C3Nano Inc.Download PDFPatent Trials and Appeals BoardSep 28, 20212021003051 (P.T.A.B. Sep. 28, 2021) Copy Citation UNITED STATES PATENT AND TRADEMARK OFFICE UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 14/087,669 11/22/2013 Xiqiang Yang 5074.07US01 7514 62274 7590 09/28/2021 CHRISTENSEN, FONDER, DARDI & HERBERT PLLC 11322 86th Ave. N. Maple Grove, MN 55369 EXAMINER GILLETT, JENNIFER ANN ART UNIT PAPER NUMBER 1789 NOTIFICATION DATE DELIVERY MODE 09/28/2021 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): docket@cfd-ip.com patents@cfd-ip.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte XIQIANG YANG, YING-SYI LI, YUNGYU HUANG, CHRIS SCULLY, CLIFFORD M. MORRIS, and AJAY VIRKAR Appeal 2021-003051 Application 14/087,669 Technology Center 1700 Before LINDA M. GAUDETTE, N. WHITNEY WILSON, and BRIAN D. RANGE, Administrative Patent Judges. WILSON, Administrative Patent Judge. DECISION ON APPEAL Pursuant to 35 U.S.C. § 134(a), Appellant1 appeals from the Examiner’s January 17, 2020 decision to reject claims 1–8, 10–17, and 37–40 (“Non-Final Action”). A video hearing was held on September 21, 2021, a transcript of which will be part of the record. We have jurisdiction under 35 U.S.C. § 6(b). 1 We use the word Appellant to refer to “applicant” as defined in 37 C.F.R. § 1.42. Appellant identifies the real party in interest as C3nano Inc. (Appeal Br. 3). Appeal 2021-003051 Application 14/087,669 2 We reverse and enter a new ground of rejection under 37 C.F.R. § 41.50(b). CLAIMED SUBJECT MATTER Appellant has two independent claims on appeal. Independent claim 1 is directed to a coated substrate with a conductive coating– comprising a fused nanostructured metal network and crosslinked polymer binder–over at least part of the substrate (Appeal Br. 4). Independent claim 10 is directed to a conductive film processing system comprising a metal nanowire ink and a fusing solution (id.). Claims 1 and 10 are reproduced below from the Claims Appendix: 1. A coated substrate comprising a substrate with a conductive coating over at least a portion of the substrate comprising a fused nanostructured metal network and a crosslinked polymer binder and having a sheet resistance of no more than about 270 ohms/square, an optical transmittance through the conductive coating of greater than about 90% and a haze of no more than about 1%, wherein the fused nanostructured metal network comprises nanowire segments fused into the network with an average diameter of no more than about 40 nm. 10. A conductive film processing system comprising a metal nanowire ink and a fusing solution, wherein the metal nanowire ink comprises a first solvent, from about 0.01 weight percent (wt%) to about 2 wt% metal nanowires, from about 0.02 wt% to about 5 wt% crosslinkable organic polymer and from about 0.05 wt% to about 2 wt% processing additive wherein the metal nanowires have an average diameter of no more than about 40 nm, and the fusing solution comprises a second solvent and a fusing agent selected from the group consisting of a Appeal 2021-003051 Application 14/087,669 3 halide anion, or a reducing agent combined with a metal ion source, or a combination thereof. REFERENCES The prior art relied upon by the Examiner is: Name Reference Date Alden et al. US 2007/0074316 A1 March 29, 2007 Allemand US 2011/0192633 A1 August 11, 2011 Magdassi et al. (Magdassi”) US 2012/0168684 A1 July 5, 2012 Magdassi et al. (“Yissum”) WO 2012/168941 A1 December 13, 2012 REJECTIONS Claims 1, 2, 4–8, 10–17, and 37–40 are rejected under 35 U.S.C. § 103 over Allemand in view of Alden, Magdassi, and Yissum. The rejection of claims 1–8 and 37–38 under 35 U.S.C. § 112(b) as indefinite has been withdrawn by the Examiner (Ans. 12–13). OPINION Claim 1. The Examiner’s findings in connection with claim 1 are set forth in the Non-Final Action at pages 4–7. The Examiner finds that Allemand teaches a substrate with a conductive coating over at least a portion of the substrate comprising a nanostructured metal network and a crosslinked polymer binder and having a sheet resistance of no more than 270 ohm/square, an optical transmittance of at least about 90%, and a haze of no more than about 1% (Non- Final Act. 4, citing Allemand Abstract, ¶¶ 8–12, 21–30, 37, 87–98, Appeal 2021-003051 Application 14/087,669 4 120–129, Table 1). The Examiner further finds that the nanostructures have an average diameter of no more than about 40 nm (Non-Final Act. 5). The Examiner finds that Allemand does not teach that the nanostructured metal network is fused, but that Magdassi discloses a low temperature fusing process for nanowires, and that Yissum teaches the use of a chemical sintering process to fuse nanoparticles to improve conductivity (Non-Final Act. 6). The Examiner also explains how and why a person of skill in the art would have combined the teachings of Allemand