Ex Parte Karna et alDownload PDFPatent Trial and Appeal BoardApr 12, 201711790052 (P.T.A.B. Apr. 12, 2017) Copy Citation United States Patent and Trademark Office UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O.Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 11/790,052 04/23/2007 Shashi P. Karna ARL 06-55 7464 21364 7590 04/12/2017 U S ARMY RESEARCH LABORATORY ATTN: RDRL-LOC-I 2800 POWDER MILL RD ADELPHI, MD 20783-1138 EXAMINER NADAV, ORI ART UNIT PAPER NUMBER 2811 MAIL DATE DELIVERY MODE 04/12/2017 PAPER Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte SHASHI P. KARNA and GOVIND MALLICK Appeal 2016-003026 Application 11/790,0521 Technology Center 2800 Before KAREN M. HASTINGS, BRIAN D. RANGE, and JENNIFER R. GUPTA, Administrative Patent Judges. RANGE, Administrative Patent Judge. DECISION ON APPEAL SUMMARY Appellants appeal under 35 U.S.C. § 134(a) from the Examiner’s decision rejecting claims 1—6, 14, 16, 18, and 20. We have jurisdiction. 35 U.S.C. § 6(b). We AFFIRM-IN-PART. 1 According to the Appellants, the real party in interest is the United States of America as represented by the Secretary of the Army. Appeal Br. 2. Appeal 2016-003026 Application 11/790,052 STATEMENT OF THE CASE2 Appellants describe the invention as relating to field effect transistor arrays utilizing single wall carbon nano-tubes as the channel for the field effect transistors. Spec. 13. Claims 1 and 20, reproduced below with emphasis added to certain key recitations, are illustrative of the claimed subject matter: 1. A field effect transistor comprising a substrate, a semiconducting channel for transistor action comprising substantially only a plurality of semiconducting carbon nano-tubes disposed on a surface of said substrate wherein said plurality of carbon nano-tubes are disposed in random directions parallel to said surface of said substrate, and a plurality of electrodes disposed over said plurality of semiconducting carbon nanotubes such that said electrodes are spaced apart from each other. 20. A metal-oxide semiconductor field effect transistor comprising: a substrate, an electrical insulating layer disposed on said substrate, a semiconducting channel for transistor action comprising substantially only a plurality of semiconducting single wall carbon nano-tubes disposed in random horizontal directions on a said electrical insulating layer, 2 In this decision, we refer to the Final Office Action mailed April 29, 2015 (“Final Act.”), the Appeal Brief filed September 14, 2015 (“Appeal Br.”), the Examiner’s Answer mailed December 1, 2015 (“Ans.”), and the Reply Brief filed January 27, 2016 (“Reply Br.”). 2 Appeal 2016-003026 Application 11/790,052 a plurality of electrodes disposed over said plurality of semiconducting single wall carbon nano-tubes such that said electrodes are spaced apart from each other, wherein said plurality of single wall carbon nano-tubes randomly disposed on the surface of said substrate contain a density of from 3 to 6 bundles of disentangled, nearly-defect-free single- walled carbon nano-tubes per 100 pm2. Appeal Br. 25, 29 (Claims App’x). REFERENCES The Examiner relies upon the prior art below in rejecting the claims on appeal: Liebau et al. (hereinafter “Liebau”) Choi et al. (hereinafter “Choi”) Zhang et al. (hereinafter “Zhang”) Zhou et al. (hereinafter “Zhou”) US 2003/0228467 Al US 6,930,343 B2 US 6,972,467 B2 US 7,014,743 B2 Dec. 11,2003 Aug. 16, 2005 Dec. 6, 2005 Mar. 21,2006 REJECTIONS The Examiner maintains the following rejections on appeal: Rejection 1. Claims 1—6, 14, 16, and 18 under 35 U.S.C. § 112 as failing to comply with the written description requirement. Ans. 2. Rejection 2. Claims 1—6, 14, 16, 18, and 20 under 35 U.S.C. § 103 as unpatentable over Liebau in view of Zhang, Zhou, or Choi. Id. at 3. 