Ex Parte Fringant et alDownload PDFBoard of Patent Appeals and InterferencesMay 17, 201210572944 (B.P.A.I. May. 17, 2012) Copy Citation UNITED STATES PATENT AND TRADEMARK OFFICE ____________ BEFORE THE BOARD OF PATENT APPEALS AND INTERFERENCES ____________ Ex parte CHRISTOPHE FRINGANT, VINCENT BODART, BERENGERE RIXENS, ROMAIN SEVERAC, YVES HERVAUD, PATRICK LACROIX-DESMAZES, and BERNARD BOUTEVIN ____________ Appeal 2011-005983 Application 10/572,944 Technology Center 1700 ____________ Before CHUNG K. PAK, PETER F. KRATZ, and KAREN M. HASTINGS, Administrative Patent Judges. PAK, Administrative Patent Judge. DECISION ON APPEAL Appellants appeal under 35 U.S.C. § 134(a) from the Examiner’s final rejection of claims 13, 15, 16, 21 through 23, 26, 28, and 36 through 47, all of the claims pending in the above-identified application.1 An oral hearing was held on March 8, 2012. We have jurisdiction under 35 U.S.C. § 6. 1 See Appeal Brief (“App. Br.”) filed September 23, 2010, 2; and Examiner’s Answer (“Ans.”) filed December 13, 2010, 2. Appeal 2011-005983 Application 10/572,944 2 STATEMENT OF THE CASE The subject matter on appeal relates to a polymer composition, to a process for preparing such a polymer composition, to its use for coating metal, polymer, paper or cellophane surfaces and for producing thin single-layer or multilayer films and moulded objects, to a process for coating such surfaces by means of said polymer composition and to the articles or parts of articles obtained. [(See Spec. 1, ll. 1-5.)] The polymer composition comprises a polymer (P1) comprising monomeric units derived from an ethylenically unsaturated monomer (M1) and at least one co-oligomer (O1) having component (A) comprising at least one monomeric unit derived from the ethylenically unsaturated monomer (M1) and component (B) comprising at least one monomeric unit (m2) derived from an ethylenically unsaturated monomer carrying at least one group, such as a phosphonate group. (See Spec. 2, ll. 1-25.) The Specification defines the term “polymer (P1)” as “a polymer of molar mass greater than that of the co-oligomer (O1)” and the term “co-oligomer (O1)” as a copolymer of low molar mass. (See Spec 2, ll. 26-28 and 7, ll. 1-2.) The Specification, at page 3, lines 4-16 and page 4, lines 29-32, also states that: For the purposes of the present invention, the expression "polymer (P1) comprising monomeric units derived from an ethylenically unsaturated monomer (M1)" is intended to denote the polymers which are obtained by addition polymerization. The polymer (P1) contains at least 50%, preferably at least 60%, particularly preferably at least 70%, by weight of monomeric units derived from the ethylenically unsaturated monomer (M1). As examples of such polymers (P1), mention may be made of halogenated polymers, polymers of acrylic acid or of its esters, polymers of methacrylic acid or of its esters, polymers of acrylonitrile or of methacrylonitrile, polymers of Appeal 2011-005983 Application 10/572,944 3 acrylamide, of methacrylamide or of their derivatives, vinyl acetate polymers, polymers of itaconic acid, of maleic acid or of maleic anhydride, polymers of ethylene, of propylene, of butadiene, of isoprene or of styrene and of its derivatives. . . . . Most particularly preferably, the polymer (P1) of the composition according to the invention is a polymer of vinylidene chloride. The ethylenically unsaturated monomer (M1) is therefore, in this case, most particularly preferably vinylidene chloride. Further, the Specification, at page 8, lines 1-7 and 18-28, states that: Component (A) of the co-oligomer (O1) may comprise at least one monomeric unit derived from at least one monomer that is copolymerizable with the monomer (M1) as defined above, i.e. a halogenated monomer and/or a nonhalogenated monomer if (M1) is preferably a halogenated monomer, a chlorinated monomer and/or a nonchlorinated monomer if (M1) is particularly preferably a chlorinated monomer, or a monomer that is copolymerizable with vinylidene chloride if (M1) is most particularly preferably vinylidene chloride. . . . . In the co-oligomer, component (B) comprises at least one monomeric unit (m2), derived from an ethylenically unsaturated monomer, carrying at least one group chosen from the following groups: -CaH2a+1 with a between 6 and 30, -(CH2)b-CcF2c+l with b between 1 and 11 and c greater than or equal to 5, -(CH2)d-(Si(CH3)2-O)e-Si(CH3)3 with d between 1 and 11 and e between 1and 1000, -COOH, -SO3H, and the phosphonate groups -PO(OH)(OR1) with R1 being a hydrogen atom or an alkyl radical containing from 1 to 11 carbon atoms. Appeal 2011-005983 Application 10/572,944 4 Details of the appealed subject matter are recited in representative claims 13 and 362 reproduced from the Claims Appendix to the Appeal Brief as shown below: Claim 13: A polymer composition comprising 1) a polymer (P1) comprising at least 50% by weight of monomeric units derived from an ethylenically unsaturated monomer (M1), and 2) at least one co-oligomer (O1) comprising at least: a) a component (A) comprising at least one monomeric unit identical to that derived from