and Magdassi as follows: Alden, disclosed by Allemand as a suitable process to prepare the thin film of his invention, teaches treatment of nanowire coatings comprising 0.05 to 1.4% nanowires, dispersants, viscosity modifiers, and solvent with heat, pressure, or chemicals to increase the conductivity of the coating. Magdassi teaches the use of a sintering agent, specifically chloride salts and hydrochloric acid in aqueous solvent (chemical treatment), to increase the conductivity of a conductive coating comprising nanoparticles through low temperature sintering. Magdassi teaches that the sintering temperature limits the potential substrates in plastic electronics, such as transparent conductors. Yissum teaches the use of chemical sintering using chloride salts and hydrochloric acid in transparent coatings, including patterned conductors, with transparencies as high as 95%. Therefore, it would have been obvious . . . to form the coated substrate of Allemand disclosed as produced according to Alden which teach[es] the use of heat or chemical post treatment to increase conductivity, wherein the silver nanostructure is . . . [fused] using the sintering agent of Magdassi, motivated by the desire of forming a conventionally known conductive substrates predictably Appeal 2021-003051 Application 14/087,669 5 suitable for use with silver nanoparticles and to predictably improve the conductivity at a low sintering temperature in order to allow a wider variety of substrates to be used by formalizing the bonds between Appeal 2021-003051 Application 14/087,669 6 the metal nanowire without destroying the transparency as disclosed by Yissum. (Non-Final Act. 7). Appellant argues, inter alia, that the combination of Allemand and Magdassi would not yield the claimed “fused metal nanostructured network” (Appeal Br. 24). In particular, Appellant contends that as used in the claims, a “fused metal nanostructured network” has a specific meaning, namely a unitary structure with original metal nanowire functions fused and the individual metal nanowires no longer present (Appeal Br. 22). It is well established that “the PTO must give claims their broadest reasonable construction consistent with the specification . . . . Therefore, we look to the specification to see if it provides a definition for claim terms, but otherwise apply a broad interpretation.” In re ICON Health & Fitness, Inc., 496 F.3d 1374, 1379 (Fed. Cir. 2007) (citation omitted). In this instance, Appellant outlines a number of instances in the Specification which describe the fused metal nanostructured network with reference to the formation of joints between nearby nanowires to form junctions, such that the individual nanowires are no longer present (Appeal Br. 21–22, citing Spec. 6:13– 21, 17:16–27, 18:1–3, 25:5–14). We agree with Appellant that the broadest reasonable construction of the phrase “fused metal nanostructured network” in light of the Specification is a unitary structure with original metal nanowire functions fused and the individual metal nanowires no longer present. Appeal 2021-003051 Application 14/087,669 7 While Appellant argues that “[n]one of the four cited references teach a fused metal nanostructured network” (Appeal Br. 23), the rejection relies on a combination of teachings from the references. Whether or not this is true, nonobviousness cannot be established by attacking the references individually when the rejection is predicated upon a combination of prior art disclosures. See In re Merck & Co., 800 F.2d 1091, 1097 (Fed. Cir. 1986). However, Appellant further argues that while Allemand and Alden are directed towards the production of transparent conductive films, Magdassi and Yissum do not pertain to transparent films, at least in the areas of conductivity, so that (a) person of skill in the art would not have combined their teachings as required by the rejection, and (b) applying Magdassi’s processing to Allemand’s system would result in a non-transparent structure, rendering Allemand’s film unsuitable for its intended purposed (Appeal Br. 25–27). Appellant’s arguments are persuasive of reversible error. Magdassi specifically states that use of its technology results in “aggregation and coalescence” of nanoparticles on a substrate (Magdassi ¶ 39). This feature of the process is illustrated, inter alia, by Magdassi’s Fig. 2, which is reproduced below: Appeal 2021-003051 Application 14/087,669 8 Magdassi’s Fig. 2 shows a scanning electron microscope (SEM) image showing the effect of Magdassi’s process on nanoparticles on a substrate. Thus, as shown in Magdassi’s Fig. 2, the Magdassi process results in the nanoparticles agglomerating into larger, more dense structures. Such structures will absorb and/or scatter light (i.e. not be transparent and increase haze). This is consistent with the fact that Magdassi does not express