Table 1 to Paragraph (c)-Organic Peroxide Table
Technical name | ID No. | Concentration (mass %) | Diluent (mass %) | Water (mass %) | Packing method | Temperature ( °C) | Notes | |||
A | B | I | Control | Emergency | ||||||
(1) | (2) | (3) | (4a) | (4b) | (4c) | (5) | (6) | (7a) | (7b) | (8) |
Acetyl acetone peroxide | UN3105 | [LESS THAN EQUAL TO]42 | [GREATER THAN EQUAL TO]48 | [GREATER THAN EQUAL TO]8 | OP7 | 2 | ||||
Acetyl acetone peroxide | UN3107 | [LESS THAN EQUAL TO]35 | [GREATER THAN EQUAL TO]8 | OP8 | 32 | |||||
Acetyl acetone peroxide [as a paste] | UN3106 | [LESS THAN EQUAL TO]32 | OP7 | 21 | ||||||
Acetyl cyclohexanesulfonyl peroxide | UN3112 | [LESS THAN EQUAL TO]82 | [GREATER THAN EQUAL TO]12 | OP4 | -10 | 0 | ||||
Acetyl cyclohexanesulfonyl peroxide | UN3115 | [LESS THAN EQUAL TO]32 | [GREATER THAN EQUAL TO]68 | OP7 | -10 | 0 | ||||
tert-Amyl hydroperoxide | UN3107 | [LESS THAN EQUAL TO]88 | [GREATER THAN EQUAL TO]6 | [GREATER THAN EQUAL TO]6 | OP8 | |||||
tert-Amyl peroxyacetate | UN3105 | [LESS THAN EQUAL TO]62 | [GREATER THAN EQUAL TO]38 | OP7 | ||||||
tert-Amyl peroxybenzoate | UN3103 | [LESS THAN EQUAL TO]100 | OP5 | |||||||
tert-Amyl peroxy-2-ethylhexanoate | UN3115 | [LESS THAN EQUAL TO]100 | OP7 | 20 | 25 | |||||
tert-Amyl peroxy-2-ethylhexyl carbonate | UN3105 | [LESS THAN EQUAL TO]100 | OP7 | |||||||
tert-Amyl peroxy isopropyl carbonate | UN3103 | [LESS THAN EQUAL TO]77 | [GREATER THAN EQUAL TO]23 | OP5 | ||||||
tert-Amyl peroxyneodecanoate | UN3115 | [LESS THAN EQUAL TO]77 | [GREATER THAN EQUAL TO]23 | OP7 | 0 | 10 | ||||
tert-Amyl peroxyneodecanoate | UN3119 | [LESS THAN EQUAL TO]47 | [GREATER THAN EQUAL TO]53 | OP8 | 0 | 10 | ||||
tert-Amyl peroxypivalate | UN3113 | [LESS THAN EQUAL TO]77 | [GREATER THAN EQUAL TO]23 | OP5 | 10 | 15 | ||||
tert-Amyl peroxypivalate | UN3119 | [LESS THAN EQUAL TO]32 | [GREATER THAN EQUAL TO]68 | OP8 | 10 | 15 | ||||
tert-Amyl peroxy-3,5,5-trimethylhexanoate | UN3105 | [LESS THAN EQUAL TO]100 | OP7 | |||||||
tert-Butyl cumyl peroxide | UN3109 | [GREATER THAN]42-100 | OP8 | 9 | ||||||
tert-Butyl cumyl peroxide | UN3108 | [LESS THAN EQUAL TO]52 | [GREATER THAN EQUAL TO]48 | OP8 | 9 | |||||
n-Butyl-4,4-di-(tert-butylperoxy)valerate | UN3103 | [GREATER THAN]52-100 | OP5 | |||||||
n-Butyl-4,4-di-(tert-butylperoxy)valerate | UN3108 | [LESS THAN EQUAL TO]52 | [GREATER THAN EQUAL TO]48 | OP8 | ||||||
tert-Butyl hydroperoxide | UN3103 | [GREATER THAN]79-90 | [GREATER THAN EQUAL TO]10 | OP5 | 13 | |||||
tert-Butyl hydroperoxide | UN3105 | [LESS THAN EQUAL TO]80 | [GREATER THAN EQUAL TO]20 | OP7 | 4, 13 | |||||
tert-Butyl hydroperoxide | UN3107 | [LESS THAN EQUAL TO]79 | [GREATER THAN]14 | OP8 | 13, 16 | |||||
tert-Butyl hydroperoxide | UN3109 | [LESS THAN EQUAL TO]72 | [GREATER THAN EQUAL TO]28 | OP8 | 13 | |||||
tert-Butyl hydroperoxide [and] Di-tert-butylperoxide | UN3103 | [LESS THAN]82 + [GREATER THAN]9 | [GREATER THAN EQUAL TO]7 | OP5 | 13 | |||||
tert-Butyl monoperoxymaleate | UN3102 | [GREATER THAN]52-100 | OP5 | |||||||
tert-Butyl monoperoxymaleate | UN3103 | [LESS THAN EQUAL TO]52 | [GREATER THAN EQUAL TO]48 | OP6 | ||||||
tert-Butyl monoperoxymaleate | UN3108 | [LESS THAN EQUAL TO]52 | [GREATER THAN EQUAL TO]48 | OP8 | ||||||
tert-Butyl monoperoxymaleate [as a paste] | UN3108 | [LESS THAN EQUAL TO]52 | OP8 | |||||||
tert-Butyl peroxyacetate | UN3101 | [GREATER THAN]52-77 | [GREATER THAN EQUAL TO]23 | OP5 | ||||||
tert-Butyl peroxyacetate | UN3103 | [GREATER THAN]32-52 | [GREATER THAN EQUAL TO]48 | OP6 | ||||||
tert-Butyl peroxyacetate | UN3109 | [LESS THAN EQUAL TO]32 | [GREATER THAN EQUAL TO]68 | OP8 | ||||||
tert-Butyl peroxybenzoate | UN3103 | [GREATER THAN]77-100 | OP5 | |||||||
tert-Butyl peroxybenzoate | UN3105 | [GREATER THAN]52-77 | [GREATER THAN EQUAL TO]23 | OP7 | 1 | |||||
tert-Butyl peroxybenzoate | UN3106 | [LESS THAN EQUAL TO]52 | [GREATER THAN EQUAL TO]48 | OP7 | ||||||
tert-Butyl peroxybenzoate | UN3109 | [LESS THAN EQUAL TO]32 | [GREATER THAN EQUAL TO]68 | OP8 | ||||||
tert-Butyl peroxybutyl fumarate | UN3105 | [LESS THAN EQUAL TO]52 | [GREATER THAN EQUAL TO]48 | OP7 | ||||||
tert-Butyl peroxycrotonate | UN3105 | [LESS THAN EQUAL TO]77 | [GREATER THAN EQUAL TO]23 | OP7 | ||||||
tert-Butyl peroxydiethylacetate | UN3113 | [LESS THAN EQUAL TO]100 | OP5 | 20 | 25 | |||||
tert-Butyl peroxy-2-ethylhexanoate | UN3113 | [GREATER THAN]52-100 | OP6 | 20 | 25 | |||||
tert-Butyl peroxy-2-ethylhexanoate | UN3117 | [GREATER THAN]32-52 | [GREATER THAN EQUAL TO]48 | OP8 | 30 | 35 | ||||
tert-Butyl peroxy-2-ethylhexanoate | UN3118 | [LESS THAN EQUAL TO]52 | [GREATER THAN EQUAL TO]48 | OP8 | 20 | 25 | ||||
tert-Butyl peroxy-2-ethylhexanoate | UN3119 | [LESS THAN EQUAL TO]32 | [GREATER THAN EQUAL TO]68 | OP8 | 40 | 45 | ||||