the monomer (M1) on which the polymer (P1) is based, and b) a component (B) comprising at least one monomeric unit (m2), derived from an ethylenically unsaturated monomer, carrying at least one phosphonate group - PO(OH)(OR1) with R1 being a hydrogen atom or an alkyl radical containing from 1 to 11 carbon atoms, wherein the number-average molar mass of polymer (P1) is greater than 30,000 and the number-average molar mass of co-oligomer (O1) is less than or equal to 30,000. Claim 36: A polymer composition comprising 1) a polymer (P1) comprising at least 50% by weight of monomeric units derived from an ethylenically unsaturated monomer (M1), and 2) at least one co-oligomer (O1) comprising at least: 2 Appellants have separately argued independent claims 13 and 36 (App. Br.6-16). Therefore, for purposes of this appeal, we select independent claims 13 and 36 and decide the propriety of the Examiner’s §103(a) rejections set forth in the Answer based on these claims alone in accordance with 37 C.F.R. § 41.37(c)(1)(vii). Appeal 2011-005983 Application 10/572,944 5 a) a component (A) comprising at least one monomeric unit identical to that derived from the monomer (M1) on which the polymer (P1) is based, and b) a component (B) comprising at least one monomeric unit (m2), derived from an ethylenically unsaturated monomer, carrying at least one -(CH2)b-CcF2c+l group with b between 1 and 11 and c greater than or equal to 5, wherein the number-average molar mass of polymer (P1) is greater than 30,000 and the number-average molar mass of co-oligomer (O1) is less than or equal to 30,000. As evidence of unpatentability of the claimed subject matter, the Examiner relies on the following prior art references at page 3 of the Answer: Messwarb3 US 2,971,948 Feb. 14, 1961 Padget EP 0 185 464 A1 Jun. 25, 1986 Behr US 6,365,769 B1 Apr. 2, 2002 Thames US 6,599,972 B2 Jul. 29, 2003 Appellants seek review of the following grounds of rejection maintained by the Examiner in the Answer: 1) Claims 13, 15, 16, 21 through 23, 26, 28, 44, and 45 under 35 U.S.C. § 103(a) as unpatentable over the combined disclosures of Padget and Messwarb; 2) Claims 36 through 43 under 35 U.S.C. § 103(a) as unpatentable over the combined disclosures of Padget and Thames; and 3 Both the Examiner and Appellants refer to “Messwarb” as “Denk et al.” in the Answer, Appeal Brief and Reply Brief. Appeal 2011-005983 Application 10/572,944 6 3) Claims 36 through 43, 46, and 47 under 35 U.S.C. § 103(a) as unpatentable over the combined disclosures of Padget and Behr. (See App. Br. 6.) DISCUSSION I. REJECTION (1) We reverse the Examiner’s § 103(a) rejection of claims 13, 15, 16, 21 through 23, 26, 28, 44, and 45 based on the collective teachings of Padget and Messwarb. As correctly indicated by Appellants at pages 6 through 11 of the Appeal Brief, the Examiner has not demonstrated that one of ordinary skill in the art would have been led to employ a vinyl phosphonate monomer useful for promoting the adhesion characteristic of Messwarb’s vinyl chloride copolymer-based lacquer products to copolymer B of Padget’s contact adhesive for bonding two substrates. On this record, the Examiner has not evinced that Messwarb’s vinyl phosphonate monomer could provide sufficient adhesive or bonding strength to Padget’s contact adhesive for the purpose of bonding two substrates. Thus, on this record, the Examiner has not established a prima facie case of obviousness regarding the subject matter recited in claims 13, 15, 16, 21 through 23, 26, 28, 44, and 45 within the meaning of 35 U.S.C. § 103(a). II. REJECTION (2) We affirm the Examiner’s § 103(a) rejection of claims 36 through 43 based on the collective teachings of Padget and Thames for the findings of Appeal 2011-005983 Application 10/572,944 7 fact set forth by the Examiner at pages 6, 7, 13 and 14 of the Answer.4 We add the following primarily for emphasis. There is no dispute that Padget teaches a latex composition for use as contact adhesives comprising copolymer A containing 10 to 70 wt% of vinylidene chloride (corresponding to the claimed copolymer P1 containing at least 50% by weight of monomeric units derived from an ethylenically unsaturated monomer (M1)) and copolymer B containing 35 to 70 wt% of vinylidene chloride (corresponding to the claimed oligomer O1), wherein exemplified copolymer A contains 27.2% vinylidene chloride (claimed M1), 70.8% n-butyl acrylate, and 2.0% acrylic acid, with a molecular weight of 114,898 (greater than 30,000) and exemplified copolymer B contains 59.4% vinylidene chloride (claimed M1), 5.1% of n-butyl acrylate, 33.5% methyl methacrylate, and 2.0% acrylic acid, with a molecular weight of 19,171(less than 30,000). (Compare Ans. 6 with App. Br. 11-14.) Although Padget does not mention that its polymer B corresponding to the claimed oligomer O1 has “component (B) comprising at least one monomeric unit (m2), derived from an ethylenically unsaturated monomer, carrying at least one –(CH2)b-CcF2c +1 group with b between 1 and 11 and c greater than or equal to 5” recited in claim 36, Appellants have not disputed the Examiner’s finding that Thames teaches