an interest in a transparent conductive film (notwithstanding that some portions of Magdassi’s film are transparent). Thus, notwithstanding the Examiner’s reasoning (Non-Final Act. 7) a person of ordinary skill in the art would have had a good reason not to apply Magdassi’s process to Allemand’s system, because doing so would risk impinging on the transparency of Allemand’s system, which is a key feature of that system (see, e.g., Allemand ¶¶ 6, 20). On balance, the preponderance of the evidence does not support the Examiner’s determination that a person of skill in the art would have been motivated to combine Magdassi’s teachings with Allemand’s teachings. Moreover, a person of skill in the art Appeal 2021-003051 Application 14/087,669 9 would have had no reasonable expectation that applying Magdassi’s sintering process to Allemand’s system would result in a transparent conductor as set forth in claim 1. Accordingly, we determine that Appellant has demonstrated reversible error in the rejection of claim 1, and reverse that rejection, as well as the claims which depend from claim 1. Claim 10. Claim 10 recites a conductive film processing system comprising a metal nanowire ink and a fusing solution. The Examiner finds that Allemand teaches a conductive film processing system comprising a metal nanowire ink and a solution of a photosensitive compound (Non-Final Act. 9), and that Magdassi teaches a sintering agent – which corresponds to the claimed fusing solution. The Examiner further finds that it would have been obvious to replace Allemand’s photosensitive compound with Magdassi’s sintering agent. We disagree with the Examiner. As discussed above in connection with claim 1, a person of skill in the art would not have combined the teachings of Magdassi with those of Allemand because Allemand is directed to a transparent conductive film and Magdassi’s process risks the transparency of the final product and does not offer a reasonable expectation of success. Thus, we reverse the rejection of claim 10 and the claims which depend therefrom. Appeal 2021-003051 Application 14/087,669 10 New Ground of Rejection of dependent claim 2. We impose a new ground of rejection on claim 2 under 35 U.S.C. § 112(d) for being in improper dependent form. Claim 1 recites that the claimed coated substrate has “a sheet resistance of no more than about 270 ohms/square” and an optical transmittance “of greater than about 90%.” Claim 2 depends from claim 1, and recites that the coated substrate has “a sheet resistance of greater than about 20,000 ohm[s]/sq[uare]” and an optical transmittance “of at least about 90%.” Therefore, the sheet resistance of the coated substrate of claim 2 must be greater than 20,000 ohms/square, while the claim from which it depends limits sheet resistance to no more than 270 ohms/square. Thus, the sheet resistance recited in claim 2 does not further limit claim 1, making claim 2 improperly dependent on claim 1. Similarly, the optical transmittance in claim 2 is “at least about 90%” which is at least a slightly broader range for the optical transmittance than in claim 1, which requires an optical transmittance of “greater than about 90%.” Thus, for this additional reason, claim 2 does not further limit claim 1 and is improperly dependent therefrom. CONCLUSION The Examiner’s rejections are reversed. A new ground of rejection is imposed on claim 2. Appeal 2021-003051 Application 14/087,669 11 DECISION SUMMARY In summary: Claims Rejected 35 U.S.C. § Reference(s)/ Basis Affirmed Reversed New Ground 1, 2, 4–8, 10–17, 37–40 103 Allemand, Alden, Magdassi, Yissum 1, 2, 4–8, 10–17, 37–40 2 112(d) Improper dependent form 2 Overall Outcome 1, 4–8, 10–17, 37–40 2 TIME PERIOD FOR RESPONSE This decision contains a new ground of rejection pursuant to 37 C.F.R. § 41.50(b). 37 C.F.R. § 41.50(b) provides “[a] new ground of rejection pursuant to this paragraph shall not be considered final for judicial review.” 37 C.F.R. § 41.50(b) also provides that the Appellant, WITHIN TWO MONTHS FROM THE DATE OF THE DECISION, must exercise one of the following two options with respect to the new ground of rejection to avoid termination of the appeal as to the rejected claims: (1) Reopen prosecution. Submit an appropriate amendment of the claims so rejected or new Evidence relating to the claims so rejected, or both, and have the matter reconsidered by the examiner, in which event the prosecution will be remanded to the examiner. . . . Appeal 2021-003051 Application 14/087,669 12 (2) Request rehearing. Request that the proceeding be reheard under § 41.52 by the Board upon the same Record. . . . Further guidance on responding to a new ground of rejection can be found in the Manual of Patent Examining Procedure § 1214.01. REVERSED; NEW GROUND OF REJECTION; 37 C.F.R. 41.50(B) Copy with citationCopy as parenthetical citation