tert-Butyl peroxy-2-ethylhexanoate [and] 2,2-di-(tert-Butylperoxy)butane | UN3106 | [LESS THAN EQUAL TO]12 + [LESS THAN EQUAL TO]14 | [GREATER THAN EQUAL TO]14 | [GREATER THAN EQUAL TO]60 | OP7 | |||||
tert-Butyl peroxy-2-ethylhexanoate [and] 2,2-di-(tert-Butylperoxy)butane | UN3115 | [LESS THAN EQUAL TO]31 + [LESS THAN EQUAL TO]36 | [GREATER THAN EQUAL TO]33 | OP7 | 35 | 40 | ||||
tert-Butyl peroxy-2-ethylhexylcarbonate | UN3105 | [LESS THAN EQUAL TO]100 | OP7 | |||||||
tert-Butyl peroxyisobutyrate | UN3111 | [GREATER THAN]52-77 | [GREATER THAN EQUAL TO]23 | OP5 | 15 | 20 | ||||
tert-Butyl peroxyisobutyrate | UN3115 | [LESS THAN EQUAL TO]52 | [GREATER THAN EQUAL TO]48 | OP7 | 15 | 20 | ||||
tert-Butylperoxy isopropylcarbonate | UN3103 | [LESS THAN EQUAL TO]77 | [GREATER THAN EQUAL TO]23 | OP5 | ||||||
tert-Butylperoxy isopropylcarbonate | UN3105 | [LESS THAN EQUAL TO]62 | [GREATER THAN EQUAL TO]38 | OP7 | ||||||
1-(2-tert-Butylperoxy isopropyl)-3-isopropenylbenzene | UN3105 | [LESS THAN EQUAL TO]77 | [GREATER THAN EQUAL TO]23 | OP7 | ||||||
1-(2-tert-Butylperoxy isopropyl)-3-isopropenylbenzene | UN3108 | [LESS THAN EQUAL TO]42 | [GREATER THAN EQUAL TO]58 | OP8 | ||||||
tert-Butyl peroxy-2-methylbenzoate | UN3103 | [LESS THAN EQUAL TO]100 | OP5 | |||||||
tert-Butyl peroxyneodecanoate | UN3115 | [GREATER THAN]77-100 | OP7 | -5 | 5 | |||||
tert-Butyl peroxyneodecanoate | UN3115 | [LESS THAN EQUAL TO]77 | [GREATER THAN EQUAL TO]23 | OP7 | 0 | 10 | ||||
tert-Butyl peroxyneodecanoate [as a stable dispersion in water] | UN3119 | [LESS THAN EQUAL TO]52 | OP8 | 0 | 10 | |||||
tert-Butyl peroxyneodecanoate [as a stable dispersion in water (frozen)] | UN3118 | [LESS THAN EQUAL TO]42 | OP8 | 0 | 10 | |||||
tert-Butyl peroxyneodecanoate | UN3119 | [LESS THAN EQUAL TO]32 | [GREATER THAN EQUAL TO]68 | OP8 | 0 | 10 | ||||
tert-Butyl peroxyneoheptanoate | UN3115 | [LESS THAN EQUAL TO]77 | [GREATER THAN EQUAL TO]23 | OP7 | 0 | 10 | ||||
tert-Butyl peroxyneoheptanoate [as a stable dispersion in water] | UN3117 | [LESS THAN EQUAL TO]42 | OP8 | 0 | 10 | |||||
tert-Butyl peroxypivalate | UN3113 | [GREATER THAN]67-77 | [GREATER THAN EQUAL TO]23 | OP5 | 0 | 10 | ||||
tert-Butyl peroxypivalate | UN3115 | [GREATER THAN]27-67 | [GREATER THAN EQUAL TO]33 | OP7 | 0 | 10 | ||||
tert-Butyl peroxypivalate | UN3119 | [LESS THAN EQUAL TO]27 | [GREATER THAN EQUAL TO]73 | OP8 | 30 | 35 | ||||
tert-Butylperoxy stearylcarbonate | UN3106 | [LESS THAN EQUAL TO]100 | OP7 | |||||||
tert-Butyl peroxy-3,5,5-trimethylhexanoate | UN3105 | [GREATER THAN]37-100 | OP7 | |||||||
tert-Butyl peroxy-3,5,5-trimethlyhexanoate | UN3106 | [LESS THAN EQUAL TO]42 | [GREATER THAN EQUAL TO]58 | OP7 | ||||||
tert-Butyl peroxy-3,5,5-trimethylhexanoate | UN3109 | [LESS THAN EQUAL TO]37 | [GREATER THAN EQUAL TO]63 | OP8 | ||||||
3-Chloroperoxybenzoic acid | UN3102 | [GREATER THAN]57-86 | [GREATER THAN EQUAL TO]14 | OP1 | ||||||
3-Chloroperoxybenzoic acid | UN3106 | [LESS THAN EQUAL TO]57 | [GREATER THAN EQUAL TO]3 | [GREATER THAN EQUAL TO]40 | OP7 | |||||
3-Chloroperoxybenzoic acid | UN3106 | [LESS THAN EQUAL TO]77 | [GREATER THAN EQUAL TO]6 | [GREATER THAN EQUAL TO]17 | OP7 | |||||
Cumyl hydroperoxide | UN3107 | [GREATER THAN]90-98 | [LESS THAN EQUAL TO]10 | OP8 | 13 | |||||
Cumyl hydroperoxide | UN3109 | [LESS THAN EQUAL TO]90 | [GREATER THAN EQUAL TO]10 | OP8 | 13, 15 | |||||
Cumyl peroxyneodecanoate | UN3115 | [LESS THAN EQUAL TO]87 | [GREATER THAN EQUAL TO]13 | OP7 | -10 | 0 | ||||
Cumyl peroxyneodecanoate | UN3115 | [LESS THAN EQUAL TO]77 | [GREATER THAN EQUAL TO]23 | OP7 | -10 | 0 | ||||
Cumyl peroxyneodecanoate [as a stable dispersion in water] | UN3119 | [LESS THAN EQUAL TO]52 | OP8 | -10 | 0 | |||||
Cumyl peroxyneoheptanoate | UN3115 | [LESS THAN EQUAL TO]77 | [GREATER THAN EQUAL TO]23 | OP7 | -10 | 0 | ||||
Cumyl peroxypivalate | UN3115 | [LESS THAN EQUAL TO]77 | [GREATER THAN EQUAL TO]23 | OP7 | -5 | 5 | ||||
Cyclohexanone peroxide(s) | UN3104 | [LESS THAN EQUAL TO]91 | [GREATER THAN EQUAL TO]9 | OP6 | 13 | |||||
Cyclohexanone peroxide(s) | UN3105 | [LESS THAN EQUAL TO]72 | [GREATER THAN EQUAL TO]28 | OP7 | 5 | |||||
Cyclohexanone peroxide(s) [as a paste] | UN3106 | [LESS THAN EQUAL TO]72 | OP7 | 5, 21 | ||||||
Cyclohexanone peroxide(s) | Exempt | [LESS THAN EQUAL TO]32 | [GREATER THAN]68 | Exempt | 29 | |||||
Diacetone alcohol peroxides | UN3115 | [LESS THAN EQUAL TO]57 | [GREATER THAN EQUAL TO]26 | [GREATER THAN EQUAL TO]8 | OP7 | 40 | 45 | 5 | ||
Diacetyl peroxide | UN3115 | [LESS THAN EQUAL TO]27 | [GREATER THAN EQUAL TO]73 | OP7 | 20 | 25 | 8, 13 | |||
Di-tert-amyl peroxide | UN3107 | [LESS THAN EQUAL TO]100 | OP8 | |||||||
([3R- (3R, 5aS, 6S, 8aS, 9R, 10R, 12S, 12aR**)]-Decahydro-10-methoxy-3, 6, 9-trimethyl-3, 12-epoxy-12H-pyrano [4, 3- j]-1, 2-benzodioxepin) | UN3106 | [LESS THAN EQUAL TO]100 | OP7 | |||||||
2,2-Di-(tert-amylperoxy)-butane | UN3105 | [LESS THAN EQUAL TO]57 | [GREATER THAN EQUAL TO]43 | OP7 | ||||||
