Ex Parte Collins et alDownload PDFPatent Trial and Appeal BoardSep 28, 201713869409 (P.T.A.B. Sep. 28, 2017) Copy Citation United States Patent and Trademark Office UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O.Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. CELAY.00758 7201 EXAMINER THAKUR, VIREN A ART UNIT PAPER NUMBER 1792 MAIL DATE DELIVERY MODE 13/869,409 04/24/2013 110933 7590 Carstens & Cahoon, LLP PO Box 802334 Dallas, TX 75380 09/28/2017 Ellis COLLINS 09/28/2017 PAPER Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte ELLIS COLLINS, VINCENT ALLEN ELDER, DAVID BRIAN EMERSON, TERRY MOROS, and RAYFORD THOMAS SMITH Appeal 2016-006570 Application 13/869,409 Technology Center 1700 Before CHUNG K. PAK, JENNIFER R. GUPTA, and MERRELL C. CASHION, JR., Administrative Patent Judges. GUPTA, Administrative Patent Judge. DECISION ON APPEAL1 Appellant2 appeals under 35 U.S.C. § 134(a) from the Examiner’s final decision rejecting claims 1—6. We have jurisdiction under 35 U.S.C. § 6(b). We affirm. 1 In this decision, we refer to Appellant’s Specification filed April 24, 2013 (“Spec.”), the Final Office Action mailed August 12, 2015 (“Final Act.”), the Appeal Brief filed October 14, 2015 (“Appeal Br.”), the Examiner’s Answer mailed April 19, 2016 (“Ans.”), and the Reply Brief filed June 17, 2016 (“Reply Br.”). 2 Appellant is the Applicant, which, according to the Appeal Brief, is Frito- Lay North America, Inc. Appeal Br. 2. Appeal 2016-006570 Application 13/869,409 The subject matter on appeal relates to a method for reducing acrylamide formation in the production of molasses. Spec. 12. According to the Specification, acrylamide has especially been found primarily in carbohydrate food products that have been heated or processed at high temperatures and, while not detrimental to humans, its presence in food products is especially undesirable at elevated levels. Id. at || 4—5. The claimed invention reduces the presence of acrylamide in molasses by controlling the pH of the molasses prior to heating to a temperature above about 120°C. Id. at 17. Claim 1, reproduced below from the Claims Appendix of the Appeal Brief, is illustrative of the claims on appeal. 1. A method of reducing acrylamide formation during heat treatment of molasses, said method comprising the steps of: adding a food grade acid to said molasses until said molasses comprises a pH between 4.0 and 5.0; and heating said molasses after said adding step to a temperature above about 120°C. Appeal Br. 22 (Claims Appendix). REJECTIONS Rejection 1: Claims 1, 2 and 6 stand rejected under pre-AIA 35 U.S.C. § 103(a) as unpatentable over Zenzes (US 2,435,248, issued February 3, 1948) (“Zenzes”) in view of William McGlynn, The Importance of Food pH in Commercial Canning Operations, Food and Agricultural Products Research and Technology Center Oklahoma State University, https://web.archive.Org/web/20051217050318/http://pods.dasnr.okstate.edu/ docushare/dsweb/Get/Document-962/FAPC-l 18web.pdf (“Food Tech Fact Sheet”) (Final Act. 2-4); 2 Appeal 2016-006570 Application 13/869,409 Rejection 2: Claims 3—6 stand rejected under pre-AIA 35 U.S.C. § 103(a) as unpatentable over Zenzes in further view of Sterling K. Long, et al., Florida Citrus Molasses as a Fermentation Substrate, 15 Applied Microbiology 1091—1094 (© 1967 American Society for Microbiology) (“Long”), Sabina Maza Gomez, Rum Aroma Descriptive Analysis, The Department of Food Science at Louisiana State University, i—145 (2002) (“Gomez”), C.G.A. Davies et al., The Maillard Reaction Application to Confectionery Products, Department of Food Science and Nutrition University of Minnesota, 1—33 (1997) (“Davies”), Donald S. Mottram et al., Acrylamide is formed in the Maillard Reaction, 419 Nature Magazine 448— 449 (2002), http://www.nature.com/nature/joumal/v419/n6906/full/419448a.html (“Mottram”), Kim et al., Reducing Acrylamide in Fried Snack Products by Adding Amino Acids, 70 J. of Food Science C354—358 (© 2005 Institute of Food Technologists) (“Kim”), and Elder (US 2005/0118322 Al, published June 2, 2005) (“Elder”) (Final Act. U-6); Rejection 3: Claim 2 stands rejected under pre-AIA 35 U.S.C. § 103(a) as unpatentable over Zenzes in view