Ex Parte Barry et alDownload PDFPatent Trial and Appeal BoardOct 25, 201712369219 (P.T.A.B. Oct. 25, 2017) Copy Citation United States Patent and Trademark Office UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O.Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 12/369,219 02/11/2009 Terence P. Barry P06336US (28243-55) 3441 76656 7590 Patent Docket Department Armstrong Teasdale LLP 7700 Forsyth Boulevard Suite 1800 St. Louis, MO 63105 EXAMINER ANDERSON, DENISE R ART UNIT PAPER NUMBER 1779 NOTIFICATION DATE DELIVERY MODE 10/27/2017 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): USpatents @ armstrongteasdale. com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte TERENCE P. BARRY, DEAN T. TOMPKINS, MARC A. ANDERSON, and WALTER A. ZELTNER Appeal 2016-004133 Application 12/369,219 Technology Center 1700 Before ADRIENE LEPIANE HANLON, LINDA M. GAUDETTE, and MONTE T. SQUIRE, Administrative Patent Judges. GAUDETTE, Administrative Patent Judge. DECISION ON APPEAL1 1 This Decision includes citations to the following documents: Specification filed Feb. 11, 2009 (“Spec.â€); Final Office Action mailed Apr. 23, 2015 (“Finalâ€); Appeal Brief filed June 2, 2015 (“Br.â€); and Examiner’s Answer mailed Dec. 16, 2015 (“Ans.â€). Appeal 2016-004133 Application 12/369,219 Appellants2 appeal under 35 U.S.C. § 134(a) from the Examiner’s decision finally rejecting claims 1—18 and 25—32. We have jurisdiction under 35 U.S.C. § 6(b). We AFFIRM. The invention relates to a photoelectrocatalytic oxidation device for use, e.g., in an aquarium or a closed, recirculating aquaculture system. See Spec. ]Hf 87, 89. Claim 1, the sole independent claim on appeal, and dependent claim 32 are reproduced below: 1. A photoelectrocatalytic oxidation device comprising: a photoelectrocatalytic composite photoanode comprising a solid nanoporous film member having a median pore diameter in the range of 0.1 nm to 500 nm constructed from TiCF nanoparticles, the nanoporous film member adhered to a conductive metal support member, a cathode, a housing member having an inlet and outlet, the housing member adapted to house the photoelectrocatalytic composite photoanode and cathode, a light source assembly adapted to emit ultraviolet light to the photoelectrocatalytic composite photoanode, and an electrical power source that applies a voltage across the photoelectrocatalytic composite photoanode and cathode in the range of+4 Vto +12 V. Br. 10 (emphasis added). 32. The photoelectrocatalytic oxidation device of claim 1, wherein water is reduced into H2 at the cathode by electrolysis. Id. at 13. 2 Appellants identify the real party in interest as Wisconsin Alumni Research Foundation. Br. 1. 2 Appeal 2016-004133 Application 12/369,219 The claims stand rejected under 35 U.S.C. § 103(a) as follows: 1. claims 1—4, 7—12, 14, 18, and 25—32 over Kaneko et al, Photoelectrochemical reaction of biomass and bio-related compounds with nanoporous HO2 fdm photoanode and 02-reducing cathode, 8 Electrochemistry Communications 336—340 (2006) (hereinafter “Kanekoâ€), in view Bray (WO 03/082750 Al, pub. Oct. 9, 2003); 2. claims 5 and 6 over Kaneko in view of Bray and Anderson (US 5,215,943, iss. June 1, 1993); 3. claim 13 over Kaneko in view of Bray and Snee (US 5,603,843, iss. Feb. 18, 1997); and 4. claims 15—17 over Kaneko in view of Bray and Brandli (US 4,349,765, iss. Sept. 14, 1982). With respect to the above-listed, first ground of rejection, Appellants present arguments in support of patentability of claims 1 and 32. See Br. 3—6. Appellants’ arguments in support of patentability of the remaining claims subject to this ground of rejection are limited to a general assertion that the applied prior art fails to disclose or suggest the recited limitations. Id. at 6. Appellants’ traversals of the above-listed, second, third, and fourth grounds of rejection are limited to general assertions that the additional references relied on by the Examiner fail to cure the deficiencies in the Examiner’s rejection of claim 1 as unpatentable over the combination of Kaneko and Bray, and that the applied prior art fails to disclose or suggest the recited limitations. Id. at 6—8. Accordingly, claims 2—18 and 25—31 will stand or fall with