Ex Parte Haas et alDownload PDFPatent Trials and Appeals BoardFeb 28, 201913949414 - (D) (P.T.A.B. Feb. 28, 2019) Copy Citation UNITED STA TES p A TENT AND TRADEMARK OFFICE APPLICATION NO. FILING DATE 13/949,414 07/24/2013 41288 7590 PA TENT CENTRAL LLC Stephan A. Pendorf 1401 Hollywood Boulevard Hollywood, FL 33020 02/28/2019 FIRST NAMED INVENTOR Herwig Haas UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www .uspto.gov ATTORNEY DOCKET NO. CONFIRMATION NO. 3926.438 5558 EXAMINER ZHANG, RACHELL ART UNIT PAPER NUMBER 1724 MAIL DATE DELIVERY MODE 02/28/2019 PAPER Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte HERWIG HAAS, JOY ROBERTS, FRANCINE BERRETTA, AMY SHUN-WEN YANG, STEPHEN LEE, and SIMA RONASI Appeal2018-005213 Application 13/949,414 1 Technology Center 1700 Before KAREN M. HASTINGS, JAMES C. HOUSEL, and JEFFREY R. SNAY, Administrative Patent Judges. HOUSEL, Administrative Patent Judge. DECISION ON APPEAL A. STATEMENT OF THE CASE Appellants filed an appeal under 35 U.S.C. § 134(a) from the Examiner's final decision rejecting claims 1-15. We have jurisdiction under 35 U.S.C. § 6(b). 2 1 Appellants are the Applicants, Daimler AG and Ford Motor Company, which, according to Appeal Brief, are the real parties in interest. Appeal Brief ("Appeal Br.") 3, filed October 23, 2017. 2 Our Decision additionally refers to the Specification ("Spec.") filed July 24, 2013, the Examiner's Answer ("Ans.") dated February 22, 2018, and the Reply Brief ("Reply Br.") filed April 23, 2018. Appeal2018-005213 Application 13/949,414 We AFFIRM. The subject matter on appeal relates to solid polymer electrolyte fuel cells and methods for increasing the tolerance of a solid polymer electrolyte fuel cell to voltage reversal (see, e.g., claims 1, 4, and 11 ). The Specification discloses that solid polymer electrolyte fuel cells subjected to repeated startup and shutdown cycles can experience unacceptably high degradation rates in performance because air can be present at the anode during start-up and shutdown. Spec. 1 :20-21. According to the Specification, this results in high potentials at the cathode, which causes carbon corrosion and platinum catalyst dissolution. Id. 1 :24--27. The Specification discloses that this leads to significant degradation in performance over time but improving the durability of fuel cells subject to repeated startup and shutdown remains a challenge. Id. I: 17-18, 1:27-28. In view of this, the invention is directed to a solid polymer electrolyte fuel cell with improved startup/shutdown durability by including a selectively conducting material and a carbon sublayer in contact with the side of the anode opposite to the solid polymer electrolyte, wherein the carbon sublayer and the selectively conducting material are selected such that the voltage of the fuel cell is greater than about 0.5 V when operating at 1.5 A/cm2. Id. 3:11-22. Independent claim 1 is illustrative and is reproduced below from the Claims Appendix of the Appeal Brief. Limitations at issue are italicized. 1. A solid polymer electrolyte fuel cell comprising a solid polymer electrolyte, a cathode, and anode components connected in series electrically wherein: i) the anode components comprise an anode, an anode gas diffusion layer, and a selectively conducting component; ii) the selectively conducting component comprises a 2 Appeal2018-005213 Application 13/949,414 selectively conducting material; and iii) the electrical resistance of the selectively conducting component in the presence of hydrogen is more than 100 times lower than the electrical resistance in the presence of air; characterized in that the anode components comprise a carbon sublayer in contact with the side of the anode opposite the solid polymer electrolyte; and the selectively conducting material and carbon sublayer are selected such that the fuel cell voltage is greater than about 0.5 V when operating at 1.5 Alcm2 . REJECTIONS ON APPEAL I. Claims 1-8 and 11-14 under 35 U.S.C. § I02(b) as being anticipated by Barsan; 3 II. Claim 10 as being unpatentable under 35 U.S.C. § I03(a) over Barsan; III. Claim 9 as being unpatentable under 35 U.S.C. § I03(a) over Barsan in view ofYe; 4 and IV. Claim 15 as being unpatentable under 35 U.S.C. § I03(a) over Barsan in view of Chen. 5 B. DISCUSSION Rejection I Claims 1-8 and 11-14 are rejected under 35 U.S.C. § I02(b) as being anticipated by Barsan. 