Long, Gomez, Davies, Mottram, Kim, and Elder, and further in view of M.Y. Jung et al., A Novel Technique for Limitation of Acrylamide Formation in Fried and Baked Corn Chips and in French Fries, 68 J. of Food Science 1287—1290 (© 2003 Institute of Food Technologies) (“Jung”), and Per Rydberg et al., Investigations of Factors that Influence the Acrylamide Content of Heated Foodstuffs, 51 J. of Agricultural and Food Chemistry 7012—7018 (© 2003 American Chemical Society) (“Rydberg”) (Final Act. 6—7); 3 Appeal 2016-006570 Application 13/869,409 Rejection 4: Claims 1—6 stand rejected under pre-AIA 35 U.S.C. § 103(a) as unpatentable over Musher (US 2,282,785, issued May 12, 1942) (“Musher”) in view of Jung, Rydberg, Long, Gomez, Davies, Panhorst (US 2003/0077362 Al, published April 24, 2003) (“Panhorst”), Mottram, Kim, and Elder (Final Act. 7—11); and Rejection 5: Claims 1—6 stand rejected under pre-AIA 35 U.S.C. § 103(a) as unpatentable over in view of Davies in view of Panhorst, Jung, Rydberg, Long, Gomez, Mottram, Kim, and Elder (Final Act. 11—14). DISCUSSION Upon consideration of the evidence on this record and each of Appellant’s contentions, we find that the preponderance of evidence supports the Examiner’s conclusion that the subject matter of Appellant’s claims is unpatentable over the applied prior art. We sustain the Examiner’s §103 rejections essentially for the reasons set out by the Examiner in the Final Action and Answer. We add the following. Rejection 1 Appellant argues the claims subject to the first ground of rejection in three separate groups: (1) claim 1 (Group I), (2) claim 2 (Group II), and claim 6 (Group III). Appeal Br. 6—12. Accordingly, we limit our discussion to these groups of claims. Zenzes discloses a process for producing maple flavored sugar and table syrup as well as jellies having new and novel flavor characteristics. Zenzes 1:1—6. The Examiner finds that Zenzes teaches reacting a sugar composition containing original and refined non-sugar impurities (e.g., molasses) with an acid until the composition has a pH of 4.7 to 5.8 before 4 Appeal 2016-006570 Application 13/869,409 heating the sugar composition to a temperature greater than 240° F. Final Act. 2—3 (citing Zenzes 2:13—16, 8:9—21). The Examiner relies on Food Tech Fact Sheet for teaching that molasses has a pH of 5—5.5. Final Act. 3; Food Tech Fact Sheet 118—7. Group I: Claim 1 Appellant argues that column 8, lines 9 through 14 of Zenzes does not teach adding a food grade acid to molasses until the molasses comprises a pH between 4.0 and 5.0. Appeal Br. 8. In addition, Appellant argues that Zenzes does not specifically teach reducing acrylamide in any foodstuffs, let alone in molasses particularly. Id. at 6. Appellant also argues that, to arrive at the claimed method, one of ordinary skill in the art would need to choose to treat molasses instead of original non-sugar impurities, to use a temperature of around 5 -C higher than the disclosed temperature, to acidify molasses to a pH of 4.0 to 5.0, and acidity before, rather than during, heat treatment. Id. at 8. According to Appellant, it is only through impermissible hindsight knowledge of the present invention that the Examiner can choose and combine the various individual features to arrive at the method recited in claim 1. Id. at 11. Further, Appellant argues that there is no reasonable expectation that the skilled person would make all the various feature choices noted above because the skilled artisan could not have reasonably predicted such combination of the noted feature choices would have any influence at all on the formation of acrylamide. Id. at 9. Appellant’s arguments are not persuasive of reversible error. The Examiner has not resorted to hindsight knowledge to choose and combine various disclosures of Zenzes. Rather, the Examiner relies on the teachings and suggestions of the Zenzes reference itself. As noted above, Zenzes 5 Appeal 2016-006570 Application 13/869,409 teaches a sugar composition containing refined non-sugar impurities (e.g., molasses) that may be acid reacted to a pH of 4.7 to 5.8 before heating to a temperature in excess of 240 -F (about 116 -C). Final Act. 2—3; Zenzes 2:13—16, 8:9—21. Based on this, the Examiner