using an ethylenically unsaturated internal plasticizing and crosslinking monomer corresponding to component B recited in claim 36 as a part of its latex composition suitable for contact adhesives. (Compare Ans. 7 with App. Br. 11-14.) Nor have 4 Any new arguments in the Reply Brief will not be considered. See Ex parte Borden, 93 USPQ2d 1473, 1474 (BPAI 2010) (Informative) (“the reply brief [is not] an opportunity to make arguments that could have been made in the principal brief on appeal to rebut the Examiner’s rejections, but were not.”). Appeal 2011-005983 Application 10/572,944 8 Appellants disputed the Examiner’s finding that copolymer B of Padget’s contact adhesive can include an internally plasticizing comonomer and that the internally plasticizing and crosslinking comonomer of Thames useful for a latex composition suitable for contact adhesives provides self-plasticized compositions with no subsequent VOC emissions. (Compare Ans. 6-7 with App. Br. 11-14; see also Padget, p. 11.) Given the above teachings, we determine that the Examiner has not reversibly erred in determining that one of ordinary skill in the art would have been led to include an internally plasticizing comonomer, such as the claimed component B disclosed in Thames, in copolymer B of Padget’s latex compositions suitable for contact adhesives, with a reasonable expectation of successfully imparting the desired plasticizing property to copolymer B of Padget’s latex composition. Appellants’ argument at pages 12 and 13 of the Appeal Brief that “Padget requires an internally plastici[z]ing comonomer in copolymer A and optionally in copolymer B” does not negate the prima facie case of obviousness established by the Examiner. The fact remains that Padget still teaches that an amount of an internally plasticizing comonomer, inclusive of that taught by Thames, can still be included in its copolymer B so long as the amount used “should be” selected to provide a Tg in the range of 0 to 80oC. (See also Padget, pp. 10-11.) Moreover, claim 36, by virtue of using the term “comprising” in the context of its copolymer P1, does not exclude the presence of an internally plasticizing comonomer in its copolymer P1 (corresponding to Padget’s copolymer A). Appellants also contend that Padget teaches away from the addition of internally plasticizing and crosslinking monomers, such as that taught by Thames, in its copolymer B. (See App. Br. 13-14.) In support of this Appeal 2011-005983 Application 10/572,944 9 contention, Appellants refer to a portion of page 13 of Padget. (See App. Br. 14.) However, Padget, at page 13 (emphasis added), teaches that The copolymer A and/or the copolymer B of the present invention may optionally contain . . . at least one multi- functional comonomer that has effected, when present, a partial . . . cross-linking during the polymeri[z]ation . . . as this can sometimes improve the creep performance properties of the copolymer. . . . . . . Nevertheless, even though such cross-linking may be used, it is not usually preferred [and] . . . it is not recommended as a general rule.” Although Padget may prefer to not employ cross-linking monomers, it does not teach away from using such internally plasticizing and crosslinking comonomer in its copolymer B. See Merck & Co., Inc. v. Biocraft Labs., Inc., 874 F.2d 804, 807 (Fed. Cir. 1989) (quoting In re Lamberti, 545 F.2d 747, 750 (CCPA 1976)(“[T]he fact that a specific [embodiment] is taught to be preferred is not controlling, since all disclosures of the prior art, including unpreferred embodiments, must be considered.”) III. REJECTION (3) We reverse the Examiner’s § 103(a) rejection of claims 36 through 43, 46, and 47 based on the collective teachings of Padget and Behr for the reasons set forth by Appellants at pages 15 and 16 of the Appeal Brief. Although the Examiner may have shown that Behr discloses component B recited in claim 36 as polymerizable surfactants in emulsion, the Examiner has not provided any apparent reason to incorporate such polymerizable surfactants as part of copolymer B of Padget as required by claim 36. As acknowledged by the Examiner at page 15 of the Answer, Padget teaches using a surfactant, but does not teach or suggest incorporating such surfactant as a part of its copolymer B. Appeal 2011-005983 Application 10/572,944 10 ORDER In view of the foregoing, it is ORDERED that the decision of the Examiner rejecting of claims 13, 15, 16, 21 through 23, 26, 28, 44, and 45 under 35 U.S.C. § 103(a) as unpatentable over the combined disclosures of Padget and Messwarb is REVERSED; FURTHER ORDERED that the decision of the Examiner rejecting claims 36 through 43 under 35 U.S.C. § 103(a) as unpatentable over the combined disclosures of Padget and Thames is AFFIRMED; FURTHER ORDERED that the decision of the Examiner rejecting claims 36 through 43, 46, and 47 under 35 U.S.C. § 103(a) as unpatentable over the combined disclosures of Padget and Behr is REVERSED; and FURTHER ORDERED that no time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a)(1)(iv). AFFIRMED -IN-PART ssl Copy with citationCopy as parenthetical citation