Ex Parte Vineis et alDownload PDFBoard of Patent Appeals and InterferencesFeb 20, 200910268425 (B.P.A.I. Feb. 20, 2009) Copy Citation UNITED STATES PATENT AND TRADEMARK OFFICE ____________ BEFORE THE BOARD OF PATENT APPEALS AND INTERFERENCES ____________ Ex parte CHRISTOPHER J. VINEIS, RICHARD WESTHOFF and MAYANK BULSARA ____________ Appeal 2008-5873 Application 10/268,425 Technology Center 1700 ____________ Decided:1 February 24, 2009 ____________ Before BRADLEY R. GARRIS, MICHAEL P. COLAIANNI, and JEFFREY B. ROBERTSON, Administrative Patent Judges. ROBERTSON, Administrative Patent Judge. 1 The two-month time period for filing an appeal or commencing a civil action, as recited in 37 C.F.R. § 1.304, begins to run from the decided date shown on this page of the decision. The time period does not run from the Mail Date (paper delivery) or Notification Date (electronic delivery). DECISION ON APPEAL STATEMENT OF THE CASE Appellants appeal under 35 U.S.C. § 134(a) (2002) from the Examiner’s rejection of claims 1-12, 14-16, 18-34, and 65-82.2 (Examiner’s Answer entered January 22, 2008, hereinafter “Ans.”). We have jurisdiction pursuant to 35 U.S.C. § 6(b) (2002). We AFFIRM-IN-PART. THE INVENTION Appellants describe methods for forming semiconductor structures. Appellants state that the methods result in substantially relaxed cap layers of uniform composition. (Spec. 5, ll. 10-14). Claims 1, 2, and 14, reproduced below, are representative of the subject matter on appeal. 1. A method for forming a semiconductor structure, comprising the steps of: providing a semiconductor substrate having a top surface and a rough edge angled away from the surface; thereafter growing a cap layer over the top surface of the substrate, the cap layer being substantially relaxed, having a uniform composition, and having a lattice constant different from a lattice constant of the semiconductor substrate; and polishing the rough edge of the substrate after at least a portion of the cap layer is grown. 2. A method for forming a semiconductor structure, comprising the steps of: providing a semiconductor substrate having a top surface and a rough edge angled away from the surface; 2 Claims 13, 17, and 35-64 have been canceled. (Appeal Brief filed November 9, 2007, hereinafter “App. Br.,” 2). Appeal 2008-5873 Application 10/268,425 forming a relaxed compositionally graded layer over the top surface of the substrate having the rough edge; and forming a cap layer over the graded layer, the cap layer being substantially relaxed and having a uniform composition, and having a lattice constant different from a lattice constant of the semiconductor substrate, wherein the rough edge has a roughness greater than 10 angstroms. 14. A method for forming a semiconductor structure, comprising the steps of: providing a semiconductor substrate having a top surface and a rough edge angled away from the surface; thereafter forming a relaxed compositionally graded layer over the top surface of the substrate; polishing the rough edge of the substrate after at least a portion of the graded layer is formed; and forming a cap layer over the graded layer, the cap layer being substantially relaxed, having a uniform composition, and having a lattice constant different from a lattice constant of the semiconductor substrate, wherein the graded layer is proximate the relaxed cap layer. THE REJECTIONS The prior art and disclosures relied upon by the Examiner in rejecting the claims on appeal are: Noguchi JP 10-270685 Oct. 9, 19983 Feichtinger et al., "Misfit Dislocation Nucleation Study in p/p+ Silicon", Journal of Electrochemical Society, 148 (7) June 2001, pp G379-G382. 3 An English translation of Noguchi is of record. 3 Appeal 2008-5873 Application 10/268,425 Cheng et al., "Electron Mobility Enhancement in Strained-Si n- MOSFETs Fabricated on SiGe-On-Insulator (SGOI) substrates", IEEE Electronic Device Letters, Vol. 22, No. 7, July 2001, pp. 321-323. Akino US 6,417,108 B1 Jul. 9, 2002 Applicant's Admitted Prior Art (AAPA), pages 3, 11, and 12 of the Specification filed October 10, 2002 in the instant application. Noguchi US 6,682,965 B1 Jan 27, 20044 There are five grounds of rejection under 35 U.S.C. § 103(a) on appeal: (1) the Examiner rejected claims 2, 3, 73, 74, and 80 as being unpatentable over Cheng in view of Feichtinger; (2) the Examiner rejected claims 2, 3, 73, 74, and 80 as being unpatentable over Cheng in view of AAPA; (3) the Examiner rejected claims 1, 4-12, 14-16, 18-25, 27-31, 33, 65-72, 75-79, 81, and 82 as being unpatentable over Cheng in view of Akino; (4) the Examiner rejected claims 32 and 34 as being unpatentable over Cheng in view of Akino and further in view of Noguchi; and (5) the Examiner rejected claim 26 as being unpatentable over Cheng in view of Akino, and further in view of AAPA or Feichtinger. Rejection of claims 2, 3, 73, 74, and 80 as being unpatentable over Cheng in view of Feichtinger The Examiner found that Cheng describes the claimed method for forming a semiconductor substrate except for providing a semiconductor substrate having a rough edge with a roughness greater than 10 Angstroms. 