Applied Research Associates, Inc.Download PDFPatent Trials and Appeals BoardMar 18, 20212020001113 (P.T.A.B. Mar. 18, 2021) Copy Citation UNITED STATES PATENT AND TRADEMARK OFFICE UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 14/060,225 10/22/2013 Edward N. Coppola 6999-133251 7481 28289 7590 03/18/2021 THE WEBB LAW FIRM, P.C. ONE GATEWAY CENTER 420 FT. DUQUESNE BLVD, SUITE 1200 PITTSBURGH, PA 15222 EXAMINER STEIN, MICHELLE ART UNIT PAPER NUMBER 1771 NOTIFICATION DATE DELIVERY MODE 03/18/2021 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): patents@webblaw.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte EDWARD N. COPPOLA, CHARLES RED JR., and SANJAY NANA Appeal 2020-001113 Application 14/060,225 Technology Center 1700 Before ERIC B. GRIMES, DEBRA L. DENNETT, and LILAN REN, Administrative Patent Judges. DENNETT, Administrative Patent Judge. DECISION ON APPEAL1 Pursuant to 35 U.S.C. § 134(a), Appellant2 appeals from the Examinerâs decision to reject claims 1â12, 14, 16â20, and 26â37. Final Act. 1. We have jurisdiction under 35 U.S.C. § 6. For the reasons set forth below, we AFFIRM. 1 In our Decision, we refer to the Specification (âSpec.â) of Application 14/060,225 filed Oct. 22, 2013 (âthe â225 App.â); the Final Office Action dated Mar. 14, 2019 (âFinal Act.â); the Appeal Brief filed Sept. 26 2019 (âAppeal Br.â); the Examinerâs Answer dated Oct. 21, 2019 (âAns.â); and the Reply Brief filed Nov. 25, 2019 (âReply Br.â). 2 We use the word âAppellantâ to refer to âapplicantâ as defined in 37 C.F.R. § 1.42. Appellant identifies Applied Research Associates, Inc. as the real party in interest. Appeal Br. 3. Appeal 2020-001113 Application 14/060,225 2 STATEMENT OF THE CASE The subject matter of the pending application relates to high-rate thermal reactor systems for converting an organic feedstock into an upgraded fuel product. Spec. ¶ 2. Claim 1, reproduced below from the Claims Appendix of the Appeal Brief, illustrates the claimed subject matter: 1. A process for upgrading an organic feedstock comprising: providing an organic feedstock and water mixture; feeding the mixture into a reactor operating at a Reynolds Number of at least 2000, wherein the mixture is subjected to heat and pressure at supercritical water conditions; maintaining the heat and pressure applied to the mixture in the reactor for a superficial residence time of less than three minutes to cause the organic components of the mixture to undergo a reaction resulting in the formation of upgraded hydrocarbon distillate products; and recovering the upgraded hydrocarbon distillate products. Appeal 2020-001113 Application 14/060,225 3 REFERENCES The Examiner relies on the following prior art: Name Reference Date Green US 4,135,982 Jan. 23, 1979 Vavruska US 5,611,947 Mar. 18, 1997 Weerstra US 5,760,297 June 2, 1998 Makino et el. (âMakinoâ) US 5,843,386 Dec. 1, 1998 Tullio et al. (âTullioâ) US 2002/0173682 A1 Nov. 21, 2002 He et al. (âHeâ) US 2008/0099374 A1 May 1, 2008 Allam US 2009/0206006 A1 Aug. 20, 2009 Babicki et al. (âBabickiâ) US 2010/0228062 A1 Sept. 9, 2010 REJECTIONS3 The Examiner rejects claims under 35 U.S.C. § 103(a) as follows: I. Claims 1â5, 7, 8, 11, 12, 14, 18, 20, 26â31, and 37 over He as evidenced by Green4; II. Claim 6 over He as evidenced by Green, and further in view of Babicki or alternatively, Makino; III. Claim 9 over He as evidenced by Green, and further in view of Vavruska; IV. Claim 10 over He as evidenced by Green, and further in view of Allam; 3 In the Final Office Action the Examiner rejects claims 34 and 35 under 35 U.S.C. § 112(a) and claims 29â35 under § 112(b). Final Act. 4â5. These rejections are not identified as asserted against the pending claims in the Answer, therefore we do not address them in the Decision. 