Ex Parte DumousseauxDownload PDFPatent Trial and Appeal BoardAug 9, 201811100566 (P.T.A.B. Aug. 9, 2018) Copy Citation UNITED STA TES p A TENT AND TRADEMARK OFFICE APPLICATION NO. FILING DATE FIRST NAMED INVENTOR 11/100,566 04/07/2005 Christophe Dumousseaux 22850 7590 08/13/2018 OBLON, MCCLELLAND, MAIER & NEUSTADT, L.L.P. 1940 DUKE STREET ALEXANDRIA, VA 22314 UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www .uspto.gov ATTORNEY DOCKET NO. CONFIRMATION NO. 397327US99X 2925 EXAMINER CHUI, MEI PING ART UNIT PAPER NUMBER 1616 NOTIFICATION DATE DELIVERY MODE 08/13/2018 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): OBLONPAT@OBLON.COM tfarrell@oblon.com patentdocket@oblon.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte CHRISTOPHE DUMOUSSEAUX Appeal2017-007107 Application 11/100,566 Technology Center 1600 Before RICHARD M. LEBOVITZ, FRANCISCO C. PRATS, and JEFFREY N. FREDMAN, Administrative Patent Judges. FREDMAN, Administrative Patent Judge. DECISION ON APPEAL This is an appeal 1,2 under 35 U.S.C. § 134 involving claims to a pigment composition. The Examiner rejected the claims as obvious. We have jurisdiction under 35 U.S.C. § 6(b). We affirm. Statement of the Case Background "Organic coloring substances are frequently used to give color to cosmetic compositions. But, with traditional organic coloring substances may not always be possible to obtain compositions that present satisfactory 1 Appellant identifies the Real Party in Interest as L'Oreal (see App. Br. 2). 2 We have considered and herein refer to the Specification of April 7, 2005 ("Spec."); Final Office Action of Feb. 18, 2016 ("Final Action"); Appeal Brief of Oct. 3, 2016 ("App. Br."); Examiner's Answer of Feb. 2, 2017 ("Answer"); and Reply Brief of Apr. 3, 2017 ("Reply Br."). Appeal2017-007107 Application 11/100,566 covering power" (Spec. ,r 3). "Moreover, in a cosmetic solvent, the shades contributed by those organic coloring substances may vary greatly between a dry state and a state in dispersion" (Id.). "Thus, a need exists to have cosmetic compositions available that can present satisfactory saturation C* and sufficiently high covering power" (Id. at 4). The Claims Claims 1-20 and 29-58 are on appeal. Claim 1 is representative and reads as follows: 1. A composition comprising particles of at least one composite pigment, said particles comprising an inorganic core comprising Ti02, said inorganic core being at least partially coated with at least one organic coloring substance, the composition being suitable for application to the skin, lips, nails, or hair of human, wherein the inorganic core is colored and has a mean size of from 1 nm to 100 nm, wherein the at least one organic coloring substance is not cochineal carmine, halo acid dyes, azo dyes, and anthraquinone dyes, wherein the at least one organic coloring substance is present in an amount ranging from 10 to 500 parts by weight per 100 parts of inorganic core, wherein the at least partially coated inorganic core is present in an amount sufficient for the saturation C* of the composition to range from 25 to 100, and wherein the composition has a covering power ranging from 25 to 100. 2 Appeal2017-007107 Application 11/100,566 The Rejections A. TheExaminerrejectedclaims 1-11, 13, 14, I8-20,29-31,and37-58 under 35 U.S.C. § I03(a) as unpatentable over Hayashi, 3 Yasuki, 4 and Henrion5 (Final Act. 3-7). B. The Examiner rejected claims 1 and 15-17 under 35 U.S.C. § I03(a) as unpatentable over Hayashi, Yasuki, Henrion, and Nishihama6 (Final Act. 8-9). C. The Examiner rejected claims 1 and 32-36 under 35 U.S.C. § I03(a) as unpatentable over Hayashi, Yasuki, Henrion, and Defossez7 (Final Act. 9-11). A. 35 US.C. § 103(a) over Hayashi, Yasuki, and Henrion The Examiner finds Hayashi teaches titanium dioxide core particles to which an organic pigment is coated with a pigment that is attached with a gluing agent, such as a silane (see Final Act. 4). The Examiner finds Hayashi teaches overlapping ranges of amounts of the pigment to the particles (see id.), as well as dyes other than those excluded by claim 1 including "phthalocyanine green" (id.). The Examiner acknowledges Hayashi "does not teach the mean size of the titanium oxide particles range from 1-100 nm," "the same range of saturation C* value," and "the composite particles in the forms as claimed" (Final Act. 5). 3 Hayashi et al., EP 1,184,426 A2, published Mar. 6, 2002. 4 Yasuki et al., EP 0,401,045 Bl, published Jan. 18, 1995. 5 Henrion et al., US 2002/0012683 Al, published Jan. 31, 2002. 6 Nishihama et al., US 6,358,495 Bl, issued Mar. 19, 2002. 