Altaimano, Inc.Download PDFPatent Trials and Appeals BoardApr 1, 202014398682 - (D) (P.T.A.B. Apr. 1, 2020) Copy Citation UNITED STATES PATENT AND TRADEMARK OFFICE UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 14/398,682 11/03/2014 Mike Coleman ALTAIR-PES018US 3793 42640 7590 04/01/2020 Yudell Isidore PLLC 5145 RR 620N, Ste F110 Austin, TX 78732 EXAMINER SIDDIQUEE, MUHAMMAD S ART UNIT PAPER NUMBER 1723 NOTIFICATION DATE DELIVERY MODE 04/01/2020 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): Patents@yudellisidore.com eofficeaction@appcoll.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE ____________________ BEFORE THE PATENT TRIAL AND APPEAL BOARD ____________________ Ex parte MIKE COLEMAN and VESELIN MANEV ____________________ Appeal 2019-001915 Application 14/398,682 Technology Center 1700 ____________________ Before N. WHITNEY WILSON, BRIAN D. RANGE, and LILAN REN, Administrative Patent Judges. WILSON, Administrative Patent Judge. DECISION ON APPEAL Appellant1 appeals under 35 U.S.C. § 134(a) from the Examiner’s January 22, 2018 decision finally rejecting claims 1–5 and 8–37 (“Final Act.”). We have jurisdiction over the appeal under 35 U.S.C. § 6(b). An oral hearing was held on March 9, 2020. A transcript of that hearing will be part of the record. We affirm, but designate the affirmance as a new ground of rejection. 1 We use the word “Appellant” to refer to “applicant” as defined in 37 C.F.R. § 1.42. Appellant identifies AltairNano as the real party in interest (Appeal Br. 3). Appeal 2018-001915 Application 14/398,682 2 CLAIMED SUBJECT MATTER Appellant’s disclosure relates to improvements in lithium ion cell performance as a result of selection of specific formulation of electrolyte for lithium ion cells (Abstract). In particular, the claims recite lithium ion battery cells and electrolytes for such cells where the electrolyte is composed of at least one cyclic ester and at least one linear ester and one or more lithium salts where the lithium salt concentration exceeds the lithium salt concentration corresponding to maximum electrolyte ionic conductivity (Appeal Br. 3).2 Increasing the concentration of the lithium salt in the electrolyte beyond the optimal salt concentration is said to lead to an increase in cell capacity, improvement in capacity retention, increase the cell rate capability and increase in cell mean and discharge voltages (id.). Details of the claimed invention are set forth in representative claims 1 and 11, which are reproduced below from the Claims Appendix to the Appeal Brief (emphasis added): 1. An electrolyte for a lithium ion battery with a Li4Ti5O12 compound as a negative electrode comprising at least one cyclic ester and at least one linear ester and a lithium salt wherein the lithium salt concentration exceeds the lithium salt concentration corresponding to maximum electrolyte ionic conductivity. 11. The lithium ion cell comprising at least one Li4Ti5O12 compound as a negative electrode and at least one lithiated transition metal oxide or lithiated transition metal phosphate as positive electrode, a separator and a non-aqueous electrolyte comprising a LiPF6 salt dissolved in a mixture of ethylene 2 We note that pages of the Appeal Brief were not numbered. The page numbers of the Appeal Brief referenced herein are based on the page with the case caption being assigned page number 1. Appeal 2018-001915 Application 14/398,682 3 carbonate and ethyl methyl carbonate solvents wherein the concentration of the said LiPF6 salt is equal or higher than 1.4 M. REJECTIONS 1. Claims 1–5 and 11–14 are rejected under 35 U.S.C. § 103(a) as unpatentable over Wagner.3 2. Claims 8–10 are rejected under 35 U.S.C. § 103(a) as unpatentable over Wagner in view of Xiao.4 3. Claims 15, 16, 18–25, 31, and 32 are rejected under 35 U.S.C. § 103(a) as unpatentable over Wagner in view of Xiao. 4. Claim 17 is rejected under 35 U.S.C. § 103(a) as unpatentable over Wagner in view of Xiao, and further in view of Ahn.5 5. Claims 26 and 27 are rejected under 35 U.S.C. § 103(a) as unpatentable over Wagner in view of Xiao, and further in view of Lee.6 6. Claims 28 and 30 are rejected under 35 U.S.C. § 103(a) as unpatentable over Wagner in view of Xiao, and further in view of Gao.7 7. Claim 29 is rejected under 35 U.S.C. § 103(a) as unpatentable over Wagner in view of Inagaki.8 3 Wagner, WO 2011/043934 A2, published April 14, 2011. Appellant and the Examiner – and the Board – make reference to the US counterpart publication – US 2012/0172613 A1, published July 5, 2012. 