.S.C. § 103(a) as unpatentable over the combination of Nagai et al. (US 2006/0133574 Al, published June 22, 2006) and Bykanov et al. (US 2008/0048133 Al, published Feb. 28, 2008). 2. Claims 9-13 and 21-23 stand rejected under 35 U.S.C. § 103(a) as unpatentable over Nagai and Bykanov, further in view ofErshov et al. (US 2007 /0001131 Al, published Jan. 4, 2007). ANALYSIS The Appellants argue the claims subject to Rejection 1 as a group. We select claim 1 as representative of the rejected claims, and the remaining 2 In headers that appear in the Final Action, the Examiner mistakenly describes both rejections as anticipation rejections under 35 U.S.C. § 102(b). See Final Act. 2, 7. However, the Examiner analyzes the rejected claims for obviousness consistent with 35 U.S.C. § 103(a). Id.; see also Ans. 2. The Appellants appropriately treat both rejections as obviousness rejections. See App. Br. 3 n.1. 2 Appeal2015-000885 Application 12/933,668 claims subject to Rejection 1 will stand or fall with claim 1. See 37 C.F.R. § 41.37(c)(l)(iv). The Appellants do not provide any additional argument for the claim subject to Rejection 2. Therefore, our decision on the rejection of claim 1 is dispositive of all claims on appeal. After review of the cited evidence in the appeal record and the opposing positions of the Appellants and the Examiner, we determine that the Appellants have not identified reversible error in the Examiner's rejections. Accordingly, we affirm the rejections for reasons set forth below, in the Final Action, and in the Examiner's Answer. See generally Final Act. 2-11; Ans. 2-5. The Examiner finds that Nagai teaches target materials for generation of EUV radiation, including Gd and Gd compounds/complexes. Final Act. 2-3; Nagai i-f 17. The Examiner further finds that a goal ofNagai is to reduce or prevent the generation of debris in the light source. Final Act. 4; Ans. 3. The Examiner finds that Bykanov, like Nagai, is concerned with the reduction of debris in an EUV light source, and that Bykanov teaches the use of, inter alia, heavy metal gallium alloys, including tin-gallium, as an EUV light source that produces reduced debris. Final Act. 3. The Examiner concludes that it would have been obvious to use a heavy metal gallium alloy, including Gd-Ga, as a target material to reduce debris. Id. In the Answer, the Examiner further finds that tin, as taught by both Bykanov and Nagai, and Gd, as taught by Nagai, are "functionally equivalent suitable alternative extreme ultraviolet light source targets," and suggests that it would have been obvious to substitute Gd for tin in Bykanov's tin-gallium compound "to shorten the wavelength of the irradiated light." Ans. 4. 3 Appeal2015-000885 Application 12/933,668 The Appellants argue that " [ c] ombining the teachings of Nagai and Bykanov in the manner proposed by the Office would not provide a modification to Gd that 'reduces the amount of source material which may escape and adversely affect optics/absorb EUV light' as asserted by the Examiner ... at least for the reason that Gd has a significantly higher melting temperature ... than Sn .... " App. Br. 6. We are not persuaded by that argument. Both Nagai and Bykanov teach heavy metal compounds for use as target materials to generate EUV radiation. Likewise, both Nagai and Bykanov express a concern for minimizing or preventing the generation of debris, which can interfere with the optics of a lithography apparatus. E.g., Nagai i-f 7 ("an object of the present invention is to provide an extreme ultraviolet light source in which extreme ultraviolet light can be emitted with high emission efficiency, and in which the generation of debris is prevented .... "); Bykanov i-f 6 ("One factor that is often considered when designing a high volume EUV light source is the generation and mitigation of debris inside the light source which may adversely affect the light source."), i-f 31 (describing goal of "reduc[ing] the amount of source material which may escape the chamber .. . and adversely affect optics/absorb EUV light."). While Bykanov provides a specific example in which SnBr4 is used, e.g., i-f 31; see also App. Br. 5---6 ( discussing SnBr4), nothing in Bykanov suggests that the goal of reducing debris is achieved only by using SnBr4. On the contrary, after identifying the problem of debris inside the light source, Bykanov expressly