Ex Parte DeBiccari et alDownload PDFBoard of Patent Appeals and InterferencesSep 20, 201011088380 (B.P.A.I. Sep. 20, 2010) Copy Citation UNITED STATES PATENT AND TRADEMARK OFFICE UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 11/088,380 03/23/2005 Andrew DeBiccari 085.11101-US (04-322) 1375 52237 7590 09/21/2010 BACHMAN & LAPOINTE, P.C. (P&W) 900 CHAPEL STREET SUITE 1201 NEW HAVEN, CT 06510-2802 EXAMINER BAREFORD, KATHERINE A ART UNIT PAPER NUMBER 1715 MAIL DATE DELIVERY MODE 09/21/2010 PAPER Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE ____________ BEFORE THE BOARD OF PATENT APPEALS AND INTERFERENCES ____________ Ex parte ANDREW DEBICCARI, MELVIN FRELING, and JEFFREY D. HAYNES ____________ Appeal 2009-007618 Application 11/088,380 Technology Center 1700 ____________ Before SALLY G. LANE, MICHAEL P. TIERNEY, and JEFFREY B. ROBERTSON, Administrative Patent Judges. ROBERTSON, Administrative Patent Judge. DECISION ON APPEAL1 1 The two-month time period for filing an appeal or commencing a civil action, as recited in 37 C.F.R. § 1.304, or for filing a request for rehearing, as recited in 37 C.F.R. § 41.52, begins to run from the “MAIL DATE” (paper delivery mode) or the “NOTIFICATION DATE” (electronic delivery mode) shown on the PTOL-90A cover letter attached to this decision. Appeal 2009-007618 Application 11/088,380 2 STATEMENT OF THE CASE Appellants seek our review under 35 U.S.C. § 134 of the Examiner’s final decision rejecting claims 3-19 and 21-48. We have jurisdiction over the appeal under 35 U.S.C. § 6(b). We AFFIRM and enter a NEW GROUND OF REJECTION under 37 C.F.R. § 41.50(b). BACKGROUND Appellants’ invention is directed to a method for applying a coating to a component, such as a turbine blade or combustion chamber liner used in an engine through the use of a cold spray process. (Spec., para. [0011], [0012].) Claims 24-26 and 29 are illustrative: 24. A process for applying a coating to a component comprising the steps of: providing a component having at least one surface to be coated; said component providing step comprises providing a combustion chamber liner formed from a nickel-based alloy or a copper based alloy; depositing at least one layer of a powder coating material onto said at least one surface using a non-oxidizing carrier gas so that said powder coating material plastically deforms without melting and bonds to said at least one surface upon impact with said at least one surface; and said depositing step comprises feeding said powdered coating material to a spray nozzle at a feed rate of from 10 grams/min to 100 grams/min and depositing said at least one layer on at least one surface of said combustion chamber liner. 25. A process for applying a coating to a component comprising the steps of: providing a component having at least one surface to be coated; Appeal 2009-007618 Application 11/088,380 3 said component providing step comprises providing an engine component having an airfoil surface and a plurality of cooling holes in said surface; depositing at least one layer of a powder coating material onto said at least one surface using a non-oxidizing carrier gas so that said powder coating material plastically deforms without melting and bonds to said at least one surface upon impact with said at least one surface; said depositing step comprises depositing said at least one layer of powder coating material without bridging said cooling holes in said surface; and said depositing step further comprising feeding said powdered coating material to a spray nozzle at a feed rate of from 10 grams/min to 100 grams/min. 26. The process according to claim 24, wherein said combustion chamber liner is formed from a nickel-based alloy and said depositing step comprises depositing a copper based alloy material on said combustion chamber liner. 