Ex Parte CHIU et alDownload PDFPatent Trial and Appeal BoardJul 9, 201814490423 (P.T.A.B. Jul. 9, 2018) Copy Citation UNITED STA TES p A TENT AND TRADEMARK OFFICE APPLICATION NO. FILING DATE 14/490,423 09/18/2014 120226 7590 07/11/2018 Patterson & Sheridan - The Boeing Company c/o Patterson & Sheridan, LLP 24 GREENWAY PLAZA, SUITE 1600 Houston, TX 77046 FIRST NAMED INVENTOR Philip CHIU UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www .uspto.gov ATTORNEY DOCKET NO. CONFIRMATION NO. BOC0/0066US (069148) 3633 EXAMINER MARTIN, BETHANY LAMBRIGHT ART UNIT PAPER NUMBER 1721 NOTIFICATION DATE DELIVERY MODE 07/11/2018 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): P AIR_eofficeaction@pattersonsheridan.com PatentAdmin@boeing.com PSDocketing@pattersonsheridan.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Exparte PHILIP CHIU, PETER HEBERT, and DHANANJA Y BHUSARI Appeal2017-009316 Application 14/490,423 Technology Center 1700 Before RAEL YNN P. GUEST, JENNIFER R. GUPTA, and MERRELL C. CASHION, JR., Administrative Patent Judges. GUPTA, Administrative Patent Judge. DECISION ON APPEAL 1 Appellant appeals under 35 U.S.C. § 134(a) from the Examiner's final decision rejecting claims 1, 5-12, 16, and 21-24. 2,3 We have jurisdiction under 35 U.S.C. § 6(b). We affirm. 1 In this Decision, we refer to the Specification filed September 18, 2014 ("Spec."); the Final Office Action dated September 12, 2016 ("Final Act."); the Appeal Brief filed December 22, 2016 ("Appeal Br."); the Examiner's Answer dated April 19, 2017 ("Ans."); and the Reply Brief filed June 15, 2017 ("Reply Br."). 2 Appellant is the Applicant, The Boeing Company, which, according to the Appeal Brief, is the real party in interest. Appeal Br. 3. 3 There is a discrepancy in the record with respect to the claims presented for review on appeal. The Examiner rejected claims 1, 5-12, 15, 16, and 21-24 Appeal2017-009316 Application 14/490,423 The subject matter on appeal relates to antireflective coatings for solar cells. Spec. ,r 2. Independent claim 1, reproduced below from the Claims Appendix of the Appeal Brief with emphasis added to highlight disputed limitations, is illustrative of the claims on appeal. 1. An antireflective coating, comprising: a first layer comprising titanium dioxide and having a first index of refraction within a range of about 2.3 to about 2.7; an intermediate layer comprising titanium dioxide disposed on the first layer, the intermediate layer having an index of refraction and a density less than the first layer; a second layer disposed on the intermediate layer, the second layer having an index of refraction less than the intermediate layer and within a range of about 1.8 to about 2.1; and a third layer disposed on the second layer, the third layer having an index of refraction within a range of about 1.6 to about 1.8. Appeal Br. 13 (Claims App.). Independent claim 11 is directed to a solar cell comprising the same antireflective coating as recited in claim 1. over prior art. See generally Final Act. As indicated by Appellant, claim 15 was previously cancelled. App. Br. 1. Although Appellant appears to only appeal claims 1, 5, 8, 11, and 21-24 (id.), Appellant also indicates that arguments presented for claims 1 and 11 are relied upon to address the rejections of claims 6, 7, 9, 10, 12, 21, and22 (id. at 11). Thus, we determine that Appellant's intent is to appeal the Examiner's decision to reject claims 1, 5-12, 16, and 21-24. With respect to the Examiner's inclusion of cancelled claim 15 in the rejection statement, we find this to be a harmless error given Appellant's acknowledgement noted above. Id. at 1. Accordingly, claim 15 is not before us for review on appeal and the appropriate rejection statement has been modified to reflect its cancellation. 2 Appeal2017-009316 Application 14/490,423 DISCUSSION The Examiner maintains the rejection of claims 1, 5, 8, 11 under 35 U.S.C. § 103 as unpatentable over Daniel J. Aiken, High performance anti-reflection coatings for broadband multi-junction solar cells, 64 Solar Energy Materials & Solar Cells 393--404 (2000) ("Aiken") in view of Chhajed et al., Nanostructured multilayer graded index antireflection coating for Si solar cells with broadband and omnidirectional characteristics," 93 Applied Physics Letters 251108-1-3 (2008) ("Schubert"4), Kalyankar et al. (US 2014/0170308 Al, published June 19, 2014) ("Kalyankar '308"), and Kalyankar et al. (US 2014/0004334 Al, published January 2, 2014) ("Kalyankar '334"). Ans. 3-15. The Examiner also maintains the rejection of claims 6, 7, 9, 10, 12, 16, and 21-24 over Aiken, Schubert, Kalyankar '308, and Kalyankar '334, and in view of various additional references. Id. at 15-29. Because Appellant does not