Ex Parte Kreiter et alDownload PDFPatent Trials and Appeals BoardFeb 12, 201913698262 - (D) (P.T.A.B. Feb. 12, 2019) Copy Citation UNITED STA TES p A TENT AND TRADEMARK OFFICE APPLICATION NO. FILING DATE FIRST NAMED INVENTOR 13/698,262 02/04/2013 Robert Kreiter 22428 7590 02/14/2019 Foley & Lardner LLP 3000 K STREET N.W. SUITE 600 WASHINGTON, DC 20007-5109 UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www .uspto.gov ATTORNEY DOCKET NO. CONFIRMATION NO. 069818-7475 2601 EXAMINER ORME, PATRICK JAMES ART UNIT PAPER NUMBER 1779 NOTIFICATION DATE DELIVERY MODE 02/14/2019 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): ipdocketing@foley.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte ROBERT KREITER, GOULVEN GILDAS PARADIS, JAAP FERDINAND VENTE, HESSEL LENNART CASTRICUM, and JOHAN EVERT TEN ELSHOF Appeal2017-004924 Application 13/698,262 Technology Center 1700 Before DONNA M. PRAISS, MICHAEL G. McMANUS, and MERRELL C. CASHION, Jr., Administrative Patent Judges. McMANUS, Administrative Patent Judge. DECISION ON APPEAL The Examiner finally rejected claims 18-3 8 and 41 of Application 13/698,262 under 35 U.S.C. §§ 102 and 103 and for nonstatutory obviousness-type double patenting. Final Act. (Oct. 28, 2015) 5-20. Appellants 1 seeks reversal of these rejections pursuant to 35 U.S.C. § 134(a). We have jurisdiction under 35 U.S.C. § 6. An oral hearing was held February 5, 2019. For the reasons set forth below, we AFFIRM. 1 The real party in interest is identified as STICHTING ENERGIEONDERZOEK CENTRUM NEDERLAND. Appeal Br. 3. Appeal2017-004924 Application 13/698,262 BACKGROUND The present application generally relates to hydrophobic, microporous hybrid membranes based on silica. Spec., Abstract. The described membranes include both monovalent and divalent organic substituents. Spec. ,r 13. The subject membranes exhibit "preference for permeation of organic or the more hydrophobic components of a mixture." Id. ,r 2. Such membranes are indicated to be useful in solvent-resistant nanofiltration and organophilic pervaporation. Id. Claim 18 is illustrative of the subject matter on appeal and is reproduced below with certain limitations bolded for emphasis: 18. A hydrophobic membrane comprising a layer based on silica, wherein (a) at least 25% of the silicon atoms have a bridging C1- C12 divalent hydrocarbylene group as a substituent, and optionally further silicon atoms having a saturated and acyclic monovalent C1-C30 organic group as a substituent; (b) either (i) at least 50% of the silicon atoms have said divalent hydrocarbylene group and the divalent hydrocarbylene group has a minimum length of 8 carbon atoms, and/or (ii) at least 25% of the silicon atoms have said monovalent organic group and the monovalent organic group has a minimum length of 6 carbon atoms; and ( c) the average number of carbon atoms in the monovalent organic groups and the divalent hydrocarbylene groups taken together is at least 3.5; and wherein the membrane retains hydrophilic molecules from a mixture of hydrophobic and hydrophilic molecules. Appeal Br. (Apr. 28, 2016) 13 (Claims App.). 2 Appeal2017-004924 Application 13/698,262 REJECTIONS The Examiner maintains the following rejections: 1. Claims 18-28, 32, 38, and 41 2 are rejected under 35 U.S.C. § I02(b) (pre-AIA) as anticipated by Sah et al. 3 Final Act. 5-8. 2. Claims 29-31 are rejected under 35 U.S.C. § I03(a) (pre-AIA) as obvious over Sah in view of Linder et al. 4 Id. at 8-9. 3. Claims 33, 34, and 37 are rejected under 35 U.S.C. § I03(a) (pre- AIA) as obvious over Sah in view of Sommer et al. 5 Id. at 9-10. 4. Claim 35 is rejected under 35 U.S.C. § I03(a) (pre-AIA) as obvious over Sah in view of Sommer and further in view of Livingston. 6 Id. at 10-11. 5. Claim 36 is rejected under 35 U.S.C. § I03(a) (pre-AIA) as obvious over Sah in view of Sommer and further in view of Boddeker. 7 Id. at 11-13. 6. Claims 18-38 and 41 are provisionally rejected on the ground of nonstatutory obviousness type double patenting over claims 1, 3-5, 2 The rejection states that claims 39 and 40 are rejected as anticipated; however, these claims were canceled by amendment dated Sept. 1, 2015. Final Act. 2, 5. 3 WO 2007/081212 Al, published July 19, 2007 ("Sah"). 4 US 5,265,734, issued Nov. 30, 1993 ("Linder"). 5 S. Sommer and T. Melin, Design and Optimization of Hybrid Separation Processes for the Dehydration of 2-Propanol and Other Organics, Ind. Eng. Chem. Res. 2004, 43, 5248-5259 ("Sommer"). 6 US 2004/0099603 Al, published May 27, 2004 ("Livingston"). 7 US 4,806,245, issued Feb. 21, 1989 ("Boddeker"). 3 Appeal2017-004924 Application 13/698,262 7, 8, 11, 14, and 15 of Kreiter et al. 8 in view of Sah, Linder, Sommer, and Livingston. Id. at 14--17. 