29. The process according to claim 25, wherein said depositing step comprises providing said powder coating material in particle form having a particle size no greater than 10 microns. The Examiner relies on the following prior art reference as evidence of unpatentability: Alkhimov US 5,302,414 April 12, 1994 Nakashima US 5,326,646 July 5, 1994 Holmes US 6,314,720 B1 Nov. 13, 2001 Beele US 6,365,013 B1 Apr. 2, 2002 Subramanian US 2002/0102360 A1 Aug. 1, 2002 Muehlberger US 6,759,085 B2 July 6, 2004 Raj US 6,838,191 B1 Jan. 4, 2005 Hu US 6,905,728 B1 June 14, 2005 U.S. Application 11/019,751 Dec. 21,2004 Appeal 2009-007618 Application 11/088,380 4 U.S. Application 11/019,871 (the ‘871 Application) Dec. 21, 2004 U.S. Application 11/020,799 Dec. 22, 2004 Appellants appeal the following rejections2: 1. Claims 3-19 and 21-48 under 35 U.S.C. § 103(a) as unpatentable over U.S. Application 11/019,871; 2. Claims 25, 29-34, 39-41, and 46-48 under 35 U.S.C. § 103(a) as unpatentable over Subramanian in view of Beele; 3. Claims 35-38 and 42-45 under 35 U.S.C. § 103(a) as unpatentable over Subramanian in view of Beele, and further in view of Muehlberger; 4. Claims 25, 29-34, 39-41, and 47 under 35 U.S.C. § 103(a) as unpatentable over Hu in view of Beele; 5. Claims 35-38 and 42-45 under 35 U.S.C. § 103(a) as unpatentable over Hu in view of Beele, further in view of Muehlberger; 6. Claims 3-8, 13-15, 21-24, and 27 under 35 U.S.C. § 103(a) as being unpatentable over Raj in view of Subramanian; 7. Claim 26 under 35 U.S.C. § 103(a) as being unpatentable over Raj in view of Subramanian, and further in view of Holmes; 8. Claims 9-12 and 16-19 under 35 U.S.C. § 103(a) as being unpatentable over Raj in view of Subramanian, further in view of Muehlberger; and 9. Claim 28 under 35 U.S.C. § 103(a) as being unpatentable over Raj in 2 The Examiner withdrew the obviousness type double patenting rejections and rejections under 35 U.S.C. § 103 of certain claims over Applications 10/671,683 and 11/003,140 due to the abandonment of both applications. (Ans. 4.) We also need not address the obviousness type double patenting rejections and rejections of certain claims under 35 U.S.C. § 103 over Applications 11/019,751 and 11/020,799, as both applications have been abandoned according to the USPTO PALM database. Appeal 2009-007618 Application 11/088,380 5 view of Subramanian, further in view of Nakashima. APPELLANTS’ CONTENTIONS Appellants contend that the ‘871 Application does not disclose a process of depositing a powder coating material to a combustion chamber liner or an airfoil surface as recited in independent claims 24 and 25. (App. Br. 37-38.) Appellants contend that the Examiner has failed to produce evidence of the aspects of the claims asserted to be well known by the Examiner. (App. Br. 38.) Appellants argue that neither Raj nor Subramanian discloses a combustion chamber liner. (App. Br. 43-44.) Appellants also contend that none of Subramanian, Beele, Hu, or Raj discloses the feed rate of the powdered coating material to a spray nozzle recited in the present claims. (App. Br. 39, 42, and 43.) Appellants argue that the Examiner’s position that the feed rate of the powder coating leaving the nozzle is the same as the feed rate of feeding the powdered coating material to the spray nozzle is pure speculation. (App. Br. 40.) Regarding claim 26, Appellants argue that there is no reason why one of ordinary skill in the art would replace Raj’s copper alloy with a nickel alloy, because Raj is directed to providing coatings for copper alloys. (App. Br. 45.) Appellants also contend that there is no disclosure in Holmes of forming a lining from a nickel based alloy and then depositing a copper based alloy over the nickel based alloy, such that Holmes teaches away from claim 26 by using a non-copper based coating. (App. Br. 46.) ISSUES Appeal 2009-007618 Application 11/088,380 6 The dispositive issues raised as a result of Appellants’ contentions are as follows: (1) Is there sufficient evidence on the record to support the Examiner’s position that applying the cold spray process disclosed in the ’871 Application to coat a chamber liner or an airfoil substrate would have been obvious to one of ordinary skill in the art? (2) Did the Examiner provide a sufficient rationale for determining that Subramanian, Beele, Hu, or Raj discloses the feed rate of the powdered coating material to a spray nozzle recited in the present claims? (3) Did the Examiner err in determining that the combination of Raj, Subramanian, and Holmes suggest a combustion chamber liner that is formed from a nickel-based alloy and a copper based alloy material deposited on the combustion chamber liner as recited in claim 26? PRINCIPLES OF LAW When the Patent Office’s position is based on logic and sound scientific principle, Appellants must specifically point out why the Patent Office’s position is unsound. In