7 Defossez et al., US 5,486,354, issued Jan. 23, 1996. 3 Appeal2017-007107 Application 11/100,566 The Examiner finds Y asuki teaches pigments "useful in the paints and cosmetics, comprising core particles of titanium dioxide having mean particle size from 0.01 to 0.1 µm (10-100 nm)" (Final Act. 5). The Examiner finds Yasuki's pigments are "coated with a layer of a colored oxide" and "exhibit different optical properties from the Ti02 pigments" (Id.). The Examiner finds Henrion teaches cosmetic compositions with "coloring agents, i.e. mineral dyes ( e.g. copper sulfate); and additives" which have "a saturation C* in the range from 19.4 to 108," "a covering power ranging from O .1 to 11 .1," and particulate pigments including titanium dioxide (Final Act. 5-6). The Examiner finds it obvious to "select the transparent titanium oxide, as disclosed by Hayashi, if such optical property (transparent) is desirable" (Final Act. 7). The Examiner further finds With respect to the saturation C* value and covering power of the composition as recited, it is merely a routine experimentation and optimization, which would have been obvious for one of ordinary skill in the art to test and select the desirable values based on the inorganic core particles color and the final product, as suggested by the prior art. (Final Act. 7). The issue with respect to this rejection is: (i) Does a preponderance of evidence of record support the Examiner's conclusion that the prior art renders the claims obvious? (ii) If so, has Appellant presented evidence of secondary considerations, that when weighed with the evidence of obviousness, is sufficient to support a conclusion of non-obviousness? 4 Appeal2017-007107 Application 11/100,566 Findings of Fact 1. Hayashi teaches a "pigment, paint and resin composition using ... composite particles" (Hayashi ,r 1) with "white pigments such as titanium dioxide, transparent titanium dioxide" (Hayashi ,r 36). 2. Hayashi teaches that by forming a gluing agent coating layer on surface of a white inorganic particle and forming an organic pigment coat on the gluing agent coating layer in an amount of 1 to 500 parts by weight based on 100 parts by weight of the white inorganic particles, the obtained composite particles having an average particle size of0.001 to 10.0 µm [1 nm to 10,000 nm] are substantially free from desorption of organic pigment from the surface thereof, and are usable as a harmless pigment. (Hayashi ,r 10). 3. Hayashi teaches The amount of the gluing agent coating layer is preferably 0.01 to 15.0% by weight, more preferably 0.02 to 12.5% by weight, still more preferably 0.03 to 10.0% by weight ( calculated as C) based on the weight of the gluing agent-coated white inorganic particles, in the case where the coupling agent except for the silane-based coupling agents, oligomers or polymer compounds are used as the gluing agent. When the amount of the gluing agent-coating layer is less than 0.01 % by weight, it may be difficult to adhere not less than one part by weight of the organic pigment onto 100 parts by weight of the white inorganic particles. When the amount of the gluing agent coating layer is more than 15.0% by weight, since it is possible to adhere 1 to 500 parts by weight of the organic pigment onto 100 parts by weight of the white inorganic particles therethrough, it is unnecessary to form the gluing agent coating layer in an amount of more than 15.0% by weight. (Hayashi ,r,r 65-66). 5 Appeal2017-007107 Application 11/100,566 4. The Specification teaches silane based binders that allow an "organic coloring substance to adhere to the surface of the inorganic core" (Spec. ,r 49). 5. Yasuki teaches "titanium dioxide-based chromatic pigments useful as a colorant of paints, printing inks, plastics, cosmetics and the like" (Y asuki 2: 3--4). 6. Y asuki teaches core particles of titanium dioxide having a mean particle size from 0.01 to 0.1 um [ 10 nm to 100 nm], said particles being coated with a layer of 1 to 30%, by weight of titanium oxide particles, of an oxide of Ni, Co, Ce, Cu, Cr, Mn, V, W or a mixture of these oxides, so that the coated core particles substantially retain the core particles transparency to visible light. (Yasuki 2:27-31 ). 7. Henrion teaches "[ c ]osmetic compositions ... contain a suitable vehicle and various coloring agents intended to give the compositions a certain color before and/or after they are applied" (Henrion ,r 2). 8. Henrion teaches "the need remains to have available coloring agents which may be used in cosmetics, to obtain a suitable coloration of the compositions and of the make-up obtained, the coloring agents moreover having at least one of the following properties: good covering power" (Henrion ,r 9). 