4 Xiao et al., US 2006/0147808 A1, published July 6, 2006. 5 Ahn et al., US 2007/0092802 A1, published April 26, 2007. 6 Lee et al., US 2011/0195308 A1, published August 11, 2011. 7 Gao et al., US 2011/0236299 A1, published September 29, 2011. 8 Inagaki et al., US 2007/0009798 A1, published January 11, 2007. Appeal 2018-001915 Application 14/398,682 4 6. Claims 33–37 are rejected under 35 U.S.C. § 103(a) as unpatentable over Wagner in view of Xiao and Abe.9 DISCUSSION Appellant does not dispute that Wagner discloses electrolytes and lithium ion cells which contain the claimed components in amounts which either encompass or overlap the claimed ranges (Appeal Br. 11). However, Appellant maintains that the ranges set forth in its claims are critical, and impart patentability to the claims (id.). Appellant summarizes its argument seeking reversal of the obviousness rejections as follows: The Appellants have, in fact, demonstrated throughout the specification, in particular the Examples and Figures, that the range of salt is a critical feature of the instantly claimed formulations (see, e.g., MPEP § 2144.05(11)(A) (“Generally, differences in concentration or temperature will not support the patentability of subject matter encompassed by the prior art unless there is evidence indicating such concentration or temperature is critical.”) As previously cited, the range of 1.0- 1.2 M LiPF6 salt is the industry standard for maximum conductance in the cell electrolyte. Surprisingly, however, a higher concentration of the lithium salt (e.g. LiPF6 salt) in the electrolyte solution results in a better cell rate capability than cells activated with electrolyte with LiPF6 salt concentration corresponding to its maximum ionic conductivity of about lM. Wagner does not indicate that the range of the Li salt is critical and relates to being above the optimal salt concentration. The range disclosed in Wagner would not work in the compositions of the present invention. Wagner discloses that the lithium salt can be in the range of 0.5 moles/liter to 3.0 moles/liter. In the present invention the lithium salt concentration must exceed the lithium salt concentration corresponding to maximum electrolyte ionic conductivity. 9 Abe et al., US 2004/0013946 A1, published January 22, 2004. Appeal 2018-001915 Application 14/398,682 5 (Appeal Br. 11–12). Appellant argues that the prior art did not teach or suggest the high concentration of LiPF6 recited in the claims, and that data presented in the Specification shows that this high concentration of the lithium salt “beyond the maximum electrolyte ionic conductivity leads to the improvement of rate capability, maximizes cell capacity, increases cell charge and discharge voltage and improves capacity retention.” (Appeal Br. 12). It is well established that Appellant has the burden of showing unexpected results. In re Freeman, 474 F.2d 1318, 1324 (CCPA 1973); In re Klosak, 455 F.2d 1077, 1080 (CCPA 1972). The burden requires Appellant to proffer factual evidence that actually shows unexpected results relative to the closest prior art, see In re Baxter Travenol Labs., 952 F.2d 388, 392 (Fed. Cir. 1991), and that is reasonably commensurate in scope with the protection sought, In re Grasselli, 713 F.2d 731, 743 (Fed. Cir. 1983); In re Clemens, 622 F.2d 1029, 1035 (CCPA 1980); In re Hyson, 453 F.2d 764, 786 (CCPA 1972). The extent of the showing relied upon by Appellant must reasonably support the entire scope of the claims at issue. See In re Harris, 409 F.3d 1339, 1344 (Fed. Cir. 2005). In this instance, claim 1 covers a very wide range of possible compounds in the electrolyte, as well as any possible compound as the positive electrode, and any lithium salt (Spec. ¶¶ 19 (lithium salts), 22 (solvents). However, the data relied on by Appellant is limited to batteries which use ethylene carbonate (EC) and ethyl methyl carbonate (EMC) as their solvents, LiPF6 as the lithium salt, and one example also uses 1,3- propane sultone as an additive (Spec. ¶¶ 8–12) . Thus, the examples and data relied upon by Appellant do not account for the myriad of possible Appeal 2018-001915 Application 14/398,682 6 compositions