re Soli, 317 F.2d 941, 945-47 (CCPA 1963). In addition, the court in Soli noted that another reference of record, although not cited for showing that the use of controls was “standard procedure” in the field of bacteriology, supported the Office’s position. (Id. (FN 3)). Our reviewing court’s predecessor court has stated “Patent Office appellate tribunals, where it is found necessary, may take notice of facts beyond the record which, while not generally notorious, are capable of such instant and unquestionable demonstration as to defy dispute.” In re Ahlert, Appeal 2009-007618 Application 11/088,380 7 424 F.2d 1088, 1091 (CCPA 1970) (citing In re Knapp-Monarch Co., 296 F.2d 230 (1961). “With respect to core factual findings in a determination of patentability, however, the Board cannot simply reach conclusions based on its own understanding or experience — or on its assessment of what would be basic knowledge or common sense. Rather, the Board must point to some concrete evidence in the record in support of these findings.” In re Zurko, 258 F.3d 1379, 1386 (Fed. Cir. 2001). FACTUAL FINDINGS We adopt the Examiner’s findings in the Answer and Final Office Action as our own, except as to those findings that we expressly overturn or set aside in the Analysis that follows. We add the following factual findings (FF): 1. Appellants’ Specification states: “[t]he cold spray process for depositing powdered materials onto portions of a component which needs to be restored is advantageous in that it provides sufficient energy to accelerate particles to high enough velocities such that, upon impact, the particles plastically deform and bond to the surface of the component being restored or onto a previously deposited layer. The cold spray process allows the build up of a relative dense coating or structural deposit.” (Spec. para. [0012].) 2. Appellants’ Specification discloses “another advantage is that with cold spray, it is possible to spray over a blade/vane surface and not have the coating bridge the cooling holes in the surface. The ability to apply a coating in a repair/refurbish operation and not have to go back and clean out the holes, or at least greatly reduce Appeal 2009-007618 Application 11/088,380 8 the labor required to do this is a great advantage over current operations.” (Spec. para. [0034].) 3. The ‘871 Application discloses that “the cold spray process may be used during the repair of turbine engine components.” (Para. [0010].) 4. The ‘871 Application discloses that a benefit of using cold spray over prior art techniques such as plasma spray is to prevent negatively impacting the properties of the underlying material. (Para. [0002], [0004].) 5. The ‘871 Application discloses that the particle size of the powder coating is between 5 and 50 microns and that providing a narrow particle size distribution contributes to uniform particle velocity. (Para. [0013].) 6. Subramanian discloses that it is known to provide an intermediate metallic bond coat to a combustion turbine environment. (Para. [0003].) 7. Subramanian discloses that a cold spray process may be beneficial for application of a metallic bond coat. (Para. [0021].) 8. Subramanian discloses that the components of a gas turbine engine “may include, for example, rotating blades, stationary vanes, combustor baskets, ring segments, transitions, etc.” (Para. [0021].) 9. Subramanian discloses that in the cold spray deposition step, particles of coating material of from 0.1 to 50 microns in size are deposited on a target surface at a feed rate of 0.1 to 2 grams per second. (Para. [0023].) Appeal 2009-007618 Application 11/088,380 9 10. Beele discloses a coating process for a turbine blade with cooling holes that avoids blocking or unacceptable narrowing of the cooling holes. (Col. 1, ll. 10-21.) 11. Beele discloses that to prevent blocking the cooling holes, a fluid is applied through the cooling holes during the coating process. (Col. 1, ll. 34-40; col. 2, l. 67 – col. 3, l. 4.) 12. Hu discloses that high pressure turbine components including airfoils may be repaired using cold gas-dynamic spray. (Col. 2, ll. 6-20; col. 4, l. 15.) 13. Hu discloses that the density of mass flow rate of the particles of 0.05 and 17 g/s-cm2. (Col. 6, ll. 41-45.) 14. Raj discloses depositing bond coats on copper alloy combustor liners, where the coating may be applied by cold spraying. (Col. 1, ll. 24-46; col. 2, ll. 41-52.) 