1,1-Di-(tert-amylperoxy)cyclohexane | UN3103 | [LESS THAN EQUAL TO]82 | [GREATER THAN EQUAL TO]18 | OP6 | ||||||
Dibenzoyl peroxide | UN3102 | [GREATER THAN]52-100 | [LESS THAN EQUAL TO]48 | OP2 | 3 | |||||
Dibenzoyl peroxide | UN3102 | [GREATER THAN]77-94 | [GREATER THAN EQUAL TO]6 | OP4 | 3 | |||||
Dibenzoyl peroxide | UN3104 | [LESS THAN EQUAL TO]77 | [GREATER THAN EQUAL TO]23 | OP6 | ||||||
Dibenzoyl peroxide | UN3106 | [LESS THAN EQUAL TO]62 | [GREATER THAN EQUAL TO]28 | [GREATER THAN EQUAL TO]10 | OP7 | |||||
Dibenzoyl peroxide [as a paste] | UN3106 | [GREATER THAN]52-62 | OP7 | 21 | ||||||
Dibenzoyl peroxide | UN3106 | [GREATER THAN]35-52 | [GREATER THAN EQUAL TO]48 | OP7 | ||||||
Dibenzoyl peroxide | UN3107 | [GREATER THAN]36-42 | [GREATER THAN EQUAL TO]18 | [LESS THAN EQUAL TO]40 | OP8 | |||||
Dibenzoyl peroxide [as a paste] | UN3108 | [LESS THAN EQUAL TO]56.5 | [GREATER THAN EQUAL TO]15 | OP8 | ||||||
Dibenzoyl peroxide [as a paste] | UN3108 | [LESS THAN EQUAL TO]52 | OP8 | 21 | ||||||
Dibenzoyl peroxide [as a stable dispersion in water] | UN3109 | [LESS THAN EQUAL TO]42 | OP8 | |||||||
Dibenzoyl peroxide | Exempt | [LESS THAN EQUAL TO]35 | [GREATER THAN EQUAL TO]65 | Exempt | 29 | |||||
Di-(4-tert-butylcyclohexyl)peroxydicarbonate | UN3114 | [LESS THAN EQUAL TO]100 | OP6 | 30 | 35 | |||||
Di-(4-tert-butylcyclohexyl)peroxydicarbonate [as a stable dispersion in water] | UN3119 | [LESS THAN EQUAL TO]42 | OP8 | 30 | 35 | |||||
Di-(4-tert-butylcyclohexyl)peroxydicarbonate [as a paste] | UN3118 | [LESS THAN EQUAL TO]42 | OP8 | 35 | 40 | |||||
Di-tert-butyl peroxide | UN3107 | [GREATER THAN]52-100 | OP8 | |||||||
Di-tert-butyl peroxide | UN3109 | [LESS THAN EQUAL TO]52 | [GREATER THAN EQUAL TO]48 | OP8 | 24 | |||||
Di-tert-butyl peroxyazelate | UN3105 | [LESS THAN EQUAL TO]52 | [GREATER THAN EQUAL TO]48 | OP7 | ||||||
2,2-Di-(tert-butylperoxy)butane | UN3103 | [LESS THAN EQUAL TO]52 | [GREATER THAN EQUAL TO]48 | OP6 | ||||||
1,6-Di-(tert-butylperoxycarbonyloxy)hexane | UN3103 | [LESS THAN EQUAL TO]72 | [GREATER THAN EQUAL TO]28 | OP5 | ||||||
1,1-Di-(tert-butylperoxy)cyclohexane | UN3101 | [GREATER THAN]80-100 | OP5 | |||||||
1,1-Di-(tert-butylperoxy)cyclohexane | UN3103 | [GREATER THAN]52-80 | [GREATER THAN EQUAL TO]20 | OP5 | ||||||
1,1-Di-(tert-butylperoxy)-cyclohexane | UN3103 | [LESS THAN EQUAL TO]72 | [GREATER THAN EQUAL TO]28 | OP5 | 30 | |||||
1,1-Di-(tert-butylperoxy)cyclohexane | UN3105 | [GREATER THAN]42-52 | [GREATER THAN EQUAL TO]48 | OP7 | ||||||
1,1-Di-(tert-butylperoxy)cyclohexane | UN3106 | [LESS THAN EQUAL TO]42 | [GREATER THAN EQUAL TO]13 | [GREATER THAN EQUAL TO]45 | OP7 | |||||
1,1-Di-(tert-butylperoxy)cyclohexane | UN3107 | [LESS THAN EQUAL TO]27 | [GREATER THAN EQUAL TO]25 | OP8 | 22 | |||||
1,1-Di-(tert-butylperoxy)cyclohexane | UN3109 | [LESS THAN EQUAL TO]42 | [GREATER THAN EQUAL TO]58 | OP8 | ||||||
1,1-Di-(tert-Butylperoxy) cyclohexane | UN3109 | [LESS THAN EQUAL TO]37 | [GREATER THAN EQUAL TO]63 | OP8 | ||||||
1,1-Di-(tert-butylperoxy)cyclohexane | UN3109 | [LESS THAN EQUAL TO]25 | [GREATER THAN EQUAL TO]25 | [GREATER THAN EQUAL TO]50 | OP8 | |||||
1,1-Di-(tert-butylperoxy)cyclohexane | UN3109 | [LESS THAN EQUAL TO]13 | [GREATER THAN EQUAL TO]13 | [GREATER THAN EQUAL TO]74 | OP8 | |||||
1,1-Di-(tert-butylperoxy)cyclohexane + tert-Butyl peroxy-2-ethylhexanoate | UN3105 | [LESS THAN EQUAL TO]43+[LESS THAN EQUAL TO]16 | [GREATER THAN EQUAL TO]41 | OP7 | ||||||
Di-n-butyl peroxydicarbonate | UN3115 | [GREATER THAN]27-52 | [GREATER THAN EQUAL TO]48 | OP7 | -15 | -5 | ||||
Di-n-butyl peroxydicarbonate | UN3117 | [LESS THAN EQUAL TO]27 | [GREATER THAN EQUAL TO]73 | OP8 | -10 | 0 | ||||
Di-n-butyl peroxydicarbonate [as a stable dispersion in water (frozen)] | UN3118 | [LESS THAN EQUAL TO]42 | OP8 | -15 | -5 | |||||
Di-sec-butyl peroxydicarbonate | UN3113 | [GREATER THAN]52-100 | OP4 | -20 | -10 | 6 | ||||
Di-sec-butyl peroxydicarbonate | UN3115 | [LESS THAN EQUAL TO]52 | [GREATER THAN EQUAL TO]48 | OP7 | -15 | -5 | ||||
Di-(tert-butylperoxyisopropyl) benzene(s) | UN3106 | [GREATER THAN]42-100 | [LESS THAN EQUAL TO]57 | OP7 | 1, 9 | |||||
Di-(tert-butylperoxyisopropyl) benzene(s) | Exempt | [LESS THAN EQUAL TO]42 | [GREATER THAN EQUAL TO]58 | Exempt | ||||||
Di-(tert-butylperoxy)phthalate | UN3105 | [GREATER THAN]42-52 | [GREATER THAN EQUAL TO]48 | OP7 | ||||||
Di-(tert-butylperoxy)phthalate [as a paste] | UN3106 | [LESS THAN EQUAL TO]52 | OP7 | 21 | ||||||
Di-(tert-butylperoxy)phthalate | UN3107 | [LESS THAN EQUAL TO]42 | [GREATER THAN EQUAL TO]58 | OP8 | ||||||
2,2-Di-(tert-butylperoxy)propane | UN3105 | [LESS THAN EQUAL TO]52 | [GREATER THAN EQUAL TO]48 | OP7 | ||||||
2,2-Di-(tert-butylperoxy)propane | UN3106 | [LESS THAN EQUAL TO]42 | [GREATER THAN EQUAL TO]13 | [GREATER THAN EQUAL TO]45 | OP7 | |||||