determines that, because Zenzes teaches acidifying molasses to a pH range that overlaps the recited pH range and teaches subsequently heating molasses to a temperature that encompasses the recited temperature range, there is a reasonable basis for one skilled in the art to expect the acid treatment and heating temperatures of the method of Zenzes to reduce the formation of acrylamide expected to otherwise form during heat treatment of the molasses absent the acid treatment. Final Act.3; Ans. 5; Zenzes 8:9—21. Appellant has not adequately explained why the combined acid treatment and heating step of Zenzes would not have resulted in reducing the formation of acrylamide as claimed. Appellant additionally argues that the data provided in Table 4 at page 13 of their Specification demonstrates the criticality of the recited pH range. Appeal Br. 13. We have reviewed Appellant’s data but do not find them persuasive. Table 4 of Appellant’s Specification compares the acrylamide concentration of two molasses samples heated to a temperature above 120 -C—a sample treated with citric acid and asparaginase (treated sample), and a sample that was not treated with an acid or enzyme (untreated sample). Spec. 13 (133). As Appellant’s claim 1 does not require adding asparaginase, the treated sample in Appellant’s Table 4 is not commensurate in scope with the claims. In addition, Appellant has not provided a comparison with Zenzes, the closest prior art, which teaches treating molasses with acid prior to heating. 6 Appeal 2016-006570 Application 13/869,409 Although the results in Table 4 demonstrate that the treated sample had less acrylamide formation than the untreated sample (Spec. 13 (134), Appellant does not provide sufficient evidence to support the assertion that the reduction would have been unexpected. See In re Geisler, 116 F.3d 1465, 1470-71 (Fed. Cir. 1997) (reiterating that unexpected results must be established by factual evidence and that an attorney’s statement is insufficient to establish unexpected results). Group II: Claim 2 Claim 2 depends from claim 1, and requires that the pH after adding food grade acid to the molasses “is between 4.3 and 4.7.” Appellant argues that Zenzes prefers acidifying molasses to a pH of 4.9 to 5.1 (Zenzes 7:75), and thus teaches away from the subject matter recited in claim 2. Appeal Br. 11—12. “[T]he fact that a specific [embodiment] is taught to be preferred is not controlling, since all disclosures of the prior art, including unpreferred embodiments, must be considered.” Merck & Co. v. Biocraft Labs., Inc., 874 F.2d 804, 807 (Fed. Cir. 1989). Although Zenzes teaches that it is preferred to acidify molasses to a pH between 4.9 and 5.1, Zenzes also teaches acidifying molasses to a pH between 4.7 and 5.8 before the composition is subjected to high temperature treatments. Zenzes 7:69—74, 10:44—66. Appellant directs us to no portion of Zenzes that supports Appellant’s assertion that the preference to acidify molasses to a pH between 4.9 and 5.1 necessarily limits Zenzes’ broader disclosure noted above. Thus, Appellant’s argument is not persuasive of reversible error in the rejection of claim 2. 7 Appeal 2016-006570 Application 13/869,409 Group III: Claim 6 Claim 6 recites “A food product coating comprising molasses made according to the method of claim 1.” Appellant argues that Zenzes teaches a method of preparing a sugar composition, but does not specifically mention a food product coating which includes molasses. Appeal Br. 12. Appellant’s argument is not persuasive of reversible error. Zenzes teaches that its method produces maple flavored sugar compositions and table syrup as well as jellies having new and novel flavor characteristics, all of which could be used as a food product coating. Zenzes 1:1—6. Accordingly, we affirm the Examiner’s rejection of claims 1, 2, and 6 under pre-AIA 35 U.S.C. § 103(a) as unpatentable over Zenzes for the reasons set out by the Examiner and given above. Rejection 2 Appellant argues the claims subject to the second ground of rejection in three separate groups: (1) claim 3 (Group IV), (2) claim 6 (Group V), and claim 4—5 (Group VI). Appeal Br. 12—13. Accordingly, we limit our discussion to these groups of claims. We refer to the Examiner’s Final Action for a statement of the rejection. Final Act. 4—6. Group IV: Claim 3 Claim 3 depends from claim 1 and further requires “adding asparaginase or lysine to said molasses” after the food grade acid is added. Appellant argues that none of the references relied upon by the Examiner disclose that asparaginase or lysine is added after the addition of food grade acid. Appeal Br. 13. 