4 The rejection includes claims 13 and 15 that are cancelled. Final Act. 3. Appeal 2020-001113 Application 14/060,225 4 V. Claims 16, 17, and 32â34 over He as evidenced by Green, and further in view of Tullio; VI. Claim 19 over He as evidenced by Green, and further in view of Makino and Weerstra; and VII. Claims 35 and 36 over He as evidenced by Green, further in view of Babicki or alternatively, Makino, and further in view of Vavruska. Final Act. 3â8. OPINION I. Rejection of claims 1â5, 7, 8, 11, 12, 14, 18, 20, 26â31, and 37 as obvious over He as evidenced by Green Regarding independent claims 1, 8, 30, and 37, the Examiner finds that He teaches the claim limitations except explicitly disclosing a Reynolds Number of at least 2000. Final Act. 3. The Examiner finds that He teaches turbulent flow, citing claim 7 of He. Id. The Examiner relies on Green as evidence that turbulent flow has a Reynolds Number of at least 2000. Id. (citing Green col. 2, ll. 36â45). Appellant argues claims 1, 3â5, 7, 8, 11, 18, 20, 26â28, and 30 as a group. Appeal Br. 15â22. We select claim 1 as representative of the group. See 37 C.F.R. § 41.37(c)(1)(iv). Claims 3â5, 7, 8, 11, 18, 20, 26â28, and 30 stand or fall with claim 1. We separately address the claims in this rejection that Appellant argues are patentable for additional reasons (claims 12 and 37, claims 14 and 31, and claims 2 and 29). A. Claims 1, 3â5, 7, 8, 11, 18, 20, 26â28, and 30 With respect to claim 1, Appellant argues that one of ordinary skill in the art at the time of the invention would not have modified He with Green to operate the reactor at a turbulent flow having a Reynolds Number of at Appeal 2020-001113 Application 14/060,225 5 least 2000, as such a modification would render Heâs process unsatisfactory for its intended purpose, would change the principle of operation, and would not have a reasonable expectation of success. Appeal Br. 16. Appellantâs argument is unpersuasive because the Examiner does not propose modifying He with teaching from Green. Rather, the Examiner relies on Green merely as evidence that a âturbulentâ flow has a Reynolds Number of at least 2000. See Final Act. 3. Under the Examinerâs rejection, He does not require modification, but merely additional explanation. Appellant argues that He does not disclose a reactor at true turbulent flow having a Reynolds Number of at least 2000. Appeal Br. 17. In support, Appellant cites and discusses the Kent Declaration (Declaration of Robert E. Kent signed Aug. 13, 2018 (âKent Decl.â)) and the Coppola Declaration (Declaration of Edward N. Coppola signed Jan. 7, 2019 (âCoppola Decl.â)). In the Kent Declaration, Reynolds Numbers were calculated based on the average preferred reactor temperature, preferred reactor pressure, and preferred reactor residence time in Heâs Example 1. Kent Decl. ¶ 12; He ¶ 75. In Heâs Example 1, preferred oil/water volume ratios are âon the order of 1:3.â He ¶ 75. Kent states that the Reynolds Number calculations were âbased on the properties of supercritical waterâ because water dominates the mass transport properties with an oil-to-water ratio of 1:3. Kent Decl. ¶ 12. Kent calculated Reynolds Numbers for a 0.25-inch outer diameter tube and a 0.5-inch outer diameter tube with a reactor length to diameter ratio (L/D) of 50 or 4000. Id. ¶ 13. Based on these parameters, Kent calculated the Reynolds Numbers to be between 3 and 1415. Based on the calculations, Kent states his opinion that âHe, with or without Green, only discloses non- Appeal 2020-001113 Application 14/060,225 6 turbulent flow reactor operation and would not suggest to one skilled in the art to feed a reaction mixture into a reactor operating at a Reynolds number of at least 2000.â Id. ¶ 14. The Kent Declaration and Appellantâs arguments related to it are unpersuasive of reversible error by the Examiner in rejecting claim 1 as obvious over He as evidenced by Green. The Kent Declaration limits the parameters used for the calculations to only those in Heâs Example 1, and does not take into account the significantly broader disclosures of He. See Kent Decl. ¶ 12. For example, Kent uses 387°C (average of 374°C and 400°C) as the reactor temperature, but He discloses 374°C to 1000°C. Compare Kent Decl. ¶ 12 with He ¶ 43. Kent uses a reactor pressure of 3600 psig (average of 3200 and 4000), but