1,1-Di-(tert-butylperoxy)-3,3,5-trimethylcyclohexane | UN3101 | [GREATER THAN]90-100 | OP5 | |||||||
1,1-Di-(tert-butylperoxy)-3,3,5-trimethylcyclohexane | UN3103 | [GREATER THAN]57-90 | [GREATER THAN EQUAL TO]10 | OP5 | ||||||
1,1-Di-(tert-butylperoxy)-3,3,5-trimethylcyclohexane | UN3103 | [LESS THAN EQUAL TO]77 | [GREATER THAN EQUAL TO]23 | OP5 | ||||||
1,1-Di-(tert-butylperoxy)-3,3,5-trimethylcyclohexane | UN3103 | [LESS THAN EQUAL TO]90 | [GREATER THAN EQUAL TO]10 | OP5 | 30 | |||||
1,1-Di-(tert-butylperoxy)-3,3,5-trimethylcyclohexane | UN3110 | [LESS THAN EQUAL TO]57 | [GREATER THAN EQUAL TO]43 | OP8 | ||||||
1,1-Di-(tert-butylperoxy)-3,3,5-trimethylcyclohexane | UN3107 | [LESS THAN EQUAL TO]57 | [GREATER THAN EQUAL TO]43 | OP8 | ||||||
1,1-Di-(tert-butylperoxy)-3,3,5-trimethylcyclohexane | UN3107 | [LESS THAN EQUAL TO]32 | [GREATER THAN EQUAL TO]26 | [GREATER THAN EQUAL TO]42 | OP8 | |||||
Dicetyl peroxydicarbonate | UN3120 | [LESS THAN EQUAL TO]100 | OP8 | 30 | 35 | |||||
Dicetyl peroxydicarbonate [as a stable dispersion in water] | UN3119 | [LESS THAN EQUAL TO]42 | OP8 | 30 | 35 | |||||
Di-4-chlorobenzoyl peroxide | UN3102 | [LESS THAN EQUAL TO]77 | [GREATER THAN EQUAL TO]23 | OP5 | ||||||
Di-4-chlorobenzoyl peroxide | Exempt | [LESS THAN EQUAL TO]32 | [GREATER THAN EQUAL TO]68 | Exempt | 29 | |||||
Di-2,4-dichlorobenzoyl peroxide [as a paste] | UN3118 | [LESS THAN EQUAL TO]52 | OP8 | 20 | 25 | |||||
Di-4-chlorobenzoyl peroxide [as a paste] | UN3106 | [LESS THAN EQUAL TO]52 | OP7 | 21 | ||||||
Dicumyl peroxide | UN3110 | [GREATER THAN]52-100 | [LESS THAN EQUAL TO]48 | OP8 | 9 | |||||
Dicumyl peroxide | Exempt | [LESS THAN EQUAL TO]52 | [GREATER THAN EQUAL TO]48 | Exempt | 29 | |||||
Dicyclohexyl peroxydicarbonate | UN3112 | [GREATER THAN]91-100 | OP3 | 10 | 15 | |||||
Dicyclohexyl peroxydicarbonate | UN3114 | [LESS THAN EQUAL TO]91 | [GREATER THAN EQUAL TO]9 | OP5 | 10 | 15 | ||||
Dicyclohexyl peroxydicarbonate [as a stable dispersion in water] | UN3119 | [LESS THAN EQUAL TO]42 | OP8 | 15 | 20 | |||||
Didecanoyl peroxide | UN3114 | [LESS THAN EQUAL TO]100 | OP6 | 30 | 35 | |||||
2,2-Di-(4,4-di(tert-butylperoxy)cyclohexyl)propane | UN3106 | [LESS THAN EQUAL TO]42 | [GREATER THAN EQUAL TO]58 | OP7 | ||||||
2,2-Di-(4,4-di(tert-butylperoxy)cyclohexyl)propane | UN3107 | [LESS THAN EQUAL TO]22 | [GREATER THAN EQUAL TO]78 | OP8 | ||||||
Di-2,4-dichlorobenzoyl peroxide | UN3102 | [LESS THAN EQUAL TO]77 | [GREATER THAN EQUAL TO]23 | OP5 | ||||||
Di-2,4-dichlorobenzoyl peroxide [as a paste with silicone oil] | UN3106 | [LESS THAN EQUAL TO]52 | OP7 | |||||||
Di-(2-ethoxyethyl) peroxydicarbonate | UN3115 | [LESS THAN EQUAL TO]52 | [GREATER THAN EQUAL TO]48 | OP7 | -10 | 0 | ||||
Di-(2-ethylhexyl) peroxydicarbonate | UN3113 | [GREATER THAN]77-100 | OP5 | -20 | -10 | |||||
Di-(2-ethylhexyl) peroxydicarbonate | UN3115 | [LESS THAN EQUAL TO]77 | [GREATER THAN EQUAL TO]23 | OP7 | -15 | -5 | ||||
Di-(2-ethylhexyl) peroxydicarbonate [as a stable dispersion in water] | UN3119 | [LESS THAN EQUAL TO]62 | OP8 | -15 | -5 | |||||
Di-(2-ethylhexyl) peroxydicarbonate [as a stable dispersion in water] | UN3119 | [LESS THAN EQUAL TO]52 | OP8 | -15 | -5 | |||||
Di-(2-ethylhexyl) peroxydicarbonate [as a stable dispersion in water (frozen)] | UN3120 | [LESS THAN EQUAL TO]52 | OP8 | -15 | -5 | |||||
2,2-Dihydroperoxypropane | UN3102 | [LESS THAN EQUAL TO]27 | [GREATER THAN EQUAL TO]73 | OP5 | ||||||
Di-(1-hydroxycyclohexyl)peroxide | UN3106 | [LESS THAN EQUAL TO]100 | OP7 | |||||||
Diisobutyryl peroxide | UN3111 | [GREATER THAN]32-52 | [GREATER THAN EQUAL TO]48 | OP5 | -20 | -10 | ||||
Diisobutyryl peroxide [as a stable dispersion in water] | UN3119 | [LESS THAN EQUAL TO]42 | OP8 | -20 | -10 | |||||
Diisobutyryl peroxide | UN3115 | [LESS THAN EQUAL TO]32 | [GREATER THAN EQUAL TO]68 | OP7 | -20 | -10 | ||||
Diisopropylbenzene dihydroperoxide | UN3106 | [LESS THAN EQUAL TO]82 | [GREATER THAN EQUAL TO]5 | [GREATER THAN EQUAL TO]5 | OP7 | 17 | ||||
Diisopropyl peroxydicarbonate | UN3112 | [GREATER THAN]52-100 | OP2 | -15 | -5 | |||||
Diisopropyl peroxydicarbonate | UN3115 | [LESS THAN EQUAL TO]52 | [GREATER THAN EQUAL TO]48 | OP7 | -20 | -10 | ||||
Diisopropyl peroxydicarbonate | UN3115 | [LESS THAN EQUAL TO]32 | [GREATER THAN EQUAL TO]68 | OP7 | -15 | -5 | ||||
Dilauroyl peroxide | UN3106 | [LESS THAN EQUAL TO]100 | OP7 | |||||||
Dilauroyl peroxide [as a stable dispersion in water] | UN3109 | [LESS THAN EQUAL TO]42 | OP8 | |||||||
Di-(3-methoxybutyl) peroxydicarbonate | UN3115 | [LESS THAN EQUAL TO]52 | [GREATER THAN EQUAL TO]48 | OP7 | -5 | 5 | ||||
Di-(2-methylbenzoyl)peroxide | UN3112 | [LESS THAN EQUAL TO]87 | [GREATER THAN EQUAL TO]13 | OP5 | 30 | 35 | ||||
Di-(4-methylbenzoyl)peroxide [as a paste with silicone oil] | UN3106 | [LESS THAN EQUAL TO]52 | OP7 | |||||||