9. Henrion teaches the "composition may also contain a particulate phase, which may comprise at least one of pigments, nacres, and fillers usually used in cosmetic compositions ... Mention may be made of titanium dioxide" (Henrion ,r 164 ). 6 Appeal2017-007107 Application 11/100,566 10. The Examiner finds that Henrion teaches cosmetic compounds with saturation C* in the range from 19 .4 to 108 (Final Act. 6, citing Henrion ,r 276, last two compounds in table). 11. The Examiner finds Henrion teaches cosmetic compounds with "a covering power ranging from 0.1 to 11.1" (Final Act. 6, citing Henrion ,r 277). 12. Henrion teaches "[w]hen L'iE* <5, the product was considered as having very high covering power; when L'iE*> 20, the product was considered as having poor covering power" (Henrion ,r 187). Principles of Law "The combination of familiar elements according to known methods is likely to be obvious when it does no more than yield predictable results." KSR Int'! Co. v. Teleflex Inc., 550 U.S. 398,416 (2007). Analysis We adopt the Examiner's findings of fact and conclusions of law (see Final Act. 3-7; FF 1-12) and agree that Hayashi, Yasuki, and Henrion render the claims obvious. We address Appellant's arguments below. Appellant contends "a person of ordinary skill would clearly lack motivation to modify titanium oxide if it is colored with the particle sizes taught by Yasuki because the result would not be a colored material" (App. Br. 8). Appellant contends: The use of teachings germane to the size from Y asuki ( to modify the operable size range in Hayashi) in which that size is attributed to give the particles transparency, a point seemingly conceded by the Examiner, would not have been used for covering power or hiding effects Transparency is a well-known (App. Br. 9). 7 Appeal2017-007107 Application 11/100,566 We find this argument unpersuasive. First, Hayashi expressly teaches particle sizes in a range of 1 nm to 10,000 nm (FF 2), fully overlapping the 1 nm to 100 nm range required by claim 1. "In cases involving overlapping ranges, we and our predecessor court have consistently held that even a slight overlap in range establishes a prima facie case of obviousness." In re Peterson, 315 F.3d 1325, 1329, 1330 (Fed. Cir. 2003). Second, we agree with the Examiner that "the instant inorganic core ( comprised of Ti02) itself is not a color core, but is made colored by coating the core with at least one organic coloring substance on the core particles" (Ans. 16). That is, Hayashi teaches that the core color derives from organic pigments linked to the core with gluing agents (FF 3), not based on the core color itself. Thus, whether the starting particles of Y asuki are colored or transparent prior to attachment of the organic pigments does not impact the fact that after organic pigments are attached to the core, the core will be colored (FF 1-3). Appellant contends one of ordinary skill seeking guidance for a suitable range of particle sizes of Ti02 in Hayashi would not have found that solution in Y asuki as there was a teachings away for using particles of Ti02 having a mean size of less than 0, 1 µm for obtaining chromatic pigments, which is what Hayashi seeks to use. (App. Br. 9-10; cf Reply Br. 2). We are not persuaded. A teaching away requires a reference to actually criticize, discredit, or otherwise discourage the claimed solution. See In re Fulton, 391 F.3d 1195, 1201 (Fed. Cir. 2004) ("The prior art's mere disclosure of more than one alternative does not constitute a teaching away from any of these alternatives because such disclosure does not 8 Appeal2017-007107 Application 11/100,566 criticize, discredit, or otherwise discourage the solution claimed"). Appellant's citation to Yasuki does not criticize, discourage or otherwise discredit the use of nanometer sized Ti02 particles as disclosed by both Hayashi and Yasuki (FF 2, 6). Moreover, even the portion quoted by Appellant that ''pearl pigments are preferably used in applications requiring a transparency" (App. Br. 10) simply represents a preferred embodiment. However, disclosed examples and preferred embodiments do not constitute a teaching away from a broader disclosure or non-preferred embodiments. In re Susi, 440 F.2d 442,446 n.3 (CCPA 1971). Appellant contends "Hayashi does not deal with cosmetics and as such it is non-analogous art" (App.Br. 11 ). Appellant contends: Under either test, the rejection fails as Hayashi has nothing to do with cosmetics (see definition