He discloses 3205 to 10,000 psia. Compare Kent Decl. ¶ 12 with He ¶ 43. Kent uses a reactor residence time of 30 minutes (average of 20 and 40 minutes), but He discloses one minute to six hours. Compare Kent Decl. ¶ 12 with He ¶ 44. Kent prepares calculations for L/D values of 50 and 4000, but He discloses a range of 50 to 10,000. Compare Kent Decl. ¶ 13 with He ¶ 54. Thus, the Kent Declaration limits its analysis to the mass transport properties of supercritical water and preferred reactor parameters in Heâs Example 1. However, â[a] reference must be considered for everything that it teaches, not simply the described invention or a preferred embodiment.â In re Applied Materials, Inc., 692 F.3d 1289, 1298 (Fed. Cir. 2012); see also Merck & Co v. Biocraft Laboratories, 874 F.2d 804, 807 (Fed. Cir. 1989) (âthe fact that a specific embodiment is taught to be preferred is not controlling, since all disclosures of the prior art, including unpreferred embodiments, must be considered.â). Moreover, a reference stands for all of Appeal 2020-001113 Application 14/060,225 7 the specific teachings thereof as well as the inferences one of ordinary skill in the art would have reasonably been expected to draw therefrom. See In re Fritch, 972 F.2d 1260, 1264â65 (Fed. Cir. 1992). The Kent Declaration is insufficient evidence to overcome the rejection. The Non-Final Office Action dated September 5, 2018, indicates that the Kent Declaration does not provide sufficient evidence of the Reynolds Numbers to be obtained from He, since He is not limited to the examples. Non-Final Act. 9. In response, Applicant submitted the Coppola Declaration. Coppola Decl. ¶¶ 7â8. However, the Coppola Declaration does not address adequately the Examinerâs complaint. The Coppola Declaration does not provide the results of calculations of Reynolds Numbers for reactors having, e.g., L/D ratios greater than 4000, but less than or equal to 10,000. See generally, id.; see also He ¶ 54. Nor does the Coppola Declaration consider reactors having temperature and/or pressure covering the full range of Heâs disclosure. Instead, the Coppola Declaration calculates L/D ratios for reactors having reactor diameters of 0.25, 0.5, 0.75, 1, and 2 inches based on âknownâ reactor parameters, which in turn are based on Re 2000 and residence time of either one minute or 360 minutes. Id. ¶¶ 11, 12, and 14. Indeed, calculations in the Coppola Declaration demonstrate that, for a Reynolds Number of 2000, L/D ratios within those disclosed by He are obtained with a reactor having a 0.25 inch or 0.5 inch tube when t=1 minute, and for a reactor having a 2 inch tube when t=360 minutes. Coppola Decl. ¶¶ 12, 14. In the face of these results, Coppola states that operation of a 0.25 inch or 0.5 inch diameter tubular reactor at t=1 minute âwould be impractical given the extremely low throughput (0.01â0.03 gallons per Appeal 2020-001113 Application 14/060,225 8 minute) over a 6â14 foot long tube, which are far outside suitable design parameters as recognized by one of skill in the art of chemical engineering.â Id. ¶ 13. And for t=360 minutes, Coppola states that the reactor lengths (specified by the declarant) are âunrealistically longâ and the volumetric flow rates are even more unrealistic and âinconsistent with a properly designed system where throughout is an important parameter.â Id. ¶ 15. Coppola concludes that the He reactor operated at a residence time of either one minute or 360 minutes âcannot be properly operated at turbulent flow (Re 2000).â Id. ¶¶ 13, 15. However, according to the Appeal Brief, â[t]ubular reactors representative of pilot systems actually tested in the present invention were selected to provide basis for the calculations.â Appeal Br. 17 (emphasis added). Appellant does not explain how âpilot systems actually testedâ are impractical, unrealistically long, or inconsistent with a properly designed system. Moreover, claim 1 requires neither these attributes, nor any specific throughput. See In re Self, 671 F.2d 1344, 1348 (CCPA 1982) (âMany of [Appellantâs] arguments fail from the outset because . . . they are not based on limitations appearing in the claims.