discloses as embodiments of the invention several target materials, including SnBr4 and tin-gallium alloys. See Bykanov i-fi-1 6, 8. Bykanov also teaches that heavy metals other than tin "with an emission line in the EUV spectrum" may be 4 Appeal2015-000885 Application 12/933,668 used. Id. if 18. Gd is a known heavy metal that emits in the EUV spectrum. E.g., Nagai iii! 17, 18. From those teachings, a person of ordinary skill in the art reasonably would have inferred that heavy metal gallium alloys, including Sn-Ga and Gd-Ga, are capable of reducing debris inside the light source. Concerning melting temperatures, the Appellants concede that a Gd- Ga alloy has a melting temperature of nearly 500°C lower than Gd alone; i.e., is "configured to decrease a melting temperature of Gd." App. Br. 5---6. The Appellants provide no persuasive explanation as to why the fact that Gd has a higher melting point than Sn would have caused a person of ordinary skill in the art to doubt the Examiner's finding that a Gd-Ga alloy would result in reduced debris when used as an EUV target material. See id.; see also In re Pearson, 494 F.2d 1399, 1405 (CCPA 1974) ("Attorney's arguments in a brief cannot take the place of evidence."). Regardless of whether the combination is viewed as ( 1) the modification ofNagai's heavy metal Gd compound to use Ga as an alloy material as suggested by Bykanov, or (2) the simple substitution ofNagai's Gd (a known element with an emission line in the EUV spectrum) for Bykanov's tin (another known element with an emission line in the EUV spectrum) in Bykanov's Sn-Ga alloy, we agree with the Examiner that the use of a Gd-Ga alloy as a target material would have been obvious to a person of ordinary skill in the art. See KSR Int 'l Co. v. Teleflex Inc., 550 U.S. 398, 416-17 (2007) ("[W]hen a patent claims a structure already known in the prior art that is altered by the mere substitution of one element for another known in the field, the combination must do more than yield a predictable result."); see also In re Bush, 296 F .2d 491, 496 (CCP A 1961) 5 Appeal2015-000885 Application 12/933,668 ("In a case of this type where a rejection is predicated on two references each containing pertinent disclosure which has been pointed out to the applicant, we deem it to be of no significance, but merely a matter of exposition, that the rejection is stated to be on A in view of B instead of on Bin view of A, or to term one reference primary and the other secondary."). As noted above, there is no dispute that a Gd-Ga alloy constitutes "a Gd- based composition configured to decrease a melting temperature of Gd," as recited by claim 1. See App. Br. 6 (identifying the melting temperatures of Gd and Gd-Ga as about 1313°C and 850°C, respectively). In the Reply Brief, the Appellants newly argue that a person of ordinary skill would not have been motivated to modify Nagai in view of Bykanov in order to reduce debris because "Nagai already provides such a solution." Reply Br. 2-3. That argument is not timely because the Appellants did not present it in the opening Appeal Brief. See 37 C.F.R. § 41.41 (b )(2). Even if it were timely, however, the argument is not persuasive. Nagai's disclosure of an alternative method of reducing debris does not negate the foregoing analysis, and the Appellants have not argued that Nagai's method is incompatible with Bykanov's method. Cf In re Fulton, 391 F.3d 1195, 1201 (Fed. Cir. 2004) ("The prior art's mere disclosure of more than one alternative does not constitute a teaching away from any of the[] [disclosed] alternatives because such disclosure does not criticize, discredit, or otherwise discourage the solution claimed .... "). Moreover, the Appellants' argument fails to explain why the proposed combination is anything more than the simple substitution of one known EUV-emitting element (Gd) for another (Sn) with predictable results. See 6 Appeal2015-000885 Application 12/933,668 KSR, 550 U.S. at 416-17 (substitution of one known element for another typically does not result in nonobvious subject matter). In view of the arguments presented, we are not persuaded of reversible error in the Examiner's obviousness rejection. CONCLUSION We AFFIRM the Examiner's rejection of claims 1, 3-13, and 20-23. No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a). AFFIRMED 7 Copy with citationCopy as parenthetical citation