3 Barsan et al., WO 2011/076396 Al, published June 30, 2011 ("Barsan"). 4 Ye, US 2009/0186248 Al, published July 23, 2009 ("Ye"). 5 Chen et al., US 2007/0238610 Al, published Oct. 11, 2007 ("Chen"). 3 Appeal2018-005213 Application 13/949,414 The Examiner finds Barsan discloses a solid polymer electrolyte fuel cell including, among other things, a selectively conducting component comprising a selectively conducting material having a thickness of 1-300 micrometers and an anode having a carbon sublayer. Ans. 3--4. Appellants contend Barsan's disclosure of a carbon sublayer does not disclose the carbon sublayer in contact with the anode, as recited in claim 1; Barsan' s examples, which the Examiner cites for the claimed fuel cell voltage, do not including a carbon sublayer; and Barsan does not disclose both (a) a carbon sublayer in contact with the side of the anode opposite to the solid polymer electrolyte and (b) a fuel cell voltage greater than 0.5 V when operating at 1.5 A/cm2, as recited in claim 1. Appeal Br. 7-8; Reply Br. 2--4. Appellants also argue Barsan is silent with regard to the voltage of a fuel cell having a carbon sublayer, Barsan's disclosure does not set forth the limitations of claim 1 as they are arranged in that claim, and it would not have been obvious to include a carbon sublayer in Barsan's examples. Appeal Br. 9-12; Reply Br. 4--5. Appellants' arguments are unpersuasive. Barsan discloses a fuel cell including a solid polymer electrolyte, a cathode, an anode, an anode gas diffusion layer, and a selectively conducting component comprising a selectively conducting material. Barsan 2--4. Barsan discloses that the selectively conducting component has an electrical resistance in the presence of hydrogen that is more than 100 times lower than its electrical resistance in air. Id. at 2. Barsan further discloses that it may be advantageous to keep the selectively conductive layer separate from the catalyst of the anode so there is no direct contact between the anode catalyst and the selectively 4 Appeal2018-005213 Application 13/949,414 conducting layer. Id. at 9. In view of this, Barsan discloses "[a] carbon sublayer may for instance be incorporated between the two for this purpose." Id. Although Barsan does not explicitly disclose that the carbon sublayer is in contact with the side of the anode opposite to the solid polymer electrolyte, as recited in claim 1, it is reasonable to infer that Barsan's carbon sublayer is in contact with that side of the anode because Barsan discloses the carbon sublayer is between the anode and the selectively conducting layer without disclosing other layers between the carbon sublayer and the anode. Further, Appellants describe the arrangement of the carbon sublayer being in contact with the side of the anode opposite to the solid polymer electrolyte, as recited in claim 1, as the carbon sublayer being "interposed between the anode and the selectively conducting material" (Appeal Br. 7 (emphasis omitted)), which is quite similar to Barsan's description for its carbon sublayer (Barsan 9 ("[a] carbon sublayer may for instance be incorporated between the two for this purpose")). With regard to the fuel cell voltage recited in claim 1, we note that where the claimed and prior art products are identical or substantially identical, or are produced by identical or substantially identical processes, the PTO can require an applicant to prove that the prior art products do not necessarily or inherently possess the characteristics of the claimed product. In re Spada, 911 F.2d 705, 708 (Fed. Cir. 1990); In re Best, 562 F.2d 1252, 1255 (CCP A 1977). The Examiner's findings demonstrate that the solid polymer electrolyte fuel cell of claim 1 and Barsan's fuel cell are substantially identical. As noted above, Barsan discloses the structures