3 Appeal 2016-003026 Application 11/790,052 ANALYSIS We review the appealed rejections for error based upon the issues identified by Appellants and in light of the arguments and evidence produced thereon. Cf. Ex parte Frye, 94 USPQ2d 1072, 1075 (BPAI 2010) (precedential) (cited with approval in In re Jung, 637 F.3d 1356, 1365 (Fed. Cir. 2011) (“it has long been the Board’s practice to require an applicant to identity the alleged error in the examiner’s rejections”)). Rejection 1. The Examiner rejects claims 1—6, 14, 16, and 18 under 35 U.S.C. § 112 as failing to comply with the written description requirement. Ans. 2. In particular, the Examiner maintains that there is no support in the Specification for the recitation “said plurality of carbon nano tubes are disposed in random directions parallel to said surface of said substrate” as recited in claim 1. Id. The Examiner finds that the Specification does not state that the nano-tubes are parallel to the substrate. Id. at 6. The Examiner also finds that the random nature of the nanotubes means that some tubes are on top of each other and are, therefore, not located in the same plane. Id. at 7, 12. Appellants explain that the Specification states: “During the carbon nano-tube formation, the carbon nano-tubes 20 grow in random directions on the wafer/substrate 14.” Appeal Br. 5 (quoting Spec. 1 5) (underlining and italics original to Appeal Brief; bolding added). Appellants also state that Figure 2 demonstrates the carbon nanotubes generally lying on the plane of the substrate. The preponderance of the evidence best supports Appellants’ position. As a threshold matter, we agree with Appellants that, in the context of claim 1 and the Specification, “parallel” does not require absolute 4 Appeal 2016-003026 Application 11/790,052 parallelism. Appeal Br. 8—9. Rather, while physical placement of elongated objects may always be less than exact, but the objects may nonetheless be considered parallel. Reply Br. 6—7 (explaining that railroad tracks are “parallel” even if the distance between them may vary slightly). Here, “parallel” in the context of claim 1 merely means that the carbon nanotubes are disposed in a horizontal direction on the electrical insulating layer. Both the text cited by Appellants and Figure 2 provide written description support for the “parallel” recitation as construed in this manner. We, therefore, do not sustain the Examiner’s rejection based on written description. Rejection 2, Claim 1. The Examiner rejects claims 1—6, 14, 16, 18, and 20 as obvious over Liebau in view of Zhang, Zhou, or Choi. Ans. 3. After considering the evidence presented in this Appeal and each of Appellants’ contentions, we are not persuaded that Appellants identify reversible error. Thus, we affirm this rejection for the reasons expressed in the Final Office Action and the Answer. We add the following primarily for emphasis. The Examiner finds that Liebau teaches in Figure 2 and related text a field effect transistor comprising most recitations of claim 1. Ans. 3 (providing citations to Liebau). The Examiner finds that Liebau does not explicitly state using the device for transistor action and does not teach using only a plurality of semiconducting carbon nano-tubes. Id. The Examiner finds, however, that Zhang, Zhou, and Choi each teach using only a plurality of semiconducting single wall carbon nano-tubes on a surface of said substrate. Id. The Examiner concludes: It would have been obvious to a person of ordinary skill in the art at the time the invention was made to use only a plurality of semiconducting single wall carbon nanotubes on a surface of 5 Appeal 2016-003026 Application 11/790,052 said substrate in prior art's device in order to use the device in an application which requires specific characteristics, such as controlling the flow of electrons by the gate voltage, which is obtained only by having a plurality of semiconducting single wall carbon nano-tubes. Id. at 4. A preponderance of the evidence supports the Examiner’s findings and conclusion. Appellants first argue that the Examiner picks a random orientation embodiment of Liebau without explanation and argue that Liebau teaches nanotubes “substantially parallel to one another” in a preferred embodiment. Appeal Br. 11 (quoting Liebau 126) (emphasis removed); see also Reply Br. 9. The Examiner properly considered the random orientation embodiment, however. See In re Lamberti, 545 F.2d 747, 750 (CCPA 1976) (“all disclosures of the prior art, including unpreferred embodiments, must be considered”). As further elaborated upon below, choosing that embodiment did not piece together select teachings. Rather, the Examiner focused on the embodiment illustrated by, for example, Figure 1 and the text of Liebau paragraph 2. Liebau, Fig. 1; Ans. 14—15. Appellants also argue that Zhang and Choi teach away from random nanotube orientations by teaching parallel orientations and argue that Zhou also does not teach the random arrangement. Appeal Br. 12—15; Reply Br. 9—10. Appellants, however, do not cite to any evidence that criticizes, discredits, or otherwise