Ex Parte Conant et alDownload PDFPatent Trial and Appeal BoardJan 19, 201813315058 (P.T.A.B. Jan. 19, 2018) Copy Citation United States Patent and Trademark Office UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O.Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 13/315,058 12/08/2011 Travis Conant 30208-US-NP 2478 102091 7590 01/23/2018 Cantor Colburn LLP - SABIC Americas 20 Church Street Hartford, CT 06103 EXAMINER FADHEL, ALI Z ART UNIT PAPER NUMBER 1772 NOTIFICATION DATE DELIVERY MODE 01/23/2018 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): usptopatentmail@cantorcolbum.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte TRAVIS CONANT and SCOTT A. STEVENSON Appeal 2017-006132 Application 13/315,058 Technology Center 1700 Before JEFFREY T. SMITH, AVELYN M. ROSS, and JEFFREY R. SNAY, Administrative Patent Judges. SNAY, Administrative Patent Judge. DECISION ON APPEAL1 Appellants2 appeal under 35 U.S.C. § 134(a) from the Examiner’s decision rejecting claims 1, 3—19, 21—23, and 26—29. We have jurisdiction under 35 U.S.C. § 6(b). We affirm. 1 We cite to the Specification (“Spec.”) filed December 8, 2011; Final Office Action (“Final Act.”) dated May 5, 2016; Appellants’ Appeal Brief (“App. Br.”) dated October 28, 2016; Examiner’s Answer (“Ans.”) dated January 3, 2017, and Appellants’ Reply Brief (“Reply Br.”) dated March 3, 2017. 2 Appellants identify Saudi Basic Industries Corporation as the real party in interest. App. Br. 2. Appeal 2017-006132 Application 13/315,058 BACKGROUND The subject matter on appeal relates to olefin metathesis. Spec. 11—3. An example metathesis reaction involves transformation of 1-butene and 2- butene to produce propylene and 2-pentene. Id. 13. Appellants state in the Specification that propylene productivity is increased by operating the metathesis reaction under mixed-phase conditions. Id. 140. Undesired reaction products are separated from the effluent and recycled to the reactor for continued processing. Id. 149. Claim 1—the sole independent claim on appeal—reads: 1. A method for olefin metathesis comprising: contacting an olefin feed stream with a metathesis catalyst in a metathesis reactor to form an olefin reaction mixture, wherein the contacting is at a reaction temperature and at a reaction pressure of 40 psig to 90 psig to maintain the olefin reaction mixture in a mixed-phase condition including components in the liquid phase and components in the gas phase to produce an olefin effluent stream; recovering an olefin product from the olefin effluent stream; fractionating the olefin effluent stream to form a plurality of fraction streams; and, recycling at least a portion of at least one of the plurality of fraction streams to the metathesis reactor; wherein the step of recovering an olefin product from the olefin effluent stream comprises recovering an olefin product from at least a portion of at least one of the plurality of fraction streams. App. Br. 11 (Claims Appendix). 2 Appeal 2017-006132 Application 13/315,058 REJECTIONS The Examiner maintains the following grounds of rejection:3 I. Claims 1,3,5, 8—17, 21—23, and 26—29 stand rejected under 35 U.S.C. § 103(a) as unpatentable over Jung4 and Leyshon.5 II. Claim 4 stands rejected under 35 U.S.C. § 103(a) as unpatentable over Jung, Leyshon, and Myers.6 III. Claims 6, 7, 18, and 19 stand rejected under 35 U.S.C. § 103(a) as unpatentable over Jung, Leyshon, and Doherty.7 OPINION Rejection I With regard to Rejection I, Appellants argue the claims as a group and present separate, additional arguments regarding each of claims 17 and 27— 29. App. Br. 4—9. In accordance with 37 C.F.R. § 41.37(c)(l)(iv), we select claim 1 as representative and decide the appeal based on the representative claim. Separately argued claims 17 and 27—29 are separately addressed. Claim 1 The Examiner finds that Jung discloses a process for metathesis of butenes using a metathesis catalyst in a distillation reactor. Final Act. 8. Jung states that butenes may be converted by metathesis to yield 3 Final Act. 7—23; Ans. 2—17. 4 US 4,709,115, issued November 24, 1987 (“Jung”). 5 US 2008/0146856 Al, published June 19, 2008 (“Leyshon”). 6 US 4,151,071, issued April 24, 1979 (“Myers”). 7 M.F. Doherty, et al., “Distillation,” Perry’s Chemical Engineer’s Handbook, J. Wiley & Sons, D. W. Perry and R. H. Green, eds., 8th ed., 2008. 