â). We sustain the rejection of claim 1 as obvious over He as evidenced by Green. Claims 1, 3â5, 7, 8, 11, 18, 20, 26â28, and 30 are argued as a group, therefore we also sustain the rejection of claims 3â5, 7, 8, 11, 18, 20, 26â28, and 30. B. Claims 12 and 37 Claim 12 depends from claim 1, and recites, âwherein the superficial residence time is 1â120 seconds.â Appeal Br. 35 (Claims App.). Appeal 2020-001113 Application 14/060,225 9 The Examiner finds that He teaches residence times including one minute, which reads on the claimed range of 1â120 seconds. Final Act. 4. Appellant contends, âHe is operated at a minimum actual residence time of 1 minute (over 4 minutes superficial residence time) which far exceeds the claimed superficial residence time of the present invention of 1â 120 seconds (i.e., 0.25â30 seconds actual residence time).â Appeal Br. 22. Appellantâs argument is unpersuasive. He discloses âresidence timeâ of one minute to six hours. He ¶ 44. We find nothing in the Specification that distinguishes between âresidence timeâ and âsuperficial residence time.â See generally Spec. It is well settled that arguments of counsel cannot take the place of factually supported objective evidence. See, e.g., In re Huang, 100 F.3d 135, 139â40 (Fed. Cir. 1996); In re De Blauwe, 736 F.2d 699, 705 (Fed. Cir. 1984). We sustain the rejection of claim 12. Claim 37 depends from claim 1, and recites, âwherein the reactor maintains a turbulent flow of the mixture at a Reynolds Number of 2000â 100,000.â Appeal Br. 38 (Claims App.). Appellant contends, âHe clearly fails to teach or suggest operating the reactor at a Reynolds Number within the 2000â100,000 range.â However, for the reasons discussed in relation to the rejection of claim 1, He meets this limitation. We sustain the rejection of claim 37 over He as evidenced by Green. C. Claims 14 and 31 Claim 14 depends from claim 1, and recites âwherein the feedstock comprises crude oils exhibiting API gravities greater than 22°; waxy crude oils comprising yellow wax and/or black wax; and mixtures thereof.â Appeal 2020-001113 Application 14/060,225 10 Appeal Br. 35 (Claims App.). Claim 31 depends from claim 1, and recites âwherein the organic feedstock is selected from the group consisting of petroleum crude oil (API>22), waxy crude oil, atmospheric gas oil (AGO), vacuum gas oil (VGO); atmospheric tower bottoms (ATB) and vacuum tower bottoms (VTB) from petroleum crude or waxy crude oils; cycle oil; straight run naphtha, kerosene, or diesel distillates; and mixtures thereof.â Id. at 37. Regarding claims 14 and 31, the Examiner finds that âHe teaches suitable hydrocarbon feeds include bitumen, shale oil, crude oils, heavy hydrocarbon fractions, vacuum gas oils, resids, etc [0031].â Final Act. 4. The Examiner finds that the feedstock in the He process is not limited to those containing asphaltenes. Ans. 9â10. Appellant argues that heavy oils in He contain asphaltenes that are not soluble in supercritical water, therefore Heâs process forms solids that must be separated from the products. Appeal Br. 23. Appellant further argues it is known that turbulent flow alone will not keep all solids in suspension, especially asphaltenes. Id. Appellant argues, â[t]he present invention is concerned with the processing of feedstocks that do not contain asphaltenes, as set forth in claims 14 and 31.â Id. at 24. Appellantâs arguments are not persuasive. He broadly teaches, â[a]ny hydrocarbon can be suitably upgraded by a process according to the present invention. Preferred are heavy hydrocarbons having an API gravity of less than 20°.â He ¶ 31. Heâs disclosure of feedstocks is not limited in the manner suggested by Appellant. We sustain the rejection of claims 14 and 31 over He as evidenced by Green. Appeal 2020-001113 Application 14/060,225 11 D. Claims 2 and 29 Claim 2 depends from claim 1, and recites âinjecting a pressurized quench stream into the hydrocarbon distillate products such that further reaction is inhibited and secondary cracking, coking, and gas formation is minimized; and/or depressurizing the hydrocarbon distillate products.