Di-(3-methylbenzoyl) peroxide + Benzoyl (3-methylbenzoyl) peroxide + Dibenzoyl peroxide | UN3115 | [LESS THAN EQUAL TO]20 + [LESS THAN EQUAL TO]18 + [LESS THAN EQUAL TO]4 | [GREATER THAN EQUAL TO]58 | OP7 | 35 | 40 | ||||
2,5-Dimethyl-2,5-di-(benzoylperoxy)hexane | UN3102 | [GREATER THAN]82-100 | OP5 | |||||||
2,5-Dimethyl-2,5-di-(benzoylperoxy)hexane | UN3106 | [LESS THAN EQUAL TO]82 | [GREATER THAN EQUAL TO]18 | OP7 | ||||||
2,5-Dimethyl-2,5-di-(benzoylperoxy)hexane | UN3104 | [LESS THAN EQUAL TO]82 | [GREATER THAN EQUAL TO]18 | OP5 | ||||||
2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexane | UN3103 | [GREATER THAN]90-100 | OP5 | |||||||
2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexane | UN3105 | [GREATER THAN]52-90 | [GREATER THAN EQUAL TO]10 | OP7 | ||||||
2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexane | UN3108 | [LESS THAN EQUAL TO]77 | [GREATER THAN EQUAL TO]23 | OP8 | ||||||
2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexane | UN3109 | [LESS THAN EQUAL TO]52 | [GREATER THAN EQUAL TO]48 | OP8 | ||||||
2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexane [as a paste] | UN3108 | [LESS THAN EQUAL TO]47 | OP8 | |||||||
2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexyne-3 | UN3101 | [GREATER THAN]86-100 | OP5 | |||||||
2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexyne-3 | UN3103 | [GREATER THAN]52-86 | [GREATER THAN EQUAL TO]14 | OP5 | ||||||
2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexyne-3 | UN3106 | [LESS THAN EQUAL TO]52 | [GREATER THAN EQUAL TO]48 | OP7 | ||||||
2,5-Dimethyl-2,5-di-(2-ethylhexanoylperoxy)hexane | UN3113 | [LESS THAN EQUAL TO]100 | OP5 | 20 | 25 | |||||
2,5-Dimethyl-2,5-dihydroperoxyhexane | UN3104 | [LESS THAN EQUAL TO]82 | [GREATER THAN EQUAL TO]18 | OP6 | ||||||
2,5-Dimethyl-2,5-di-(3,5,5-trimethylhexanoylperoxy)hexane | UN3105 | [LESS THAN EQUAL TO]77 | [GREATER THAN EQUAL TO]23 | OP7 | ||||||
1,1-Dimethyl-3-hydroxybutylperoxyneoheptanoate | UN3117 | [LESS THAN EQUAL TO]52 | [GREATER THAN EQUAL TO]48 | OP8 | 0 | 10 | ||||
Dimyristyl peroxydicarbonate | UN3116 | [LESS THAN EQUAL TO]100 | OP7 | 20 | 25 | |||||
Dimyristyl peroxydicarbonate [as a stable dispersion in water] | UN3119 | [LESS THAN EQUAL TO]42 | OP8 | 20 | 25 | |||||
Di-(2-neodecanoylperoxyisopropyl)benzene | UN3115 | [LESS THAN EQUAL TO]52 | [GREATER THAN EQUAL TO]48 | OP7 | -10 | 0 | ||||
Di-(2-neodecanoyl-peroxyisopropyl) benzene, as stable dispersion in water | UN3119 | [LESS THAN EQUAL TO]42 | OP8 | -15 | -5 | |||||
Di-n-nonanoyl peroxide | UN3116 | [LESS THAN EQUAL TO]100 | OP7 | 0 | 10 | |||||
Di-n-octanoyl peroxide | UN3114 | [LESS THAN EQUAL TO]100 | OP5 | 10 | 15 | |||||
Di-(2-phenoxyethyl)peroxydicarbonate | UN3102 | [GREATER THAN]85-100 | OP5 | |||||||
Di-(2-phenoxyethyl)peroxydicarbonate | UN3106 | [LESS THAN EQUAL TO]85 | [GREATER THAN EQUAL TO]15 | OP7 | ||||||
Dipropionyl peroxide | UN3117 | [LESS THAN EQUAL TO]27 | [GREATER THAN EQUAL TO]73 | OP8 | 15 | 20 | ||||
Di-n-propyl peroxydicarbonate | UN3113 | [LESS THAN EQUAL TO]100 | OP3 | -25 | -15 | |||||
Di-n-propyl peroxydicarbonate | UN3113 | [LESS THAN EQUAL TO]77 | [GREATER THAN EQUAL TO]23 | OP5 | -20 | -10 | ||||
Disuccinic acid peroxide | UN3102 | [GREATER THAN]72-100 | OP4 | 18 | ||||||
Disuccinic acid peroxide | UN3116 | [LESS THAN EQUAL TO]72 | [GREATER THAN EQUAL TO]28 | OP7 | 10 | 15 | ||||
Di-(3,5,5-trimethylhexanoyl) peroxide | UN3115 | [GREATER THAN]52-82 | [GREATER THAN EQUAL TO]18 | OP7 | 0 | 10 | ||||
Di-(3,5,5-trimethylhexanoyl)peroxide [as a stable dispersion in water] | UN3119 | [LESS THAN EQUAL TO]52 | OP8 | 10 | 15 | |||||
Di-(3,5,5-trimethylhexanoyl) peroxide | UN3119 | [GREATER THAN]38-52 | [GREATER THAN EQUAL TO]48 | OP8 | 10 | 15 | ||||
Di-(3,5,5-trimethylhexanoyl)peroxide | UN3119 | [LESS THAN EQUAL TO]38 | [GREATER THAN EQUAL TO]62 | OP8 | 20 | 25 | ||||
Ethyl 3,3-di-(tert-amylperoxy)butyrate | UN3105 | [LESS THAN EQUAL TO]67 | [GREATER THAN EQUAL TO]33 | OP7 | ||||||
Ethyl 3,3-di-(tert-butylperoxy)butyrate | UN3103 | [GREATER THAN]77-100 | OP5 | |||||||
Ethyl 3,3-di-(tert-butylperoxy)butyrate | UN3105 | [LESS THAN EQUAL TO]77 | [GREATER THAN EQUAL TO]23 | OP7 | ||||||
Ethyl 3,3-di-(tert-butylperoxy)butyrate | UN3106 | [LESS THAN EQUAL TO]52 | [GREATER THAN EQUAL TO]48 | OP7 | ||||||
1-(2-ethylhexanoylperoxy)-1,3-Dimethylbutyl peroxypivalate | UN3115 | [LESS THAN EQUAL TO]52 | [GREATER THAN EQUAL TO]45 | [GREATER THAN EQUAL TO]10 | OP7 | -20 | -10 | |||
tert-Hexyl peroxyneodecanoate | UN3115 | [LESS THAN EQUAL TO]71 | [GREATER THAN EQUAL TO]29 | OP7 | 0 | 10 | ||||
tert-Hexyl peroxypivalate | UN3115 | [LESS THAN EQUAL TO]72 | [GREATER THAN EQUAL TO]28 | OP7 | 10 | 15 | ||||
tert-Hexyl peroxypivalate | UN3117 | [LESS THAN EQUAL TO]52 as a stable dispersion in water | OP8 | +15 | +20 | |||||