4 The Examiner cited US 6,682,965 B1 to Noguchi as a translation of JP 10- 270685 to Noguchi. (Ans. 9). 4 Appeal 2008-5873 Application 10/268,425 (Ans. 3 and 4). The Examiner found that the semiconductor substrate disclosed by Feichtinger inherently has a rough edge due to the mechanical edge shaping process used to produce the semiconductor substrate. (Ans. 4). The Examiner determined that it would have been obvious to modify Cheng’s substrate with the mechanical edge shaping process of Feichtinger so that the substrate could withstand further mechanical handling and to produce a wafer that is more resistant to breakage. (Ans. 4). The Examiner also determined that because Cheng in view of Feichtinger disclose a similar method of edge shaping as Appellants, the semiconductor substrate would be expected to have an edge roughness greater than 100 Angstroms. (Ans. 4 and 5). Appellants contend that Feichtinger teaches polishing the substrate edge prior to deposition of a silicon epitaxial layer, which teaches against depositing a layer on a substrate having a rough edge. (App. Br. 13). ISSUE Have Appellants shown that the Examiner reversibly erred in determining that providing a semiconductor substrate having a rough edge would have been obvious over Cheng in view of Feichtinger? We answer this question in the negative. FINDINGS OF FACT The record supports the following findings of fact (FF) by a preponderance of the evidence. 1. Appellants disclose that substrates with a rough edge provide a heterogeneous source for nucleation of misfit dislocations, which 5 Appeal 2008-5873 Application 10/268,425 helps prevent localized regions of high misfit densities, reducing the conditions that cause dislocation pile-ups. (Spec. 5, ll. 5-9). 2. Appellants’ Specification states, “the process of relaxation occurs through the formation of misfit dislocations at the interface between two lattice-mismatched layers . . . Because dislocations cannot terminate inside a crystal, misfit dislocations have vertical dislocation segments at each end (termed ‘threaded dislocations’), that may rise through the crystal to reach a top surface of the wafer.” (Spec. 2, ll. 18-22). 3. Appellants’ Specification states, “[t]he stress field associated with misfit dislocations may also cause dislocation pile-ups under certain conditions. Dislocation pile-ups are a linear agglomeration of threading dislocations. Because pile-ups represent a high localized density of threading dislocations, they may render devices formed in that region unusable.” (Spec. 2, l. 29 - 3, l. 2). 4. Cheng describes a substrate fabrication process where a relaxed SiGe cap layer is deposited over a SiGe buffer layer grown on a Si donor wafer. (p. 321, right column). 5. Cheng does not disclose whether the Si donor wafer has been edge polished. 6. Cheng discloses that the donor wafer is bonded to a handle wafer, and the donor wafer is removed, where a strained Si layer is grown on top of a relaxed SiGe layer. (Paragraph bridging pages 321 and 322). 7. Cheng teaches that no relaxation via misfit dislocation is introduced into the strained Si layer. (p. 322, left column). 6 Appeal 2008-5873 Application 10/268,425 8. Feichtinger discloses that crystalline damage to semiconductor wafers is introduced during the mechanical edge shaping process, where the edge shaping process is employed to make wafers more resistant to breakage. (P. G379, right column). 9. Feichtinger discloses that different damage removal steps are employed to reduce the damage to the wafer, including caustic etching and a combination of caustic etching and chemical mechanical edge polishing. (P. G379, right column). 10. Feichtinger teaches that “[t]he misfit dislocation density and length decreases with the change of the mechanical edge shaping from coarse to fine (decreased roughness).” (p. G380, right column). 