â Appeal Br. 35 (Claims App.). Claim 29 depends from claim 28, which depends from claim 27, which depends from independent claim 8. Appeal Br. 36 (Claims App.). Claim 29 recites â[t]he process of claim 28, including quenching by injection of a quench stream and/or depressurization of the product exiting the reactor to terminate conversion reactions and minimize secondary cracking, coking, and gas formation.â Id. The Examiner finds that He teaches using water to quench the reaction to control the temperature. Final Act. 3. Because the quenching would reduce the temperature, the Examiner finds that it would inherently inhibit further reaction such as secondary cracking, coking, or gas formation. Id. at 3, 5. The Examiner finds that Appellant does not distinguish the quenching process step in the claims over Heâs disclosure of quenching. Ans. 10. Appellant argues that He teaches quenching to control the reactor temperature and to bring down the reaction temperature. Appeal Br. 24. Appellant contends that, in contrast to He, the present invention quenches âto terminate conversion reactions and minimize secondary cracking, coking, and gas formation.â Id. Appellant also argues that He fails to teach rapid depressurization to achieve quenching and to minimize secondary cracking, coke formation, undesirable secondary reactions, and corrosion. Id. at 25. Appeal 2020-001113 Application 14/060,225 12 During prosecution, an applicationâs claims are given their broadest reasonable scope consistent with the specification. In re Am. Acad. of Sci. Tech. Ctr., 367 F.3d 1359, 1364 (Fed. Cir. 2004). Claim 2 requires injecting a pressurized quench stream into the hydrocarbon distillate products to minimize specified reactions and/or depressurizing the products. Appeal Br. 33 (Claims App.). Claim 29 requires quenching by injection and/or depressurization of the product to minimize the same reactions listed in claim 2. Id. at 36. The use of and/or means that both claims require performance of only one of either quenching or depressurizing, although both quenching and depressurizing may be performed within the scope of the claims. Given our construction of the quenching limitation, Appellantâs assertion that He fails to teach rapid depressurization is not persuasive of reversible error by the Examiner, as depressurization is not required by claim 2 or 29 if quenching is performed. Appellantâs argument that Heâs disclosure of quenching does not âterminate conversion reactions and minimize secondary cracking, coking, and gas formationâ (Appeal Br. 24) is also unpersuasive. He discloses, â[w]ater molecules, especially under supercritical conditions, can quench and stabilize hydrocarbon radicals and therefore prevent them from over cracking and polymerization.â He ¶ 46. Our reviewing court held [W]here âall process limitations . . . are expressly disclosed by [the prior art reference], except for the functionally expressed [limitation at issue],â the PTO can require an applicant âto prove that the subject matter shown to be in the prior art does not possess the characteristic relied on.â In re Best, 562 F.2d 1252, 1254â55 (CCPA 1977) (emphases added) (internal quotation marks omitted). The court noted that â[w]hether the Appeal 2020-001113 Application 14/060,225 13 rejection is based on âinherencyâ under 35 U.S.C. § 102, [or] on âprima facie obviousnessâ under 35 U.S.C. § 103, . . . the burden of proof is the same.â Id. Southwire Co. v. Cerro Wire LLC, 870 F.3d 1306, 1311 (Fed. Cir. 2017). Appellantâs mere assertion that quenching as disclosed in He differs from quenching in the claims is insufficient to distinguish claims 2 and 29 from He. We sustain the rejection of claims 2 and 29 over He as evidenced by Green. II. Rejection of claim 6 as obvious over He as evidenced by Green, and further in view of Babicki or alternatively, Makino Claim 6 depends from claim 5, which depends from claim 1. Appeal Br. 34 (Claims App.). Claim 5 recites, âwherein the mixture is heated in the reactor to a temperature of 400â700°C.