7. Claims 18-37 are provisionally rejected on the ground of nonstatutory obviousness type double patenting over claims 1, 3, 4, 6, 8, 9-12, 15, and 169 of Sah II, 10 in view of Sah, Linder, Sommer, and Livingston. Id. at 18-20. DISCUSSION Rejection 1. The Examiner rejected claims 18-28, 32, 41, and 38--40 as anticipated by Sah. Id. at 5-8. In support of the rejection, the Examiner determined that Sah teaches a silica-based membrane with divalent and/or monovalent organic substituents. Final Act. 5. The Examiner determined that the average number of carbons in the monovalent and divalent groups, considered together, is at least 3.5. Id. The Examiner further found that Sah teaches a membrane that retains hydrophilic molecules from a mixture of hydrophobic and hydrophilic molecules. Id. (citing Sah, 14:4--6, 11-12). In this regard, Sah discloses that "[t]he selectivity number for water over the alcohol is constant at -300, for about 2 months and then decreases to 150 and remains steady." Sah, 14:4--6. In the Response to Arguments section of the Final Action, the Examiner indicated that the final limitation of claim 18, "wherein the 8 US 8,709,254 B2, issued Apr. 29, 2014 ("Kreiter"). 9 In the Final Action, the Examiner stated that certain claims were rejected over "[c]laims 1, 3, 4, 6, 8, 19-12, 15, and 16" of Sah in combination with other references. We construe "19-12" to mean "9-12" for purposes of the present rejection. 10 US 8,277,661 B2, issued Oct. 2, 2012 ("Sah II"). 4 Appeal2017-004924 Application 13/698,262 membrane retains hydrophilic molecules from a mixture of hydrophobic and hydrophilic molecules," would not be given patentable weight as it did not limit the membrane structurally. Final Act. 3. Appellants assert error on several bases. First, Appellants argue that "wherein the membrane retains hydrophilic molecules from a mixture of hydrophobic and hydrophilic molecules" is a structural limitation that should be accorded patentable weight. Appeal Br. 6-8. "A patent applicant is free to recite features of an apparatus either structurally or functionally." In re Schreiber, 128 F.3d 1473, 1478 (Fed. Cir. 1997); In re Swinehart, 439 F.2d 210,212 (CCPA 1971) ("there is nothing intrinsically wrong with the use of [ functional language] in drafting patent claims"). In order to be accorded patentable weight, however, functional language in an apparatus claim must limit the claim in terms of structure rather than function. In re Schreiber, 128 F.3d at 1477-78; MPEP § 2114. That is, "apparatus claims cover what a device is, not what a device does." Hewlett-Packard Co. v. Bausch & Lomb Inc., 909 F.2d 1464, 1468 (Fed. Cir. 1990). Here, the Specification indicates that the "present invention provides hybrid membranes having increased organophilicity compared to prior art organic-inorganic hybrid membranes. These new membranes enhance the permeance of organic solvents." Spec. 4. The Specification further teaches that "[t]he separation mechanism of these membranes is ... based on affinity rather than size." Id. at 5. Thus, the functional limitation limits the permissible range of organophilicity of the subject membrane. Accordingly, we determine that such limitation limits the structure of the claimed membrane and will be accorded patentable weight. 5 Appeal2017-004924 Application 13/698,262 Appellants additionally argue that Sah does not anticipate the claims as Sah's membrane does not "retain[] hydrophilic molecules from a mixture of hydrophobic and hydrophilic molecules" as required by claim 18 ( and its dependents). Specifically, Appellants argue that Sah's membranes are "designed to perform exactly the opposite function" as claimed. Appeal Br. 6 ( emphasis in original). In support, Appellants point to a portion of Sah which provides that "[t]he selectivity number for water over the alcohol is constant at -300, for about 2 months and then decreases to 150 and remains steady." Sah, 14:4--6. Sah is additionally discussed in the Specification, which provides as follows: Importantly, although these membranes are stable in aggressive organic solvents, their application in organic nanofiltration or in organophilic pervaporation, in which the organic solvent is the permeating component, is unfeasible. This is due to the relatively polar pore structure of these membranes, probably because of the presence of large numbers of hydroxyl groups in the micropores. Because of this polarity, the permeance of organic components through these membranes is very low compared to their water permeance. Intrinsically, the membranes disclosed in WO 2007 /081212 [Sah] are therefore selective for water over organics. Spec. 4:20-28 (emphasis added). Thus, there is support for Appellants' argument that the membrane of Sah has low permeance for organic components relative to the permeance of water. This, however, is not dispositive. The limitation at issue requires only that "the membrane retains hydrophilic molecules from a mixture of hydrophobic and hydrophilic molecules." It does not specify any particular degree of selectivity. Indeed, the Examiner indicates that Appellants amended their claims so as to remove 6 Appeal2017-004924 Application 13/698,262 any "selectivity" limitation. Answer (Dec. 2, 2016) 6; see also Amendment and Reply Under 37 CPR 1.111 (dated Sept. 1, 2015). During examination, claims are given their broadest reasonable interpretation consistent with the Specification. See In re Am. A cad. of Sci. Tech Ctr., 367 F.3d 1359, 1364 (Fed. Cir. 2004). "Construing claims broadly during prosecution is not unfair to the applicant ... because the applicant has the opportunity to amend the claims to obtain more precise claim coverage." Id. Giving the limitation its broadest reasonable construction consistent with the Specification, we construe the phrase "the membrane retains hydrophilic molecules from a mixture of hydrophobic and hydrophilic molecules" to require only that the membrane retains some hydrophilic molecules from the stated mixture. The Examiner has determined that the teachings of Sah regarding the selectivity number of the membrane indicate that a certain amount of water is retained by the membrane. Final Act. 3; Answer 6. Appellants argue that such determination is in error because Sah teaches only that its "membrane enriches alcohol in the retentate and water in the permeate, [whereas] the hydrophobic membrane of the claimed invention enriches water in the retentate and alcohol in the permeate." Appeal Br. 9. Similarly, Appellants argue that "[t]he degree of selectively of Sah's membranes does in fact change over time, but the selectively of water over alcohol remains constant." Reply Br. 4 ( emphasis omitted). These arguments fail as they concern the relative retention and permeation of different molecules. Appellants do not show that there is no water retained by the membrane of Sah. 7 Appeal2017-004924 Application 13/698,262 In view of the foregoing, Appellants have not shown reversible error in the Examiner's determination that Sah teaches a membrane that "retains hydrophilic molecules from a mixture of hydrophobic and hydrophilic molecules." Appellants additionally argue that Sah does not teach that "the average number of carbon atoms in the monovalent organic groups and the divalent hydrocarbylene groups taken together is at least 3.5." Appeal Br. 9--10. Appellants concede that Sah teaches certain monovalent organic groups with more than 3 .5 carbon atoms and certain divalent hydrocarbylene groups with more than 3.5 carbon atoms. Id. at 9. Sah additionally teaches monovalent and divalent organic groups with fewer than 3 .5 carbon atoms. Sah, 2:28--4:29. Appellants argue, however, that Sah does not teach that the average number of carbons is greater than 3 .5 when the monovalent and divalent groups are taken together. Appeal Br. 9. A reference may anticipate where it includes an anticipatory teaching in a list that includes components falling outside the scope of the claim at issue. See Perricone v. Medicis Pharm. Corp., 432 F.3d 1368, 1376 (Fed. Cir. 2005) ("This court rejects the notion that one of these ingredients cannot anticipate because it appears without special emphasis in a longer list.") Here, Sah teaches a preferred membrane where the number of carbons (designated as "m") in the divalent substituent is "m = 6." Sah, 3:38. Sah further teaches that"[ e ]xamples include: ... Si-cycohexylene-Si, Si- phenylene-Si" and others. Id. at 4:1-3. Thus, Sah teaches divalent substituents having more than 3.5 carbons. In regard to the monovalent substituent, Sah teaches that "[ t ]he monovalent organic moiety may be any group having from 1 to 10 carbon atoms, which is connected to silicon via a carbon atom." Id. at 4: 12-13. 