8 Appeal 2016-006570 Application 13/869,409 We find this argument unavailing. As the Examiner notes, Elder teaches that acrylamide is formed from the presence of amino acids, for example asparagine, and reducing sugars. Final Act. 4; Ans. 10; Elder 17. Further, Elder teaches that adding asparaginase and lysine prior to heating reduces the formation of acrylamide in fabricated food products. Elder 36, 72, 130; Final Act. 4—5; Ans. 10. Elder also teaches using a combination of acrylamide-reducing agents (e.g., citric acid, asparaginase, and lysine) to achieve increasingly lower levels of acrylamide in foods. Elder 11 107, 125, 153; Final Act. 5. Thus, Elder’s disclosure would suggest to one skilled in the art to add the asparaginase and lysine before or after addition of the food grade acid. Appellant’s argument does not address these teachings by Elder in the rejection presented by the Examiner. Group V: Claim 6 Appellant’s argument that none of the references relied upon by the Examiner mention a food coating comprising molasses made according to the method claim 1 is not persuasive. As discussed above with regard to Rejection 1, Zenzes teaches that its method produces maple flavored sugar compositions and table syrup as well as jellies having new and novel flavor characteristics all of which could be used as a food product coating. Zenzes 1:1—6. Group VI: Claims 4—5 Claim 4 indirectly depends from claim 1 and requires adding asparaginase to the molasses after the addition of the food grade acid. Claim 5 indirectly depends from claim 1 and requires adding asparaginase and lysine to the molasses after the addition of the food grade acid. 9 Appeal 2016-006570 Application 13/869,409 Appellant argues that the Examiner has not properly considered the data provided in Table 5 at page 14 of their Specification. Appeal Br. 13. According to Appellant, the data demonstrate that the order in which citric acid and enzyme are added is critical to maximize the reduction of acrylamide in molasses. Id. Appellant contends that the reduction is “unexpected.” Id. Appellant’s arguments are not well-taken. The Examiner has considered the data in Table 5 of Appellant’s Specification but does not find them persuasive in demonstrating non-obviousness of the claimed subject matter because, as well stated by the Examiner, the data shows that acrylamide formation was reduced when citric acid is added before or after the enzyme when compared to the control. Ans. 12. Although Appellant’s Specification states that adding citric acid before asparaginase is more “efficient” in reducing acrylamide as compared with adding asparaginase enzyme before citric acid or adding citric acid alone (Spec. 136), the evidence in the record is insufficient to show that the order of addition for the citric acid and the enzyme is critical or produces an unexpected result. In re Burhans, 154 F.2d 690, 692 (CCPA 1946) (where a combination of prior art suggests the claimed process, reordering the steps is not patentable absent proof in the record that the order of performing the steps produces a new and unexpected result.). Accordingly, we affirm the Examiner’s prior art rejection of claims 3— 6 for the reasons set out by the Examiner and given above. Rejection 3 Appellant’s argument that Zenzes’ teaching at column 9, lines 57 through 64 of further acidifying its maple flavored product, which includes 10 Appeal 2016-006570 Application 13/869,409 molasses, to a pH of between 2.8 and 3.5 teaches away from acidifying molasses to a pH of “between 4.3 and 4.7,” as recited in claim 2 is not persuasive. “The prior art’s mere disclosure of more than one alternative does not constitute a teaching away from any of these alternatives because such disclosure does not criticize, discredit, or otherwise discourage