Ex Parte Kamineni et alDownload PDFPatent Trial and Appeal BoardJun 28, 201814457370 (P.T.A.B. Jun. 28, 2018) Copy Citation UNITED STA TES p A TENT AND TRADEMARK OFFICE APPLICATION NO. FILING DATE FIRST NAMED INVENTOR 14/457,370 08/12/2014 Vimal Kamineni 10742 7590 07/02/2018 GLOBALFOUNDRIES INC. c/o Amerson Law Firm, PLLC 2500 Fondren Road, Suite 220 UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www .uspto.gov ATTORNEY DOCKET NO. CONFIRMATION NO. 2 l 62.249000/EU760 1094 EXAMINER TURNER, BRIAN Houston, TX 77063 ART UNIT PAPER NUMBER 2894 NOTIFICATION DATE DELIVERY MODE 07/02/2018 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): uspto@amersoniplaw.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte VIMAL KAMINENI, XIUYU CAI, and XUNYUAN ZHANG Appeal2017-008702 Application 14/457,370 Technology Center 2800 Before ROMULO H. DELMENDO, DONNA M. PRAISS, and SHELDON M. McGEE, Administrative Patent Judges. DELMENDO, Administrative Patent Judge. DECISION ON APPEAL The Applicant (hereinafter "Appellant") 1 appeals under 35 U.S.C. § 13 4( a) from the Primary Examiner's final decision to reject claims 1-10 and 16-25. 2 We have jurisdiction under 35 U.S.C. § 6(b). We affirm. 1 The Appellant is the Applicant, "GLOBALFOUNDRIES, Inc.," which, according to the Brief, is the real party in interest ( Appeal Brief filed December 19, 2016, hereinafter "Appeal Br.," 2). 2 Appeal Br. 4--11; Reply Brief filed May 24, 2017, hereinafter "Reply Br.," 2-7; Final Office Action entered July 25, 2016, hereinafter "Final Act.," 3- 17; Examiner's Answer entered March 24, 2017, hereinafter "Ans.," 2-5. Appeal2017-008702 Application 14/457,370 I. BACKGROUND The subject matter on appeal relates to a method for forming an MIS (Metal-Insulator-Semiconductor) contact structure for semiconductor devices, such as transistors, including a step in which an insulating material is deposited selectively (Specification filed August 12, 2014, hereinafter "Spec.," 1, 11. 6-20). Figure 2D, which illustrates the method after the selective deposition step, is reproduced from the Drawings as follows: 100 Figure 20 126 I 124 I 122 114 '· 102 Figure 2D above depicts a device 100 after performing a selective deposition process (e.g., a metal-oxide chemical vapor deposition (CVD) process) to form a metal-oxide insulating material 128 ( e.g., materials "comprised of a variety of different metal-oxide materials, including, but not limited to, a high-k insulating material (k value of 10 or greater), such as Ti02, La20 3, Ah03, Hf02, etc.") on exposed portions of source/drain regions 122 through contact openings 126 formed on insulating material 124 without depositing any material on sidewalls 126S (id. at 12, 1. 10-13, 1. 10). 2 Appeal2017-008702 Application 14/457,370 Representative claim 1 is reproduced from page A-1 of the Claims Appendix to the Appeal Brief (some indentations and emphasis added), as follows: 1. A method of forming an MIS contact structure, compnsmg: forming at least one layer of insulating material above a semiconductor layer; performing at least one contact opening etching process to form a contact opening in said at least one layer of insulating material that exposes a surface portion of said semiconductor layer; performing a selective material deposition process to selectively deposit a metal-oxide insulating material through said contact opening on the exposed surface portion of said semiconductor layer; and forming a conductive contact in said contact opening that contacts said metal-oxide insulating material. II. REJECTIONS ON APPEAL On appeal, the Examiner maintains four rejections under AIA 35 U.S.C. § 103, as follows: A. Claims 1, 2, 4---6, 16, and 17 as unpatentable over Alptekin et al. 3 (hereinafter "Alptekin") in view of Zhu et al. 4 (hereinafter "Zhu"); B. Claims 3 and 7-10 as unpatentable over Alptekin in view of Zhu and King et al. 5 (hereinafter "King"); C. Claims 18-22, 24, and 25 as unpatentable over Alptekin in view of Zhu and Hermes; 6 and 3 US 2015/0270179 Al, published September 24, 2015. 4 US 2010/0006926 Al, published January 14, 2010. 5 US 2013/0292835 Al, published November 7, 2013. 6 US 2005/0208745 Al, published September 22, 2005. 