independent claim 1, from which they depend. See 37 C.F.R. § 41.37(c)(l)(iv) (2013). Appellants’ arguments with respect to the Examiner’s rejection of claim 1 (see Br. 3—5) raise the following issue: Have Appellants identified reversible error 3 Appeal 2016-004133 Application 12/369,219 in the Examiner’s finding that one of ordinary skill in the art would have been motivated, based on Bray’s disclosure, to “construct the Kaneko . . . device with an electrical power source that applies a voltage across the photoelectrocatalytic composite photoanode and cathode in the range of +4 V to +12 V †(Final 8)? We answer this question in the negative for the reasons explained below. With respect to the argued claim 1 limitation (see italicized language in claim 1, supra, p. 2), the Examiner found Kaneko discloses “a photofuel cell that provides electrical power by the photoelectrochemical decomposition of biomass, bio-related materials such as ammonia, and other electron-donating compounds.†Final 5—6. The Examiner further found Kaneko discloses two sources of electrical power: the fuel provided to the photofuel cell device, and an additional power source “as evidenced by (1) a cyclic voltammogram that was generated with a voltage scanning rate of 20 mVs'1 and a sweep direction of 0 —> -0.9 —> +0.4 —> 0 V, and (2) a xenon light source at an intensity [of] 505 mW cm'2 which is used to run the photochemistry.†Id. at 6 (citing Kaneko, Fig. 1). The Examiner found Bray discloses a device that, like Kaneko’s device, uses an electrochemical process to decompose compounds such as ammonia. Id. at 3 (citing Bray 4—5). The Examiner found, more specifically, that Bray discloses “ammonia is oxidized to nitrogen with a pulsed electrical power source having [an] ‘output between 5 Volts and 25 Volts,â€â€™ and that, for titanium electrodes, a suitable applied voltage is from 6 Volts up to 12 Volts. Id. at 8 (citing Bray, Abstract, 5, 7—8). The Examiner found Bray teaches the pulsed power source provides “[p]recise control over the electrochemical process [to] maintain[] the optimum conditions under which oxidation takes place and organic compounds are broken down with a high degree of efficiency. When the apparatus is ‘switched-on’ the oxidation process begins and continues until it is ‘switched-off’.†Id. at 2 (citing Bray 4,11. 18—21). Based 4 Appeal 2016-004133 Application 12/369,219 on this noted advantage, the Examiner found the ordinary artisan at the time of the invention would have modified Kaneko to include a pulsed electrical power source as disclosed in Bray whereby, when the power source is switched-on, electricity is consumed to provide control over the electrochemical process as described in Bray, and when the power source is switched-off, electricity is generated via the photoelectrochemical decomposition described in Kaneko. Id. at 2—3. Appellants’ principal argument is that one of ordinary skill in the art would not have modified Kaneko to include a power source that applies a voltage in the claimed range of +4 V to +12 V because such modification would have rendered Kaneko’s device unsatisfactory for its intended purpose of generating electricity. Br. 4—5. Appellants argue, more specifically, that Kaneko’s device is intended to generate a maximum of 0.94 V. Id. at 5. According to Appellants, if modified to include a power source that applies a voltage between 4 and 12 times greater than the maximum voltage output, Kaneko’s device would consume more power than it generates, thereby changing the principle of operation of the device and rendering it unsatisfactory for its intended purpose of electricity generation. Id. We agree with the Examiner that Appellants’ argument is not persuasive of error in the rejection of claim 1 for the reasons stated in the Answer. See Ans. 20— 26. As explained by the Examiner, Appellants have not identified persuasive evidence to support their assertion that Kaneko’s device, if modified to include a pulsed electrical power source as disclosed in Bray, would be rendered unsatisfactory for its intended purpose. See Ans. 23 (“The argument is unpersuasive because it appears to be merely attorney argument. . . .