the solution claimed in the . . . application.” In re Fulton, 391 F.3d 1195, 1201 (Fed. Cir. 2004). At column 9, lines 57—60, Zenzes teaches that its maple flavored product is acidified to a pH of between 4.7 and 5.8. Appellant directs us to no portion of Zenzes that supports Appellant’s assertion that the preference for a maple syrup having a pH between 2.8 and 3.5 necessarily limits Zenzes’ broader disclosure noted above. Accordingly, we affirm the Examiner’s prior art rejection of claim 2 for the reasons set out by the Examiner and given above. Rejection 4 Appellant argues the claims subject to the fourth ground of rejection in two separate groups: (1) claims 1, 2, and 6 (Group VIII), and (2) claims 3—5 (Group IX). Appeal Br. 16—18. Accordingly, we limit our discussion to these groups of claims. We refer to the Examiner’s Final Action for a statement of the rejection. Final Act. 7—11. Group VIII: Claims 1, 2, and 6 Appellant argues that Musher does not teach that the pH range and temperature values used in its process are for reducing acrylamide formation during heat treatment of molasses. Appeal Br. 17. 11 Appeal 2016-006570 Application 13/869,409 Appellant’s argument is not persuasive of reversible error. The Examiner finds, and Appellant does not dispute, that Musher teaches adding acid to molasses to adjust the pH to 4 to 6.9, and then heating molasses to temperatures greater than about 200 -F. Final Act. 8 (citing Musher 1, 11. 29-38 (left col.), 11. 18—29 (right col.)). The Examiner also finds, and Appellant does not dispute, that Musher discloses that its finished product containing molasses may be used for baking purposes and in the manufacture of confectionary products. Final Act. 8 (citing Musher 1, 11. 36-40 (right col.)). Given that Musher’s product is used in food products, the Examiner determines that it would have been obvious to one having ordinary skill in the art to use a food grade acid in Musher’s process. Concerning acrylamide formation, the Examiner also determines that, because Musher teaches acidifying molasses to a pH range that overlaps the recited pH range and teaches subsequently heating molasses to a temperature that encompasses the recited temperature range, there is a reasonable basis for one of ordinary skill in the art to reasonably expect that Musher’s process would reduce the formation of acrylamide expected to otherwise form during heat treatment of the molasses absent the addition of the food grade acid. Ans. 16. On this record, Appellant has not adequately explained why the combined acid treatment and heating step of Musher would not have resulted in reducing the formation of acrylamide as claimed. Group IX: Claims 3—5 Claims 3—5 directly or indirectly depend from claim 1 and require that asparaginase and/or lysine is added to molasses after adding the food grade acid. 12 Appeal 2016-006570 Application 13/869,409 Appellant argues that none of the references explain or suggest that asparaginase or lysine should be added after the food grade acid and before heating. Appeal Br. 18. Additionally, Appellant argues that the data in their application demonstrate that adding asparaginase enzyme after adding the food grade acid provides an unexpected improvement as compared with adding the asparaginase enzyme before adding the food grade acid. Id. As with Rejection 2, the Examiner relies on Elder as teaching that adding asparaginase and lysine prior to heating reduces the formation of acrylamide in fabricated food products. Final Act. 9; Ans. 10; Elder H 7, 9, 36, 72, 130. We find this argument unavailing for the reasons presented in our discussion of Rejection 2. We again reiterate that Elder’s disclosure of adding asparaginase and lysine prior to heating reduces the formation of acrylamide in fabricated food products, and combining acrylamide-reducing agents (e.g., citric acid, asparaginase, and lysine) to achieve increasingly lower levels of acrylamide in foods, would suggest to one skilled in the art to add the asparaginase and lysine before or after addition of the food grade acid. Elder 1136, 72, 125, 130. We have also reviewed the data presented in Appellant’s application, but do not find them persuasive. As previously discussed, the data in Table 5 at page 14 of Appellant’s Specification are insufficient to show that the order of addition for the citric acid and the enzyme is critical or produces an unexpected result. Accordingly, we affirm the Examiner’s prior art rejection of claims 1— 6 for the reasons set out by the Examiner and given above. 