3 Appeal2017-008702 Application 14/457,370 D. Claim 23 as unpatentable over Alptekin in view of Zhu, Hermes, and King. (Ans. 2-5; Final Act. 3-17.) III. DISCUSSION Rejection A. The Appellant's arguments focus only on claim 1 (Appeal Br. 4--9). Therefore, we confine our discussion to claim 1, which we select as representative pursuant to 37 C.F.R. § 4I.37(c)(l)(iv). As provided by this rule, claims 2, 4---6, 16, and 17 stand or fall with claim 1. The Examiner finds that Alptekin describes a method for forming an MIS contact structure including most of the limitations recited in claim 1 but acknowledges it does not teach the disputed limitations highlighted above in reproduced claim 1 (Final Act. 3--4). Specifically, the Examiner finds that Alptekin describes "selectively form[ing] a metal-oxide insulating material (i1i10043-0046: 519/520/525) through [a] contact opening on the exposed surface portion of [a] semiconductor layer (i-f 0043: 519/520/525 formed selectively on surface of 51 O)" (id. at 3) but acknowledges that the reference "does not teach the method of selectively forming the metal-oxide insulating material comprises selective deposition of metal-oxide insulating material" (id. at 4). The Examiner finds further, however, that "Zhu teaches a method of atomic layer deposition [ ALD] ( equivalent to that of Alptekin) comprising selective deposition of metal-oxide insulating material selected from a group comprising aluminum oxide and lanthanum oxide" (id.). Based on these findings, the Examiner concludes (id.): It would have been obvious to one of ordinary skill in the art at the time the invention was filed to use the selective deposition of metal-oxide insulating material taught by Zhu to 4 Appeal2017-008702 Application 14/457,370 form the selective metal oxide insulating material layer taught by Alptekin, as a means to reduce the number of manufacturing steps by directly depositing the metal-oxide insulating material, thereby improving manufacturing efficiency and reducing costs. Since all the claimed methods were known in the prior art, and one skilled in the art could have combined the elements as claimed by known methods with no change in their respective functions, the combination would have yielded nothing more than predictable results to one of ordinary skill in the art. In the Answer, the Examiner clarifies that "the rejection of claim 1 does not assert that the atomic layer deposition taught by Zhu is equivalent to the thermal growth process taught by Alptekin, but rather the atomic layer deposition taught by Zhu ... is similarly taught by Alptekin" (Ans. 2 ( citing, inter alia, Alptekin ,r 46)). The Appellant's principal argument is that "the suggested modification based on the teachings of Zhu would ... completely void the fundamental premise of the Alptekin disclosure, which is directed to the diffusion-controlled oxygen depletion of a semiconductor contact interface" (Appeal Br. 5). Specifically, the Appellant argues that,/or smaller semiconductor component structures, Alptekin teaches replacing conformally-deposited metal oxide layers (e.g., by ALD) within a contact structure with metal oxides formed in situ during an annealing step performed after depositing certain materials at the contact's bottom to reduce parasitic resistance and parasitic capacitance (id. at 5---6). According to the Appellant, combining the references "would therefore leave the resulting devices open to the type of performance deficiencies associated with the increased parasitic resistance and parasitic capacitance experienced by the ever-shrinking size and increased packing densities of modem semiconductor circuit devices----deficiencies that the Alptekin disclosure is 5 Appeal2017-008702 Application 14/457,370 specifically directed to overcoming" (id. at 6-7). In the Reply Brief, the Appellant disputes one of the Examiner's stated reasons for combining the references ( reduced number of manufacturing steps) (Final Act. 4 ), arguing that "contrary to the Examiner's assertions, additional processing steps would still be required in order to form the two remaining silicide and metal layers 645, 650 that are otherwise fundamental to the Alptekin method" (Reply Br. 5 (referring to Alptekin's Fig. 6)). The Appellant's arguments fail to identify any reversible error in the Examiner's rejection. In re Jung, 637 F.3d 1356, 1365 (Fed. Cir. 2011). Alptekin describes a method for manufacturing semiconductor contacts and controlling their electrical characteristics (parasitic resistance and parasitic capacitance) "by taking advantage of anneal-driven diffusion in layers of a contact structure" (Alptekin ,r 15). Specifically, an embodiment is disclosed in Alptekin's Figure 5, which we reproduce as follows: .