15. Raj discloses that a bond coating material is applied between the substrate and the top protective coating, where the bond coating material includes Cu-Cr alloys that are applied by directly spraying the powder on the substrate. (Col. 5, ll. 17-31.) 16. Holmes discloses protective coatings applied to the lining of combustion chambers, where the lining materials include copper and nickel-based alloys. (Col. 2, ll. 41-52.) ANALYSIS Appellants have argued certain dependent claims subject to each ground of rejection separately. However, for many of the dependent claims, Appellants have done no more than point out what the claims recite, which Appeal 2009-007618 Application 11/088,380 10 are not considered arguments for separate patentability for those claims. See 37 C.F.R. § 41.37(c)(1)(vii). Accordingly, we confine our discussion to appealed claims 24-26, which contain claim limitations representative of the arguments made by Appellants, and address other claims only to the extent that Appellants have argued them separately pursuant to 37 C.F.R. § 41.37(c)(1)(vii).3 Issue 1 Rejection 1 While we agree with Appellants that the Examiner failed to point to where the ‘871 Application discloses depositing a powder coating material to a combustion chamber liner formed from a nickel based or copper based material, or to an airfoil surface without bridging the cooling holes present in the airfoil surface, we also note that Appellants have not pointed out the errors in the Examiner’s statements that the aspects of the claims not disclosed in the ‘871 Application are well-known. (See Ans. 47-48.) Specifically, the Examiner stated that applying a powder coating material via a cold spray process to such substrates was well known in the art. (Ans. 12.) Our reviewing court has warned that basic knowledge cannot be relied on for core factual determinations in a determining of patentability without concrete evidence. Zurko, 258 F.3d at 1386. However, in the present case there is ample evidence on the record to support the Examiner’s position. Not only does the ‘871 Application disclose that a cold spray process may be used to repair gas turbine engine components, but Raj and Hu expressly 3 Only those arguments actually made by Appellants have been considered in this decision. Arguments which Appellants could have made but chose not to make have not been considered and are deemed to be waived. See 37 C.F.R. § 41.37(c)(1)(vii) (2009). Appeal 2009-007618 Application 11/088,380 11 disclose that cold spray may be used for coating or repairing combustion chamber liners and airfoils, respectively. (FF 12, 14.) In addition, Beele also evidences that it is well known to coat an airfoil substrate without blocking the airfoil holes. (FF 11.) Further, Appellants have not addressed the Examiner’s rationale that it would have been obvious to use a cold spraying process to the specific well –known substrates of turbine engines in order to impart the advantages of applying particles with plastic deformation and without melting. Regarding claims 3 and 4, as pointed out by the Examiner, the particle sizes recited in the claims overlap or lie within the particle sizes disclosed by the ‘871 Application. (Ans. 48; FF 5.) Moreover, contrary to Appellants’ argument, the ‘871 Application appears to recognize the same benefits to the particle sizes as disclosed in Appellants’ Specification. (FF 5.) Therefore, we affirm the Examiner’s rejection of the claims as being obvious over the ‘871 Application, but because our rationale includes reference to Raj, Hu, and Beele, we designate our affirmance of this rejection as a new ground of rejection. Issue 2 Rejections 2 and 3 We are unconvinced by Appellants’ argument that Subramanian discloses the feed rate of the material leaving the nozzle rather than the recited feed rate to the nozzle, and consequently Subramanian does not provide a basis for one skilled in the art to have optimized the feed rate into Appeal 2009-007618 Application 11/088,380 12 the nozzle. As stated by the Examiner, Subramanian does not specify whether the disclosed feed rate is the feed rate of the material as it enters the nozzle or the feed rate of the material as it leaves the nozzle. (Ans. 51.) The Examiner’s position is that Alkhimov, incorporated by reference