in Claim 1) and one of ordinary skill would not have found guidance in Hayashi for teachings germane to a cosmetic. It would not have been obvious to a person of ordinary skilled in the art to use particles used for automobile bodies in cosmetics. Particles used in cosmetics have to meet safety requirements of higher level than particles used for automobile bodies. (App. Br. 11-12). We find this argument unpersuasive. We need not address whether paint and cosmetics are in the same field of endeavor because a "reference is reasonably pertinent if, even though it may be in a different field of endeavor, it is one which, because of the matter with which it deals, logically would have commended itself to an inventor's attention in considering his problem." In re Clay, 966 F.2d 656, 659 (Fed. Cir. 1992). In this case, Y asuki evidences that the inventor would have considered teachings related to both paints and cosmetics because "titanium dioxide- 9 Appeal2017-007107 Application 11/100,566 based chromatic pigments useful as a colorant of paints, printing inks, plastics, cosmetics and the like" (FF 5). Thus, Y asuki provides a direct statement that titanium dioxide based chromatic pigments are pertinent to both paints and cosmetics and therefore Hayashi is pertinent to, and analogous art for, the claimed invention. Appellant contends: "A major advantage of the present invention is to provide a cosmetic composition with a high covering power" (App. Br 12). Appellant contends "[ c ]omparative tests between a comparative composition comprising composite pigments comprising a Ti02 core having a mean size of 250 nm (as the one Hayashi of example 12) and a composition according to the invention comprising composite pigments comprising a Ti02 core having a mean size of 25 nm" (App. Br. 13; cf Reply Br. 3-5). We find this argument unpersuasive because Appellant provides no evidence that this result is unexpected, whether by way of Declaration or citation to a statement in the Specification that this result is unexpected or otherwise surprising. "It is well settled that unexpected results must be established by factual evidence. Mere argument or conclusory statements ... [do] not suffice." In re Soni, 54 F.3d 746, 750 (Fed. Cir. 1995). The Dumousseaux8 Declaration never states the changes in the L * and C* values are unexpected, only that the results are "advantageous" (see Dumousseaux Deel. 3). Moreover, the single result in the Dumousseaux Declaration for a single pigment with a single ratio of coloring substance and a single core size is not commensurate in scope with claim 1, which recites a range of 8 Declaration of Dr. Christophe Dumousseaux, dated June 23, 2014. 10 Appeal2017-007107 Application 11/100,566 core sizes from 1 to 100 nm as well as ratios of coloring substance from 10 to 500 parts by weight (see Claim 1 ). Unexpected results must be "commensurate in scope with the degree of protection sought by the claimed subject matter." In re Harris, 409 F.3d 1339, 1344 (Fed. Cir. 2005). Conclusion of Law A preponderance of the evidence of record supports the Examiner's conclusion that the prior art renders the claims obvious. Appellant has not presented evidence of secondary considerations, that when weighed with the evidence of obviousness, is sufficient to support a conclusion of non- obviousness. B. 35 US.C. § 103(a) over Hayashi, Yasuki, Henrion, and Nishihama Appellant contends The Examiner has not reasonably established that a person of ordinary skill seeking to create a "protective effect on human skin" as alleged to flow from Nishihama's teachings would have any relevance to a transparent material that has not been shown to have any protective effect. In other words, these two teachings in the Hiyashi modified with Y asuki and that in Nishihama are inapposite and not properly combinable. (App. Br. 14). The Examiner finds Hayashi' s pigment comprises composite particles utilizing titanium oxide in the core or as the core particles, wherein said core particles are coated with organic pigments that is coloring substance .... Nishihama is relied upon to teach that titanium oxide has the highest refractive index, which is 2.3 to 2.6, compared to other inorganic powders. 