~500 FIG. 5 6 Appeal2017-008702 Application 14/457,370 Alptekin's Figure 5 above depicts an intermediate manufacturing structure 500 that may be used to form contacts, wherein the structure 500 includes an opening 516 in a dielectric material 515 on a semiconductor substrate 505's silicon-containing region 510, on which are deposited a silicon-containing oxide layer 519, a first metal layer 520, and a second metal layer 525 (id. ,r,r 39-42). Alptekin teaches that "both the oxygen from the oxide layer 519 and the metals in the metal stack and the oxygen in the silicon dioxide may diffuse to produce a metal-insulator-silicon (MIS) contact structure" to form "a layer of a metallic oxide such as aluminum oxide Ab03 beneath a metal silicide layer that may form" (id. ,r 43). According to Alptekin, "growing a metal oxide layer 519 in situ on top of the exposed portion of the semiconductor substrate 518 permits manufacturers to realize a smaller contact opening during the manufacturing process than may be possible absent the in situ film growth during millisecond laser anneal steps" and the space saved "may be used for increasing the amount of dielectric material 515 between the contact opening and the transistor gate to decrease the amount of parasitic capacitance in the semiconductor circuit" (id. ,r 46). But Alptekin also teaches another method for forming a metallic oxide such as aluminum oxide or lanthanum oxide on the semiconductor (id.). Specifically, Alptekin teaches (id. (emphasis added)): methods of forming metallic oxide layers in contact openings include atomic layer deposition (ALD), which deposits a conformal layer of a metallic oxide such as aluminum oxide or lanthanum oxide on the top of the wafer surface, on the side or wall of the contact opening, and on the exposed silicon- containing source or drain region of an NFET or PFET. Although Alptekin teaches that "[i]n order to have a sufficiently wide opening within the contact to receive metal fill, the original opening must be 7 Appeal2017-008702 Application 14/457,370 wider to accommodate the layer of a ( e.g., ALD deposited) metallic oxide on the sidewall" (id.), the reference contemplates depositing aluminum oxide or lanthanum oxide on the top of the wafer surface. In this regard, Zhu demonstrates that metallic oxides such as aluminum oxide or lanthanum oxide may be deposited selectively by ALD onto a short channel active region 104 on a semiconductor substrate 100 (Zhu ,r 23; Fig. 7). Given the collective teachings found in the prior art references, we discern no reversible error in the Examiner's conclusion that a person having ordinary skill in the art would have found it obvious to implement a selective ALD technique in Alptekin to deposit a metallic oxide such as aluminum oxide or lanthanum oxide on top of a semiconductor substrate through a contact opening as an alternative to Alptekin's metal stack diffusion technique. KSR Int 'l Co. v. Teleflex Inc., 550 U.S. 398, 417 (2007) ("If a person of ordinary skill can implement a predictable variation, § 103 likely bars its patentability. "). Although Alptekin's metal stack diffusion technique may be advantageous for certain structures having particular dimensions or sizes, that fact does not establish that a selective ALD technique would be unsuitable for all purposes. Indeed, claim 1 on appeal does not specify any particular dimensions for the contact structure, and, therefore, the claimed method would not be expected to be immune from any potential drawback that may result from such a selective ALD technique. In re Fulton, 391 F.3d 1195, 1200 (Fed. Cir. 2004) ("[C]ase law does not require that a particular combination must be the preferred, or the most desirable, combination described in the prior art in order to provide [the] motivation [ or reason] for the current invention."); In re Gurley, 27 F.3d 551, 553 (Fed. Cir. 1994) 8 Appeal2017-008702 Application 14/457,370 ("Even reading [ the prior art]' s description as discouraging use of epoxy for this purpose, Gurley asserted no discovery beyond what was known to the art."). The Appellant appears to be arguing that claim 1 excludes layers such as silicide layer 645 and metal layer 650 as shown in Alptekin's Figure 6 (Reply Br. 5 ( citing, e.g., Alptekin ,r 48)). Alptekin teaches "a metallic oxide 640 that rests on the exposed silicon-containing region 610 of a semiconductor substrate 605" (Alptekin ,r 48). The Appellant fails to explain why layers 645 and 650 on top of metal oxide 640 would be precluded by the language recited in claim 1. For these reasons, we uphold the Examiner's rejection. Rejections B-D. The Appellant relies on the same arguments offered against Rejection A, adding only that the additional references do not cure the perceived deficiencies in Rejection A (Appeal Br. 9-11). Because no reversible error has been identified for Rejection A, we uphold Rejections B-D for the same reasons. IV. SUMMARY Rejections A through Dare sustained. Therefore, the Examiner's final decision to reject claims 1-10 and 16-25 is affirmed. No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a). AFFIRMED 9 Copy with citationCopy as parenthetical citation