â Id. at 33. Claim 6 recites, âwherein the mixture is heated in the reactor at a rate of 10â50°C/sec.â Id. at 34. The Examiner acknowledges that He as evidenced by Green does not disclose the heating rate, and relies on Babicki or Makino to teach this limitation. Final Act. 5. The Examiner determines that it would have been obvious to select the heating rate disclosed by Babicki or Makino âfor the benefit of obtaining the set temperature and to easily control the reaction.â Id.; Ans. 10. Appellant argues that one of ordinary skill in the art would not look to Babicki or Makino when determining a rate of heating within the reactor of He because the processes taught by Babicki and Makino are very different from Heâs process. Appeal Br. 25. Appellant argues that Babicki is directed to a fast pyrolysis process using biomass or solid feedstock, adds hydrogen (rather than water) to the reaction chamber, and is performed at low Appeal 2020-001113 Application 14/060,225 14 pressureâall different from He. Id. Appellant argues that Makino is directed to a hydrothermal reaction apparatus in the form of curved piping including a plurality of reactor units and injects hydrogen gas to restrict generation of cokes during the reaction process. Id. at 25â26. Appellant contends that the Examiner fails to address the differences between the references and He, how the references are relevant to Heâs process, and why one of ordinary skill would reasonably expect that using the heating rates from different processes would have been successful in He. We are not persuaded by Appellantâs argument. Claim 1 requires âthe mixture is subjected to heat and pressure at supercritical water conditions,â thus applying heat at some rate of heating is necessary. See Appeal Br. 33 (Claims App.). Babicki discloses rates of heating to temperature ranges that overlap those of claim 4. See Babicki ¶ 45. Makino discloses a desire to increase temperature quickly in order to instantaneously obtain the set temperature and easily control the reaction. Makino, col. 12, ll. 11â27. The Examinerâs explanation of the reasons a person of ordinary skill in the art would have had to combine the prior art teachings is sufficient when an allowance is made for âthe inferences and creative steps that a person of ordinary skill in the art would employ.â KSR Intâl Co. v. Teleflex Inc., 550 U.S. 398, 418 (2007). âAs long as some motivation or suggestion to combine the references is provided by the prior art taken as a whole, the law does not require that the references be combined for the reasons contemplated by the inventors.â In re Beattie, 974 F.2d 1309, 1312 (Fed. Cir. 1992). Moreover, â[t]he combination of familiar elements according to known methods is likely to be obvious when it does no more than yield predictable results.â KSR, 550 U.S. at 416. The recited Appeal 2020-001113 Application 14/060,225 15 heating rate is no more than the predictable use of prior art elements according to their established functions. Id. We sustain the rejection of claim 6. III. Rejection of claim 9 as obvious over He as evidenced by Green, and further in view of Vavruska Claim 9 depends from claim 1 and recites, âwherein the reactor is configured to maintain a turbulent flow of the mixture and achieve a Reynolds Number greater than 10,000.â Appeal Br. 34 (Claims App.). The Examiner finds that He teaches turbulent flow is required in order to avoid precipitation. Final Act. 6. The Examiner finds that Vavruska teaches a similar process in which Reynolds Numbers of up to 30,000 are used to create turbulent flow and provide intimate mixing of steam and other reactants. Id. The Examiner determines that it would have been obvious to select a Reynolds Number such as that disclosed by Vavruska âfor the benefit of creating the turbulent flow required by He, and to provide intimate mixing of the reactants.