recited in claim 1, 5 Appeal2018-005213 Application 13/949,414 including contact between the carbon sublayer and the side of the anode opposite to the solid polymer electrolyte. Moreover, Appellants' Specification states the selectively conducting layer and the carbon layer can be engineered to provide desired overall fuel cell performance characteristics but only describes a thickness for each layer (i.e., a thickness of about 10 to about 15 micrometers for the selectively conducting component). Spec. 6: 16-24. Barsan discloses a thickness of about 1-300 micrometers for its selectively conductive layer (Barsan 9) and its examples have a thickness of about 5-15 micrometers for the selectively conducting component (id. at 12- 13). 6 Each of those thickness ranges disclosed by Barsan overlap the thickness range disclosed by Appellants for the selectively conductive layer. 6 Although Barsan does not explicitly disclose a thickness for its carbon sublayer, it is not clear that the carbon sublayer has a significant effect upon the voltage for a solid polymer electrolyte fuel cell. For instance, the Examiner finds Barsan's examples exhibit the claimed fuel cell voltage (Ans. 3; Barsan 16, Table 2), which Appellants agree with (Appeal Br. 8 ("Appellants respectfully point out that the carbon sublayer is taught by Barsan on page 9, para. 2, and the voltage greater than about 0.5 V when operating at 1.5 A/cm2 is taught on page 16, Table 2 (emphasis omitted))). However, Barsan's examples have a selectively conducting component thickness (i.e., about 5-15 micrometers) that encompasses Appellants' thickness (i.e., about 10 to about 15 micrometers) (compare Spec. 6:16-19 with Barsan 12-13). Thus, Barsan's examples achieve the claimed fuel cell voltage at the selectively conducting component thickness disclosed by Appellants without inclusion of the carbon sublayer, which indicates the carbon sublayer has little to no effect upon the voltage of a fuel cell. Nonetheless, even if the converse were true, Barsan discloses a broader range for the thickness of the selectively conductive components (i.e., about 1-300 micrometer (id. at 9)) and teaches that the thickness of the selectively conductive layer is a variable that affects its resistance characteristics (id.), which suggests it would have been obvious to modify the thickness of the selectively conductive component to optimize its resistance and the overall voltage of a fuel cell including the selectively conductive component. 6 Appeal2018-005213 Application 13/949,414 Once the Examiner provides a reasonable basis to believe that the characteristic is inherent, the burden shifts to the applicant to prove that the prior art products do not necessarily possess the characteristics of his claimed product. In re Best, at 1254--55 (discussing In re Swinehart, 439 F.2d 210 (CCPA 1971) and In re Ludtke, 441 F.2d 660 (CCPA 1971)). Here, Appellants have not directed our attention to evidence or persuasive technical reasoning that Barsan's fuel cell would not possess the claimed voltage. Therefore, Appellants have not met the burden of demonstrating that Barsan's fuel cell would not necessarily possess the voltage recited in claim 1. Appellants also assert unexpected results for the claimed fuel cell, citing examples in Appellants' Specification. Appeal Br. 12-14. As noted by the Examiner at page 8 of the Examiner's Answer, unexpected results are not applicable to an anticipation rejection. See In re Malagari, 499 F .2d 1297, 1302 (CCPA 1974) ("If the rejection under§ 102 is proper, however, appellant cannot overcome it by showing such unexpected results or teaching away in the art, which are relevant only to an obviousness rejection."). 