discourages the random orientation. Mere disclosure of alternative embodiments, in this instance, does not persuasively establish a teaching away that would negate obviousness. Cf. In re Fulton, 391 F.3d 1195, 1201 (Fed. Cir. 2004) (“The prior art’s mere disclosure of more than one alternative does not constitute a teaching away from any of these 6 Appeal 2016-003026 Application 11/790,052 alternatives because such disclosure does not criticize, discredit, or otherwise discourage the solution claimed in the ’198 application.”). Moreover, even if Zhang, Choi, and Zhou do not teach the random arrangement, this does not establish error because the Examiner relies on Liebau for this teaching. “Non-obviousness cannot be established by attacking references individually where the rejection is based upon the teachings of a combination of references.” In re Merck & Co., 800 F.2d 1091, 1097 (Fed. Cir. 1986). Appellants also argue that Fiebau does not teach a field effect transistor (FET) and, therefore, none of the references teach a field effect transistor with randomly arranged carbon nanotubes. Appeal Br. 15—16; Reply Br. 10—12. The Appellants, however, do not persuasively dispute the Examiner’s finding that Fiebau teaches that it was already well known in the art to use semiconducting carbon nanotubes as semiconductors in nano circuitry. Ans. 16—18. The evidence supports the Examiner’s position and supports that even random distributions of bundles of nanotubes were used for such purpose: Since nanotubes, in particular carbon nanotubes, are suitable for use as metallic conductors and as semiconductors, in the context of nanocircuitry it is desirable for nanotubes of this type to be applied in targeted structured form to planar substrates. The use of nanotubes, such as in particular carbon nanotubes, as components, e.g. in electric circuits, requires them to make contact with metallic conductors. Nanotubes of this type are usually available as dispersions or as powders. When dispersions of this type are applied to planar surfaces, however, random distributions of bundles of nanotubes and of isolated nanotubes are usually obtained. Therefore, nanotubes from dispersions are applied to surfaces which have already been prestructured. 7 Appeal 2016-003026 Application 11/790,052 Liebau 12 (emphases added). We find, as the Examiner found, that this passage of Linder is best understood as referring to FET-based semiconductor circuitry and referring to the use of carbon nanotubes as providing a semiconducting channel for transistor action in the FET-based circuitry. Ans. 17—18. Appellants argue that rather than teaching a FET device, Liebau teaches the use of carbon nanotubes as electric lines. Appeal Br. 15. Appellants, however, focus solely on latter portions of Liebau rather than the passage reproduced above. The preponderance of the evidence indicates that Liebau teaches both functions of randomly oriented carbon nanotubes. Appellants also argue that none of the reference teach “comprising . . . only a plurality of semiconducting carbon nano-tubes” as recited in claim 1 because neither Zhang nor Choi teach removing metallic carbon nanotubes. Appeal Br. 16—17; Reply Br. 12—13. The Examiner, however, cites passages from Zhang and Choi that teach using only semiconducting single wall carbon nano-tubes. Ans. 21—22. Choi, for example, teaches that nanotubes may be metal nanotubes or semiconductor nanotubes and, shortly thereafter, states “[a] memory device according to the present invention uses semiconductor nanotubes.” Choi 3:42-44. Thus, a preponderance of the evidence supports the Examiner’s position that Zhang and Choi teach this recitation. Appellants also argue that the Examiner’s rationale for combining the cited references’ teachings “is quite suspect.” Appeal Br. 17. The Examiner stated a technical rationale for combining the references, however, and Appellants did not persuasively refute that rationale. As such, Appellants have not identified harmful error in the rationale. 