11. Feichtinger teaches that the roughness of the substrate edge is between 100 and 150 Angstroms when no polishing treatment is applied, about 50 Angstroms when a caustic etch step is applied, and greater than 0 Angstroms when a combination of caustic etching and chemical mechanical polishing is applied. (P. G381, right column; Fig. 6). PRINCIPLES OF LAW In an obviousness rejection, the combination of references must be considered as a whole, rather than the specific teaching of each reference. In re McLaughlin, 443 F.2d 1392, 1395 (CCPA 1971); In re Simon, 461 F.2d 1387, 1390 (CCPA 1972). ANALYSIS 7 Appeal 2008-5873 Application 10/268,425 We select appealed claim 2 as being representative pursuant to 37 C.F.R. § 41.37(c)(1)(vii) (2006). Appellants contend that the combination of Cheng and Feichtinger would make no sense because Cheng requires the presence of a relaxed layer, and Feichtinger teaches removal of misfit dislocations, where misfit dislocations provide the only mechanism of relaxation. (Reply Brief filed March 24, 2008, hereinafter “Rep. Br.,” 4). However, Appellants overlook what Feichtinger as a whole conveys to one of ordinary skill in the art. Specifically, Feichtinger discloses that in order to decrease misfit dislocation density the edge roughness of the substrate may be decreased. (FF 10). However, Feichtinger also discloses that the substrate edge is rough when no polishing treatment is applied. (FF 11). Thus, we agree with the Examiner that because Cheng is silent as to the characteristics of the substrate (FF 5), one of ordinary skill in the art would have performed Feichtinger’s mechanical edge shaping process to render the substrate more resistant to breakage. (FF 8). One of ordinary skill in the art would have also not polished the substrate edge subsequent to mechanical edge shaping to allow for sufficient misfit dislocations in order to form Cheng’s relaxed layer. (See FF 10 and 11). Indeed, one of ordinary skill in the art would seek to avoid polishing the substrate after edge shaping, otherwise, a strained layer would form. (See Rep. Br. 4). Appellants also assert that the Examiner incorrectly interprets Feichtinger to disclose that polishing the wafers after mechanical edge shaping makes a wafer more vulnerable to breakage. (Rep. Br. 5). The Examiner’s statement is: “Feichtinger [teaches] that it would have been obvious to a person of ordinary skill in the art at the time of the invention to 8 Appeal 2008-5873 Application 10/268,425 perform epitaxial deposition on a substrate without any subsequent polishing because mechanical edge shaping [makes] wafers more resistant to breakage.” (Ans. 13). Contrary to Appellants’ assertion, the Examiner does not state that polishing makes a wafer more vulnerable to breakage, but merely recognizes that polishing is not necessary to obtain the benefits of breakage resistance obtained from mechanical edge shaping. Therefore, Appellants’ argument is not persuasive. Rejection of claims 2, 3, 73, 74, and 80 as being unpatentable over Cheng in view of AAPA The Examiner found that Cheng describes the claimed method for forming a semiconductor substrate except for providing a semiconductor substrate having a rough edge with a roughness greater than 10 Angstroms. (Ans. 3 and 4). The Examiner found that AAPA teaches that the recited roughness of the substrate is inherently present as a result of the mechanical edge shaping process conventionally used to form the semiconductor substrate. (Ans. 4). The Examiner determined that it would have been obvious to modify Cheng’s substrate with the mechanical edge shaping process of AAPA so that the substrate could withstand further mechanical handling and produce a wafer that is more resistant to breakage. (Ans. 4). The Examiner also determined that in view of AAPA, the use of the conventional edge shaping process would be expected to produce substrates that have an edge roughness greater than 100 Angstroms. (Ans. 4). Appellants argue that the material characterized by the Examiner as AAPA, is not prior art, but a description of the invention. (App. Br. 13). 9 Appeal 2008-5873 Application 10/268,425 ISSUE Have Appellants shown that the Examiner erred in determining that Appellants’ Specification is admitted prior art? We answer this question in the affirmative. ADDITIONAL FINDING OF FACT 12. Appellants Specification states, “[t]he roughness of the rough edge 20 is inherently present in substrate 10 when, for example, substrate 10 is cut from a boule traditionally formed by the Czochralski method, and is subjected to the conventional mechanical edge shaping process described above.” (Spec. 11, l. 30 – 12, l. 2). PRINCIPLES OF LAW A statement by an applicant in the specification or made during prosecution identifying the work of another as “prior art” is an admission which can be relied upon for both anticipation and obviousness determinations, regardless of whether the admitted prior art would otherwise qualify as prior art under the statutory categories of 35 U.S.C. 102. Riverwood Int ’l Corp. v. R.A. Jones & Co., 324 F.3d 1346, 1354 (Fed. Cir. 2003). ANALYSIS We agree with Appellants