13 Appeal 2016-006570 Application 13/869,409 Rejection 5 Appellant argues the claims subject to the fifth ground of rejection in two separate groups: (1) claims 1, 2, and 6 (Group X), and (2) claims 3—5 (Group XI). Appeal Br. 18—20. Accordingly, we limit our discussion to these groups of claims. Group X: Claims 1, 2, and 6 Appellant argues that the combined teachings of the cited art would not have led one of ordinary skill in the art to add acid to molasses until the molasses has a pH between 4.0 and 5.0, and then heat the molasses to a temperature of above about 120 -C to reduce acrylamide formation during heat treatment of molasses, as recited in the claimed method. See Appeal Br. 19. Appellant’s argument is not persuasive of reversible error. The Examiner finds, and Appellant does not dispute, that Davies teaches that molasses has Maillard reactivity when heated to above 100 -C. Final Act. 12; Davies 8. As with Rejections 2 and 4, the Examiner again relies on Long, Gomez, Davies, and Elder, as evidence that molasses comprises reducing sugars, amino acids such as asparagine, and has Maillard reaction activity (i.e., forms acrylamide when heated or processed at high temperatures). Final Act. 12—14; ElderH 7, 9, 36, 130; Gomez 12; Davies 8. The Examiner finds, and Appellant does not dispute, that Elder teaches adding phosphoric acid prior to heating to reduce the formation of acrylamide. Elder Abstract, and 1110. The Examiner finds, and Appellant does not dispute, that Jung teaches that acrylamide formation is reduced with a pH of 4.0 or 5.0. Jung 1289 (Fig. 4). Based on these disclosures, the Examiner determines that one of ordinary skill in the art would have been 14 Appeal 2016-006570 Application 13/869,409 led to lower the formation of acrylamide in molasses, as taught by Davies and Elder, by adding a food grade acid such as phosphoric acid to a pH between 4.0 and 5.0, as taught by Elder and Jung, before heating to a temperature above 100 -C, as taught by Elder and Davies, to reduce the undesirable acrylamide formation in molasses. See Final Act. 12—14. A preponderance of the evidence supports the Examiner’s findings and determinations. Thus, we are not persuaded of reversible error in the Examiner’s rejection of claims 1, 2, and 6. Group XI: Claims 3—5 Claims 3—5 directly or indirectly depend from claim 1 and require that asparaginase and/or lysine is added to molasses after adding the food grade acid. Appellant argues that none of the references explain or suggest that asparaginase or lysine should be added after acid and before heating. Appeal Br. 20. Additionally, Appellant argues that the data in their application demonstrates an unexpected improvement by adding asparaginase enzyme after adding the acid as compared to adding enzyme before adding the acid. Id. Appellant’s arguments are similar to the line of arguments presented for Rejection 2. We have addressed these arguments above and do not find them persuasive for the reasons discussed above with regard to Rejection 2. Regarding the data in Appellant’s Specification (e.g., Table 5), we do not find the evidence persuasive for the reasons discussed above with regard to Rejections 2 and 4. Accordingly, we affirm the Examiner’s prior art rejection of claims 1— 6 for the reasons set out by the Examiner and given above. 15 Appeal 2016-006570 Application 13/869,409 CONCLUSION Accordingly, based on the totality of the appeal record, including due consideration of Appellant’s arguments and evidence, we determine that the preponderance of the evidence weighs most heavily in favor of obviousness of the subject matter recited in claims 1—6 within the meaning of 35 U.S.C. § 103(a). DECISION For the above reasons, the Examiner’s decision to reject claims 1—6 is affirmed. No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a). AFFIRMED 16 Copy with citationCopy as parenthetical citation