8 Appeal 2016-003026 Application 11/790,052 Because Appellants’ arguments do not identify reversible error, we sustain the Examiner’s rejection of claim 1. Rejection 2, claim 20. Appellants argue that claim 20 recites “[a] metal-oxide semiconductor field effect transistor” (i.e., a MOSFET) and that the Examiner has not adequately explained how this recitation is taught by the art. Appeal Br. 18; Reply Br. 14. The Examiner first states that this recitation is not limiting because it appears in the preamble of the claim. We disagree. The recitation limits the scope of claim 20 because it adds structure rather than merely reciting the intended use of structure or merely providing a descriptive name to the claim as a whole. Pitney Bowes, Inc. v. Hewlett-Packard Co., 182 F.3d 1298, 1305 (Fed. Cir. 1999) (“If the claim preamble, when read in the context of the entire claim, recites limitations of the claim . . . then the claim preamble should be construed as if in the balance of the claim”). In the alternative, the Examiner finds that a MOSFET is not fundamentally different from a FET and cites Choi as teaching conventional MOSFETs. Ans. 25. Appellants, however, persuasively argue that not all FETs are MOSFETs. Reply Br. 14. The Examiner also has not explained why, in view of the cited references, a person of skill in the art would have been inclined to apply the random nanotube orientations of Liebau to a MOSFET. Rather, the citation to Choi refers to a then prior art device (Reply Br. 14 n.7), and the Examiner has not explained that Choi encourages the use of nanotubes (or randomly orientated nanotubes) for a MOSFET. We, therefore, agree with Appellants that “it was in error for the Examiner to rely solely [on the] teaching of a FET as supposedly rendering obvious a 9 Appeal 2016-003026 Application 11/790,052 MOSFET” (Reply Br. 14), and, based on the present record, we do not sustain the Examiner’s rejection of claim 20. Rejection 2, claim 2. Claim 2 recites “[t]he transistor as defined in claim 1 wherein said electrodes are linear, elongated and parallel to each other so that at least one of said nano-tube extends below and connects at least two of the plurality of electrodes.” Appeal Br. 25 (Claims App’x). Appellants argue that the Examiner has not adequately explained why it would be obvious to implement this recited feature. Id. at 20; Reply Br. 17. The Examiner cites Zhang to support this point (Ans. 28—29), but the Examiner cites no art that uses this electrode configuration or that teaches any reason to use this configuration as compared to other possibilities. Rather, as Appellants note, Figure IB of Choi shows electrodes in a circular pattern. Although it is possible that the Examiner may be correct that such configurations are “well-known in the art” (Ans. 28 (emphasis removed)), the Examiner has not identified adequate evidence in the current record to support this proposition. We decline to attempt to identify a teaching concerning this configuration in the first instance on appeal. Accordingly, we do not sustain the Examiner’s rejection of claim 2. Rejection 2, claims 3 and 4. Claim 3 recites “[t]he transistor as defined in claim 1 wherein said substrate comprises a doped silicon layer covered at least in part by an electrical insulating layer.” Appeal Br. 25 (Claims App’x). Claim 4 recites “[t]he transistor as defined in claim 3 wherein said insulating layer comprises an oxide layer.” Id. The Examiner finds that such layers are well-known in the art as evidenced by Zhang and Choi and explains why a semiconductor device would not work without the recited configuration. Ans. 29—30. Appellants 10 Appeal 2016-003026 Application 11/790,052 do not persuasively rebut the Examiner’s findings. Reply Br. 18—19. Rather, Appellants argue that the Examiner previously stated that “Zhou and Choi are only cited to teach an artisan that only semiconducting nanotubes can be used . . . .” Id. at 18 (emphasis removed). The Examiner’s statement, however, does not preclude the Examiner from also using these references to evidence semiconductor basics. Appellants also argue that Liebau teaching a FET would contradict the Examiner’s contention that it is necessary to cover the semiconductor layer, in part, to ensure proper operation. Id. at 18—19. Appellants do not persuasively explain, however, why this is a contradiction especially considering that claim 3 only requires a partial covering. We thus, sustain the Examiner’s rejection of claims 3 and 4. Rejection 2, claims 5 and 6. Claim 5 recites “[t]he transistor as defined in claim 1 wherein each said electrode comprises gold.” Appeal Br. 25 (Claims App’x). Claim 6 recites “[t]he transistor as defined in claim 1 wherein the electrodes comprise a titanium and gold alloy.” Id. at 26. Appellants argue that the Examiner speculates by finding that use of these materials would improve conductivity. Appeal