3-Hydroxy-1,1-dimethylbutyl peroxyneodecanoate | UN3115 | [LESS THAN EQUAL TO]77 | [GREATER THAN EQUAL TO]23 | OP7 | -5 | 5 | ||||
3-Hydroxy-1,1-dimethylbutyl peroxyneodecanoate [as a stable dispersion in water] | UN3119 | [LESS THAN EQUAL TO]52 | OP8 | -5 | 5 | |||||
3-Hydroxy-1,1-dimethylbutyl peroxyneodecanoate | UN3117 | [LESS THAN EQUAL TO]52 | [GREATER THAN EQUAL TO]48 | OP8 | -5 | 5 | ||||
Isopropyl sec-butyl peroxydicarbonat + Di-sec-butyl peroxydicarbonate + Di-isopropyl peroxydicarbonate | UN3111 | [LESS THAN EQUAL TO]52 + [LESS THAN EQUAL TO]28 + [LESS THAN EQUAL TO]22 | OP5 | -20 | -10 | |||||
Isopropyl sec-butyl peroxydicarbonate + Di-sec-butyl peroxydicarbonate + Di-isopropyl peroxydicarbonate | UN3115 | [LESS THAN EQUAL TO]32 + [LESS THAN EQUAL TO]15 -18 + [LESS THAN EQUAL TO]12 -15 | [GREATER THAN EQUAL TO]38 | OP7 | -20 | -10 | ||||
Isopropylcumyl hydroperoxide | UN3109 | [LESS THAN EQUAL TO]72 | [GREATER THAN EQUAL TO]28 | OP8 | 13 | |||||
p-Menthyl hydroperoxide | UN3105 | [GREATER THAN]72-100 | OP7 | 13 | ||||||
p-Menthyl hydroperoxide | UN3109 | [LESS THAN EQUAL TO]72 | [GREATER THAN EQUAL TO]28 | OP8 | ||||||
Methylcyclohexanone peroxide(s) | UN3115 | [LESS THAN EQUAL TO]67 | [GREATER THAN EQUAL TO]33 | OP7 | 35 | 40 | ||||
Methyl ethyl ketone peroxide(s) | UN3101 | [LESS THAN EQUAL TO]52 | [GREATER THAN EQUAL TO]48 | OP5 | 5, 13 | |||||
Methyl ethyl ketone peroxide(s) | UN3105 | [LESS THAN EQUAL TO]45 | [GREATER THAN EQUAL TO]55 | OP7 | 5 | |||||
Methyl ethyl ketone peroxide(s) | UN3107 | [LESS THAN EQUAL TO]40 | [GREATER THAN EQUAL TO]60 | OP8 | 7 | |||||
Methyl isobutyl ketone peroxide(s) | UN3105 | [LESS THAN EQUAL TO]62 | [GREATER THAN EQUAL TO]19 | OP7 | 5, 23 | |||||
Methyl isopropyl ketone peroxide(s) | UN3109 | (See remark 31) | [GREATER THAN EQUAL TO]70 | OP8 | 31 | |||||
Organic peroxide, liquid, sample | UN3103 | OP2 | 12 | |||||||
Organic peroxide, liquid, sample, temperature controlled | UN3113 | OP2 | 12 | |||||||
Organic peroxide, solid, sample | UN3104 | OP2 | 12 | |||||||
Organic peroxide, solid, sample, temperature controlled | UN3114 | OP2 | 12 | |||||||
3,3,5,7,7-Pentamethyl-1,2,4-Trioxepane | UN3107 | [LESS THAN EQUAL TO]100 | OP8 | |||||||
Peroxyacetic acid, type D, stabilized | UN3105 | [LESS THAN EQUAL TO]43 | OP7 | 13, 20 | ||||||
Peroxyacetic acid, type E, stabilized | UN3107 | [LESS THAN EQUAL TO]43 | OP8 | 13, 20 | ||||||
Peroxyacetic acid, type F, stabilized | UN3109 | [LESS THAN EQUAL TO]43 | OP8 | 13, 20, 28 | ||||||
Peroxyacetic acid or peracetic acid [with not more than 7% hydrogen peroxide] | UN3107 | [LESS THAN EQUAL TO]36 | [GREATER THAN EQUAL TO]15 | OP8 | 13, 20, 28 | |||||
Peroxyacetic acid or peracetic acid [with not more than 20% hydrogen peroxide] | Exempt | [LESS THAN EQUAL TO]6 | [GREATER THAN EQUAL TO]60 | Exempt | 28 | |||||
Peroxyacetic acid or peracetic acid [with not more than 26% hydrogen peroxide] | UN3109 | [LESS THAN EQUAL TO]17 | OP8 | 13, 20, 28 | ||||||
Peroxylauric acid | UN3118 | [LESS THAN EQUAL TO]100 | OP8 | 35 | 40 | |||||
1-Phenylethyl hydroperoxide | UN3109 | [LESS THAN EQUAL TO]38 | [GREATER THAN EQUAL TO]62 | OP8 | ||||||
Pinanyl hydroperoxide | UN3105 | [GREATER THAN]56-100 | OP7 | 13 | ||||||
Pinanyl hydroperoxide | UN3109 | [LESS THAN EQUAL TO]56 | [GREATER THAN EQUAL TO]44 | OP8 | ||||||
Polyether poly-tert-butylperoxycarbonate | UN3107 | [LESS THAN EQUAL TO]52 | [GREATER THAN EQUAL TO]48 | OP8 | ||||||
Tetrahydronaphthyl hydroperoxide | UN3106 | [LESS THAN EQUAL TO]100 | OP7 | |||||||
1,1,3,3-Tetramethylbutyl hydroperoxide | UN3105 | [LESS THAN EQUAL TO]100 | OP7 | |||||||
1,1,3,3-Tetramethylbutyl peroxy-2-ethylhexanoate | UN3115 | [LESS THAN EQUAL TO]100 | OP7 | 15 | 20 | |||||
1,1,3,3-Tetramethylbutyl peroxyneodecanoate | UN3115 | [LESS THAN EQUAL TO]72 | [GREATER THAN EQUAL TO]28 | OP7 | -5 | 5 | ||||
1,1,3,3-Tetramethylbutyl peroxyneodecanoate [as a stable dispersion in water] | UN3119 | [LESS THAN EQUAL TO]52 | OP8 | -5 | 5 | |||||
1,1,3,3-tetramethylbutyl peroxypivalate | UN3115 | [LESS THAN EQUAL TO]77 | [GREATER THAN EQUAL TO]23 | OP7 | 0 | 10 | ||||
3,6,9-Triethyl-3,6,9-trimethyl-1,4,7-triperoxonane | UN3110 | [LESS THAN EQUAL TO]17 | [GREATER THAN EQUAL TO]18 | [GREATER THAN EQUAL TO]65 | OP8 | |||||
3,6,9-Triethyl-3,6,9-trimethyl-1,4,7-triperoxonane | UN3105 | [LESS THAN EQUAL TO]42 | [GREATER THAN EQUAL TO]58 | OP7 | 26 |
Notes:
Table 2 to Paragraph (d): Maximum Quantity per Packaging/Package
[For packing methods OP1 to OP8]
Maximum quantity | Packing method | |||||||
OP1 | OP21 | OP3 | OP41 | OP5 | OP6 | OP7 | OP8 | |
Solids and combination packagings (liquid and solid) (kg) | 0.5 | 0.5/10 | 5 | 5/25 | 25 | 50 | 50 | 2 400 |
Liquids (L) | 0.5 | 5 | 30 | 60 | 60 | 3 225 |
1 If two values are given, the first applies to the maximum net mass per inner packaging and the second to the maximum net mass of the complete package.