11 Appeal2017-007107 Application 11/100,566 (Ans. 18-19). The Examiner finds "the combination ofNishihama with Hayashi does not actually alter the composite pigment of Hayashi, but provided the knowledge of titanium oxide (i.e. refractive index) that is well- known in the relevant art" (Ans. 19). We agree with the Examiner. As already noted, Y asuki demonstrates that the ordinary artisan would recognize titanium dioxide based pigments as colorants in both paints and cosmetics (FF 5), rendering the pigments of Hayashi pertinent to the cosmetics of Y asuki, Henrion, and Nishihama. We also agree with the Examiner that the ordinary artisan, interested in using titanium dioxide based cosmetics as taught by Yasuka (FF 57), would have had reason to employ Nishihama's compositions where the "refractive index of titanium oxide is 2.3 to 2.6" because "[h]iding power of titanium oxide is also greatest among white pigments" and "it is desirable to prevent sunburn with making the application of the inorganic powder inconspicuous" (Nishihama 1 :37--44). We note that Nishihama also teaches particle sizes of "20 to 200 nm" within the range of claim 1 (see Nishihama 4: 12). Thus, the ordinary artisan interested in improving the cosmetics rendered obvious by Hayashi, Y asuki, and Henrion would have reasonably modified the titanium dioxide as suggested by Nishihama in order to improve hiding power and prevent sunburn. We further note that Appellant provides no evidence that the final materials used in Hiyashi or Y asuki would have been transparent, and Hiyashi teaches using "white pigments such as titanium dioxide, transparent titanium dioxide" (Hiyashi ,r 36). Thus, Hiyashi recognizes that even the starting material may be either transparent or not, but then teaches coating this starting material with an organic pigment (FF 3) that is not reasonably 12 Appeal2017-007107 Application 11/100,566 interpreted as "transparent". See In re Pearson, 494 F.2d 1399, 1405 (CCPA 1974) ("Attorney's argument in a brief cannot take the place of evidence."). C. 35 US.C. § 103(a) over Hayashi, Yasuki, Henrion, and Defossez Appellant contends the Examiner failed to consider that the primary reference being modified (Hayashi) is not related to cosmetics. Moreover, in the Examiner's construct of the prior art (Hayashi modified by Y asuki' s particle size), the resultant material would be transparent and as taught by Hayashi "transparent Ti02, the extender pigments or pearl pigments are preferably used in applications requiring a transparency". See paragraph [0036]. The Examiner has not reasonably established that a person of ordinary skill seeking to create a "a covering effect" as alleged to flow from Defossez's teachings would have any relevance to a transparent material that has not been shown to have any protective effect. (App. Br. 14--15). The Examiner finds Defossez is relied upon to teach the coloring substances as claimed in claims 32-36 are known color pigments in the cosmetic art, and they have been employed and used previously in cosmetic compositions, for applying to human skin ( e.g. foundation or lipstick; the eyes, i.e. mascaras; or the nail varnish), and these coloring substances are clearly suitable to be used in pigments that comprise titanium oxide. (Ans. 19-20). We agree with the Examiner. We have already extensively addressed Appellant's arguments regarding transparent Ti02 above, and remain unpersuaded for the reasons given. Hayashi generally teaches the use of 13 Appeal2017-007107 Application 11/100,566 organic pigments (FF 3), and lists a number of specific pigments (see Hayashi ,r,r 70-73). The Examiner reasonably relies upon Defossez as evidence that a number of different organic pigments were known equivalents in the prior art (see Ans. 15; Defossez 3:3-20). We agree that selecting such known equivalents would have been obvious. See KSR, 550 U.S. at 417 ("If a person of ordinary skill can implement a predictable variation,§ 103 likely bars its patentability.") This result is also consistent with Wrigley, which found a "strong case of obviousness based on the prior art references of record. [The claim] recites a combination of elements that were all known in the prior art, and all that was required to obtain that combination was to substitute one well-known ... agent for another." Wm. Wrigley Jr. Co. v. Cadbury Adams USA LLC, 683 F.3d 1356, 1364 (Fed. Cir. 2012). SUMMARY In summary, we affirm the rejection of claim 1 under 35 U.S.C. § 103(a) as unpatentable over Hayashi, Yasuki, and Henrion. Claims 2-11, 13, 14, 18-20, 29-31, and 37-58 fall with claim 1. We affirm the rejection of claims 1 and 15-17 under 35 U.S.C. § 103(a) as unpatentable over Hayashi, Yasuki, Henrion, and Nishihama. We affirm the rejection of claims 1 and 32-36 under 35 U.S.C. § 103(a) as unpatentable over Hayashi, Yasuki, Henrion, and Defossez. No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a). AFFIRMED 14 Copy with citationCopy as parenthetical citation