â Id. Appellant argues that Vavruska operates in a steam environment, not a supercritical water/oil environment. Appeal Br. 27. Appellant also argues that He mixes in a separate mixer, not in a reactor, and fails to teach mixing anywhere near true turbulent flow. As discussed above, He as evidenced by Green discloses turbulent flow with a Reynolds Number of at least 2000, thus Appellantâs contention that He âfails to teach mixing anywhere near true turbulent flowâ is unpersuasive of reversible error. Appellantâs assertion that He mixes in a separate mixer, not in a reactor, does not address the limitations in claim 9. Appeal 2020-001113 Application 14/060,225 16 Claim 9 recites the reactor is âconfigured toâ maintain a turbulent flow, which is satisfied by He. The reactor is also âconfigured toâ achieve a Reynolds Number greater than 10,000, but need not maintain such Reynolds Number for any specified amount of time. Any achievement of the Reynolds Number satisfies the claim limitation. The Examiner finds that Vavruska shows that one of ordinary skill in the art would have a reasonable expectation of success in obtaining the claimed Reynolds Numbers. Ans. 10. Appellant fails to explain why the Examiner is incorrect, other than to argue that Vavruska does not operates in supercritical water/oil environment. We sustain the rejection of claim 9. IV. Rejection of claim 10 as obvious over He as evidenced by Green, and further in view of Allam Claim 10 depends from claim 1 and recitesâ including adding a homogeneous catalyst to the water or organic feedstock to enhance or target specific reactions, and wherein the catalyst is selected from the group consisting of metal oxides, compounds that form metal oxides, carbonates, sulfates, and transition metal salts.â Appeal Br. 34 (Claims App.). The Examiner finds that He teaches catalysts are permissible, and Allam teaches a similar process for conversion of hydrocarbons with supercritical water, using carbonate catalysts or metal catalysts. Final Act. 6. Appellant argues that Allam proposes adding carbonates to facilitate desulfurization of heavy hydrocarbon feedstock. Appeal Br. 27â28. Appellant contends that Allam is not at turbulent flow, and is a partial oxidation process, thus is a completely different process from He. Id. at 28. Appeal 2020-001113 Application 14/060,225 17 âAs long as some motivation or suggestion to combine the references is provided by the prior art taken as a whole, the law does not require that the references be combined for the reasons contemplated by the inventor.â In re Beattie, 974 F.2d 1309, 1312 (Fed. Cir. 1992). He discloses that use of added catalysts is permissible, but does not disclose any particular catalyst. He ¶ 42. One of ordinary skill in the art intending to employ a catalyst would reasonably investigate references related to conversion of hydrocarbonsâsuch as Allamâto determine an appropriate catalyst. We sustain the rejection of claim 10. V. Rejection of claims 16, 17, and 32â34 as obvious over He as evidenced by Green, and further in view of Tullio Claims 16, 17, and 32â34 depend directly or indirectly from claim 1 and recite limitations on the feedstock. Claim 16 recites, âwherein the feedstock comprises hydrocarbons obtained from Fischer-Tropsch processes, alkylation processes, oligomerization processes, polymerization processes, and/or biosynthetic processes.â Appeal Br. 35 (Claims App.). Claim 17 recites âwherein the feedstock comprises renewable plant oil comprising canola, soy bean, Carinata, and castor; waste vegetable oil; corn oil derived from distillers grains; animal tallow; algal oil; microbial oil; terpenes and other pine-related byproducts from tall oils; biosynthetic oils, and mixtures thereof.â Id. Claim 32 recites âwherein the organic feedstock is selected from the group consisting of Fischer-Tropsch wax; products of polymerization, alkylation or oligomerization processes; and waste plastics.â Id. at 37. Claim 33 recites, âwherein the organic feedstock is a renewable plant oil.