â€). For example, Appellants do not provide a citation to Kaneko in support of their contention that Kaneko’s device is intended to generate a maximum of 0.94 V. See Br. 3—5. This value appears in Table 1 of Kaneko which is described as showing 5 Appeal 2016-004133 Application 12/369,219 “[pjhotofuel cell (PFC) characteristics of various compounds.†Kaneko 339. We are unable to locate, however, any description in Kaneko indicating that this is the maximum voltage output of Kaneko’s device as alleged by Appellants. But see Br. 3^4 (“Examples of the PFC characteristics demonstrated in Kaneko et al., specifically the electricity generated is illustrated by the open-circuit voltage (Voc), which Kaneko et al. discloses as between 0.44 V and 0.94 V based upon different fuels.†(emphasis added)); cf. Ans. 24 (noting that Appellants’ Figure 1 and Kaneko’s Figure 2 are substantially the same and, therefore, if Appellants’ argument is correct, then Appellants’ device is also necessarily limited to generating a maximum of 0.94 V). In sum, we are not persuaded of reversible error in the Examiner’s rejection of claim 1. Accordingly, we sustain the rejections of claims 1—18 and 25—31. Turning now to claim 32, the additional arguments advanced by Appellants raise the following issue: Have Appellants shown that the Examiner, in concluding the invention as recited in claim 32 would have been obvious, reversibly erred by failing to consider that Kaneko teaches away from reducing water into H2 at the cathode? We answer this question in the negative for the reasons explained below. Appellants argue Kaneko teaches away from reducing water into H2 at the cathode because Kaneko discloses that “it is important... to reduce 02 at a counter cathode electrode to generate electricity instead of reducing protons into H2 there.†Br. 6. With respect to claim 32, the Examiner found Kaneko’s device, as modified by Bray, would be capable of reducing water to H2 at the cathode because the electrical power source, in use, would apply a voltage in the range of +6 V to +12 V across the photoelectrocatalytic composite photo anode and cathode. Final 13, 6 Appeal 2016-004133 Application 12/369,219 18 (citing Cleveland, Encyclopedia of Energy, Elsevier Academic Press (2004) as evidence that the electrolysis of water begins to occur at a voltage of 1.23 V). “A reference may be said to teach away when a person of ordinary skill, upon reading the reference, would be discouraged from following the path set out in the reference, or would be led in a direction divergent from the path that was taken by the applicant.†In re Gurley 27 F.3d 551, 553 (Fed. Cir. 1994). Kaneko’s alleged teaching away relates to operation of the device during electricity generation. Kaneko 337, col. 1, lines 6—9 (“[I]t is important... to reduce O2 at a counter cathode electrode to generate electricity instead of reducing protons into H2 there.â€). Appellants have not explained why this disclosure would have discouraged the ordinary artisan from using a pulsed electrical power source as taught by Bray to provide improved control over Kaneko’s electrochemical process during power consumption. See Ans. 27—29. Appellants have not shown error in the Examiner’s finding that Kaneko’s device, as modified to include an electrical power source as taught by Bray, would be capable of functioning in the manner recited in claim 32 during the power consumption phase. See Ans. 27 (“The argument is unpersuasive because it appears to be merely attorney argument since Appellant failed to provide any scientific statistical evidence showing that the Combination's device is not operable to carry out the intended use.â€). Accordingly, we sustain the rejection of claim 32. In sum, we have considered the arguments in support of patentability advanced by Appellants in their Appeal Brief, but are not convinced of reversible error in the Examiner’s conclusion of obviousness as to appealed claims 1—18 and 25—32. We sustain all four grounds of rejection based on the Examiner’s fact finding and reasoning in the Final Office Action and the Answer. 7 Appeal 2016-004133 Application 12/369,219 No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. §1.136(a)(l)(iv). AFFIRMED 8 Copy with citationCopy as parenthetical citation