7 7 Moreover, the asserted results, which use certain materials and thicknesses for the selectively conductive component and carbon sublayer (Spec. 8:7-15, 11-12, Table 2), are not commensurate in scope with claim 1, which does not limit the material for the selectively conducting component or the carbon sublayer or limit the thickness for these components. A showing of unexpected results generally must be commensurate in scope with a claimed range. In re Harris, 409 F.3d 1339, 1344 (Fed. Cir. 2005). In addition, Appellants' Specification does not describe the asserted results as "unexpected." "It is well settled that unexpected results must be established by factual evidence. Mere argument or conclusory statements in the 7 Appeal2018-005213 Application 13/949,414 Appellants do not argue claims 2-8 and 11-14 separately from claim 1. Appeal Br. 14. For these reasons and those set forth in the Examiner's Answer, we sustain the Examiner's § 102(b) rejection of claims 1-8 and 11-14. Rejection II Claim 10 is rejected as being unpatentable under 35 U.S.C. § 103(a) over Barsan. Appellants contend claim 10 is allowable for the same reasons as claim 1, notably because Barsan's disclosure of a carbon sublayer is a separate disclosure from its examples that exhibit the fuel cell voltage of claim 1. Appeal Br. 15. Thus, Appellants do not argue claim 10 separately from claim 1. As discussed above, Appellants have not identified a reversible error in the rejection of claim 1. Therefore, we sustain the Examiner's§ 103(a) rejection of claim 10. Rejection III Claim 9 is rejected as being unpatentable under 35 U.S.C. § 103(a) over Barsan in view of Ye. Appellants assert Ye' s material is used for a different purpose and is used as a catalyst. Appeal Br. 15-16. This argument is unpersuasive because Ye discloses a polymer electrolyte membrane fuel cell including, among other things, an anode having an anode catalyst layer comprising a specification does not suffice." In re De Blauwe, 736 F.2d 699, 705 (Fed. Cir. 1984) (citing In re Lindner, 457 F.2d 506, 508 (CCPA 1972)). 8 Appeal2018-005213 Application 13/949,414 catalyst on a corrosion resistance supporting material and a carbon sublayer. Ye ,r,r 2, 18, 40. Ye discloses the corrosion resistant support material may comprise synthetic graphite or acetylene black. Id. ,r 93. To the extent Ye does not explicitly disclose the use of synthetic graphite or acetylene black for the carbon sublayer, Ye demonstrates it was known to use such materials for the anode ( e.g., as the corrosion resistance supporting material) and, as discussed above with regard to claim 1, Barsan already demonstrates it was known to include a carbon sublayer in a solid polymer electrolyte fuel cell. Therefore, the substitution of one known element ( e.g., synthetic graphite or acetylene black) for another (e.g., the material ofBarsan's carbon sublayer) would have yielded no more than a predictable result. KSR Int'! Co. v. Teleflex Inc., 550 U.S. 398,416 (2007). Further, as explained by the Examiner ( Ans. 5), Ye' s teaching that its carbon material provides corrosion resistance (Ye ,r 93) would have provided a reason for one of ordinary skill in the art to use Ye's material for Barsan's carbon sublayer. Appellants further argue that Ye' s material is very different from the present invention because it includes metal oxide particles having particle- to-particle interfaces with other conductive particles and "one would not expect that Ye would exhibit the large difference in resistances of the present invention when measured in air and hydrogen." Appeal Br. 16. These arguments are also unpersuasive because claim 9 uses comprising language, which permits the inclusion of additional components and materials, and because claim 9 does not recite a particular resistance. For these reasons and those set forth in the Examiner's Answer, we sustain the Examiner's§ 103(a) rejection of claim 9. 9 Appeal2018-005213 Application 13/949,414 Re} ection IV Claim 15 is rejected as being unpatentable under 35 U.S.C. § 103(a) over Barsan in view of Chen. Appellants do not argue claim 15 separately from claim 1. Appeal Br. 16. As discussed above, Appellants have not identified a reversible error in the rejection of claim 1. Therefore, we sustain the Examiner's§ 103(a) rejection of claim 15. C. DECISION The decision of the Examiner is affirmed. No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a). AFFIRMED 10 Copy with citationCopy as parenthetical citation