present arguments pertaining to the additional references, we do not discuss them herein. We review the appealed rejections for error based upon the issues identified by the Appellant and in light of the arguments and evidence produced thereon. Ex parte Frye, 94 USPQ2d 1072, 107 5 (BP AI 2010) (precedential) (cited with approval in In re Jung, 637 F.3d 1356, 1365 (Fed. Cir. 2011) ("[I]t has long been the Board's practice to require an applicant to identify the alleged error in the examiner's rejections")). After consideration of the evidence on this record and each of Appellant's contentions, we find 4 Appellant and the Examiner refer to this reference as "Schubert," the second named author of the reference. To avoid confusion, and to be consistent with the record, we will also refer to this reference by its second named author. 3 Appeal2017-009316 Application 14/490,423 that the preponderance of evidence supports the Examiner's conclusions that the subject matter of Appellant's claims is unpatentable over the applied prior art. Accordingly, we sustain the Examiner's§ 103 rejections for substantially the findings and reasons set forth by the Examiner in the Final Office Action, Answer, and below. Appellant's arguments focus on independent claims 1 and 11. Appellant does not present separate arguments for patentability of independent claim 24 or dependent claims 5-10, 12, 16, and 21-23. We select independent claim 1 as representative, and claims 5-12, 16, and 21-23 will stand or fall with claim 1. 37 C.F.R. § 41.37 (c)(l)(iv). Regarding claim 1, the Examiner finds that Aiken's Figures 3 and 4 disclose a solar cell that includes an anti-reflective coating with a first layer having an optimum refractive index of approximately 2.65 (nH) ( corresponding to claim 1 and claim 11 's "a first layer having a first index of refraction within a range of about 2.3 to about 2.7"). Final Act. 5, 11. The Examiner also finds that Aiken's Figures 3 and 4 disclose a second layer stacked on the first layer having an optimum refractive index of approximately 2.1 (nM) ( corresponding to the claimed "a second layer, the second layer having an index of refraction within a range of about 1. 8 to about 2.1 "), and a third layer stacked on the second layer having an optimum refractive index of approximately 1. 7 ( nL) ( corresponding to the claimed "a third layer disposed on the second layer, the third layer having an index of refraction within a range of about 1.6 to about 1.8"). Id. at 6. The Examiner relies on Schubert for the material for the first layer of the anti-reflective coating. Final Act. 5-6. The Examiner finds that Schubert teaches that it is well-known to employ a first layer of titanium 4 Appeal2017-009316 Application 14/490,423 oxide with a refractive index of 2.66 as the base layer in a multilayer antireflective coating. Schubert 251108-2, Fig. 3; see also Final Act. 5---6. The Examiner finds that one having ordinary skill in the art would be led to use Schubert's titanium oxide material to form the first layer of Aiken's anti- reflective coating because the titanium oxide material exhibits the desired refractive index for the ideal first layer of Aiken's anti-reflective coating. Final Act. 6. The Examiner relies on Kalyankar '308 for a teaching regarding an intermediate layer disposed between a first and second layer of an anti- reflective coating. Final Act. 7. The Examiner finds that Kalyankar '308 teaches using a grading process on its anti-reflective coating to cause and/or enhance diffusion of the material of the second anti-reflective layer into the material of the first anti-reflective layer, resulting in an intermediate sublayer disposed between the first and second layer, where the intermediate layer has a refractive index less than the first layer. See id. ( citing Kalyankar '308, ,r,r 24--27, and Fig. 6). The Examiner finds that Kalyankar '308 teaches that such a graded structure results in a smoother transition between anti-reflective layers, improving anti-reflective properties. Id. The Examiner relies on Kalyankar '334 for teaching an intermediate layer, disposed on a first layer, and having a density less than the first layer. Final Act. 8. The Examiner finds that Kalyankar '334 teaches varying the porosity and index of refraction of the layers of a multilayer anti-reflective coating in a graded fashion to improve the anti-reflective property of the coated layers. Final Act. 8 (citing Kalyankar '334, ,r 48). 