2 60 kg for jerricans/200 kg for boxes and, for solids, 400 kg in combination packagings with outer packagings comprising boxes (4C1, 4C2, 4D, 4F, 4G, 4H1, and 4H2) and with inner packagings of plastics or fiber with a maximum net mass of 25 kg.
3 60 L for jerricans.
Table 3 to Paragraph (e)-Organic Peroxide IBC Table
UN No. | Organic peroxide | Type of IBC | Maximum quantity (liters) | Control temperature | Emergency temperature |
3109 | ORGANIC PEROXIDE, TYPE F, LIQUID: | ||||
tert-Butyl cumyl peroxide | 31HA1 | 1000 | |||
tert-Butyl hydroperoxide, not more than 72% with water | 31A | 1250 | |||
31HA1 | 1000 | ||||
tert-Butyl peroxyacetate, not more than 32% in diluent type A | 31A | 1250 | |||
31HA1 | 1000 | ||||
tert-Butyl peroxybenzoate, not more than 32% in diluent type A | 31A | 1250 | |||
tert-Butyl peroxy-3,5,5-trimethylhexanoate, not more than 37% in diluent type A | 31A | 1250 | |||
31HA1 | 1000 | ||||
Cumyl hydroperoxide, not more than 90% in diluent type A | 31HA1 | 1250 | |||
Dibenzoyl peroxide, not more than 42% as a stable dispersion | 31H1 | 1000 | |||
2,5-Dimethyl-2,5-di(tert-butylperoxy)hexane, not more than 52% in diluent type A | 31HA1 | 1000 | |||
Di-tert-butyl peroxide, not more than 52% in diluent type B | 31A | 1250 | |||
31HA1 | 1000 | ||||
1,1-Di-(tert-Butylperoxy) cyclohexane, not more than 37% in diluent type A | 31A | 1250 | |||
1,1-Di-(tert-butylperoxy) cyclohexane, not more than 42% in diluent type A | 31H1 | 1000 | |||
Dicumyl peroxide, less than or equal to 100% | 31A | 1250 | |||
31HA1 | 1000 | ||||
Dilauroyl peroxide, not more than 42%, stable dispersion, in water | 31HA1 | 1000 | |||
Isopropyl cumyl hydroperoxide, not more than 72% in diluent type A | 31HA1 | 1250 | |||
p-Menthyl hydroperoxide, not more than 72% in diluent type A | 31HA1 | 1250 | |||
Peroxyacetic acid, stabilized, not more than 17% | 31A | 1500 | |||
31H1 | 1500 | ||||
31H2 | 1500 | ||||
31HA1 | 1500 | ||||
Peroxyacetic acid, not more than 26% hydrogen peroxide | 31A | 1500 | |||
31HA1 | 1500 | ||||
Peroxyacetic acid, type F, stabilized | 31A | 1500 | |||
31HA1 | 1500 | ||||
3,6,9-Triethyl-3,6,9-trimethyl-1,4,7-triperoxonane not more than 27% diluent type A | 31HA1 | 1000 | |||
3110 | ORGANIC PEROXIDE TYPE F, SOLID: | ||||
Dicumyl peroxide, less than or equal to 100% | 31A | 2000 | |||
31H1 | |||||
31HA1 | |||||
3119 | ORGANIC PEROXIDE, TYPE F, LIQUID, TEMPERATURE CONTROLLED: | ||||
tert-Amyl peroxy-2-ethylhexanoate, not more than 62% in a diluent type A | 31HA1 | 1000 | +15 °C | +20 °C | |
tert-Amyl peroxypivalate, not more than 32% in diluent type A | 31A | 1250 | +10 °C | +15 °C | |
tert-Amyl peroxypivalate, not more than 42% as a stable dispersion in water | 31HA1 | 1,000 | 0 °C | +10 °C | |
tert-Butyl peroxy-2-ethylhexanoate, not more than 32% in diluent type B | 31HA1 | 1000 | +30 °C | +35 °C | |
31A | 1250 | +30 °C | +35 °C | ||
tert-Butyl peroxyneodecanoate, not more than 32% in diluent type A | 31A | 1250 | 0 °C | +10 °C | |
tert-Butyl peroxyneodecanoate, not more than 52%, stable dispersion, in water | 31A | 1250 | -5 °C | +5 °C | |
tert-Butyl peroxypivalate, not more than 27% in diluent type B | 31HA1 | 1000 | +10 °C | +15 °C | |
31A | 1250 | +10 °C | +15 °C | ||
tert-Butyl peroxypivalate, not more than 42% in a diluent type A | 31HA1 31A | 1,000 1,250 | 10 °C 10 °C | 15 °C 15 °C | |
Cumyl peroxyneodecanoate, not more than 52%, stable dispersion, in water | 31A | 1250 | -15 °C | -5 °C | |
Di-(4-tert-butylcyclohexyl) peroxydicarbonate, not more than 42%, stable dispersion, in water | 31HA1 | 1000 | +30 °C | +35 °C | |
Dicetyl peroxydicarbonate, not more than 42%, stable dispersion, in water | 31HA1 | 1000 | +30 °C | +35 °C | |
Dicyclohexylperoxydicarbonate, not more than 42% as a stable dispersion, in water | 31A | 1250 | +10 °C | +15 °C | |
Di-(2-ethylhexyl) peroxydicarbonate, not more than 62%, stable dispersion, in water | 31A | 1250 | -20 °C | -10 °C | |
31HA1 | 1000 | -20 °C | -10 °C | ||
Diisobutyryl peroxide, not more than 28% as a stable dispersion in water | 31HA1 | 1000 | -20 °C | -10 °C | |
31A | 1250 | -20 °C | -10 °C | ||
Diisobutyryl peroxide, not more than 42% as a stable dispersion in water | 31HA1 | 1000 | -25 °C | -15 °C | |
31A | 1250 | -25 °C | -15 °C | ||
Dimyristyl peroxydicarbonate, not more than 42%, stable dispersion, in water | 31HA1 | 1000 | +15 °C | +20 °C | |
Di-(2-neodecanoylperoxyisopropyl) benzene, not more than 42%, stable dispersion, in water | 31A | 1250 | -15 °C | -5 °C | |
Di-(3,5,5-trimethylhexanoyl) peroxide, not more than 52% in diluent type A | 31HA1 | 1000 | +10 °C | +15 °C | |
31A | 1250 | +10 °C | +15 °C | ||
Di-(3,5,5-trimethylhexanoyl) peroxide, not more than 52%, stable dispersion, in water | 31A | 1250 | +10 °C | +15 °C | |