into Subramanian, provides evidence that the mass flow rate of particles, which is related to mass feed rate, is a result effective variable. (Ans. 52-53.) Thus, contrary to Appellants’ argument, the Examiner’s position that the flow rate is a result effective variable is not mere speculation, but based on the specific teachings of the prior art. Accordingly, Appellants’ arguments are not persuasive. Regarding claims 29 and 30, Subramanian discloses particle sizes of between 0.1 to 50 microns, which overlap the ranges recited in claims 29 and 30. (FF 9.) Appellants argue that neither Subramanian nor Beele recognize the significance to keeping the particles size within this range in order to increase particle size velocities. (App. Br. 40-41.) However, we agree with the Examiner that Appellants have not established any showing of unexpected benefits of increased particle size velocity. Therefore, Appellants have not overcome the Examiner’s prima facie case of obviousness. Rejections 4 and 5 We are not persuaded by Appellants’ argument that because Hu is directed to repairing components, Hu does not teach coating processes. We agree with the Examiner that Appellants have provided no persuasive evidence to support the position that repairing and coating are mutually exclusive. (Ans. 55-56.) Moreover, Appellants’ Specification states that the Appeal 2009-007618 Application 11/088,380 13 cold spray process is for restoring or repairing components. (FF 1.) Accordingly, we are not convinced by Appellants’ argument. Appellant also argues that the feed rate cannot be optimized as recited in the present claims because Hu does not disclose the feed rate of the particle coating material in the nozzle. However, Appellants have not addressed the Examiner’s rationale that the mass flow rate density provides evidence that the recited feed rate is a result effective variable. (Ans. 19- 20.) Therefore, we affirm the Examiner’s rejection over Hu in view of Beele. Rejections 6, 8, and 9 Raj expressly discloses that the bond coatings on the combustion chamber liners may be applied by cold spraying. (FF 14.) Therefore, Appellants’ argument that Raj does not disclose cold spray processes fails to consider the teachings of Raj as a whole. As discussed above, Subramanian provides evidence that the feed rate is a result effective variable. Thus, Appellants’ arguments are not persuasive. Issue 3 Rejection 7 We are also unconvinced by Appellants’ argument that the claim 26 would not have been obvious to one of ordinary skill in the art in view of Raj in view of Subramanian and Holmes. Appellants admit that Holmes discloses that the combustion chamber liner may either be copper or nickel based alloy. (App. Br. 46; FF 16.) Contrary to Appellants’ argument, Raj discloses the use of copper alloys as bond coatings on the liner substrate. (FF 15.) Accordingly, we agree with the Examiner, that it would have been Appeal 2009-007618 Application 11/088,380 14 obvious to coat a nickel alloy combustion chamber liner with a copper alloy using a cold spray process. DECISION We affirm the Examiner’s § 103 rejections of claims 3-19 and 21-48. However, we designate our affirmance of the Examiner’s rejection of claims 3-19 and 21-48 over the ‘871 Application as a new ground of rejection. This decision contains a new ground of rejection pursuant to 37 C.F.R. § 41.50(b). 37 C.F.R. § 41.50(b) also provides that the Appellants, WITHIN TWO MONTHS FROM THE DATE OF THE DECISION, must exercise one of the following two options with respect to the new ground of rejection to avoid termination of the appeal as to the rejected claims: (1) Reopen prosecution. Submit an appropriate amendment of the claims so rejected or new evidence relating to the claims so rejected, or both, and have the matter reconsidered by the Examiner, in which event the proceeding will be remanded to the Examiner . . . . (2) Request rehearing. Request that the proceeding be reheard under § 41.52 by the Board upon the same record . . . . TIME PERIOD No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a). See 37 C.F.R. § 1.136(a)(1) (2009). ORDER AFFIRMED NEW GROUND OF REJECTION (37 C.F.R. §41.50(b)) Appeal 2009-007618 Application 11/088,380 15 rvb BACHMAN & LAPOINTE, P.C. (P&W) 900 CHAPEL STREET SUITE 1201 NEW HAVEN, CT 06510-2802 Copy with citationCopy as parenthetical citation