8 Appeal2017-004924 Application 13/698,262 Sah further teaches that "preferred examples or moieties having formula - CrHsQ are linear or branched C1-C6 alkyl .... " Id. at 4:22-23. Thus, Sah has clear teachings of embodiments having more than 3.5 carbons for both the monovalent and divalent organic substituents. That such teachings occur as part of a well-delineated list does not diminish the disclosure of Sah. Further, Appellants indicate that Examples 5 and 6 of Sah have an "average number of carbon atoms in the monovalent and divalent groups [that] is at least 3.5." Reply Br. (Feb. 2, 2017) 2 (Table). The Examiner further found that Sah' s embodiments which use the precursors methyl-triethoxysilane (MTES), tetracthoxysilane (TEOS), and bis(triethoxysilyl)ethane (BTESE) result in an average number of carbon atoms of at least 3 .5. Ans. 6-7. Appellants argue that such precursors would yield groups with a lower number of carbon atoms. See Appeal Br. 10 n.18; Reply Br. 4--5. Appellants, however, do not provide declaratory or other factual evidence in support of their argument. See, e.g., Gemtron Corp. v. Saint-Gobain Corp., 572 F.3d 1371, 1380 (Fed. Cir. 2009) ("[U]nswom attorney argument ... is not evidence and cannot rebut ... other admitted evidence .... "). Further, as above, Appellants indicate that Examples 5 and 6 of Sah have an average number of carbon atoms that is at least 3.5. Reply Br. 2. Accordingly, we adopt the Examiner's analysis in this regard. In view of the foregoing, we determine that Appellants have not shown reversible error in the rejection of claims 18-28, 32, 3 8, and 41 as anticipated by Sah. Rejections 2-5. The Examiner rejected claims 29-31 as obvious over Sah in view of Linder. Final Act. 8-9. The Examiner additionally rejected 9 Appeal2017-004924 Application 13/698,262 claims 33, 34, and 37 as obvious over Sah in view of Sommer. Id. at 9--10. The Examiner additionally rejected claim 35 as obvious over Sah in view of Sommer and further in view of Livingston. Id. at 10-11. The Examiner additionally rejected claim 36 as obvious over Sah in view of in view of Sommer and further in view of Boddeker. Id. at 11-13. Appellants argue that these rejections should be reversed because Sah does not teach "retain[ing] hydrophilic molecules from a mixture of hydrophobic and the hydrophilic molecules" nor that "the average number of carbon atoms in the monovalent organic groups and the divalent hydrocarbylene groups taken together is at least 3. 5." Appeal Br. 10-11. As we have not found such arguments to be persuasive for the reasons set forth above, we determine that Appellants have not shown reversible error with regard to the rejections at issue. Rejections 6 and 7. The Examiner provisionally rejected claims 18- 3 8, and 41 on the ground of nonstatutory double patenting over claims 1, 3- 5, 7, 8, 11, 14, and 15 of Kreiter in view of Sah, Linder, Sommer, and Livingston. Id. at 14--17. The Examiner additionally provisionally rejected claims 18-3 7 on the ground of nonstatutory double patenting over claims 1, 3, 4, 6, 8, 9--12, 15, and 16 ofSah II in view ofSah, Linder, Sommer, and Livingston. Id. at 18-20. Appellants argue that the rejection of claims 1, 3-5, 7, 8, 11, 14, and 15 over Kreiter in view of Sah, Linder, Sommer, and Livingston (Rejection 6) should be reversed because Kreiter does not teach that "the average number of carbon atoms in the monovalent organic groups and the divalent hydrocarbylene groups taken together is at least 3.5" nor that "the membrane retains hydrophilic molecules from a mixture of hydrophobic and 10 Appeal2017-004924 Application 13/698,262 hydrophilic molecules." Appeal Br. 11. The Examiner, however, does not rely upon Kreiter as teaching such features. Rather, the Examiner cites to Sah as teaching these limitations. Final Act 15. Appellants' arguments that Sah does not teach such elements have been considered, as set forth above, but found not to be persuasive. Accordingly, Appellants have not shown reversible error with regard to the rejection of claims 18-3 8 and 41 on the ground ofnonstatutory double patenting over claims 1, 3-5, 7, 8, 11, 14, and 15 of Kreiter in view of Sah, Linder, Sommer, and Livingston (Rejection 6). Appellants further argue that the rejection of claims 18-37 over claims 1, 3, 4, 6, 8, 9-12, 15, and 16 ofSah II in view ofSah, Linder, Sommer, and Livingston (Rejection 7) should be reversed because Sah II does not teach the same limitations noted above. Appeal Br. 11. Appellants, however, do not put forth any specific argument regarding Sah II. Indeed, Appellants' brief does not include a single citation to any specific portion of Sah II. Accordingly, Appellants have failed to show error in this regard. See 37 C.F.R. § 4I.37(c)(l)(iv) ("the brief shall contain .... The arguments of appellant with respect to each ground of rejection, and the basis therefor, with citations of the statutes, regulations, authorities, and parts of the Record relied on. The arguments shall explain why the examiner erred as to each ground of rejection contested by appellant."). CONCLUSION The rejections of all claims are affirmed. 11 Appeal2017-004924 Application 13/698,262 No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a). AFFIRMED 12 Copy with citationCopy as parenthetical citation