3-Hydroxy-1,1-dimethylbutyl peroxy-neodecanoate, not more than 52%, stable dispersion, in water | 31A | 1250 | -15 °C | -5 °C | |
1,1,3,3-Tetramethylbutyl peroxy-2-ethylhexanoate, not more than 67%, in diluent type A | 31HA1 | 1000 | +15 °C | +20 °C | |
1,1,3,3-Tetramethylbutyl peroxyneodecanoate, not more than 52%, stable dispersion, in water | 31A | 1250 | -5 °C | +5 °C | |
31HA1 | 1000 | -5 °C | +5 °C |
Table 4 to Paragraph (g): Organic Peroxide Portable Tank Table
UN No. | Hazardous material | Minimum test pressure (bar) | Minimum shell thickness (mm-reference steel) See. . . | Bottom opening requirements See. . . | Pressure-relief requirements See. . . | Filling limits | Control temperature | Emergency temperature |
3109 | ORGANIC PEROXIDE, TYPE F, LIQUID | |||||||
tert-Butyl hydroperoxide, not more than 56% with diluent type B2 | 4 | § 178.274(d)(2) | § 178.275(d)(3) | § 178.275(g)(1) | Not more than 90% at 59 °F (15 °C) | |||
tert-Butyl hydroperoxide, not more than 72% with water *Provided that steps have been taken to achieve the safety equivalence of 65% tert-Butyl hydroperoxide and 35% water | 4 | § 178.274(d)(2) | § 178.275(d)(3) | § 178.275(g)(1) | Not more than 90% at 59 °F (15 °C) | |||
Cumyl hydro-peroxide, not more than 90% in diluent type A | 4 | § 178.274(d)(2) | § 178.275(d)(3) | § 178.275(g)(1) | Not more than 90% at 59 °F (15 °C) | |||
Di-tert-butyl peroxide, not more 32% in diluent type A | 4 | § 178.274(d)(2) | § 178.275(d)(3) | § 178.275(g)(1) | Not more than 90% at 59 °F (15 °C) | |||
Dicumyl peroxide, less than or equal to 100% in diluent type B | 4 | § 178.274(d)(2) | § 178.275(d)(3) | § 178.275(g)(1) | Not more than 90% at 59 °F (15 °C) | |||
Isopropyl cumyl hydro-peroxide, not more than 72% in diluent type A | 4 | § 178.274(d)(2) | § 178.275(d)(3) | § 178.275(g)(1) | Not more than 90% at 59 °F (15 °C) | |||
p-Menthyl hydro-peroxide, not more than 72% in diluent type A | 4 | § 178.274(d)(2) | § 178.275(d)(3) | § 178.275(g)(1) | Not more than 90% at 59 °F (15 °C) | |||
Pinanyl hydro-peroxide, not more than 56% in diluent type A | 4 | § 178.274(d)(2) | § 178.275(d)(3) | § 178.275(g)(1) | Not more than 90% at 59 °F (15 °C) | |||
3110 | ORGANIC PEROXIDE, TYPE F, SOLID | |||||||
Dicumyl peroxide less than or equal to 100% with inert solids *Maximum quantity per portable tank 2,000 kg | 4 | § 178.274(d)(2) | § 178.275(d)(3) | § 178.275(g)(1) | Not more than 90% at 59 °F (15 °C) | |||
3119 | ORGANIC PEROXIDE, TYPE F, LIQUID, TEMPERATURE CONTROLLED | |||||||
tert-Amyl peroxyneodecanoate, not more than 47% in diluent type A | 4 | § 178.274 (d)(2) | § 178.275 (d)(3) | § 178.275 (g)(1) | Not more than 90% at 59 °F (15 °C) | -10 °C | -5 °C. | |
tert-Butyl peroxyacetate, not more than 32% in diluent type B | 4 | § 178.274(d)(2) | § 178.275(d)(3) | § 178.275(g)(1) | Not more than 90% at 59 °F (15 °C) | + 30 °C | + 35 °C | |
tert-Butyl peroxy-2-ethylhexanoate, not more than 32% in diluent B | 4 | § 178.274(d)(2) | § 178.275(d)(3) | § 178.275(g)(1) | Not more than 90% at 59 °F (15 °C) | + 15 °C | + 20 °C | |
tert-Butylperoxypivalate, not more than 27% in diluent type B | 4 | § 178.274(d)(2) | § 178.275(d)(3) | § 178.275(g)(1) | Not more than 90% at 59 °F (15 °C) | + 5 °C | + 10 °C | |
tert-Butyl peroxy-3,5,5-trimethyl-hexanoate, not more than 32% in diluent type B | 4 | § 178.274(d)(2) | § 178.275(d)(3) | § 178.275(g)(1) | Not more than 90% at 59 °F (15 °C) | + 35 °C | + 40 °C | |
Di-(3,5,5-trimethyl-hexanoyl) peroxide, not more than 38% in diluent type A or type B | 4 | § 178.274 (d)(2) | § 178.275 (d)(3) | § 178.275 (g)(1) | Not more than 90% at 59 °F (15 °C) | 0 °C | + 5 °C. | |
Peroxyacetic acid, distilled, stabilized, not more than 41%.1 | 4 | § 178.274(d)(2) | § 178.275(d)(3) | § 178.275(g)(1) | Not more than 90% at 59 °F (15 °C) | + 30 °C | + 35 °C |
Notes:
1. "Corrosive" subsidiary risk placard is required.
2. Diluent type B is tert-Butyl alcohol.
Where:
q = heat absorption (W)
A = wetted area (m2)
F = insulation factor (-)
Where:
U = K/L = heat transfer coefficient of the insulation (W·m-2·K-1); where K = heat conductivity of insulation layer (W·m-1·K-1), and L = thickness of insulation layer (m).
TPO = temperature of material at relieving conditions (K).
Note to paragraph (h)(3)(vi): An example of a method to determine the size of emergency-relief devices is given in Appendix 5 of the UN Manual of Tests and Criteria (IBR, see § 171.7 of this subchapter). A second example of a test method for venting sizing is given in the American Institute of Chemical Engineers Process Safety Progress Journal, June 2002 issue (Vol. 21, No. 2) (Informational materials not requiring incorporation by reference, see § 171.7(b) ).
49 C.F.R. §173.225