5 Appeal2017-009316 Application 14/490,423 Based on the teachings of Kalyankar '308, and Kalyankar '334, the Examiner determines that it would have been obvious to one of ordinary skill in the art at the time of the invention to modify Aiken's triple layer anti- reflective coating, as modified by Schubert, to include an intermediate sublayer between the first and second layers ( the intermediate layer disposed on the first layer, and the second layer disposed on the intermediate layer) that has a refractive index and porosity slightly less than the first layer, as taught by Kalyankar '308 and Kalyankar '334, to achieve a smoother transition between layers and improve antireflective properties. See Final Act. 7-10. Appellant argues that Kalyankar '334 does not provide an example of a porous titanium oxide layer having an index of refraction above 1.3. Reply Br. 2; Appeal Br. 8. Therefore, Appellant argues that any assertion that one of ordinary skill in the art would have been led to apply Kalyankar '334's porosity scheme to Aiken to form a porous titanium oxide layer having a refractive index greater than 1.3 is "purely unsupported speculation by the Examiner." Reply Br. 2; Appeal Br. 8. Appellant's arguments are not persuasive of reversible error because they do not address the Examiner's findings regarding Kalyankar '334 or the Examiner's reasoning for modifying Aiken's anti-reflective coating based on Kalyankar '334's teachings. As the Examiner explains, Kalyankar '334 is not relied upon for teaching the refractive index of an intermediate layer disposed between first and second layers. Ans. 29. Nor does the Examiner rely on Kalyankar 334's disclosure of a titanium dioxide having a refractive index of 1.3. See Ans. 29; see also Final Act. 8-9. 6 Appeal2017-009316 Application 14/490,423 As discussed above, the Examiner relies upon Kalyankar '308 for teaching a process of grading a multi-layer anti-reflective coating that causes and/or enhances diffusion of the material of the second anti-reflective layer into the material of the first anti-reflective to produce an intermediate layer with a refractive index layer between the two layers. Ans. 29--30; see also Kalyankar '308, ,r,r 24--27. The Examiner finds, and Appellant does not dispute, that one of ordinary skill in the art would have been led, based on Kalyankar '308, to grade the first and second layers of Aiken's triple layer anti-reflective coating, as modified by Schubert, to form an intermediate sublayer between the first and second layers ( the intermediate layer disposed on the first layer, and the second layer disposed on the intermediate layer) that has a refractive index less than the first layer "to achieve a smoother transition between layers and improve anti[-]reflective properties." Compare Final Act. 7, and Ans. 30, with Appeal Br. 7-9. In other words, Aiken's triple layer anti-reflective coating, as modified by Schubert and Kalyankar '308, would have included a first layer comprising titanium dioxide having a first index of refraction of approximately 2.65, a second layer having an index of refraction of approximately 2 .1, and an intermediate layer comprising titanium dioxide having a graded index of refraction between 2.1 and 2.65. The Examiner finds, and Appellant does not dispute, that Kalyankar '334 teaches an alternative method for grading a multi-layer anti- reflective coating that introduces air into a material (specifically titanium dioxide) so as to increase porosity and decrease refractive index of the layers of a multi-layer anti-reflective coating, and improve the anti-reflective properties of the coated layers. Compare Final Act. 8-9 ( citing Kalyankar 7 Appeal2017-009316 Application 14/490,423 '334, ,r 48), and Ans. 30-31, with Appeal Br. 7-9. Further, Appellant has not identified reversible error in the Examiner's determination that it would have been prima facie obvious for one of ordinary skill in the art to use Kalyankar '334's porosity method to form the layers of Aiken's anti- reflective coating, as modified by Schubert and Kalyankar '308, with varying porosity and refractive indices to improve the anti-reflective properties of the multi-layer anti-reflective coating of Aiken. Id. Appellant argues that even if a porous titanium oxide layer having the asserted refractive index could be formed as asserted by the Examiner, there is no teaching or suggestion in any reference that such a layer is suitable in an anti-reflective stack. Id. Appellant's argument is not persuasive because Kalyankar '334 teaches using a porous titanium oxide layer in a multi-layer anti-reflective coating. Kalyankar '334, ,r 48. Because Appellant's arguments do not identify reversible error in the Examiner's rejections, we sustain the rejections of claims 1, 5-12, 16, and 21-24. DECISION For the above reasons, the rejections of claims 1, 5-12, 16, and 21-24 are affirmed. No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a). AFFIRMED 8 Copy with citationCopy as parenthetical citation