Br. 21. The Examiner finds, however, that gold has higher conductivity than aluminum (Ans. 30). Appellants dispute the lack of citation for the Examiner’s finding but do not dispute the finding’s accuracy (Reply Br. 19). We agree with the Examiner that the use of gold for conductivity and for circuits is exceptionally well known. We, therefore, sustain the Examiner’s rejection of claim 5. The Examiner, however, does not present any similar findings for an alloy of gold and titanium and does not present evidence establishing that 11 Appeal 2016-003026 Application 11/790,052 such an alloy is a known substitution in this context. Reply Br. 19. Therefore, based on the record before us, do not sustain the Examiner’s rejection of claim 6. Rejection 2, claim 14. Claim 14 recites “[t]he transistor as defined in claim 1 wherein the carbon nano-tubes comprise single wall carbon nano tubes.” Appeal Br. 27 (Claims App’x). Appellants argue that Liebau mentions that the nanotubes maybe multi-walled. Id. Appellants, however, do not persuasively dispute the Examiner’s finding that Liebau teaches single wall carbon nano-tubes. Final Act. 3; see also Liebau 117. Because all embodiments of the art must be considered, Appellants’ argument does not identify reversible error. See In re Lamberti, 545 F.2d at 750. We thus, sustain the Examiner’s rejection of claim 14. Rejection 2, claims 16 and 18. Claim 16 recites carbon nano-tube bundle density: “[t]he transistor as defined in claim 14 wherein the single wall carbon nano-tubes are randomly disposed on the surface of said substrate in bundles that comprise single wall carbon nano-tubes wherein the bundles are disposed on the surface of said substrate at a density of from 3 to 6 bundles per 100 pm2.” Appeal Br. 27 (Claims App’x). Likewise, claim 18 recites: “[t]he transistor as defined in claim 1 wherein the carbon nano-tubes are randomly disposed on the surface of said substrate in bundles and further wherein between 375 and 500 bundles extend below and connect one of said plurality of electrodes to an adjacent electrode.” Id. at 28. Appellants’ arguments as to these recitations were also presented in the context of claim 20 which has a similar recitation. Appeal Br. 18—19, 22. The Examiner finds that Liebau and Zhou each teach that use of bundles of carbon nanotubes is conventional and well-known in the art. Ans. 27—28; 12 Appeal 2016-003026 Application 11/790,052 see also Liebau 12 (“random distributions of bundles of nanotubes ... are usually obtained”). The Examiner further finds that a person of skill in the art would adjust the density of nano-tube bundles to achieve different current densities. Ans. 28. Appellants do not persuasively dispute the Examiner’s finding of fact or even assert that the finding is factually wrong. We therefore also adopt the Examiner’s finding. The Examiner’s finding supports that bundle density is a result effective variable and supports the Examiner’s obviousness conclusion. See In re Boesch, 617 F.2d 272, 276 (CCPA 1980) (“[Djiscovery of an optimum value of a result effective variable in a known process is ordinarily within the skill of the art.”); In re Aller, 220 F.2d 454, 456 (CCPA 1955) (“where the general conditions of a claim are disclosed in the prior art, it is not inventive to discover the optimum or workable ranges by routine experimentation.”). Instead of arguing against the Examiner’s finding that a person of skill would have adjusted density, Appellants argue that Liebau only teaches bundled nanotubes in describing “a then-prior art process. . . .” Reply Br. 15. The Examiner, however, may rely on Liebau for all that it teaches, and, as explained above, it is the prior art process of Liebau’s paragraph two that the Examiner also relies upon as teaching the use of carbon nanotubes as a FET. Appellants’ argument therefore does not identify reversible error, and we sustain the Examiner’s rejection of claims 16 and 18. DECISION For the above reasons, we affirm the Examiner’s rejection of claims 1, 3, 4, 5, 14, 16, and 18 as obvious. We reverse the Examiner’s rejection of claims 1—6, 14, 16, and 18 as failing to comply with the written description 13 Appeal 2016-003026 Application 11/790,052 requirement of 35 U.S.C. § 112. We reverse the Examiner’s rejection of claims 2, 6, and 20 as obvious. No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a). AFFIRMED-IN-PART 14 Copy with citationCopy as parenthetical citation