â Id. Claim 34 depends from claim 33, and recites, âwherein the renewable plant oils comprise virgin plant oils, used cooking oil, yellow Appeal 2020-001113 Application 14/060,225 18 grease, brown grease, tallow, distillers corn oil, microbial oils and/or tall oil.â Id. The Examiner finds that Tullio teaches various feedstocks that include those of claims 16, 17, and 32â34. Final Act. 7. The Examiner determines that it would have been obvious to one of ordinary skill in the art to substitute Tullioâs feeds for those of He, as Tullio teaches that the disclosed feeds are suitable for a similar process for upgrading heavy oils with water under supercritical conditions. Id. Appellant argues that He is concerned with processing heavy feedstock having high asphaltene contents, thus one of ordinary skill in the art would not have been motivated to substitute the intermediate refinery streams of Tullio in He. Appellant also argues that Tullio fails to overcome the deficiencies of He. Appellantâs arguments are not persuasive. In an obviousness inquiry, we consider the prior art for all that it teaches and suggests to the skilled artisan. In re Lamberti, 545 F.2d 747, 750 (CCPA 1976) (â[A]ll disclosures of the prior art, including unpreferred embodiments, must be considered.â). He teaches any hydrocarbon can be suitably upgraded, thus is not limited to asphaltenes, thus the Examinerâs motivation for combining He and Tullio is acceptable. See Ans. 9. In addition, as discussed above, we do not find He deficient, and there is no need for Tullio to overcome any asserted deficiency. We sustain the rejection of claims 16, 17, and 32â34. VI. Rejection of claim 19 as obvious over He as evidenced by Green, and further in view of Makino and Weestra Appeal 2020-001113 Application 14/060,225 19 Claim 19 depends from claim 1 and recites, âwherein olefinic gas is produced as a byproduct and the process further comprising converting the olefinic byproduct gas to high-octane naphtha and/or heavier hydrocarbons by one of alkylation or oligomerization. Appeal Br. 36 (Claims App.). The Examiner relies on the findings regarding claim 1 and, in addition, finds that Makino teaches production of olefins and Weerstra teaches that refinery byproducts such as olefin gas may be subject to alkylation in order to obtain high octane products. Final Act. 7. Appellant argues that neither Makino nor Weerstra overcome the deficiencies of He. Appeal Br. 29. At least because we determine that He as evidenced by Green is not deficient in its teaching, we sustain the rejection of claim 19. VII. Rejection of claims 35 and 36 as obvious over He as evidenced by Green, and further in view of Babicki or alternatively, Makino, and further in view of Vavruska Claim 35 is independent and includes the limitations of claims 1, 5, and 6. Appeal Br. 33, 34, and 38 (Claims App.). Claim 36 depends from claim 35 and recites, âwherein the feedstock is a deasphalted feedstock. Id. at 38. The Examiner finds that the claims are obvious over He as evidenced by Green, further in view of Babicki or Makino, and further in view of Vavruska. Final Act. 8. Appellant repeats unpersuasive arguments made in relation to claim 1 (regarding He), claim 6 (regarding Babicki and Makino), and claim 9 (regarding Vavruska). See Appeal Br. 29â30. We sustain the rejection of claim 35 and 36. Appeal 2020-001113 Application 14/060,225 20 CONCLUSION The rejections of claims 1â12, 14, 16â20, and 26â37 under 35 U.S.C. § 103 is affirmed. DECISION SUMMARY In summary: Claim(s) Rejected 35 U.S.C. § Reference(s)/Basis Affirmed Reversed 1â5, 7, 8, 11, 12, 14, 18, 20, 26â 31, 37 103(a) He, Green 1â5, 7, 8, 11, 12, 14, 18, 20, 26â 31, 37 6 103(a) He, Green, Babicki, Makino 6 9 103(a) He, Green, Vavruska 9 10 103(a) He, Green, Allam 10 16, 17, 32â 34 103(a) He, Green, Tullio 16, 17, 32â 34 19 103(a) He, Green, Makino, Weestra 19 35, 36 103(a) He, Green, Babicki, Makino, Vavruska 35, 36 Overall Outcome 1â12,14, 16â20, 26â 37 TIME PERIOD FOR RESPONSE No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a). AFFIRMED Copy with citationCopy as parenthetical citation