3 Appeal 2017-006132 Application 13/315,058 propylene—a desired product. Jung 3:1—8, 13—16. The Examiner finds that Jung’s reactive distillation process involves a mixed phase reaction mixture. Final Act. 9. The Examiner also finds that Jung teaches a reactor pressure in the range of 0—1,000 psig, and states a pressure of 80 psig in one of the disclosed examples. Id. at 8. In light of these findings, the Examiner determines that Jung teaches or suggests a process that includes all of the steps recited in claim 1, except that Jung does not teach fractionation of the effluent product stream and recycling a fractionated part back to the reactor. Id. at 9. In that regard, the Examiner finds that Leyshon teaches that propylene production in a metathesis reaction process may be increased by fractionating the effluent and recycling ethylene by-product along with unreacted butenes to the reactor. Id. at 10-11. Appellants do not dispute the foregoing findings. Appellants argue that the Examiner fails to provide a reason for combining the teachings of Leyshon with Jung. App. Br. 5. Appellants also argue that, because Leyshon uses a significantly higher reactor pressure, “[o]ne skilled in the art simply would not combine Jung and Leyshon.” Id. at 7. These arguments are not persuasive of error. As the Examiner explains, “the motivation of fractionating the effluent from the contacting step is to recover unreacted starting material (butene) and by-product ethylene and to recycle these recovered streams . . . to make more of the desired product propylene.” Ans. 18. Appellants fail to explain why Leyshon’s selection of a different reactor pressure negates applying Leyshon’s teaching of effluent fractionation and recycling to predictably improve production in Jung’s process. See KSR Int 7 Co. v. Teleflex Inc., 550 U.S. 398, 416 (2007) (“The combination of familiar elements according 4 Appeal 2017-006132 Application 13/315,058 to known methods is likely to be obvious when it does no more than yield predictable results.”). Appellants additionally argue that the claimed method does not require reactive distillation to conduct olefin metathesis. App. Br. 8. In response, the Examiner explains that Jung’s use of a distillation column reactor for metathesis serves as an example of the claimed use of a metathesis reactor in a mixed-phase condition. Ans. 21. Appellants do not contest the Examiner’s reasoning in their Reply Brief. Nor do Appellants point to any recitation in claim 1 that precludes reactive distillation. As such, Appellants’ argument in this regard is unpersuasive. For the foregoing reasons, we sustain Rejection I as applied to claim 1. The Rejection as applied to each of claims 3, 5, 8—16, 21—23, and 26, which Appellants’ do not separately argue, also is sustained. Claims 17 and 27—29 Appellants additionally argue that the method recited in claims 17 and 27—29 involves an overall reaction of C4->C3, C6, whereas Jung’s overall reaction is C4->C2, C3, C5, C6 and unreacted C4 and Leyshon’s overall reaction is C2+C4->C2, C3, C5, and C6. App. Br. 9. However, as the Examiner correctly observes (Ans. 22—23), Appellants’ argument is not commensurate with what is recited in the claims. Claim 17 requires that the starting olefin stream includes butenes (C4), which Jung admittedly satisfies. Claim 27 requires that the olefin product comprises any one of ethylene (C2), propylene (C3), pentene (C5), hexene (C6), unreacted butene, or a combination thereof. Appellants acknowledge that Jung’s effluent contains each of these components. App. Br. 9. Claim 28 depends from claim 27 and requires that at least one of the listed components is fractionated and 5 Appeal 2017-006132 Application 13/315,058 recycled. That recitation is met by the undisputed teaching in Leyshon of separating and recycling ethylene and unreacted butene. Claim 29 requires that the olefin product is propylene, hexene, or a combination thereof, which Jung admittedly satisfies. Appellants fail to persuade us that any of claims 17 and 27—29 requires an overall reaction that is not met by Jung or the combined teachings of Jung and Leyshon. Accordingly, Rejection I as applied to these claims also is sustained. Rejections II and III Appellants seek reversal of Rejections II and III based solely on the same arguments presented against Rejection I. App. Br. 10. Because we find those arguments unpersuasive, Rejections II and III are sustained for the above-stated reasons. DECISION The Examiner’s decision rejection claims 1, 3—19, 21—23, and 26—29 is affirmed. No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a). AFFIRMED 6 Copy with citationCopy as parenthetical citation