that the portion of the Specification relied on by the Examiner as AAPA is not admitted prior art, but a description of how to obtain the recited rough edge of the semiconductor substrate. Although Appellants rely on techniques that are “traditionally” used or “conventional” in the course of forming their substrate, Appellants do not 10 Appeal 2008-5873 Application 10/268,425 identify the semiconductor substrate recited in the claims as the work of another. (See FF 12). Thus, the recited semiconductor substrate is not admitted prior art. Therefore, we reverse the Examiner’s rejection of Cheng in view of AAPA because the Examiner improperly relies on Appellants’ disclosure to reject the claims. Rejection of claims 1, 4-12, 14-16, 18-25, 27-31, 33, 65-72, 75-79, 81, and 82 as being unpatentable over Cheng in view of Akino and Rejections of claims 26, 32, and 34 The Examiner found Cheng teaches the claimed method of forming a semiconductor structure except for polishing the rough edge of the substrate after at least a portion of the graded layer or cap layer is formed. (Ans. 5 and 7). The Examiner found that Akino teaches a structure including a support made of silicon, a semiconductor layer of SiGe, and an insulation layer, where the semiconductor layer and insulating layer are edge polished in order to prevent chipping. (Ans. 6). The Examiner determined that it would have been obvious to modify Cheng by polishing the edge of the SiGe layer to prevent chipping. (Ans. 6). Appellants argue that neither Cheng nor Akino teaches or suggests polishing a rough edge of the substrate after the growth of a graded layer or cap layer over the substrate. (App. Br. 15 and 16). Appellants contend that Akino discloses polishing a handle wafer, while Cheng discloses growing a cap layer over a graded layer over a donor wafer. (App. Br. 15). Appellants argue that one of ordinary skill in the art would not have polished the donor wafer of Cheng in accordance with the method of Akino prior to transferring 11 Appeal 2008-5873 Application 10/268,425 the material to the handle wafer and removing the donor wafer. (App. Br. 15). ISSUE Have Appellants shown that the Examiner erred in determining that polishing the rough edge of the substrate after a portion of a graded layer or cap layer is formed would have been obvious over Cheng in view of Akino? We answer this question in the affirmative. ADDITIONAL FINDINGS OF FACT 13. Akino states: According to an aspect of the invention, the above object is achieved by providing a semiconductor substrate comprising a support member, an insulation layer arranged on the support member and a semiconductor layer arranged on the insulation layer, characterized in that the outer peripheral extremity of said semiconductor layer is located inside the outer peripheral extremity of said support member and the outer peripheral extremity of said insulation layer is located between the outer peripheral extremity of said semiconductor layer and that of said support member so that the outer peripheral portion of the semiconductor substrate including said insulation layer and said semiconductor layer shows a stepped profile. (Col. 3, ll. 4-16). 14. Akino states: More specifically, the bottom of the outer peripheral extremity of the semiconductor layer 3 and the top of the outer peripheral extremity of the insulation layer 2 are offset relative to each other by a horizontal distance d so that . . . the outer peripheral extremity of the semiconductor layer 3 does not show an overhanging profile. . . . Therefore, the outer peripheral 12 Appeal 2008-5873 Application 10/268,425 extremity of the semiconductor layer 3 can hardly give rise to a chipping phenomenon and debris. (Col. 4, ll. 30-40). 15. Akino discloses that a rotary-type edge polisher may be used to remove the outer peripheral portions of the substrate. (Col. 11, ll. 51-65). PRINCIPLES OF LAW It is well settled that all the claim limitations must be taught or suggested by the prior art to establish a prima facie case of obviousness. In re Royka, 490 F.2d 981, 985 (CCPA 1974). The Court in KSR stated, “[o]ften, it will be necessary for a court to look to interrelated teachings of multiple patents; the effects of demands known to the design community or present in the marketplace; and the background knowledge possessed by a person having ordinary skill in the art, all in order to determine whether there was an apparent reason to combine the known elements in the fashion claimed by the patent at issue. To facilitate review, this analysis should be made explicit. See In re Kahn, 441 F.3d 977, 988 (CA Fed. 2006) (“[R]ejections on obviousness grounds cannot be sustained by mere conclusory statements; instead, there