which would fall within the limitations of claim 1, in particular the use of different solvents, different positive electrodes, and different lithium ions. Accordingly, even if the showing were otherwise sufficient to overcome the prima facie of obviousness – a question we need not and do not reach – it is not commensurate in scope with claim 1. Accordingly, Appellant has not demonstrated reversible error in the rejection of claim 1. With regards to the remaining independent claims, as noted by the Examiner (Ans. 14), Appellant only explicitly argues against claim 1 (see Appeal Br. 8). However, Appellant does make arguments specific to some of the additional limitations set forth in the other independent claims, such as the use of LiPF6 as the lithium ion, the use of an EC/EMC solvent mixture, and the use of sultones as an additional additive. Therefore, while it might be appropriate to conclude that Appellant waived its arguments with respect to claims other than claim 1, we need not reach such a conclusion. For the general reasons outlined above, the data relied upon by Appellant as showing unexpected results is not commensurate in scope with the remaining independent claims. In particular, the data relied on by Appellant is not commensurate in scope with (1) the possible range of positive electrodes, which can be any lithiated transition metal oxide or lithiated transition metal phosphate (claims 11, 13, 15, 18, 21), (2) many different organic carbonate cyclic esters and organic carbonate linear esters in the solvent (claims 13, 18), or also various electrolytic additives (claims 18 and 21). Accordingly, we determine that Appellant has not demonstrated reversible error in the rejections on appeal. If prosecution resumes, Appeal 2018-001915 Application 14/398,682 7 Appellant, for example, may seek to amend the claims such that they are commensurate in scope with the data presented or may present additional data to support the patentability of the claims on appeal. Because our reasoning for sustaining the rejection substantially expands upon the Examiner’s reasoning, we designate this decision as a new ground of rejection pursuant to 37 C.F.R. § 41.50(b). 37 C.F.R. § 41.50(b) provides “[a] new ground of rejection pursuant to this paragraph shall not be considered final for judicial review.” Section 41.50(b) also provides: When the Board enters such a non-final decision, the appellant, within two months from the date of the decision, must exercise one of the following two options with respect to the new ground of rejection to avoid termination of the appeal as to the rejected claims: (1) Reopen prosecution. Submit an appropriate amendment of the claims so rejected or new Evidence relating to the claims so rejected, or both, and have the matter reconsidered by the examiner, in which event the prosecution will be remanded to the examiner. The new ground of rejection is binding upon the examiner unless an amendment or new Evidence not previously of Record is made which, in the opinion of the examiner, overcomes the new ground of rejection designated in the decision. Should the examiner reject the claims, appellant may again appeal to the Board pursuant to this subpart. (2) Request rehearing. Request that the proceeding be reheard under § 41.52 by the Board upon the same Record. The request for rehearing must address any new ground of rejection and state with particularity the points believed to have been misapprehended or overlooked in entering the new ground of rejection and also state all other grounds upon which rehearing is sought. Appeal 2018-001915 Application 14/398,682 8 Further guidance on responding to a new ground of rejection can be found in the Manual of Patent Examining Procedure § 1214.01. CONCLUSION In summary: Claims Rejected 35 U.S.C. § References(s)/Basis Affirmed Reversed 1–5, 11–14 103(a) Wagner 1–5, 11–14 8–10 103(a) Wagner, Xiao 8–10 15, 16, 18– 25, 31, 32 103(a) Wagner, Xiao 15, 16, 18– 25, 31, 32 17 103(a) Wagner, Xiao, Ahn 17 26, 27 103(a) Wagner, Xiao, Lee 26, 27 28, 30 103(a) Wagner, Xiao, Gao 28, 30 29 103(a) Wagner, Inagaki 29 33–37 103(a) Wagner, Xiao, Abe 33–37 Overall Outcome 1–5, 8–37 No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a). See 37 C.F.R. § 1.136(a)(1)(iv). AFFIRMED, DESIGNATED AS NEW GROUND OF REJECTION Copy with citationCopy as parenthetical citation