must be some articulated reasoning with some rational underpinning to support the legal conclusion of obviousness”).” KSR Int'l Co. v. Teleflex Inc., 127 S. Ct. 1727, 1740-41 (2007). ANALYSIS The claims recite polishing the rough edge of the substrate after at least a portion of the cap layer (claim 1) or graded layer (claim 14) is 13 Appeal 2008-5873 Application 10/268,425 formed. Cheng describes fabricating a substrate where a relaxed cap layer is deposited over a buffer layer grown on a Si donor wafer. (FF 4). Therefore, in order to meet the claim limitation, the donor substrate of Cheng must be polished, because it is the substrate on which the graded layer and/or cap layer is formed. We agree with Appellants, that Cheng in view of Akino fails to disclose polishing the donor substrate. (App. Br. 15). Akino describes polishing the outer peripheral layer of a semiconductor substrate to produce a stepped profile and eliminate an overhanging profile to reduce chipping. (FF 13 and 14). As argued by Appellants, Cheng discloses that the donor wafer is “flipped” and bonded to the handle wafer. (App. Br. 17). Thus, if a stepped profile according to Akino is applied to Cheng’s donor wafer prior to bonding with the handle wafer, the stepped profile would be inverted, resulting in an overhanging profile when transferred onto the handle wafer. This is the very problem that Akino seeks to eliminate in order to prevent chipping and debris. (FF 14). Therefore, one of ordinary skill in the art would not have applied Akino’s polishing method to Cheng in the manner suggested by the Examiner. The Examiner’s statement that “removing the [chipping] problem at its earliest stage would have been obvious to one of ordinary skill at the time of the invention” (Ans. 15) does not sufficiently explain how one of ordinary skill in the art would have modified Akino’s method in order to polish Cheng’s donor wafer before it is removed from the semiconductor structure while still producing the stepped profile necessary for reduced chipping. Further, if Cheng’s handle wafer is polished after the donor wafer is bonded thereto and removed, the claim limitation of “polishing the rough 14 Appeal 2008-5873 Application 10/268,425 edge of the substrate” would not be met. The handle wafer substrate is not the substrate over which the cap layer or graded layer is grown. (See FF 4 and 6). Thus, polishing the handle wafer to form a stepped profile after the donor wafer is removed is not polishing the rough edge of “the substrate” as recited in the claim. The Examiner has not provided any other sufficient rationale to account for the deficiencies of the combination of Cheng and Akino. Therefore, we reverse the Examiner’s rejection of claims 1, 4-12, 14-16, 18-25, 27-31, 33, 65-72, 75-79, 81 as being unpatentable over Cheng in view of Akino. We reverse the Examiner’s rejection of claims 32 and 34 as being unpatentable over Cheng in view of Akino and further in view of Noguchi and claim 26 as being unpatentable over Cheng in view of Akino, and further in view of AAPA or Feichtinger for the same reasons. CONCLUSION Appellants have failed to demonstrate that the Examiner erred in determining that providing a semiconductor substrate having a rough edge would have been obvious over Cheng in view of Feichtinger. Appellants have demonstrated that the Examiner erred in determining that Appellants’ Specification is admitted prior art. Appellants have demonstrated that the Examiner erred in determining that polishing the rough edge of the substrate after a graded layer or cap layer is formed would have been obvious over Cheng in view of Akino. 15 Appeal 2008-5873 Application 10/268,425 ORDER We affirm the Examiner’s decision rejecting claims 2, 3, 73, 74, and 80 under 35 U.S.C. § 103(a) as being unpatentable over Cheng in view of Feichtinger. We reverse the Examiner’s decision rejecting claims 2, 3, 73, 74, and 80 under 35 U.S.C. § 103(a) as being unpatentable over Cheng in view of AAPA. We reverse the Examiner’s decision rejecting claims 1, 4-12, 14-16, 18-25, 27-31, 33, 65-72, 75-79, 81, and 82 under 35 U.S.C. § 103(a) as being unpatentable over Cheng in view of Akino. We reverse the Examiner’s decision rejecting claims 32 and 34 as being unpatentable over Cheng in view of Akino and further in view of Noguchi. We reverse the Examiner’s decision rejecting claim 26 as being unpatentable over Cheng in view of Akino, and further in view of AAPA or Feichtinger. No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. §1.136(a)(1)(iv). AFFIRMED-IN-PART tc GOODWIN PROCTER, LLP PATENT ADMINISTRATOR 53 STATE STREET EXCHANGE PLACE BOSTON, MA 02109-2881 16 Copy with citationCopy as parenthetical citation